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Optimizing synergistic effects: creating oxygen vacancies in NiCoWO4via a solid-state grinding method for improved energy storage performance

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Dalton Trans., 2024, 53,17948-17962
DOI: 10.1039/D4DT02118E, Paper
Anandhavalli Jeevarathinam, Arun Annamalai, Ramya Ravichandran, Kumaresan Annamalai, Sundaravadivel Elumalai
We disclose, for the first time we report the synthesis of an oxygen vacancy-enriched NiCoWO4 electrode by a simple solid state grinding method using NaBH4 as a mild reducing agent without any solvents.
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Heats of formation on the way from B2H6 to B20H16: thermochemical consequences of multicenter bonding in ab initio and DFT methods

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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02589J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jindřich Fanfrlík, Jan Řezáč, Drahomír Hnyk, Josef Holub
The objective of this study is to evaluate the effectiveness of various computational methods in reproducing the experimental heats of formation of boron hydrides using the atomization energy approach.
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Investigation of the effect of Al2O3/water nanofluid on the performance of a thermoelectric cooler to harvest water from humid air

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Environ. Sci.: Water Res. Technol., 2024, 10,3035-3044
DOI: 10.1039/D4EW00367E, Paper
Emad Nazari, Mohammad Hassan Vakili, Mahdi Reiszadeh
One of the sources of fresh water, especially in desert and water-scarce areas is atmospheric air.
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Different routes of bismuth mineral transformation during pertechnetate and perrhenate uptake for subsurface remediation

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Environ. Sci.: Water Res. Technol., 2024, 10,2646-2654
DOI: 10.1039/D4EW00496E, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
D. Boglaienko, M. E. Bowden, N. M. Escobedo, Q. M. Collins, A. R. Lawter, T. G. Levitskaia, C. I. Pearce
Removal of pertechnetate 99TcO4− and perrhenate ReO4− during mineral transformation of the non-toxic basic bismuth subnitrate for subsurface remediation.
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Removal of Cu2+ from AMD by goethite modified biochar combined with sodium alginate: characterization, performance and mechanisms

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Environ. Sci.: Water Res. Technol., 2024, Advance Article
DOI: 10.1039/D4EW00664J, Paper
Hong Yang, Ruixue Zhang, Li An, Pan Wu, Yuran Fu, Jiajun Zou, Min Yu
An innovative method for resource utilization of agricultural waste crops.
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Improved microbial water quality and ozone performance following coagulation: implications for carbon based advanced treatment for potable reuse

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Environ. Sci.: Water Res. Technol., 2024, Advance Article
DOI: 10.1039/D4EW00638K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Christina M. Morrison, Ariel J. Atkinson, Daniel Gerrity, Eric C. Wert
Coagulation/flocculation of secondary effluent with FeCl3 (1) removed MS2 bacteriophage and bacterial endospores up to 2–3 LRVs, (2) removed rapid surrogates at levels correlative with microbial removal, and (3) improved downstream O3 performance.
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Fintech Progcap to digitise supply chains of MSMEs to make them part of formal economy

By www.thehindu.com
Published On :: Thu, 07 Nov 2024 15:38:15 +0530


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Digital University Kerala presents report on digital transformation study of judicial systems to Kerala High Court

By www.thehindu.com
Published On :: Sun, 27 Oct 2024 19:59:58 +0530

DUK Vice-Chancellor emphasises the report’s focus on harnessing cutting-edge technology to streamline the judicial process, reduce case pendency and optimise case management workflows.


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Kerala digital varsity’s Centre for Digital Transformation in Culture to get a website

By www.thehindu.com
Published On :: Tue, 29 Oct 2024 21:02:56 +0530


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Kohli can be made captain for all formats, says Ajit Agarkar

By www.thehindu.com
Published On :: Sun, 22 May 2016 03:45:02 +0530


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Harness information for progress of country, CSIR DG tells IIIT-H graduates

By www.thehindubusinessline.com
Published On :: Sat, 13 Jul 2024 19:26:39 +0530

She was addressing the graduating students of IIIT-H at its 23rd convocation here on Saturday


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Nemetschek India and ICT Academy sign MoU to boost digital transformation in education

By www.thehindubusinessline.com
Published On :: Fri, 02 Aug 2024 19:50:33 +0530

The partnership aims to upskill students and professionals for the AEC industry through workshops, seminars, and certifications


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Information matters

By www.thehindu.com
Published On :: Mon, 05 Nov 2012 12:18:18 +0530

An educational website that answers queries on sexual health and sexuality anonymously


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Rishi Sunak’s performance has been disappointing: India-born Rajesh Agrawal

By www.thehindu.com
Published On :: Thu, 04 Jul 2024 00:03:44 +0530

India-born Rajesh Agrawal is the Labour Party candidate for Leicester East


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Well-regulated structure-featuring giant-molecule acceptors enable long-term stability and high-performance binary organic solar cells

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Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03754E, Paper
Jingyu Shi, Pengfei Ding, Jintao Zhu, Zhenyu Chen, Shuangjiao Gao, Xueliang Yu, Xiaochun Liao, Quan Liu, Ziyi Ge
Through systematically selecting the numbers and positions of selenium atom of giant-molecule acceptors, the device based on PM6:GMA-SSeS yields the highest PCE of 19.37% with high VOC of 0.917 V and exhibits extended t80% lifetimes of 5600 h.
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From generation to collection – impact of deposition temperature on charge carrier dynamics of high-performance vacuum-processed organic solar cells

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Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03623A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Richard Adam Pacalaj, Yifan Dong, Ivan Ramirez, Roderick C. I. MacKenzie, Seyed Mehrdad Hosseini, Eva Bittrich, Julian Eliah Heger, Pascal Kaienburg, Subhrangsu Mukherjee, Jiaying Wu, Moritz Riede, Harald Ade, Peter Müller-Buschbaum, Martin Pfeiffer, James Robert Durrant
Substrate heating during co-evaporation of bulk heterojunction organic solar cells aids phase separation and improves performance. While recombination remains unaffected, hole transport improves due to more crystalline donor domains.
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Cover matters: Enhanced performance of multistage solar evaporator with tuned optical and thermal cover properties

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Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE02710H, Paper
Shiteng Li, Shang Liu, Qijun Yang, Shuai Deng, Meng Lin
To address global water scarcity and improve off-grid pure water production, this study focuses on enhancing the performance of inverted solar evaporators by optimizing the design of cover materials. By...
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A novel high-performance all-liquid formic acid redox fuel cell: simultaneously generating electricity and restoring the capacity of flow batteries

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Energy Environ. Sci., 2024, 17,8545-8556
DOI: 10.1039/D4EE02450H, Paper
Dongbo Wei, Lyuming Pan, Jing Sun, Meisheng Han, Manrong Song, Jincong Guo, Qing Zhang, Cailin Xiao, Zheng Li, Shuaibin Wan, Yubai Li, Lin Zeng, Lei Wei, Tianshou Zhao
This work presents an all-liquid formic acid redox fuel cell using degraded redox flow battery electrolyte as the cathode fuel. This approach efficiently generates power while regenerating the electrolyte, advancing energy conversion and storage.
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Trimming defective perovskite layer surfaces for high-performance solar cells

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Energy Environ. Sci., 2024, 17,8582-8592
DOI: 10.1039/D4EE03585B, Paper
Chanhyeok Kim, Kihoon Kim, Youngmin Kim, Nikolai Tsvetkov, Nam Joong Jeon, Bong Joo Kang, Hanul Min
The defect density on the top surface of the perovskite thin film was significantly higher than that in the bulk. A trimming solvent treatment removed the defective top surface, substantially reducing the defect concentration and strain.
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Unraveling the relationship between the phenethylammonium-induced 2D phase on the perovskite surface and inverted wide bandgap perovskite solar cell performance

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Energy Environ. Sci., 2024, 17,8658-8669
DOI: 10.1039/D4EE02133A, Paper
Xiaomin Huo, Silvia Mariotti, Yaoyao Li, Ting Guo, Chenfeng Ding, Penghui Ji, Shuai Yuan, Tongtong Li, Ning Meng, Xiaomin Liu, Jiahao Zhang, Ilhem Nadia Rabehi, Yu Zhang, Suling Zhao, Hengyuan Wang, Dandan Song, Luis K. Ono, Zheng Xu, Yabing Qi
We studied the impact of phenethylammonium chloride on PIN-structured wide bandgap perovskite solar cells. Elimination of the 2D phase results in a champion efficiency of 20.61% and a VOC loss of only 410 mV with hysteresis-free J–V curves.
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Reducing carrier recombination loss by suppressing Sn loss and defect formation via Ag doping in Cu2ZnSn(S,Se)4 solar cells

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Energy Environ. Sci., 2024, 17,8609-8620
DOI: 10.1039/D4EE02485K, Paper
SeongYeon Kim, Jaebaek Lee, Dae-Ho Son, Wook Hyun Kim, Shi-Joon Sung, Dae-Kue Hwang, Tae Ei Hong, Namuundari Otgontamir, Enkhjargal Enkhbayar, Tae-Hee Lee, Min-Yeong Kim, Ji-Soo Choi, Sang-Mo Koo, JunHo Kim, Jin-Kyu Kang, Dae-Hwan Kim, Kee-Jeong Yang
The position of Ag of the CZTSSe precursor significantly impacts the carrier recombination loss and overall efficiency, offering crucial insights for optimizing the CZTSSe solar cell design.
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Promoted thermoelectric performance in cubic-phase GeTe via grain-boundary phase elimination under phase diagram guidance

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Energy Environ. Sci., 2024, 17,8691-8701
DOI: 10.1039/D4EE03090G, Paper
Fudong Zhang, Baopeng Ma, Yiyuan Luo, Lujun Zhu, Weishuai Wang, Yalin Shi, Beiquan Jia, Zhen-Hua Ge, Zupei Yang, Di Wu, Jiaqing He
The Ag8GeTe6 grain boundary phase gets eliminated in cubic-phase δ-TAGS as guided by a quaternary phase diagram.
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Achieving high performance triboelectric nanogenerators simultaneously with high-voltage and high-charge energy cycle

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Energy Environ. Sci., 2024, 17,8734-8744
DOI: 10.1039/D4EE02447H, Paper
Open Access
Yikui Gao, Jiaqi Liu, Linglin Zhou, Lixia He, Di Liu, Peiyuan Yang, Bingzhe Jin, Zhong Lin Wang, Jie Wang
This work achieves a high-voltage and high-charge energy cycle for TENGs, as well as lossless energy transmission between TENGs and PMCs.
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Engineering ultrafast exciton dynamics to boost organic photovoltaic performance

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Energy Environ. Sci., 2024, 17,8776-8786
DOI: 10.1039/D4EE03315A, Paper
Yu Guo, Guangchao Han, Jing Guo, Haotian Guo, Yuang Fu, Xiaodan Miao, Zhen Wang, Dongsheng Li, Shuixing Li, Xiaomin Xu, Xinhui Lu, Hongzheng Chen, Yuanping Yi, Philip C. Y. Chow
Y-type acceptors exhibiting faster migration (shorter τ) of local excitons (LEs) in disordered regions of aggregates to intermolecular charge-transfer (ICT) excitons in ordered regions can achieve higher efficiencies in organic solar cells.
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Self-healing polymer dielectric exhibiting ultrahigh capacitive energy storage performance at 250 °C

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Energy Environ. Sci., 2024, 17,8866-8873
DOI: 10.1039/D4EE03705G, Paper
Open Access
Wenhan Xu, Fei Yang, Guodong Zhao, Shixian Zhang, Guanchun Rui, Muchen Zhao, Lingling Liu, Long-Qing Chen, Qing Wang
The Anderson localization effect has been exploited in the design of high-temperature dielectric polymers, resulting in reduced conduction loss and outstanding capacitive energy storage performance over a wide temperature range up to 250 °C.
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Global softening to manipulate sound velocity for reliable high-performance MgAgSb thermoelectrics

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Energy Environ. Sci., 2024, 17,8810-8819
DOI: 10.1039/D4EE03521F, Paper
Open Access
Airan Li, Longquan Wang, Jiankang Li, Takao Mori
A global softening strategy using stearic acid in MgAgSb to reduce sound velocity has been shown to enhance its thermoelectric performance, achieving high zT values and demonstrating strong potential for low-grade heat harvesting.
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High-entropy doping for high-performance zero-cobalt high-nickel layered cathode materials

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Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE05020G, Paper
Jiahui Zhou, Jiehui Hu, Xia Zhou, Zhen Shang, Yue Yang, Shengming Xu
Considering the high price and scarcity of cobalt resource, zero-cobalt, high-nickel layered cathode material (LNM) have been considered as the most promising material for next-generation high-energy-density lithium-ion batteries (LIBs). However,...
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Surface-deprotonated ultra-small SnO2 quantum dots for high-performance perovskite solar cells

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Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03193H, Paper
Wuchen Xiang, Yiheng Gao, Bobo Yuan, Shuping Xiao, Rui Wu, Yiran Wan, Zhiqiang Liu, Liang Ma, Xiang-Bai Chen, Weijun Ke, Guojia Fang, Pingli Qin
SnO2 electron transport layers (ETLs) have improved perovskite solar cell (PSC) efficiencies but face issues with surface protonation, leading to energy loss and instability. We developed ultra-small (2.5 nm) SnO2...
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A decade of India’s transformative sanitation mission

By www.thehindu.com
Published On :: Sun, 03 Nov 2024 03:00:00 +0530

The sanitation revolution, the Swachh Bharat Mission, is not just India’s achievement but is also a global one


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The electrochemical oxidation of a thioether to form an API intermediate and the effects of substrate electronics on impurity formation

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React. Chem. Eng., 2024, 9,883-887
DOI: 10.1039/D3RE00632H, Paper
Hamish R. Stephen, Holly Longhurst, Michael Nunn, Christopher D. Parsons, Matthew Burns
Electrochemistry was explored as a means of oxidising a thioether to form a sulfone API intermediate.
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Determination of intermediates and products of the uranyl aerosol formation in UF6 hydrolysis in the gas phase

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00665D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Christian Mark Salvador, Jason M. Richards, Shannon M. Mahurin, Meng-Dawn Cheng, Joshua A. Hubbard
A graphical representation of the uranyl aerosol formation.
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Tata Motors’ Q2 profit falls 11.18% due to weak performance

By www.thehindubusinessline.com
Published On :: Fri, 08 Nov 2024 19:51:28 +0530

Lower sales volumes, supply constraints and underperformance of JLR, PVs resulted in the decline in profits


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Solid-state fermentation of green lentils by Lactiplantibacillus plantarum leads to formation of distinct peptides that are absorbable and enhances DPP-IV inhibitory activity in an intestinal Caco-2 cell model

By pubs.rsc.org
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Food Funct., 2024, 15,11220-11235
DOI: 10.1039/D4FO03326D, Paper
Elisa Di Stefano, Nico Hüttmann, Pieter Dekker, Monic M. M. Tomassen, Teresa Oliviero, Vincenzo Fogliano, Chibuike C. Udenigwe
In vitro gastrointestinal digestion, brush border enzyme activity, and microbial fermentation with Lactiplantibacillus plantarum influenced the peptidome of green lentils and peptide transport across the intestinal Caco-2 cell monolayer.
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Editorial. FMCG firms should look within for falling performance

By www.thehindubusinessline.com
Published On :: Tue, 29 Oct 2024 21:20:59 +0530

FMCG multinationals seem to be hurt more by sector-specific disruptions that they have failed to foresee, than any economy-wide distress


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Editorial. Subdued performance

By www.thehindubusinessline.com
Published On :: Tue, 05 Nov 2024 20:54:42 +0530

Q2 earnings point to challenges in many sectors


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Deshwal powers Jaipur Pink Panthers with 19-point performance against Bengaluru Bulls

By www.thehindu.com
Published On :: Wed, 13 Nov 2024 05:10:28 +0530

Arjun Deshwal scored 19 points for the two-time PKL champions, with the second-highest scorer for the Jaipur Pink Panthers being Lucky Sharma


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Gram Sabha meetings to discuss village panchayats’ performance in sanitation

By www.thehindu.com
Published On :: Wed, 13 Nov 2024 00:28:45 +0530


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Microplastics promote cloud formation, with likely effects on weather and climate

By www.thehindu.com
Published On :: Tue, 12 Nov 2024 17:24:57 +0530

Scientists show that microplastic particles can have the same effects, producing ice crystals at temperatures 5 to 10 degrees Celsius warmer than droplets without microplastics.


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Riveting performance

By www.thehindu.com
Published On :: Thu, 01 Sep 2016 16:46:21 +0530

The classic comedy of ‘Barrister Parvateesam’ was enacted brilliantly


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Shining a light on methane dry reforming – exploring the impact of visible light on carbon formation over Co/xCeO2–Al2O3

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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00925H, Paper
George E. P. O'Connell, Richard F. Webster, Elise Elkington, Rose Amal, Jason Scott, Emma C. Lovell
Introducing light to thermal DRM may be an effective strategy to improve catalyst stability, but light's role in the stability mechanism is not well understood.
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Enhanced catalytic performance of single-atom Cu on Mo2C toward CO2/CO hydrogenation to methanol: a first-principles study

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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00703D, Paper
Open Access
Anna Vidal-López, Estefanía Díaz López, Aleix Comas-Vives
First-principles calculations show the crucial role of the Cu/Mo2COx interface in enabling low-energy pathways for CO2/CO hydrogenation to methanol via successive heterolytic H2 cleavages.
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First-principles investigation of an efficient non-noble single-atom catalyst Fe1/Ti2CO2 for formaldehyde oxidation

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Catal. Sci. Technol., 2024, 14,6233-6246
DOI: 10.1039/D4CY00809J, Paper
Yongkang Zhang, Yuting Fu, Kaibin Su, Yuhang Wang, Fengping Wang
Indoor formaldehyde (HCHO) removal holds paramount significance for human health, particularly in mild conditions. Fe1/Ti2CO2 is an efficient catalyst that can remove indoor formaldehyde.
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Reducing meso-lactide formation from racemic lactic acid using shape-selective H-Beta zeolite

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Catal. Sci. Technol., 2024, 14,6331-6337
DOI: 10.1039/D4CY01046A, Paper
Ling Ding, Lou Gao, Di Pan, Ke Du, Jiayu Yu, Wanyi Li, Yahong Zhang, Yi Tang
Efficiently reduce the formation of meso-lactide from racemic lactic acid by utilizing H-Beta zeolite shape selectivity towards lactic acid dimers.
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Synthesis of Co3O4 catalysts with different morphologies and their excellent catalytic performance for soot combustion

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Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY01115E, Paper
Xinyu Zhang, Chunlei Zhang, Siyu Gao, Xinyu Chen, Siyuan Chen, Shengran Zhou, Di Yu, Lanyi Wang, Xiaoqiang Fan, Xuehua Yu, Zhen Zhao
A series of Co3O4 catalysts with different morphologies were prepared by a hydrothermal method. Among them, the sea urchin shaped Co3O4 catalyst exhibits the best catalytic performance for soot combustion.
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Oxygen vacancy-dependent low-temperature performance of Ni/CeO2 in CO2 methanation

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Catal. Sci. Technol., 2024, 14,6537-6549
DOI: 10.1039/D4CY00679H, Paper
Luliang Liao, Kunlei Wang, Guangfu Liao, Muhammad Asif Nawaz, Kun Liu
The transformative power of CO2 methanation can efficiently transform greenhouse gases into high-value products, aligning with the carbon neutrality goals.
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Copper cluster complex-catalyzed C–S bond formation

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Catal. Sci. Technol., 2024, 14,6609-6620
DOI: 10.1039/D4CY00968A, Paper
Nien-Chi Chang Liao, R. Sidick Basha, Bo-Hao Shih, Chia-Chun Liu, Miao-Han Wang, Po-Heng Lin, Chin-Fa Lee
Three distinct copper cluster complexes (A–C) were synthesized and their bonding was investigated by XRD studies. These complexes effectively catalyze the C–S coupling reaction of less reactive aliphatic thiols to synthesize thioether derivatives.
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In situ preparation and performance of iron-based electro-magnetic synergistic electrochemical nitrogen fixation catalysts

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Catal. Sci. Technol., 2024, 14,6592-6599
DOI: 10.1039/D4CY01008F, Paper
Kaidi Chen, Run Deng, Chen Zhao, Qikun Zhang
An iron-based catalyst was prepared in situ in FeSO4 solution by electrochemical technology to catalyze the reduction of N2 to NH3. It was found that the applied magnetic field can significantly increase the current density.
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Recyclable copper(I)-catalyzed cascade C–S and C–N bond formation between 2-iodoanilines and 2-bromobenzenethiols towards functionalized phenothiazines

By pubs.rsc.org
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Catal. Sci. Technol., 2024, 14,6561-6572
DOI: 10.1039/D4CY00888J, Paper
Yan Wang, Chengkai Luo, Li Wei, Mingzhong Cai
Heterogeneous copper-catalyzed heterocyclization between 2-iodoanilines and 2-bromothiophenols has been developed for the assembly of substituted phenothiazines.
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Study on the effect and mechanism of Ag and Bi2MoO6 modification on the CO2 photo-thermal reduction performance of g-C3N4 catalysts with localized surface plasmon resonance

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Catal. Sci. Technol., 2024, 14,6621-6640
DOI: 10.1039/D4CY00930D, Paper
Bin Guan, Junyan Chen, Zhongqi Zhuang, Zhan Gao, Zeren Ma, Xuehan Hu, Chenyu Zhu, Sikai Zhao, Kaiyou Shu, Hongtao Dang, Tiankui Zhu, Zhen Huang
As a promising future energy material, g-C3N4 as a CO2 photo-thermal-reduction catalyst can effectively convert CO2 to renewable fuel, but the low yield and low product selectivity significantly limit its further development and application.
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