en

Crystal reconstruction and defect healing enabled high-quality Sb2Se3 films for solar cell applications

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00734D, Paper
Qi Zhao, Bo Che, Haolin Wang, Xiaoqi Peng, Junjie Yang, Rongfeng Tang, Changfei Zhu, Tao Chen
A post-sulfurization technique has been developed to refine Sb2Se3 crystallization. This process enables high-quality Sb2Se3 with a smooth surface, large compact crystal grains and benign [hkl] growth orientation. It also mitigates the device VOC deficit, owing to the healed deep level defects.
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Porous carbon nitride rods as an efficient photoanode for water splitting and benzylamine oxidation

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00237G, Paper
Sanjit Mondal, Gabriel Mark, Ayelet Tashakory, Michael Volokh, Menny Shalom
A polymeric carbon nitride layer with controlled directionality, morphology, and nitrogen defects serves as a photoanode to allow photoelectrochemical (PEC) water-splitting and benzylamine oxidation.
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Correction: Superhydrophobic and mechanical properties enhanced the electrospinning film with a multiscale micro-nano structure for high-efficiency radiation cooling

J. Mater. Chem. A, 2024, 12,9241-9241
DOI: 10.1039/D4TA90062F, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lijing Kong, Puqing Sun, Jincheng Liu, Yongxing Lin, Chao Xiao, Chao Bao, Kang Zheng, Meng Xue, Xian Zhang, Xianglan Liu, Xingyou Tian
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Unveiling the fundamental understanding of two dimensional π-conjugated FeN4+4 sites for boosting peroxymonosulfate activation

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01195C, Paper
Sijia Jin, Wenxian Tan, Xiaofeng Tang, Xia Yao, Yingjian Bao, Haiyan Zhang, Shuang Song, Tao Zeng
The precisely defined FeN4+4 active sites in fully π-conjugated polyphthalocyanine frameworks establish a dual-pump-driven electron fast shuttle path—electron-rich Fe centers and electron-poor C atoms—ensuring continuous production of 1O2.
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Identifying lithium difluoro(oxalate)borate as a multifunctional electrolyte additive to enable high-voltage Li4Ti5O12 lithium-ion batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00750F, Paper
Ou Ka, Fang Cheng, Lang Wen, Xiaoqu Wang, Ting Wang, Xinyu Zeng, Wen Lu, Liming Dai
Lithium difluoro(oxalate)borate (LiDFOB) is identified as a multifunctional electrolyte additive, stabilizing the electrolyte and protecting the electrodes, to enable the LiNi0.5Mn1.5O4//Li4Ti5O12 battery with an excellent performance at 3.50 V.
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Retraction: Nickel nanoparticles immobilized on three-dimensional nitrogen-doped graphene as a superb catalyst for the generation of hydrogen from the hydrolysis of ammonia borane

J. Mater. Chem. A, 2024, 12,9247-9247
DOI: 10.1039/D4TA90071E, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Mojtaba Mahyari, Ahmad Shaabani
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en

Correction: Super-adsorbent hydrogel for removal of methylene blue dye from aqueous solution

J. Mater. Chem. A, 2024, 12,9242-9246
DOI: 10.1039/D4TA90061H, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xiao-Sai Hu, Rui Liang, Guoxing Sun
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en

Superhydrophilic covalent organic frameworks accelerate photocatalytic production of hydrogen peroxide through proton channels

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01785D, Paper
Xiaojuan Bai, Linlong Guo, Tianqi Jia, Zhuofeng Hu
Superhydrophilic COFs with D–A structure accelerate photocatalytic synthesis of H2O2 using water as a proton supply reservoir.
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en

A review of noble metal-free high entropy alloys for water splitting applications

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00690A, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hamzah Kamaruddin, Zhang Jianghong, Liang Yu, Wei Yuefan, Huang Yizhong
Nano-sized high entropy alloy (HEA) catalysts have attracted much attention as extraordinary electrocatalysts in water-splitting applications, i.e., the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER).
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Photothermal conversion enabled temperature modulation for the growth of complex polymorphic architectures of calcium carbonate

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00802B, Paper
Boning Shi, Lifu Zhang, Zeda Yang, Jiangnan Deng, Shun An, Benwei Fu, Chengyi Song, Peng Tao, Tao Deng, Wen Shang
As a highly efficient and eco-friendly heat generation approach, photothermal conversion process has been applied to many important areas such as desalination and medical treatments. We explored in this work...
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en

Prolonging exciton diffusion length via manipulating molecular stacking enables pseudo-planar heterojunction organic solar cells over 19% efficiency

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00594E, Paper
Wang Ke, Fuwen Zhao, Yufan Zhu, Yi He, Zesheng Liu, Xiao Han, Qi Ai, Xingxing Shen, Bao Li, Jianqi Zhang, Yuze Lin, Chun-Ru Wang, Dan He
The limited exciton diffusion length (LD) of organic semiconductors constraints exciton dissociation in pseudo-planar heterojunction (PPHJ) organic solar cells (OSCs), which is deemed as the bottleneck issue hampering the further...
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en

Aggregation between oligomeric Ir photosensitizers promote efficient and long-lifetime photocatalytic hydrogen evolution

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D3TA07365C, Paper
Yifan Huang, Shihan Liu, Bo Wang, Ying Wang, Yifan Zhang, Pengyang Deng
In this paper, the aggregation effect between oligomeric Ir photosensitizers on photocatalytic hydrogen evolution was first discovered and investigated. Four oligomeric Ir photosensitizers were synthesized by copolymerization of [Ir(ppy)2(dabpy)](PF6) (H1)...
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en

Rapid in situ growth of high-entropy oxide nanoparticles with reversible spinel structures for efficient Li storage

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA08101J, Paper
Open Access
Siyu Zhu, Wei Nong, Lim Jun Ji Nicholas, Xun Cao, Peilin Zhang, Yu Lu, Mingzhen Xiu, Kang Huang, Gang Wu, Shuo-Wang Yang, Junsheng Wu, Zheng Liu, Madhavi Srinivasan, Kedar Hippalgaonkar, Yizhong Huang
Using laser radiation, high-entropy nanoparticles were rapidly fabricated on conductive carbon. The high-entropy nanomaterials with reversible spinel structures exhibit better cycling and rate performances in LIBs.
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From scrap metal to highly efficient electrodes: harnessing the nanotextured surface of swarf for effective utilisation of Pt and Co for hydrogen production

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00711E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Madasamy Thangamuthu, Emerson C. Kohlrausch, Ming Li, Alistair Speidel, Adam T. Clare, Richard Plummer, Paul Geary, James W. Murray, Andrei N. Khlobystov, Jesum Alves Fernandes
Atomically deposited Pt and Co on nano-grooves result in active and stable electrocatalysts for hydrogen evolution and oxygen evolution reactions.
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Design of Interfacial Dual Schottky Junctions to Modulate Charge Transfer for Enhanced Piezo-assisted Photocatalytic Degradation RhB Performances

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00619D, Paper
Xiaoqi Jiang, Shengdong Sun, Yuqiao Wang, Lebing Zhao, Fangzhi Huang, Shikuo Li
Regulating charge transfer is a great challenge to improving the efficiency of piezoelectric photocatalytic reactions. Herein, sandwich-like Bi2WO6@Ag/MXene nanoflower spheres (BWO@Ag/MXene) with piezoelectric/plasma dual characteristics were synthesized by a facile...
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en

Deciphering the role of 2D graphene oxide nanofillers in polymer membranes for vanadium redox flow batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00001C, Review Article
Sadhasivam Thangarasu, Shalu, Gowthami Palanisamy, Subramani Sadhasivam, Karuppaiah Selvakumar, Krishna Rao Eswar Neerugatti, Tae Hwan Oh
This comprehensive review article explains the influence of various GO and GO-polymer membrane modifications for VRFB, which range from cation and anion exchange to amphoteric and zwitterionic membranes.
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en

Probing the potential of Al2CO/SiC heterostructures for visible light driven photocatalytic water splitting using first-principles strategies

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00885E, Paper
Amina Shehbaz, Abdul Majid, Hira Batool, Mohammad Alkhedher, Sajjad Haider, Kamran Alam
Photocatalytic water splitting is a sustainable and eco-friendly method for renewable energy production. The fabrication of an efficient photocatalyst based on two-dimensional (2D) interfaces with suitable band offsets is at...
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en

Oxygen vacancy-induced efficient hydrogen spillover in Ni17W3/WO3−x/MoO3−x for a superior pH-universal hydrogen evolution reaction

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00729H, Paper
Open Access
Yiqing Sun, Yiwei Bao, Di Yin, Xiuming Bu, Yuxuan Zhang, Kaihang Yue, Xiaoshuang Qi, Ziyan Cai, Yongqiang Li, Xiulan Hu, Johnny C. Ho, Xianying Wang
By regulating the oxygen vacancy in the WO3−x/MoO3−x support synergistically, the active phase transition can be accomplished at low voltage, resulting in fast intermediate hydrogen uptake/transfer/desorption kinetics on the prepared catalyst surface and interface.
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Engineering electronic band structure of ternary thermoelectric nanocatalysts for highly efficient detection of hydrogen sulfide

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00438H, Paper
Hongyuan Shang, Xiaofei Zhang, Aiping Zhang, Jinwen Du, Ruiping Zhang
This study rationally designs a ternary thermoelectric nanocatalyst PtTeCu nanorod for the accurate detection of hydrogen sulfide in biomedical applications.
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A sacrificial separator facilitating in situ creation of a durable CEI layer and tailoring lithium dendrites for practical lithium metal batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01234H, Paper
Sung Joon Park, Yun Jeong Choi, Jaemun Cheon, Hyungjun Kim, Jong-Won Lee, Taeeun Yim, Ki Jae Kim
The TBB–PE separator can form a robust and uniform boron-rich CEI (cathode electrolyte interphase) layer on the cathode surface via electrochemical oxidation as well as inhibit the growth of lithium dendrites by anion anchoring.
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Synthesis of a pyridine-based covalent organic framework as an anode material for lithium-ion batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00892H, Paper
Shixi Zhong, He Zhao, Yingming Ji, Xiuhua Li, Ting Shu, Zhiming Cui, Shijun Liao
Covalent organic framework (COF) materials with redox activity have emerged as promising electrode materials for lithium-ion batteries.
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Origin of sputter damage during transparent conductive oxide deposition for semitransparent perovskite solar cells

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA06654A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Qing Yang, Weiyuan Duan, Alexander Eberst, Benjamin Klingebiel, Yueming Wang, Ashish Kulkarni, Andreas Lambertz, Karsten Bittkau, Yongqiang Zhang, Svetlana Vitusevich, Uwe Rau, Thomas Kirchartz, Kaining Ding
The origin of sputter damage during transparent conductive oxide deposition is ion bombardment rather than plasma radiation. Ion bombardment increased recombination, whereas plasma radiation reduced recombination.
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Enhanced catalytic activity and stability of SOFC electrodes through plasma-driven surface modification

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA06111F, Paper
Open Access
Hyunduck Shin, Jongsu Seo, SungHyun Jeon, Seung Jin Jeong, Jinwook Kim, Siwon Lee, Jeong Jin Lee, WooChul Jung
Plasma-induced surface amorphization prevents Sr phase separation, boosting the catalytic activity and stability of SOFC cathode. This finding expands the application of amorphous features to practical electrodes, previously limited to model studies.
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Atomically Dispersed Ru Sites on MOF-derived NC-ZnO for Efficient Oxygen Evolution Reaction in Acid Media

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00586D, Paper
Sagar Varangane, Ragunath Madhu, Saad Mehmood, Bhavya Jaksani, Vidha Bhasin, Moses Abraham Abraham Bokinala, Ammavasi Nagaraj, Chandra Shobha Vennapoosa, Venkata Subba Reddy Basireddy, Subrata Kundu, Ujjwal Pal
Developing acid-stable oxygen evolution/reduction reaction (OER/ORR) electrocatalysts is essential for high-performance water splitting. Still, the slow kinetics of the ORR and OER during the discharge and charge processes seriously impede...
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Heteroatom-doped Graphene for Marvellous Hydrogen Storage: Unveiling Recent Advances and Future Pathways

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00717D, Review Article
Shankar Ghotia, Tripti Rimza, Shiv Singh, Neeraj Dwivedi, Avanish Kumar Srivastava, Pradip Kumar
Hydrogen energy and storage are gaining significant attention due to their potential to address various energy and environmental challenges. Storage of hydrogen in a solid–state media is an area of...
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en

Scalable preparation of flexible heterogeneous graphene oxide structures for high performance wet power generation

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01819B, Paper
Yu Gao, Xiaoming Cai, Yuzhou Zhao, Wentian Huang, Jian Lv, Jie Wang, Zhenliang Hao, Huiming Liang, Honglin Tan, Jinming Cai
Moisture-driven energy generation (MEG) has attracted great attention in recent years, and the interaction of functionalized nanomaterials with water offers the possibility of MEG. However, current MEG devices require specific...
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en

Bi-intercalated vanadium pentoxide synthesized via hydrogen peroxide-induced phase transition for highly stable cathode in aqueous zinc ion batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07984H, Paper
Jian-an Chen, Xuejun Hou, Xueli Wang, Chunxia Wang, Jiawei Wen, Yongjie Bu, Guoyong Huang, Tiantian Cao, Shengming Xu
Operating principle of aqueous zinc-ion batteries (ZIBs).
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The balancing act between high electronic and low ionic transport influenced by perovskite grain boundaries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA04458K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Nadja Glück, Nathan S. Hill, Marcin Giza, Eline Hutter, Irene Grill, Johannes Schlipf, Udo Bach, Peter Müller-Buschbaum, Achim Hartschuh, Thomas Bein, Tom Savenije, Pablo Docampo
Grain size and orientation's impact on charge carriers is explored via a new solvent engineering method for MAPbI3 solar cells. Drift-diffusion simulations connect s-shaped JV curves to slower ions.
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Structure–property–performance relationship of vanadium- and manganese-based metal–organic frameworks and their derivatives for energy storage and conversion applications

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00736K, Review Article
Reza Abazari, Soheila Sanati, Ashok Kumar Nanjundan, Qiyou Wang, Deepak P. Dubal, Min Liu
The current review discusses on vanadium- and manganese-based metal–organic frameworks and their derivatives for energy storage and conversion applications along with the potential future advancements in these fields.
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Dioxygen atom co-doping g-C3N4 for boosted photoreduction activity of CO2 and mechanistic investigation

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00156G, Paper
Zhang Jiang, Mingnv Guo, Zhongqing Yang, Ruiming Fang, Ziqi Wang, Jingyu Ran
Visible-light photocatalytic reduction of carbon dioxide with the help of photocatalysts has become an important means to mitigate the greenhouse effect.
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Metal–support interaction triggered d–p orbital hybridization for efficient electrocatalytic semi-hydrogenation of alkynes

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01240B, Paper
Qiong Wan, Jiaxun Zhang, Xuan Liu, Huizhi Li, Abdullah, Taotao Ren, Qiyuan Liu, Yongheng Xu, Jia Liu, Jicheng Liu, Bingqing Yao, Yiyun Fang, Xinzhe Li, Chi He
Atomic restructuring in Pd/Fe2O3 catalysts weakens Pd binding to chemisorbed 4-aminophenylacetylene and hydrogen intermediates, boosting conversion and selectivity in 4-aminophenylacetylene semi-hydrogenation, surpassing Pd/C and other catalysts.
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Enhanced photocatalytic activity in Mn-doped multiferroic BiFeO3

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00886C, Paper
Jafar Hussain Shah, Zhi Huaqian, Rashid Mehmood, Ali Imran Channa, Jamal Kazmi, Liang Zhang, Federico Rosei, Zhiming Wang
Mn doping in ferroelectric BiFeO3 enhanced photocatalytic activity through the synergistic effect of the enhanced band bending on the surface as a result of internal screening of polarization bound charges and formation of inter-band energy levels while shifting the energy bands closer together.
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Development of diverse aluminium concentration gradient profiles in Ni-rich layered cathodes for enhanced electrochemical and thermal performances

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00433G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xinwei Jiao, Junwei Yap, Junbin Choi, Mengyuan Chen, Devendrasinh Darbar, Gongshin Qi, Xiaosong Huang, Jung-Hyun Kim
Nickel (Ni)-rich cathodes with elemental concentration gradients within particles have attracted great interest due to their considerably enhanced interfacial stability and electrochemical performance for advanced Li-ion batteries.
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Achieving giant energy density/efficiency in light-metal-element-rich relaxor ferroelectric ceramic by annihilating the volatile Schottky defects

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00867G, Paper
Kunjie Lou, Yizheng Bao, Jun Chai, Jiyue Wu, Yanshuang Hao, Shaozheng Zhang, Genshui Wang
With the rapid growth of energy storage capacitors in advanced power systems, the pursuit of lightweight is gradually important despite the urgent need for device miniaturization. To reduce the weight...
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en

Size and orientation of polar nanoregions characterized by PDF analysis and using a statistical model in a Bi(Mg1/2Ti1/2)O3–PbTiO3 ferroelectric re-entrant relaxor

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00240G, Paper
Laijun Liu, Kaiyuan Chen, Dawei Wang, Manuel Hinterstein, Anna-Lena Hansen, Michael Knapp, Biaolin Peng, Xianran Xing, Yuanpeng Zhang, Jing Kong, Abhijit Pramanick, Mads Ry Vogel Jørgensen, Frederick Marlton
Local structure information of relaxor ferroelectrics is key to a clear understanding of their structure–property relationships. The size of polar nanoregions is determined based on the local atomic displacement and dielectric response.
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A heterostructured WO3–SnO2 nanocomposite for the efficient photocatalytic production of H2O2 under visible light

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01223B, Paper
Diya Xie, Chen Chen, Yaru Wang, Cheng Sun, Yiming Xu, Jianguo Huang
A WO3–SnO2 (WSN) nanocomposite was synthesized with unique heterostructures formed in-between the two phases, resulting in the efficient production of H2O2 under visible light due to the synergistic effect.
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Regulating Pt-Covalent Triazine Frameworks Schottky Junction by Tailor-Made Nitrogen Sites towards Efficient Photocatalysis

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00618F, Paper
Chao Li, Lijiang Guan, Jin Zhang, Cheng Cheng, Zhaoqi Guo, Zhihong Tian, Li-Ming Yang, Shangbin Jin
Covalent triazine frameworks (CTFs) of designable nitrogen-rich structures, which can form Schottky Junction with Pt nanoparticles, have been extensively studied in photocatalysis. However, how to tune the interaction inside the...
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Cationic Radical Metal–Organic Framework Enabling Low Water Evaporation Enthalpy and High Photothermal Conversion Efficiency for Solar-Driven Water Purification

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01126K, Paper
Zi-Yu Wang, Rui Wang, Hannah M Johnson, Lei Cai, An-An Zhang, Qiang Zhang, Tianfu Liu
Solar vapor generation is a promising and sustainable strategy to purify seawater and contaminated water sources. Yet, efficient integration between solar capture and desalination remains a critical challenge. In this...
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en

Renewable Aromatic Hydrocarbons from Waste Cooking Oil over Hierarchical Imidazole Supported Zeolite

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00416G, Paper
Bipul Sarkar, Bhanu Joshi, Omvir Singh, Ankit Agrawal, Neha Dhiman, Bhanu Prasad Vempatapu, Navin Gopinathan , Anjan Ray
Unlike coal, oil, or natural gas, waste cooking oil (WCO) acts as a renewable source of carbon. It can be converted into energy, fuels, and fine chemicals, instead of being...
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en

Modulation of active metal species in MOF-derived catalysts for Efficient NO reduction by CO

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01075B, Paper
Ning-Rui Zhou, Zhen Yang, Ying Tang, Ming-Qi Zhang, Yun-Peng Zha, Min-Min Liu, Feng Yu, Jiang Liu
Transition metal oxides are usually used as one of the most excellent catalysts for NO selective catalytic reduction by CO (CO-SCR), but their catalytic activity is limited by the content...
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en

Deciphering cycling voltage-dependent failures of O3-layered cathode for sodium ion battery

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07967H, Paper
Xuejiao Zhao, Lihan Zhang, Xiaoqi Wang, Jinhui Li, Lin Zhang, Di Liu, Rui Yang, Xu Jin, Manling Sui, Pengfei Yan
Interfacial degradations dominate the performance decay of O3-layered cathode during low-voltage cycling; high voltage cycling induced bulk failures cause rapid performance decay due to transition metal cation migration.
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Boosting the electrocatalytic activity of single atom iron catalysts through sulfur-doping engineering for liquid and flexible rechargeable Zn–air batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00524D, Paper
Tianfang Yang, Bingcheng Ge, XuPo Liu, Zunjie Zhang, Ye Chen, Yang Liu
A practical strategy is reported to design single-Fe atom decorated S/N-doped C (Fe SAs@S/N–C) catalysts with a high Fe loading of 5.45 wt%. The prepared catalysts exhibit excellent performances for liquid and all-solid-state Zn–air batteries.
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Regulating the local microenvironment on porous Cu nanosheets for enhancing electrocatalytic CO2 reduction selectivity to ethylene

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01198H, Paper
Dan Wang, Qingqing Song, Kaibin Li, Yuwei Zhou, Junjun Mao, Chenchen Zhang, Yang Lou, Chengsi Pan, Jiawei Zhang, Yongfa Zhu, Ying Zhang
Local microenvironments of the ECO2RR play an important role in tuning the adsorption energy of crucial intermediates, which helps enhance ECO2RR selectivity.
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A high-current initiated formation strategy for improved cycling stability of anode-free lithium metal batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01043D, Paper
Kangning Cai, Mengtian Zhang, Geng Zhong, Guohuang Kang, Jie Biao, Chuang Li, Yanru Liu, Guangmin Zhou, Feiyu Kang, Yidan Cao
Anode-free lithium metal batteries (AFLMBs) are considered as one of the most promising candidates for next-generation high-energy-density rechargeable lithium batteries. An efficient high-current initiated formation strategy is developed for AFLMBs.
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Boosting reaction kinetics of polycrystalline phase Fe7S8/FeS2 heterostructures encapsulated in hollow carbon nanofiber for superior fast sodium storage

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01241K, Paper
Hui Cai, Fei Wang, Huiyan Feng, Zhendong Liu, Chengzhi Zhang, Anbang Lu, Xi Zhao, Qiuhong Lu, Quanbing Liu, Jun Tan
Metal sulfides have been regarded as highly competitive anode materials for fast sodium storage due to the excellent redox reversibility and comparatively great electron properties. Nevertheless, metal sulfides suffer from...
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In situ construction of a double perovskite heterostructure with exsolved FeNi3 alloy nanoparticles for CO2 electrolysis in solid oxide electrolysis cells

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07820E, Paper
Xiaoyu Wang, Haibo Hu, Caiyue Xie, Yifei Wang, Haowei Li, Xifeng Ding
FeNi3 nanoparticles anchored on the (PrBa)0.95Fe1.6Ni0.4O6−δ double perovskite enhance the electrochemical performance and durability in direct CO2 electrolysis.
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Multifunctional buried interface modification for efficient and stable SnO2-based perovskite solar cells

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00108G, Paper
Rui Wu, Junhua Meng, Yiming Shi, Zhengchang Xia, Chunxia Yan, Lisheng Zhang, Wenkang Liu, Jinliang Zhao, JinXiang Deng, Xing Wang Zhang
Buried interface modification with multiple roles is key to boost the performance of perovskite solar cells (PSCs). Herein, a multifunctional passivator, N-(2-hydroxyethyl) ethylene diamine triacetic acid trisodium salt (HEDTA-3Na), is...
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An electrically conducting 3D coronene-based metal–organic framework

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07120K, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Marina I. Schönherr, Patricia I. Scheurle, Laura Frey, Marta Martínez-Abadía, Markus Döblinger, Andre Mähringer, Dominik Fehn, Lena Gerhards, Irina Santourian, Alfred Schirmacher, Tatjana Quast, Gunther Wittstock, Thomas Bein, Karsten Meyer, Aurelio Mateo-Alonso, Dana D. Medina
A novel electrically conducting cubic mesoporous metal–organic framework (MOF), consisting of hexahydroxy-cata-hexabenzocoronene (c-HBC) and FeIII ions is presented.
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Efficient photocatalytic hydrogen evolution based on Z-scheme 2D OV-LaVO4/Mo-doped SV-ZnIn2S4 heterojunctions

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00754A, Paper
Wei Guan, Lin Zhang, Peng Wang, Ying Wang, Haoyu Wang, Xingchen Dong, Liyan Yu, Zhixing Gan, Lifeng Dong, Lina Sui
The purposeful design and construction of two-dimensional (2D) semiconductor heterojunctions offers a promising avenue for achieving efficient photocatalytic activity. However, the challenge of enabling efficient charge migration at the interface...
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Oxygen insertion at the cage center: an unconventional tuning strategy for enhancing the photocatalytic performance of atomically precise copper cluster cocatalysts

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07218E, Paper
Yun-Dong Cao, Di Yin, Ming-Liang Wang, Hong Liu, Yi Feng, Lin-Lin Fan, Cai-Li Lv, Guang-Gang Gao
This work not only confirms the long-standing prediction that the Cu8 center can accommodate an oxygen atom but also demonstrates a novel central atom regulation strategy to obtain highly active copper clusters as photocatalysts.
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