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Heterogenous catalysis for oxygen tolerant photoredox atom transfer radical polymerization and small-molecule dehalogenation

Polym. Chem., 2024, 15,4264-4280
DOI: 10.1039/D4PY00899E, Paper
Open Access
Kriti Kapil, Mingkang Sun, Ting-Chih Lin, Hironobu Murata, Grzegorz Szczepaniak, Khidong Kim, Stephen DiLuzio, Jaepil Jeong, Mitchell Baumer, Stefan Bernhard, Tomasz Kowalewski, Krzysztof Matyjaszewski
Heterogeneous photocatalysts (PCs) have garnered attention for their sustainability and cost-effectiveness.
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Backbone editing of oxidized polyethylene: insertion of oxygen and nitrogen atoms via hydroxyalkyl azide-mediated rearrangements

Polym. Chem., 2024, 15,4554-4561
DOI: 10.1039/D4PY00973H, Paper
Andrew J. King, Ryan P. Sherrier, Jeffrey Aubé, Aleksandr V. Zhukhovitskiy
Hydroxyalkyl azide-mediated rearrangement modularly inserts heteroatoms and pendent functionality into oxidized polyethylene.
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Combined and rapid detection of anti-Brucella IgG/IgM in clinical samples based on surface-enhanced Raman scattering-lateral flow immunochromatography

J. Mater. Chem. B, 2024, 12,11012-11024
DOI: 10.1039/D4TB01367K, Paper
Yongwei Zhang, Ziyue Li, Aolin Zhu, Qian Zhang, Hao Zhou, Xuelei Zhou, Tingwei Liu, Chunyan Liu, Hefei Zha, Xin Zhang, Hui Zhao, Jiutong Li, Guodong Lü, Xinxia Li
Brucellosis is a bacterial infectious disease caused mainly by Brucella. Transmission is mainly by contact with infected domestic or wild animals or their excreta.
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Mitigating intubation stress, mucosa injury, and inflammatory response in nasogastric tube intubation via suppression of the NF-κB signaling pathway by engineering a hydration lubrication coating

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01171F, Paper
Xi Liao, Meng-Han Bai, Yu-Wei Liu, Yu-Qing Wei, Jun-Yang Wang, Zhi-Guo Wang, Rui Hong, Ju-Xiang Gou, Jia-Zhuang Xu, Zhong-Ming Li, Ka Li
The hydrated micelle coating, composed of hyaluronic acid and Pluronic, demonstrated superior hydrophilicity and aqueous lubricity to effectively alleviate mucosal lesions and inflammation caused by NGT insertion.
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3D-printed biomimetic scaffolds loaded with ADSCs and BMP-2 for enhanced rotator cuff repair

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01073F, Paper
Zhonglian Wu, Jian Yang, Hui Chong, Xiaomei Dai, Haidi Sun, Junli Shi, Meijuan Yuan, Dianwei Liu, Mengbo Dang, Hang Yao, Wenyong Fei
The schematic diagram of a 3D-printed biomimetic scaffold applied to tendon–bone interface repair.
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A near-infrared superoxide generator based on a biocompatible indene-bearing heptamethine cyanine dye

J. Mater. Chem. B, 2024, 12,11202-11209
DOI: 10.1039/D4TB01663G, Paper
Nikita Bel’ko, Anna Mal’tanova, Anastasiya Bahdanava, Anatol Lugovski, Sviatlana Fatykhava, Polina Shabunya, Adam Smaliakou, Sergey Poznyak, Tatsiana Kulahava, Michael Samtsov
A heptamethine cyanine dye with an indene moiety and 4-meso-chloride generates superoxide inside cells upon near-infrared photoactivation, inducing cell death.
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At K Sureshkumar’s pedagogical laboratory in Thiruvananthapuram students understand basic concepts of Physics by doing experiments on their own

National award-winning science teacher K Sureshkumar’s pedagogical laboratory in Thiruvananthapuram enables students of high school to conduct experiments in Physics and learn the concepts themselves



  • Life & Style

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‘Real Dictators’ and their regimes of suffering

A riveting podcast charts the making of the men who unleashed carnage on the planet




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Storing liquid chromatographic separations on surface energy traps: decoupling the LC and the mass spectrometer

Analyst, 2024, 149,5336-5343
DOI: 10.1039/D4AN00828F, Paper
Timothy T. Salomons, David Simon, Richard Oleschuk
A micro-fractionation device to archive liquid chromatographic separations on an array of surface energy traps.
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Microfluidic methods for the diagnosis of acute respiratory tract infections

Analyst, 2024, Advance Article
DOI: 10.1039/D4AN00957F, Tutorial Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kan-Zhi Liu, Ganghong Tian, Alex C.-T. Ko, Matthias Geissler, Lidija Malic, Byeong-Ui Moon, Liviu Clime, Teodor Veres
We review emerging methods for the detection of acute respiratory tract infections using microfluidic technologies.
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Ti-based MOF nanosheets as a mass spectrometry imaging matrix for low molecular weight compounds to reveal the spatiotemporal content changes of hepatotoxic components during the processing of Polygonum multiflorum

Analyst, 2024, Advance Article
DOI: 10.1039/D4AN00964A, Paper
Feng-yan Kuang, De-jun Hu, Lu Wang, Fei Chen, Guang-ping Lv
The selection of the matrix is crucial for matrix assisted laser desorption ionization mass spectrometry imaging (MALDI-MSI).
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A time-independent, variational method for studying the photodissociation of triatomic molecules

Phys. Chem. Chem. Phys., 2024, 26,27519-27529
DOI: 10.1039/D4CP02771J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Marco Pezzella, Georgi Mitev, Sergei N. Yurchenko, Jonathan Tennyson, Alexander O. Mitrushchenkov
The photodissociation of molecules is becoming an increasingly important factor to consider in the evolution of exoplanets' atmospheres orbiting around UV-rich stars, as it leads to the enrichment of atmospheric complexity.
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Participation of transition metal atoms in noncovalent bonds

Phys. Chem. Chem. Phys., 2024, 26,27382-27394
DOI: 10.1039/D4CP03716B, Paper
Steve Scheiner
All metals of the d-block are capable of forming σ and π-hole bonds to a nucleophile. Some of these bonds are typical of noncovalent bonds, but others are strong enough to be characterized as a covalent coordinate bond.
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Experimental and theoretical study of the Sn–O bond formation between atomic tin and molecular oxygen

Phys. Chem. Chem. Phys., 2024, 26,27763-27771
DOI: 10.1039/D4CP03687E, Paper
Iakov A. Medvedkov, Anatoliy A. Nikolayev, Shane J. Goettl, Zhenghai Yang, Alexander M. Mebel, Ralf I. Kaiser
In this article, we combine state-of-art electronic structure calculations and crossed beam experiments to expose the reaction dynamics of 120Sn(3Pj) + 16O2(X3Σg) → 120Sn16O(X1Σ+) + 16O(3P) reaction that involve extensive ISC.
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Simulated conformality of atomic layer deposition in lateral channels: the impact of the Knudsen number on the saturation profile characteristics

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP00131A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Christine Gonsalves, Jorge A. Velasco, Jihong Yim, Jänis Järvilehto, Ville Vuorinen, Riikka L. Puurunen
Systematic analysis of saturation profile characteristics allowed development of an extended slope method that relates the slope of the adsorption front to the sticking coefficient for any Knudsen number.
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A theoretical investigation on the OER and ORR activity of graphene-based TM–N3 and TM–N2X (X = B, C, O, P) single atom catalysts by density functional theory calculations

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03779K, Paper
Jiaxiang Wu, Erjun Kan, Cheng Zhan
Promising ORR/OER single atom catalysts have been designed in the form of TM–N2X via DFT simulation.
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Insight into physico-chemical properties of oxalatoborate-based ionic liquids through combined experimental-theoretical characterization

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP02296C, Paper
Open Access
Matteo Palluzzi, Giorgia Mannucci, Akiko Tsurumaki, Matteo Busato, Maria Assunta Navarra, Paola D’Angelo
An anion–anion attraction was inferred from the thermal behavior of oxalate-borate ionic liquids and confirmed through computational methods.
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Mechanistic Insights into CO2 Activation on Pristine, Vacancy-containing and Doped Goldene: A Single-Atom Layer of Gold

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03087G, Paper
Kamal Kumar, Nora Henriette De Leeuw, Jost Adam, Abhishek Kumar Mishra
Goldene, a one-atom-thick gold sheet, is an emerging graphene-like flat 2-dimensional material. In this study, the geometrical and electronic properties, as well as CO2 adsorption characteristics, of the pristine,...
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ato

The local atomic distribution in tetragonal PZT

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03354J, Paper
Jun-Yu Niu, zengzhe Xi, Chong Li
Expanding on the comprehensive research conducted by previous scholars. Herein, to elucidate the intrinsic piezoelectricity of tetragonal Pb(Zr1-xTix)O3 (PZT), we focus on the local atomic distribution which was neglected for...
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Electronic Relaxation Pathways in Thio-Acridone and Thio-Coumarin: Two Heavy-Atom-Free Photosensitizers Absorbing Visible Light

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03720K, Paper
Open Access
Chris Acquah, Sean J. Hoehn, Sarah E. Krul, Steffen Jockusch, Shudan Yang, Sourav Kanti Seth, Eric Lee, Han Xiao, Carlos E. Crespo-Hernández
Heavy-atom-free photosensitizers (HAF-PSs) have emerged as a new class of photosensitizers aiming to broaden their applicability and versatility across various fields of the photodynamic therapy of cancers. The strategy involves...
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High triboelectrification and charge collection efficiency of direct current triboelectric nanogenerator achieved by tri-synergistic enhancement strategy

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03784G, Paper
Shuyan Xu, Jian Wang, Chuncai Shan, Kaixian Li, Huiyuan Wu, Gui Li, Shaoke Fu, Qionghua Zhao, Yi Xi, Chenguo Hu
Direct current triboelectric nanogenerator (DC-TENG) utilized air-breakdown effect to collect triboelectrification charges from dielectric tribo-layers, providing a new type of mechanical energy harvesting mode for TENGs, which has demonstrated its...
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ato

Towards high performance and durable soft tactile actuators

Chem. Soc. Rev., 2024, 53,3485-3535
DOI: 10.1039/D3CS01017A, Review Article
Open Access
Matthew Wei Ming Tan, Hui Wang, Dace Gao, Peiwen Huang, Pooi See Lee
This review assesses diverse strategies to enhance the actuation performance and durability of soft tactile actuators, enabling optimal functionality in real-world conditions.
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Innovative, combinatorial and high-throughput approaches to degrader synthesis

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS01127E, Tutorial Review
Rebecca Stevens, James D. F. Thompson, Julie C. L. Fournier, Glenn A. Burley, David J. Battersby, Afjal H. Miah
In this review we highlight how the synthesis of degraders has evolved in recent years, in particular the application of high-throughput chemistry and screening approaches such as D2B and DEL technologies to expedite discovery timelines.
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On the fundamentals of quantum rate theory and the long-range electron transport in respiratory chains

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00662J, Tutorial Review
Paulo Roberto Bueno
The quantum rate concept v = E/h = c*/L implies relativistic electrodynamics, permitting the transport of electrons in long-range paths of length L and explaining the respiration mechanism if a suitable Boltzmannian statistical setting of E is applied.
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Carlos Sainz — the smooth operator with a hard edge

The 29-year-old returned from emergency appendix surgery to win the Australian GP, remaining the only driver outside Red Bull to triumph since 2022. Out of contract at the end of the season, the Spaniard’s analytical approach and aggressive driving style are set to attract top suitors




ato

INRC Rally of Coimbatore | Aditya Thakur leads the pack on day one




ato

Rally of Coimbatore | No stopping Aditya Thakur




ato

Engineering for curious kids : an illustrated introduction to building machines and amazing structures! / [author: Chris Oxlade ; illustrator: Alex Foster]

Oxlade, Chris, author




ato

All about insects : an illustrated guide to bugs and creepy-crawlies / [author: Polly Cheeseman ; illustrator: Iris Deppe]

Cheeseman, Polly, author




ato

Wild symphony / Dan Brown ; illustrated by Susan Batori

Brown, Dan, 1964- author




ato

It’s a lonely battle for brand aggregators 

Why e-commerce roll-up — banding together smaller online brands for growth — didn’t find strength in numbers 




ato

Supramolecular self-sorting predicted by a simple harmonic oscillator model

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05336B, Communication
Open Access
Adriana Sacristán-Martín, Nerea Álvarez-Llorente, Eric Masson, Alberto Diez-Varga, Héctor Barbero
The self-sorting process of homobimetallic Pt(II) terpyridyl acetylide dimers secured by a pair of Cucurbit[8]uril macrocycles with recognition motif mismatch can be quantified using a model comprising two coupled harmonic oscillators.
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What could be the low-temperature limit of atomic layer deposition of platinum using MeCpPtMe3 and oxygen?

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04679J, Communication
Hao Van Bui, Anh Phan Nguyen, Manh Duc Dang, Truong Duc Dinh, Patricia J. Kooyman, J. Ruud Van Ommen
Room-temperature atmospheric-pressure ALD enables the deposition of highly dispersed Pt sub-nanometer clusters on a gram-scale quantity of TiO2 nanopowder.
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Direct alkene functionalization via photocatalytic hydrogen atom transfer from C(sp3)–H compounds: a route to pharmaceutically important molecules

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05026F, Highlight
Hangqian Fan, Yuxin Fang, Jingbo Yu
Direct functionalization of alkenes with C(sp3)–H substrates offers unique opportunities for the rapid construction of pharmaceuticals and natural products.
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Employing a PhI(OAc)2-mediated domino reaction to assemble nitrogen-containing heterocyclic derivatives and assessing their anti-inflammatory activity

Chem. Commun., 2024, 60,13352-13355
DOI: 10.1039/D4CC03245D, Communication
Xinyue Li, Yuhua Fang, Yuanyuan Zhao, Shenshen Luo, Yuhui Xue, Tingting Yong, Bin Wang
Metal-free radical cascade synthesis of substituted pyrazole derivatives was initiated by PhI(OAc)2 at 23 °C.
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Atomistic insight into the promising thermoelectric performance of the copper-based ternary phosphide CaCuP

Chem. Commun., 2024, 60,13400-13403
DOI: 10.1039/D4CC04660A, Communication
Un-Gi Jong, Chol Ryu, Ji-Min Hwang, Su-Hyang Kim, Il-Gwang Ju, Chol-Jun Yu
We provide a valuable atomistic insight into the thermoelectric properties of hexagonal CaCuP, revealing that nano-structuring can double the thermoelectric figure of merit by further reducing lattice thermal conductivity.
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Metal-free photocatalysts with charge-transfer excited states enable visible light-driven atom transfer radical polymerization

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04470C, Communication
Yuchen Huang, Yangxin Liu, Yingde Yan, Yanjun Gong, Yifan Zhang, Yanke Che, Jincai Zhao
Photoredox-catalyzed atom transfer radical polymerization (O-ATRP) offers powerful tools for the precise control of polymer synthesis. Metal-free photocatalysts are particularly desirable due to their high level of control in O-ATRP...
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Coimbatore’s Kaapi 2.0 offers healthy snacks with strong filter coffee

Kaapi 2.0, a new chain of minimalist cafes in the city, offers healthy snack options to munch on along with filter coffee



  • Life & Style

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Coimbatore’s Karumbukkadai comes alive at iftar

As the city soaks in the spirit of the holy month of Ramzan, we have crispy potato samosas, piping hot kebabs, and refreshing nungu milk for iftar at Karumbukkadai and Podanur



  • Life & Style

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A healthy lunch bowl or gourmet food? Cloud kitchens in Coimbatore offer a diverse menu

From gourmet food, and healthy bowls to vegetarian sushi and experimental cuisines, cloud kitchens in the city are offering intricate culinary experiences. We pick three of them and sample what they offer 



  • Life & Style

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The millet makeover: Nutrihub, ICAR-IIMR’s technology business incubator for millet start-ups is a game changer

Scientists at the Indian Institute of Millet Research are helping start-ups create products, from icecream to beer, with the grain at Nutrihub



  • Life & Style

ato

Unveiling the influence of oxidation state and heavy atom effects in chalcogen group on boron centered D(X)BNA core: a computational study on RTP versus TADF

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00131A, Paper
Ramalingam Mahaan, Murugesan Panneerselvam, Luciano T. Costa, Aruljothy John Bosco
The effects of heavy atoms and oxidation states in chalcogen groups on D(X)BNA cores, combined with substitutions of weak and strong donors, led to the identification of potential TADF and RTP molecules among the 14 molecules.
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Adsorption behavior of chloramphenicol on an activated carbon from pomelo peel using KHCO3 activator

New J. Chem., 2024, 48,7081-7091
DOI: 10.1039/D3NJ05838G, Paper
Haixia Li, Hai Zhu, Junqiang Qiu, Danning Zheng, Lifang Gao, Dan Zhou, Dan Xu
The pomelo peel-based activated carbon as a high-performance adsorbent for chloramphenicol is synthesized by KHCO3 activator through a solid pyrolysis method.
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ato

For the TEAtotaller

Tea is just more than a few leaves in hot water. Startup, Teabox, which ships Indian and Nepalese tea to over 95 countries, has shown what a good cup of the brew can do




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Broadway Cinemas opens in Coimbatore with IMAX Laser and EPIQ Premium Large Format screens

With state-of-the-art laser projection and 12-channel sound with EPIQ premium large format, Broadway Cinemas offers an immersive movie experience




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Coimbatore Reads: A silent reading community to find new books and friends

Coimbatore Reads is one of the many chapters of Cubbon Reads, which has sparked a silent reading movement in several parts of the world




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Construction of a nontoxic nano-pesticide and its co-application with natural predators for perfect cooperative pest management: an innovative strategy for pesticide reduction

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00060A, Paper
Shangyuan Wu, Qinhong Jiang, Chunyang Huang, Hailin Yang, Changhua Zhang, Meizhen Yin, Jie Shen, Shuo Yan, Hu Li
The current study develops a nano-pesticide that is nontoxic toward the predatory stinkbug but with enhanced bioactivity toward the common cutworm, which proposes to co-apply the nano-pesticide with predator as an innovative pest control technique.
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Rapid Synthesis of MXenes and Its Potential Risk to Bacterial Communities in Tomato Rhizosphere

Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D3EN00827D, Communication
cheng chen, Yuchen Liu, Houpu Zhang, Jie Ren, Chao Zhang, Mao Xu, Dan Liu, Yuru Wang, Weiwei Lei, Xiaoli Zhao
As a thriving group of two-dimensional (2D) nanomaterials, MXenes offer tremendous application and development prospects because of their excellent physical and chemical properties. Rhizosphere bacteria colonize the narrow ecosystem region...
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Mg–Al LDH nanosheets as a nanotechnological tool in agriculture: an exploratory toxicity evaluation study

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00733B, Paper
Rafael Salinas-Jiménez, Gloria Vera, Mariola Tobar, Jeimy Moscote, Giovana Acha, Ariel Herrera-Vásquez, Diego Rojas-Rivera, Elena A. Vidal, Andrea Miyasaka Almeida, Manuel Ahumada
The possible toxicity effect of Mg–Al LDH nanosheets was evaluated on some agricultural target organisms. Overall, nanoparticle innocuity was observed at the tested concentrations, showing a low risk of toxicity for its agricultural implementation.
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Introduction of new guest molecules into BEDT-TTF radical-cation salts with tris(oxalato)ferrate

CrystEngComm, 2024, 26,1962-1975
DOI: 10.1039/D4CE00099D, Paper
Open Access
Toby J. Blundell, Elizabeth K. Rusbridge, Rebecca E. Pemberton, Michael J. Brannan, Alexander L. Morritt, Joseph O. Ogar, John D. Wallis, Hiroki Akutsu, Yasuhiro Nakazawa, Shusaku Imajo, Lee Martin
We present the crystal structures of five new BEDT-TTF radical-cation salts with tris(oxalato)ferrate anions using solid or liquid additives toluene, phenol, benzaldehyde, 4-bromobenzaldehyde, and kojic acid.
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