ia Unravelling the potential of low-valent tunable vanadium complexes in the nitrogen reduction reaction (NRR) By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02217C, PaperBijoy Ghosh, Sahtaz Ahmed, Ashwini K. PhukanComprehensive computational investigations predict the potential of several hitherto unknown tripodal vanadium complexes in the nitrogen reduction reaction (NRR) without the probability of generation of hydrazine as a side product.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ia Structural and Mechanistic Insights into Oxidative Biaryl Coupling to form Arylomycin Core by an Engineered CYP450 By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02197E, PaperVandana Kardam, Vaibhav Bhatt, Kshatresh DubeyArylomycin, a potent antibiotic targeting bacterial signal peptidases, is difficult to synthesize experimentally due to its poor to moderate yields and the formation of a mixture of compounds. A recent...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ia Zn(II) coordination influences the secondary structure, but not antimicrobial activity of the N-terminal histatin 3 hydrolysis product By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02274B, PaperEmilia Dzień, Joanna Wątły, Aleksandra Hecel, Aleksandra Mikołajczyk, Agnieszka Matera-Witkiewicz, Miquel Adrover, Miquel Barceló-Oliver, Alicia Domínguez-Martín, Magdalena Rowińska-ŻyrekHistatin 3 and 4 have greater activity against Gram(+) than Gram(−) bacteria, and Cu(II) or Zn(II) binding can moderately increase their antimicrobial activity. The N-terminal part of histatin 3 becomes α-helical upon Zn(II) binding.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ia High-pressure synthesis and crystal structure analysis of PbTeO4, a UV transparent material By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02697G, Paper Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Michael Hladik, Armin Penz, Felix R. S. Purtscher, Thomas S. Hofer, Gunter Heymann, Matthias WeilCrystal structure of PbTeO4 with presumed position of the PbII lone-pair electrons (turquoise spheres). The electron localization function was used to emphasize the presence of the electron lone pair E.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ia Quantitative determination and subcellular mapping of Pt-based drugs in single breast tumour cells via laser ablation-ICP-mass spectrometry By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02467B, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Legna Colina-Vegas, Thibaut Van Acker, Wilmer Villarreal, Olivier De Wever, Alzir Azevedo Batista, Joaquim Araújo Nóbrega, Frank VanhaeckeThis study utilizes LA-ICP-MS to reveal the distribution and determine the concentration of Pt in MDA-MB-231 cells, providing insight into the mechanism and efficacy of Pt-based chemotherapeutic drugs.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ia Solvent-dependent Ln(III) clusters assembled by immobilization of CO2 in the air: zero-field single-molecule magnets and magnetic refrigerant materials By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02310B, PaperCai-Ming Liu, Xiang Hao, Zhao-Bo Hu, He-Rui WenThe automatic fixation of CO2 in the air plays a key role in the construction of Dy(III) single-molecule magnets (SMMs) and Gd(III) magnetic refrigeration molecular materials using Ln(III)Cl3 (Ln =...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ia Alkyl initiated ring opening polymerization of lactide by indium complexes supported by NCN pincer ligands By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02603A, PaperTakeo Iwase, Afagh Habibzadeh, Chatura Goonesinghe, Kudzanai Nyamayaro, Joseph Chang, Jason Wai-Lok Poon, Salik Hasan Rushdy, Justin Koh, Brian O. Patrick, Parisa MehrkhodavandiAlkyl-indium NCN pincer complexes supported by amine donors are significantly more active for lactide polymerization than the analogous imine derivatives.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ia A Zr-based metal–organic framework drug release system with long-lasting antibacterial behavior for accelerating wound healing By pubs.rsc.org Published On :: Dalton Trans., 2024, Advance ArticleDOI: 10.1039/D4DT02734E, PaperHui-Qian Zheng, Han-Xiao Feng, Bing-Xin Li, Yi-Fei Hui, Yi-Han Lin, Xian-Feng Su, Lai-Peng Yan, Zijie Zhou, Zu-Jin Lin, Faqiang TangA biocompatible Zr-based metal–organic framework drug release system, CIP@SU-102, was fabricated by the cation exchange method, which shows superior and long-lasting antibacterial activity as well as effective promotion of infected wound healing.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ia Highly selective organo-gallium hydroxamate mediated inhibition of antibiotic resistant Klebsiella pneumoniae By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02440K, PaperRebekah N. Duffin, Jenisi Kelderman, Megan Herdman, Philip Craig AndrewsFive complexes of gallium derived from hydroxamic acids have been synthesised, characterised, and their anti-bacterial activity and mammalian cell toxicity established. These are three metal-organic complexes; [Ga(BPHA]3 1, [Ga(BHA-H]3 2,...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ia Molecular Fe(II)–Ln(III) dyads for luminescence reading of spin-state equilibria at the molecular level By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17756-17765DOI: 10.1039/D4DT01868K, Frontier Open Access This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Timothée Lathion, Neel Deorukhkar, Charlotte Egger, Homayoun Nozary, Claude PiguetEfficient and easy lanthanide(III)-based luminescence reading of iron(II) spin-state equilibria presents an attractive challenge, owing to the delicate combination of the primogenic effect and the Fermi golden rule.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ia Direct O2 mediated oxidation of a Ni(II)N3O structural model complex for the active site of nickel acireductone dioxygenase (Ni-ARD): characterization, biomimetic reactivity, and enzymatic implications By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17852-17863DOI: 10.1039/D4DT02538E, PaperKelsey E. Kirsch, Mary E. Little, Thomas R. Cundari, Emily El-Shaer, Georgia Barone, Vincent M. Lynch, Santiago A. ToledoA structural and functional biomimetic Ni(II)N3O complex, capable of O2 mediated dioxygenase like C–C bond cleavage, via a putative high-valent Ni intermediate.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ia Structure modification and luminescence regulation in new violet light excitable Sr(2−y)BayY4La4(SiO4)6O2:xEu2+ phosphors via cation substitution By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17989-18002DOI: 10.1039/D4DT02195A, PaperJie Zhang, Langping Dong, Feng Wang, Jingshan Hou, Yongzheng FangA series of violet light excitable Sr(2−y)BayY4La4(SiO4)6O2:xEu2+ phosphors with tunable luminescence for high-quality white LEDs was developed through cation regulation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ia Optimizing synergistic effects: creating oxygen vacancies in NiCoWO4via a solid-state grinding method for improved energy storage performance By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17948-17962DOI: 10.1039/D4DT02118E, PaperAnandhavalli Jeevarathinam, Arun Annamalai, Ramya Ravichandran, Kumaresan Annamalai, Sundaravadivel ElumalaiWe disclose, for the first time we report the synthesis of an oxygen vacancy-enriched NiCoWO4 electrode by a simple solid state grinding method using NaBH4 as a mild reducing agent without any solvents.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ia Catalytic partial oxidation of methane over oxide-ion-conductive lanthanum silicate apatites By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,18021-18026DOI: 10.1039/D4DT02421D, PaperAfif Pamungkas, Yuta Goto, Kazumasa Murata, Saburo Hosokawa, Satoshi Ogawa, Kosaku Ohishi, Tomohiro Matsumoto, Miwa Saito, Teruki MotohashiThe oxide-ion-conductive lanthanum silicate La9.33Si6O26 with an apatite-type structure exhibits high activity for the catalytic partial oxidation of methane (CPOX).The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ia An acidity-triggered aggregation nanoplatform based on degradable mesoporous organosilica nanoparticles for precise drug delivery and phototherapy of focal bacterial infection By pubs.rsc.org Published On :: Dalton Trans., 2024, 53,17893-17901DOI: 10.1039/D4DT02111H, PaperYunhan Huang, Wei Guo, Xinyu Wang, Jingrui Chang, Bo LuAn acidity-triggered aggregation antibacterial nanoplatform based on biodegradable mesoporous organic silica nanoparticles, is reported. It enables precise drug release and spatial accuracy for photodynamic therapy and photothermal therapy.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ia Recent Advances in Syntheses and Emerging Applications of 2D Borophene based Nanomaterials with a Focus on Supercapacitors By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02573C, FrontierPrashanta Pal, Mahasweta NandiTwo dimensional (2D) nanosheet of boron i.e. borophene, triggered interest in progressive research as a result of the vast field of opportunities to explore, from its innovative synthetic techniques to...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ia Detailed mechanism of DNA/RNA nucleobase substituting bridging ligand in diruthenium (II,III) and dirhodium (II,II) tetraacetato paddlewheel complexes: Protonation of the leaving acetate is crucial By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02621G, Paper Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Iogann Tolbatov, Tiziano Marzo, Paolo Umari, Diego La Mendola, Alessandro MarronePaddlewheel complexes of bimetallic scaffolds are emerging metallic agents in the bioinorganic chemistry landscape. In the most commonly employed construct, these complexes are decorated by carboxylate moiety, prompting their possible...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ia Alleviating hypoxia by integrating MnO2 with metal-organic frameworks coated upconversion nanocomposites for enhanced photodynamic therapy in vitro By pubs.rsc.org Published On :: Dalton Trans., 2024, Accepted ManuscriptDOI: 10.1039/D4DT02605E, PaperJunxun Zhou, Mengyue Jiang, Qiangqiang Zhang, Yuan Jiang, Haifang Wang, Lining SunPhotodynamic therapy (PDT) requires the participation of abundant oxygen while the hypoxic tumor microenvironment limits the efficacy of PDT. Here, upconversion luminescent nanocomposites coated with metal-organic frameworks (MOFs) were synthesized...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ia Fourth wave scare: Covid-19 cases in Asia surpass 100 million, India, Japan, South Korea worst-hit By Published On :: Wednesday, March 30, 2022, 13:23 +0530 The highly contagious but less deadly BA.2 sub-variant of Omicron has pushed the figures to greater highs in recent weeks in South Korea, China and Vietnam. Full Article
ia Media invited but not welcomed! By www.thehindubusinessline.com Published On :: Fri, 19 Apr 2013 15:11:49 +0530 Full Article Siddhartha P Saikia
ia Media & Freebies: a murky connection By www.thehindubusinessline.com Published On :: Fri, 31 May 2013 16:21:44 +0530 Full Article Siddhartha P Saikia
ia The richness of Indian languages By www.thehindu.com Published On :: Sun, 25 Aug 2024 03:48:00 +0530 The idioms in everyday usage display the creativity and punch of the tongues Full Article Open Page
ia A traveller’s diary By www.thehindu.com Published On :: Sun, 01 Sep 2024 03:55:00 +0530 An edge-of-the-seat drive through treacherous mountain roads Full Article Open Page
ia Nothing has changed for women in India By www.thehindu.com Published On :: Sun, 22 Sep 2024 01:15:00 +0530 From Nirbhaya to Abhaya, violence continue to be perpertrated against women in the country Full Article Open Page
ia Marks mania By www.thehindu.com Published On :: Sun, 29 Sep 2024 01:48:00 +0530 A child may have great talent, but she is judged only by her marks Full Article Open Page
ia Permeating partiarchy By www.thehindu.com Published On :: Sun, 20 Oct 2024 03:05:00 +0530 It’s no longer about confining women to the kitchen; it subtly disguises itself as praise for how well women juggle careers and family Full Article Open Page
ia Appeal to Karnataka government to officially celebrate Shankar Nag’s birthday as ‘Driver’s Day’ By www.thehindu.com Published On :: Sun, 10 Nov 2024 17:22:47 +0530 Several auto drivers’ unions made an appeal to Transport Minister Ramalinga Reddy Full Article Karnataka
ia Siddaramaiah, Shivakumar term PM’s allegations of raising ₹700 cr. to fund Maharashtra polls as a ‘lie’ By www.thehindu.com Published On :: Sun, 10 Nov 2024 21:32:57 +0530 Full Article Karnataka
ia Guarantee money is deposited to beneficiaries’ bank accounts when election is around the corner, alleges B.Y. Vijayendra By www.thehindu.com Published On :: Mon, 11 Nov 2024 07:00:00 +0530 Full Article Karnataka
ia Woman and her associates booked for cheating homemakers in Bengaluru By www.thehindu.com Published On :: Mon, 11 Nov 2024 07:56:42 +0530 Full Article Karnataka
ia Siddaramaiah to launch projects in Mysuru on November 12 and 13 By www.thehindu.com Published On :: Mon, 11 Nov 2024 21:06:08 +0530 Full Article Karnataka
ia Fog affects 16 flights at KIA By www.thehindu.com Published On :: Mon, 11 Nov 2024 21:37:59 +0530 Full Article Karnataka
ia Chief Minister Siddaramaiah has no moral right to seek resignation of Prime Minister Narendra Modi, says Union Minister By www.thehindu.com Published On :: Tue, 12 Nov 2024 07:00:00 +0530 Pralhad Joshi was responding to a challenge by Mr. Siddaramaiah to the PM to prove charges of corruption in Karnataka or resign. Full Article Karnataka
ia State-level mock Parliament competition for high school and PU students in Shivamogga tomorrow By www.thehindu.com Published On :: Tue, 12 Nov 2024 19:08:32 +0530 Full Article Karnataka
ia Allocation for development works nails BJP’s lie of resource crunch in State, says Siddaramaiah By www.thehindu.com Published On :: Tue, 12 Nov 2024 20:02:22 +0530 Full Article Karnataka
ia D’Cunha report revealed ₹918 crore misappropriated in COVID equipment procurement: Sharan Prakash Patil By www.thehindu.com Published On :: Tue, 12 Nov 2024 21:01:16 +0530 Full Article Karnataka
ia Judicial Commission visits MUDA office in Mysuru By www.thehindu.com Published On :: Tue, 12 Nov 2024 21:01:18 +0530 The State government constituted the Commission headed by Justice P.N. Desai to look into the alleged irregularities in the allotment of sites by the MUDA Full Article Karnataka
ia Messi's Miami stunned by Atlanta in MLS By www.rediff.com Published On :: Miami were overwhelming favourites to win it all after producing a league record 74 points in the regular season but could not keep the momentum after Matias Rojas' close-range goal in the 17th minute and Messi's score in the 65th minute. Full Article
ia Fringe of the fringe : queering punk media history / edited by Kathrin Dreckmann, Elfi Vomberg, Linnea Semmerling. By darius.uleth.ca Published On :: Berlin : Hatje Cantz, [2023] Full Article
ia Integrated motivational interviewing and cognitive behavioral therapy (ICBT) [electronic resource] : a practitioners guide / Joseph Hyde, Maria Torres, Win Turner, R. Lyle Cooper. By darius.uleth.ca Published On :: Hoboken, New Jersey : John Wiley & Sons, Inc., [2024] Full Article
ia The neuroscience of psychotherapy [electronic resource] : healing the social brain / Louis J. Cozolino By darius.uleth.ca Published On :: [New York] : W. W. Norton & Company, Incorporated, 2024. Full Article
ia Winter's end [electronic resource] : dementia and dying well / Lewis Cohen. By darius.uleth.ca Published On :: New York, NY : Oxford University Press, [2024] Full Article
ia Ketamine [electronic resource] : the story of modern psychiatry's most fascinating molecule / by Keith G. Rasmussen. By darius.uleth.ca Published On :: Washington, DC : American Psychiatric Association Publishing, [2024] Full Article
ia Mumbai artist's diamond portrait of Ratan Tata to be sold for his charities By www.newkerala.com Published On :: Thu, 17 Oct 2024 20:00:03 +0530 Full Article
ia Maha CM asks officials to provide compensation for farm losses due to unseasonal rains By www.newkerala.com Published On :: Sun, 20 Oct 2024 12:22:02 +0530 Full Article
ia People have seen our work... Devendra Fadnavis exudes confidence in Mahayuti alliance retaining power in Maharashtra By www.newkerala.com Published On :: Fri, 25 Oct 2024 19:06:02 +0530 Full Article
ia Maharashtra key to India's growth story being scripted in Modi 3.0: EAM Jaishankar By www.newkerala.com Published On :: Mon, 28 Oct 2024 00:14:02 +0530 Full Article
ia PMAY beneficiaries in Maharashtra's Beed thank PM Modi for affordable housing By www.newkerala.com Published On :: Mon, 11 Nov 2024 22:48:01 +0530 Full Article
ia Dhruv Jurel shines again but India A lose by 6 wickets against Australia A By www.thehindu.com Published On :: Sat, 09 Nov 2024 14:38:23 +0530 Dhruv Jurel shines with bat, but India A falls to Australia A in unofficial Test series 0-2 Full Article Cricket
ia IND vs SA second T20I: India needs top-order to bat better against South Africa By www.thehindu.com Published On :: Sat, 09 Nov 2024 15:21:15 +0530 India need to address lack of runs from other key batters to ensure that the burden doesn't fall too heavily on their in-form keeper-batter. Full Article Cricket
