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Turning his lens on musicians

Rajiv Menon talks about how ragas and legends of Carnatic music have inspired him as a filmmaker. Renuka Suryanarayan writes.




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Musician Nadaka on the geet-taar, a string instrument he crafted, and his fascination for Indian classical music

Nadaka says the geet-taar, with its integration of four instruments, helps him play the nuances and micro-tones of Carnatic music.




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India's net direct tax collections surge 15.4 pc to Rs 12.1 lakh crore in April-Nov




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India is leading in AI adoption at 30%, surpassing global average of 26%: BCG report




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Political stability boosts India's apparel appeal for exports




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Smart snacking grows 1.2 times faster than traditional snacks in India




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India's solar product exports record over 20-fold jump to $2 bn in last 2 years




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India's IT spending to reach $160 bn in 2025: Report




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Centre directs officials to speed up resolution of industrial disputes cases




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NN bond cleavage in diazirines by a cyclic diborane(4) compound

Chem. Sci., 2024, 15,18048-18051
DOI: 10.1039/D4SC04980B, Edge Article
Open Access
Minling Zhong, Jie Zhang, Zuowei Xie
Reactions of o-carborane-fused diborane(4) with 3H-diazirines lead to the complete cleavage of the NN bond, with one nitrogen atom being incorporated into the B–B bond.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Spotting d-band centers of single-atom catalysts by oxygen intermediate-boosted electrochemiluminescence

Chem. Sci., 2024, 15,18085-18092
DOI: 10.1039/D4SC03763D, Edge Article
Open Access
Ruyu Xie, Kaitao Li, Rui Tian, Chao Lu
We have proposed an oxygen intermediate-boosted electrochemiluminescence probe for rapid spotting of the d-band centers of single-atom catalysts: the d-band centers closer to the Fermi level contributed to higher luminol ECL intensities.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Reactivities of tertiary phosphines towards allenic, acetylenic, and vinylic Michael acceptors

Chem. Sci., 2024, 15,18111-18126
DOI: 10.1039/D4SC04852K, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Feng An, Jan Brossette, Harish Jangra, Yin Wei, Min Shi, Hendrik Zipse, Armin R. Ofial
Combined experimental and quantum-chemical studies were used to characterise the philicity/fugality features of tertiary phosphines and Michael acceptors in phospha-Michael reactions, which are key steps in phosphine-catalysed organic reactions.
The content of this RSS Feed (c) The Royal Society of Chemistry




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FragGen: towards 3D geometry reliable fragment-based molecular generation

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC04620J, Edge Article
Open Access
Odin Zhang, Yufei Huang, Shichen Cheng, Mengyao Yu, Xujun Zhang, Haitao Lin, Yundian Zeng, Mingyang Wang, Zhenxing Wu, Huifeng Zhao, Zaixi Zhang, Chenqing Hua, Yu Kang, Sunliang Cui, Peichen Pan, Chang-Yu Hsieh, Tingjun Hou
FragGen introduces a novel fragment-based AI-based molecular design method. It proposes the geometry handling protocol to improve the generation quality and has been applied to design highly bioactive type II kinase inhibitors.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Boronic ester-templated pre-rotaxanes as versatile intermediates for rotaxane endo-functionalisation

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC04879B, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jingjing Yu, Marius Gaedke, Satyajit Das, Daniel L. Stares, Christoph A. Schalley, Fredrik Schaufelberger
Dynamic covalent boronic ester bonds can pre-organise diol-containing threads and V-shaped boronic acid ligands towards mechanical interlocking. After interlocking, the pre-rotaxane could be modified to create many unique [2]rotaxanes architectures.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Electrochemical trifluoromethylation of alkynes: the unique role of DMSO as a masking auxiliary

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06780K, Edge Article
Open Access
Jihoon Jang, Ho Seong Hwang, Haeryeong Jeong, Eun Jin Cho
An electrochemical trifluoromethylation method for terminal alkynes has been developed, facilitating the synthesis of CF3-alkynes with DMSO as a masking auxiliary.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Pd(II)-Catalyzed Enantioselective C-H Olefination and Photoregulation of Sterically-Hindered Diarylethenes

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05375C, Edge Article
Open Access
Guanlun Zhang, Xu Wu, Shiyu Mao, Mengqi Li, Honglong Hu, Bing-Feng Shi, Weihong Zhu
Sterically-hindered diarylethenes with intrinsic chirality have shown great potential in chiral signal regulation, light-controlled liquid crystals (LCs), etc. Their unique enantiospecific phototransformation between axial chirality of ring-open isomer and central...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Selective lignin depolymerization via transfer hydrogenolysis using Pd/hydrotalcite catalysts: model compounds to whole biomass

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC03942D, Edge Article
Open Access
Darren Dolan, Rebekah Brucato, Christopher William Reid, Adam F. Lee, Karen Wilson, Adelina M Voutchkova-Kostal
Cleavage of lignin ether bonds via transfer hydrogenolysis is a promising route to valorize lignin, but processes that use mild reaction conditions and exploit renewable hydrogen donor solvents (rather than...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Enantioselective dearomative formal (3+3) cycloadditions of bicyclobutanes with aromatic azomethine imines: access to fused 2,3-diazabicyclo[3.1.1]heptanes

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06334A, Edge Article
Open Access
Xue-Chun Yang, Feng Wu, Wen-Biao Wu, Xu Zhang, Jian-Jun Feng
We present the first enantioselective dearomative (3+3) cycloadditions of bicyclobutanes (BCBs) utilizing a chiral Lewis acid catalyst and bidentate chelating BCB substrates.
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A polymer deposition-mediated surface-charge reformation strategy: reversing the MOF biomineralization behavior

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05935B, Edge Article
Open Access
Yanbin Xu, Huangsheng Yang, Anlian Huang, Linjing Tong, Wei Huang, Guosheng Chen, Wei Yi, Siming Huang, Gangfeng Ouyang
A biocompatible polymer deposition-mediated surface-charge reformation strategy is reported that enables the in-place MOF biomineralization onto different enzyme templates.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Pd/NHC sequentially catalyzed atroposelective synthesis of planar-chiral macrocycles

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05482B, Edge Article
Open Access
Gongming Yang, Shangde Liu, Shujie Ji, Xingsen Wu, Jian Wang
The unprecedented non-enzymatically atroposelective synthesis of planar-chiral macrocycles via a Pd/NHC sequential catalytic intermolecular macrocyclization is reported.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Three in one: engineering MOF channels via coordinated water arrays for regulated separation of alkanes and alkenes

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05286B, Edge Article
Open Access
Lu-Lu Ma, Pavel N. Zolotarev, Kang Zhou, Xin Zhou, Jiaqi Liu, Jiafeng Miao, Shenfang Li, Guo-Ping Yang, Yao-Yu Wang, Davide M. Proserpio, Jing Li, Hao Wang
Regulated adsorptive separation of alkane/alkenes has been achieved through engineering the coordinated water arrays in MOF channels.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Zinc borylation and reduction by a diborane(4) species via B–O bond formation

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06389A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Liam P. Griffin, Simon Aldridge
Zinc boryl and metal–metal bonded Zn(I) complexes can be accessed from a common Zn(II) iodide precursor and bis(pinacolaton)diboron(4).
To cite this article before page numbers are assigned, use the DOI form of citation above.
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CuBr-mediated surface-initiated controlled radical polymerization in air

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06012A, Edge Article
Open Access
Menglu Chen, Shuai You, Tingting Guo, Haohao Ren, Longzu Zhu, Peize Wang, Wenbo Sheng, Chenliang Gong, Wei Li
CuBr-mediated surface-initiated controlled radical polymerization for polymer brushes with patterned and block architectures over large areas in air is reported.
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Understanding ketone hydrogenation catalysis with anionic iridium(III) complexes: The crucial role of counterion and solvation

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04629C, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Paven Kisten, Sandrine Vincendeau, Eric Manoury, Jason Martin Lynam, John M. Slattery, Simon B Duckett, Agusti Lledos, Rinaldo Poli
The catalytic asymmetric hydrogenation of ketones reflect an important way to prepare valuable chiral alcohols. Understanding how transition metals promote these reactions is key to the rational design of more...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Differentiating carrier protein interactions in biosynthetic pathways using dapoxyl solvatochromism

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05499G, Edge Article
Open Access
Matthew G. Miyada, Yuran Choi, Kyle Rich, James J. La Clair, Michael D. Burkart
A highly sensitive solvatochromic system was developed to monitor the loading and interactivity of carrier proteins associated with fatty acid, polyketide and non-ribosomal peptide biosynthesis.
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Photochemical carboborylation and three-component difunctionalization of α,β-unsaturated ketones with boronic acids via tosylhydrazones

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC06537A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Álvaro Valdés-Maqueda, Manuel Plaza, Carlos Valdés
The photochemical carboborylation of α,β-unsaturated tosylhydrazones with boronic acids gives tertiary allylboronates. A one pot sequence involving an aldehyde allylation provides a powerful three-component method for diversity oriented synthesis.
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Synergetic effect of mild hypothermia and antioxidant treatment on ROS-mediated neuron injury under oxygen-glucose deprivation investigated by scanning electrochemical microscopy

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05977H, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Junjie Zhang, Yulin Liu, Yuxiang Zhao, Siyu Zhang, Feng Xu, Fei Li
Ischemic stroke and reperfusion injury result in neuronal damage and dysfunction associated with oxidative stress, leading to overproduction of cellular reactive oxygen species (ROS) and reactive nitrogen species (RNS). In...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Morphology of Lithium Halides in Tetrahydrofuran from Molecular Dynamics with Machine Learning Potentials

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04957H, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Marinella de Giovanetti, Sondre H. Hopen Eliasson, Sigbjørn L. Bore, Odile Eisenstein, Michele Cascella
The preferred structures of lithium halides (LiX, with X = Cl, Br, I) in organic solvents have been the subject of a wide scientific debate, and a large variety of...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Photoactivated hydride therapy under hypoxia beyond ROS

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06576J, Edge Article
Open Access
Xia Wang, Yijian Gao, Ting Wang, Zhaobin Wang, He Hang, Shengliang Li, Fude Feng
As compared to oxidative phototherapy, studies on reactive reductive species-participating photodynamic therapy (PDT) are rare. Porphyrins are typical photosensitizers restricted with oxygen level, but efficacy and selectivity are always uncompatible...
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Spin State Modulation and Kinetic Control of Thermal Contraction in a [Fe2Co2] Discrete Prussian Blue Analogue

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05792A, Edge Article
Open Access
Jyoti Yadav, Sanjit Konar
Stimuli-responsive switchable molecules represent an important category of magnetic materials with significant potential for functional devices. However, engineering complexes with controlled switchability remains challenging due to their sensitivity to lattice...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Food trucking through India

AfterAirlift, Raja Krishna Menon is makingChef, a road movie that explores the flavours in the country




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Industrial yet bespoke

Tucked away in the lanes of Ballard Estate is a roomy new restaurant that typifies the changing spaces in the city, courtesy the team that launched Indigo




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Russian reconnect

The Russian Film Days festival showcases the best of the country’s contemporary cinema and strives to restore lost cinematic ties between the two countries in the aftermath of Perestroika




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Share Market Highlights 18 April 2024: Sensex falls 330 pts, Nifty at 22,000; media, metal stocks shine, FMCG, healthcare drag

Sensex, Nifty updates on 18th April 2024: Equity benchmarks BSE Sensex and NSE Nifty extended losses on Thursday. As per provisional figures, BSE Sensex fell 332.23 pts or 0.46 per cent to trade at 72,611.45 as of 3.35 pm and Nifty 50 declined 103.70 pts or 0.47 per cent to trade at 22,044.20., Bharti Airtel, Power Grid Corp, M&M, BPCL, and Tata Steel were the top gainers, while Nestle, Apollo Hospitals, Axis Bank, HCL Technologies, and ONGC were the major laggards. The stocks that hit a 52-week high on the NSE include AAA Tech (19.33 per cent), Just Dial (12.95 per cent), Indo Tech (10 per cent) and Hi-Tech Gear (10 per cent).




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Should you invest in ICICI Prudential Credit Risk Fund?

Credit risk funds, which invest at least 65 per cent of their portfolio in corporate bonds rated AA or below, offer a shot at high accrual returns




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In debt funds, the focus is on high-quality credit strategies: Rahul Goswami, CIO-India Fixed Income, Franklin Templeton Mutual Fund

Rahul Goswami, CIO &MD - India Fixed Income, Franklin Templeton Asset Management, on what investors can expect on the debt side from the AMC and on his rate cut expectations




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Should you subscribe to the Motilal Oswal Nifty India Defence Index fund NFO?

Exposure to indigenised defence spending through a passive fund




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Mutual Funds and NRIs: If you are a non-resident Indian, here is how you can partake in the India growth story

If you’re a Non-Resident Indian eyeing India’s growth story, here are the basics that matter




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ICICI Prudential Flexicap Fund: A steady outperformer for the long term

ICICI Prudential Flexicap’s performance over the past three years places it in the top-quartile of its category




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Franklin Templeton India makes a debt fund comeback: Should you invest in its ultra short duration NFO?

The ultra short duration scheme is a new offering from the fund house after a long gap




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Sailing vessel INSV Tarini arrives at Fremantle in Australia




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Justice Sanjiv Khanna sworn in as 51st Chief Justice of India




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New CJI Sanjiv Khanna aims to reduce trial duration




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India's first-ever space exercise 'Antariksha Abhyas' begins




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'Namo buddhaya': Kiren Rijiju expresses gratitude on visit to Buddha memorial in Maharashtra's Nashik




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India warns 'least common denominator' model of UNSC reforms could derail major change




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India warns 'least common denominator' model of UNSC reforms could derail major change




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Baku climate talks: India not attending World Leaders Climate Action Summit




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Mass Historia Reviewed by Monsters & Critics

Book Review: Mass Historia
Fiction Book Reviews

Emmy award winning comedy writer Chris Regan has turned his considerable talents to past events and come out with a winner in this uproarious look at 365 days in history. Embellishing facts with liberal doses of light humor, history has never been more entertaining as demonstrated by the January 4 entry celebrating Utah’s statehood that explains how Utah became the forty-fifth state which coincidentally, was the average number of wives enjoyed by most Utah men at the time. Then learn about the army suppression of an uprising of a hoard of Donnie Osmond groupies and the five top Mormon fun facts.

Even better, on June 24, 1997 the U.S. Air Force released their final report on the Roswell incident, a 231-page tome that would prove to be light reading for those who can polish off 251 pages of a Dune novel while awaiting a Star Trek rerun. Or how about the November 15, 1887 entry highlighting the birth of Georgia O’Keeffe with the notation, “After being born, the baby looks up at where she came from, and gets her first-and last-idea for a painting.”

Chock full of fun “facts”, sidebars and irreverently captioned pictures, this is not history as we learned it in school, thank goodness! Regan’s view of history is smart, pointed, frequently not PC but always entertaining. Think History Channel crossed with equal portions South Park and Robot Chicken and you get the general idea.

http://www.monstersandcritics.com/books/fiction/reviews/article_1441330.php/Book_Review_Mass_Historia




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Secrets of the Red Lantern Named Best Asian Cookbook of 2008

Secrets of the Red Lantern: Stories and Vietnamese Recipes from the Heart
by Pauline Nguyen has been named Best Asian Cookbook of 2008 by epicurious.com:


BEST ASIAN
Secrets of the Red Lantern
by Pauline Nguyen (Andrews McMeel Publishing)
Recipe to try: Salt and Pepper Tofu

Whether you want amazingly accessible Vietnamese recipes or just a good, honest family story with food, this Sydney restaurateur delivers. Her family memoir is a great tale of what immigrants both give up and gain in choosing (or not) to pack up and try another country, and if it's not always pretty, it is inspiring, especially with both vintage photos and pictures of the contemporary food Nguyen creates. The book is so beautiful you can almost taste the braised duck with ginger and scallions or the banana fritters.

http://www.epicurious.com/articlesguides/howtocook/cookbooks/bestof2008