ge General ppm-level Pd-catalysed asymmetric diarylalkyne hydrosilylation to access structurally diverse Si-stereogenic vinylsilanes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01698J, Research ArticleHeng Xu, Han-Xiao Yu, An-Jiu Wen, Fang-Ying Ling, Fei Ye, Li Li, Fuk Yee Kwong, Li-Wen XuThe first example of enantioselective Pd-catalyzed hydrosilylation of symmetric and asymmetric diarylalkynes to access novel Si-stereogenic vinylsilanes with excellent ee and a high TON is realized under mild reaction conditions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ge Mechanistic insight into the dehydrogenation reaction catalyzed by an MLC catalyst with dual ancillary ligand sites By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01767F, Research ArticleGui-Xiang Zhou, Cheng HouThis study reveals a mechanism in which a ruthenium complex catalyst improves catalytic efficiency and lowers the energy barrier in the dehydrogenation of benzyl alcohol by dynamically switching ligand sites.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ge Photocatalytic arylation/alkylation of olefins/alkynes via halogen-atom transfer mediated by NHC-BH3 By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01562B, Research ArticleXinhan Li, Yao Zhong, Fengsong Tan, Yusong Fei, Xiaohan Zhao, Jianbin Xu, Baomin FanA versatile method for radical reductive cross-coupling of iodides and activated olefins under mild conditions, facilitated by NHC-BH3 through photocatalysis, was developed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ge Photoinduced cobaloxime catalysis for allylic mono- and diphosphinylation of alkenes with hydrogen evolution By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01638F, Research ArticleAijun Zhang, Miao-Miao Li, Lei Guo, Huaixiang Yang, Jiefei Guo, Da Xu, Wei DingA highly efficient allylic radical mono- and diphosphinylation of alkenes with secondary phosphine oxides is developed, via visible-light-induced cobaloxime catalysis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ge The reactivity of alkenyl boron reagents in catalytic reactions: recent advances and perspectives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01703J, Review ArticleYa-Li Feng, Bo-Wen Zhang, Youzhi Xu, Shengnan Jin, Daniele Mazzarella, Zhong-Yan CaoRecent advances focusing on novel reactivity of alkenyl boron reagents in polar or radical pathways within catalytic reactions by employing transition metal catalysis, organocatalysis have been summarized and discussed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ge Transition-metal-catalyzed regiodivergent sulfonylation of aziridrines for the synthesis of β-amino sulfones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6340-6346DOI: 10.1039/D4QO01376J, Research ArticleQinqiong Zeng, Yujia Gong, Xiaochun He, Xuemei Zhang, Zhong LianWe developed the first transition-metal-catalyzed, regiodivergent sulfonylation of aziridines, enabling the efficient synthesis of diverse β-amino sulfones under mild conditions with broad substrate compatibility and high regioselectivity.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ge Phosphine-controlled divergent reactions of MBH-carbonates with azaheptafulvenes: access to o-anilinyl diene and benzazepine derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6418-6425DOI: 10.1039/D4QO01298D, Research ArticleWei Hao, Yiwen Zhang, Xiao Han, Zhen Wang, Weijun YaoA phosphine controlled divergent cascade reaction of MBH-carbonates with azaheptafulvenes was disclosed. PPh3 provided o-aminophenyl diene while PCy3 offered benzazepine derivative through formal [8 + 3] annulation/ring contraction cascade.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ge 18F-labelling of nitrogen-containing aryl boronates – anti-cancer drug melflufen as a case study By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6411-6417DOI: 10.1039/D4QO01594K, Research Article Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Kevin Bajerke, Fredrik Lehmann, Gunnar Antoni, Kálmán J. SzabóThis study addresses the 18F-labelling of nitrogen-containing arenes via copper-mediated radiofluorination (CMRF). In this case study, derivatives/fragments of the anti-cancer drug melflufen were targeted.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ge Visible light-induced aerobic photooxidative cleavage of C(sp3)–C(sp2) σ-bonds of allylarenes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6385-6392DOI: 10.1039/D4QO01243G, Research ArticleJinyu Tang, Xi Zhao, Jinxuan Ni, Yanping Huo, Yang Gao, Xianwei Li, Yan Liu, Keiji Maruoka, Qian ChenA cleavage of C(sp3)–C(sp2) σ-bonds of allylarenes to aromatic aldehydes and ketones has been achieved via a visible light-induced photocatalysis.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ge A general method for E-selective olefination of acylsilanes with isocyanides via silver catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6450-6458DOI: 10.1039/D4QO01528B, Research ArticleXiu-Xia Liang, Dan-Ni Yang, Xiao-Hui Yan, Peng Wang, Man-Yi HanA silver-catalyzed olefination reaction between acylsilanes and isocyanides is developed, resulting in E-vinylsilanes with good yields and high stereoselectivities.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ge Carbonate-assisted selectively deoxygenative cross-coupling reaction between aryl and aliphatic aldehydes: a straightforward route to access α-alkylated aryl ketones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6510-6517DOI: 10.1039/D4QO01517G, Research ArticleYu Sun, Yi Wang, Zhijun ZuoA novel reductive cross-coupling reaction of two different aldehydes for rapidly assembling α-alkylated aryl ketones has been developed. The inexpensive carbonate served not only as a base but also as an efficient electron donor.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ge Transition-metal-catalyzed C–Ge coupling reactions By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6558-6572DOI: 10.1039/D4QO01637H, Review ArticleJie Ke, Cadmus Du Chen, Li-Qing Ren, Bing Zu, Bin Li, Chuan HeThis review covers the development and recent progress in transition-metal-catalyzed C–Ge coupling reactions. The goal is to provide a clear overview of the field, identify current challenges, and inspire further applications in this growing area.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ge Recent developments in the ring-opening transformations of gem-difluorocyclopropanes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, 11,6518-6533DOI: 10.1039/D4QO01583E, Review ArticleLeiyang Lv, Junqi Su, Zhiping LiThis review summarizes the advances of gem-F2CPs as fluoroallylic synthons in transition metal-catalysed ring-opening/cross-coupling reactions via single, double or no C-F bond cleavage on the last two years.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ge Charge Transfer Complex Enabled Mechanochemical Synthesis of Chalcogenoacetylenes via Alkynyl Radicals By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01827C, Research Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Fang Tan, Chang-Zhen Fang, Bing-Sheng Qiu, He Sheng, Yong-Liang Tu, Xiang-Yu ChenMechanochemistry has become an appealing strategy to enable numerous organic transformations. While significant advances have been achieved, the radical coupling reaction under mechanochemical conditions is still in its infancy. In...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ge Nickel-catalyzed reductive 1,2-alkylarylation of alkenes via a 1,5-hydrogen atom transfer (HAT) cascade By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01875C, Research ArticleXi Chen, Qiang Wang, Xiao-Ping Gong, Rui-Qiang Jiao, Xue-Yuan Liu, Yong-Min LiangA nickel-catalyzed 1,2-alkylarylation of alkenes has been developed, leveraging amidyl radical-triggered 1,5-HAT with electrophiles as functionalizing reagents.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ge Visible-light responsive defluorination-acyl fluoride exchange for photoclick labeling based on phenoxazine chromophores By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01870B, Research ArticleLijun Deng, Sitong Li, Cefei Zhang, Yuqiao Zhou, Zhishan Su, Changwei Hu, Xiaohu Zhao, Zhipeng YuWe developed a new generation of photo-DAFEx reagents to realize photoaffinity labeling for drug discovery under 405 nm light control.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ge Synthesis of oxa-bridged carbocycles via rhodium/Lewis acid catalyzed [3 + 3] and [4 + 3] cycloadditions of carbonyl ylides with donor–acceptor strained carbocycles By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01831A, Research ArticleJiale Li, Lingfei Wang, Pei-Nian Liu, Xingguang LiA method for cooperative rhodium/Lewis acid-catalyzed cycloadditions of carbonyl ylides with donor–acceptor (D–A) strained carbocycles is described. It affords structurally diverse oxa-bridged carbocycles with high efficiency and stereoselectivity.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ge Influence of hydrogen bonds and π-π stacking on the self-assembly of aryldipyrrolidones By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QO01577K, Research Article Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Pedro Ximenis, Llorenç Rubert, Heike Ehmann, Bartolome SoberatsWe report on the self-assembly behaviour in solution and solid-state of two newly designed bisdendronized aryldipyrrolidones (BDP and NDP) dyes with two free N-H at the lactam positions. Interestingly, while...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ge Modular dehydrogenative cross-nucleophile coupling for direct construction of tetrasubstituted carbons By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO01641F, Research ArticlePeng Wang, Qiang Wang, Meng Wang, Liang Wang, Lubin Xu, Xiong-Li Liu, Fangzhi Hu, Shuai-Shuai LiAn FeCl3-catalyzed cross-dehydrogenative coupling reaction for the construction of various types of C–Y (Y = C, N, O, S) bonds with air as a green oxidant.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ge Convergent Synthetic Approaches to Polycyclic Aromatic Dicarboximides By pubs.rsc.org Published On :: Org. Chem. Front., 2025, Accepted ManuscriptDOI: 10.1039/D4QO01828A, Review ArticleKazutaka Shoyama, Frank WuerthnerPolycyclic aromatic dicarboximides (PADIs) as represented by naphthalene and perylene bis(dicarboximide) are useful molecules for a variety of functional materials and remain important synthetic targets for organic chemists. In this...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ge Telangana pharmaceutical industries logged 97 major fire accidents in past decade: Fire Services Director-General Y. Nagi Reddy By www.thehindu.com Published On :: Thu, 07 Nov 2024 18:58:18 +0530 The new government would like to decentralise and set up pharma villages, in 10 clusters, Special Chief Secretary Jayesh Ranjan said Full Article Telangana
ge Key agent in Cambodia job racket arrested in Delhi By www.thehindu.com Published On :: Fri, 08 Nov 2024 18:11:22 +0530 Full Article Telangana
ge Hyderabad man loses ₹1.73 lakh trying to get 0% interest loan on insurance policy worth ₹10 lakh By www.thehindu.com Published On :: Fri, 08 Nov 2024 18:29:42 +0530 Full Article Telangana
ge Eleven transgenders arrested for public nuisance in Cyberabad By www.thehindu.com Published On :: Fri, 08 Nov 2024 20:59:02 +0530 Full Article Telangana
ge Cockroach infestation found at CCMB canteen; hygiene violations flagged at Nacharam restaurants By www.thehindu.com Published On :: Sat, 09 Nov 2024 18:01:58 +0530 Full Article Hyderabad
ge Kishan Reddy slams Revanth government for failing farmers, challenges Rahul Gandhi to tour villages in Telangana By www.thehindu.com Published On :: Sat, 09 Nov 2024 18:56:29 +0530 Full Article Telangana
ge Telangana govt. urged to release caste survey forms in English and Urdu By www.thehindu.com Published On :: Sat, 09 Nov 2024 20:26:10 +0530 Full Article Telangana
ge Minister Ponnam Prabhakar urges caste associations to support ongoing comprehensive survey in Telangana By www.thehindu.com Published On :: Sun, 10 Nov 2024 23:47:20 +0530 Full Article Telangana
ge Pending bills paid to contractors, but situation of BC students remains unchanged: National BC welfare association chief By www.thehindu.com Published On :: Mon, 11 Nov 2024 11:34:20 +0530 He demanded Telangana government to immediately release reimbursement and scholarship dues amount to about ₹4,000 crore Full Article Telangana
ge Agitated villagers chase govt officials over proposed pharma plant in Vikarabad By www.thehindu.com Published On :: Mon, 11 Nov 2024 16:09:21 +0530 The villagers have been protesting for several weeks against the proposed pharma company Full Article Telangana
ge Vigil mounted in erstwhile Adilabad district following ‘sighting’ of a tiger By www.thehindu.com Published On :: Mon, 11 Nov 2024 20:52:15 +0530 Full Article Telangana
ge Officials demand strict action against those involved in ‘confrontation’ at Vikarabad village By www.thehindu.com Published On :: Tue, 12 Nov 2024 00:48:38 +0530 Full Article Telangana
ge GHMC’s claims for budget allocations delayed due to absence of full time commissioner By www.thehindu.com Published On :: Tue, 12 Nov 2024 17:15:30 +0530 Full Article Hyderabad
ge India vs New Zealand, 3rd Test, Day 2: Spinners dominate, time for batters to salvage pride; Test poised for exciting finish By www.thehindu.com Published On :: Sat, 02 Nov 2024 12:28:49 +0530 New Zealand ended day two with an overall lead of 143, which might look small but even a target in the vicinity of 150 will pose serious challenge for the Indian batters Full Article Cricket
ge IND vs NZ third Test: India takes a narrow lead, with the Test poised on a knife’s edge By www.thehindu.com Published On :: Sat, 02 Nov 2024 19:19:18 +0530 Pant leads the way with an entertaining knock, while Gill is unlucky to miss his hundred; Azaz once again excels with a five-for to keep the Kiwis in the hunt on a turning track turning hostile for the batters with every passing hour Full Article Cricket
ge Ball-change controversy involving Kishan dominates India A's 7-wicket loss to Australia A By www.thehindu.com Published On :: Mon, 04 Nov 2024 04:42:00 +0530 Resuming at the overnight score of 139 for 3 while chasing 225, skipper Nathan McSweeney (88 not out) and Beau Webster (61) remained unbeaten, stitching unconquered 141 runs for the fourth wicket to ensure the comfortable win for the hosts. Full Article Cricket
ge Crisis manager Cummins guides Australia to tense win over Pakistan By www.thehindu.com Published On :: Mon, 04 Nov 2024 17:11:10 +0530 Playing his first ODI since last year's World Cup in India, Cummins produced a nerveless knock of 32 from 31 balls to push the hosts past Pakistan's modest total of 203 with 16.3 overs to spare Full Article Cricket
ge RANJI TROPHY | Mumbai gets a Shreyas boost as it takes on Odisha By www.thehindu.com Published On :: Tue, 05 Nov 2024 18:08:24 +0530 CRICKET | The defending champion will look to reignite its topsy-turvy campaign thus far with a dominant show against a side that has struggled to get going this season Full Article Cricket
ge KL Rahul's form and batting number in focus as India A gets 'G' experience By www.thehindu.com Published On :: Wed, 06 Nov 2024 17:39:26 +0530 With Boland, one of Australia's senior reserve pacers steaming in and hitting the deck, it will be a stern test for the likes of Abhimanyu Easwaran, Ruturaj Gaikwad, B Sai Sudharsan and Devdutt Padikkal Full Article Cricket
ge James Anderson wants to grow his 'knowledge of the game' through IPL By www.thehindu.com Published On :: Thu, 07 Nov 2024 17:50:25 +0530 In a surprising move, James Anderson, who last played a T20 match in 2014 and never played a match in the IPL, registered himself for the auction Full Article Cricket
ge Ranji Trophy | Bhambri leads the way as Chandigarh nudges ahead of Delhi By www.thehindu.com Published On :: Thu, 07 Nov 2024 19:54:37 +0530 Almost all batters make handy contributions as the host takes a 48-run first-innings lead; spinners Badoni and Mathur shine with the ball for the visitor Full Article Cricket
ge NewGen stars have a chance to shine as Proteas challenge awaits By www.thehindu.com Published On :: Fri, 08 Nov 2024 05:37:00 +0530 It is imperative for them to shed the tag of sidekicks and establish themselves as the first-choice players in this format. Full Article Cricket
ge Ageing Kohli, Rohit must rekindle youthful mindset to rediscover lost glory: Greg Chappell By www.thehindu.com Published On :: Fri, 08 Nov 2024 13:30:40 +0530 According to Chappell, the ageing Sharma and Kohli must summon the same drive and focus that once marked their prime years if India hopes to reclaim its form on foreign soil Full Article Cricket
ge Hyperverge: An early start and growing By www.thehindu.com Published On :: Sun, 11 Oct 2015 17:00:47 +0530 The startup company aims at solving the problem of photo organisation for smart-phone users. Full Article Careers
ge The UPSC challenge By www.thehindu.com Published On :: Sun, 24 Jan 2016 17:00:58 +0530 Several myths surround the UPSC examination, but here is what you need to do to succeed. Full Article Careers
ge The challenge of Economics By www.thehindu.com Published On :: Sat, 05 Mar 2016 15:22:46 +0530 How prepared are you to face the CBSE exam on this application-oriented subject? Full Article Careers
ge Civil services club in colleges? By www.thehindu.com Published On :: Sun, 10 Apr 2016 17:00:44 +0530 Want to become a bureaucrat? Here’s a lowdown on all that you need to know. Full Article Education Plus
ge Private engineering colleges demand fee hike By www.thehindu.com Published On :: Wed, 04 May 2016 00:00:00 +0530 Full Article Karnataka
ge Bridge the skills gap By www.thehindu.com Published On :: Sun, 07 Aug 2016 17:00:46 +0530 The employment landscape can be changed only by integrating skills with regular mainstream education in schools. Full Article Education Plus
ge Gain that analytical edge By www.thehindu.com Published On :: Sun, 23 Oct 2016 17:00:26 +0530 Want to get more out of your study programmes before you embark on your career? Full Article Education Plus
