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Synthesis of amorphous Geobacter-manganese oxide biohybrid as efficient water oxidation catalysts

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/C9GC04353E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Shafeer Kalathil, Krishna Katuri, Pascal Saikaly
The development of low cost and efficient oxygen evolution reaction (OER) catalyst has paramount importance to meet future sustainable energy demand. Nature’s photosynthetic machinery deploy manganese-based complex in photosystem II...
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Solvent-free hydrogenation of levulinic acid to γ-valerolactone using a Shvo catalyst precursor: optimization, thermodynamic insights, and life cycle assessment

Green Chem., 2020, 22,2443-2458
DOI: 10.1039/C9GC02088H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Christian A. M. R. van Slagmaat, Marie A. F. Delgove, Jules Stouten, Lukas Morick, Yvonne van der Meer, Katrien V. Bernaerts, Stefaan M. A. De Wildeman
We studied the solvent-free hydrogenation of levulinic acid to γ-valerolactone with the Shvo catalyst involving comparative catalysis, DFT, and LCA.
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Ga/ZSM-5 catalyst improves hydrocarbon yields and increases alkene selectivity during catalytic fast pyrolysis of biomass with co-fed hydrogen

Green Chem., 2020, 22,2403-2418
DOI: 10.1039/C9GC03408K, Paper
Kristiina Iisa, Yeonjoon Kim, Kellene A. Orton, David J. Robichaud, Rui Katahira, Michael J. Watson, Evan C. Wegener, Mark R. Nimlos, Joshua A. Schaidle, Calvin Mukarakate, Seonah Kim
An integrated experimental and computational study to understand the catalytic upgrading of biomass vapors into high yield of alkenes.
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Dioxomolybdenum complex as an efficient and cheap catalyst for the reductive depolymerization of plastic waste into value-added compounds and fuels

Green Chem., 2020, 22,2419-2425
DOI: 10.1039/C9GC04206G, Paper
Beatriz F. S. Nunes, M. Conceição Oliveira, Ana C. Fernandes
Several types of PCL, PLA, PDO, PET and PBT plastic waste were efficiently converted into value-added compounds and fuels catalyzed by MoO2Cl2(H2O)2.
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Novel insights into biomass delignification with acidic deep eutectic solvents: a mechanistic study of β-O-4 ether bond cleavage and the role of the halide counterion in the catalytic performance

Green Chem., 2020, 22,2474-2487
DOI: 10.1039/C9GC02569C, Paper
André M. da Costa Lopes, José R. B. Gomes, João A. P. Coutinho, Armando J. D. Silvestre
The potentiality of acidic deep eutectic solvents for β-O-4 ether bond cleavage is herein demonstrated from a mechanistic point of view.
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Efficient base-free oxidation of monosaccharide into sugar acid under mild conditions using hierarchical porous carbon supported gold catalysts

Green Chem., 2020, 22,2588-2597
DOI: 10.1039/C9GC04333K, Paper
Xintong Meng, Zengyong Li, Di Li, Yiming Huang, Jiaojiao Ma, Chuanfu Liu, Xinwen Peng
The highly selective synthesis of D-xylonic acid and D-gluconic acid from monosaccharide catalyzed by Au/NC-3 under base-free aerobic oxidation conditions.
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Direct C(sp3)–H acyloxylation of indolin-3-ones with carboxylic acids catalysed by KI

Green Chem., 2020, 22,2354-2358
DOI: 10.1039/C9GC04446A, Communication
Yong-Long Zhao, Yong-Qin Tang, Xing-Hai Fei, Fen-Fen Yang, Zhuo-Xian Cao, Dong-Zhu Duan, Qing-Jie Zhao, Yuan-Yong Yang, Meng Zhou, Bin He
The first KI-catalyzed direct acyloxylation of indolin-3-ones with carboxylic acids has been developed using 30% aq. H2O2 as a green oxidant at room temperature. Moreover, mechanism studies indicated that a radical oxidation process may be involved for this transformation.
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Synthesis of bioderived polycarbonates with adjustable molecular weights catalyzed by phenolic-derived ionic liquids

Green Chem., 2020, 22,2488-2497
DOI: 10.1039/D0GC00493F, Paper
Wei Qian, Lei Liu, Zengliang Zhang, Qian Su, Weizhen Zhao, Weiguo Cheng, Li Dong, Zifeng Yang, Ruibing Bai, Fei Xu, Yanqiang Zhang, Suojiang Zhang
Phenolic ionic liquid structure can be designed readily to control the molecular weight of isosorbide-derived polycarbonates.
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A non-phosgene process for bioderived polycarbonate with high molecular weight and advanced property profile synthesized using amino acid ionic liquids as catalysts

Green Chem., 2020, 22,2534-2542
DOI: 10.1039/D0GC00265H, Paper
Zhencai Zhang, Fei Xu, Yaqin Zhang, Chenhao Li, Hongyan He, Zifeng Yang, Zengxi Li
Bio-based polycarbonate with high molecular weight and advanced property profile was synthesized using amino acid ionic liquids as catalysts.
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Visible-light-induced photocatalyst-free C-3 functionalization of indoles with diethyl bromomalonate

Green Chem., 2020, 22,2543-2548
DOI: 10.1039/D0GC00292E, Paper
Guangmiao Gu, Mengmeng Huang, Jung Keun Kim, Jianye Zhang, Yabo Li, Yangjie Wu
A visible-light-induced and XB-promoted green approach to construct α-indolyl diethyl malonates was developed.
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Hierarchically porous covalent organic frameworks assembled in ionic liquids for highly effective catalysis of C–C coupling reactions

Green Chem., 2020, 22,2605-2612
DOI: 10.1039/D0GC00223B, Paper
Jikuan Qiu, Huiyong Wang, Yuling Zhao, Pengxin Guan, Zhiyong Li, Hucheng Zhang, Hongshuai Gao, Suojiang Zhang, Jianji Wang
A simple and environmentally benign strategy was reported for the synthesis of hierarchically porous COFs in ionic liquids, and the obtained materials show highly effective catalytic performance for C–C bond formation reactions.
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Solvent-free and montmorillonite K10-catalyzed domino reactions for the synthesis of pyrazoles with alkynylester as a dual synthon

Green Chem., 2020, 22,2388-2393
DOI: 10.1039/D0GC00162G, Communication
Sesuraj Babiola Annes, Rajendhiran Saritha, Saravanan Subramanian, Bhaskaran Shankar, Subburethinam Ramesh
A highly regioselective, solvent-free and montmorillonite K10 clay-catalyzed domino process with an unprecedented C–C bond formation reaction is described for the synthesis of new class of tri-substituted and di-substituted pyrazole derivatives.
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Reusable, homogeneous water soluble photoredox catalyzed oxidative dehydrogenation of N-heterocycles in a biphasic system: application to the synthesis of biologically active natural products

Green Chem., 2020, 22,2575-2587
DOI: 10.1039/D0GC00569J, Paper
S. Srinath, R. Abinaya, Arun Prasanth, M. Mariappan, R. Sridhar, B. Baskar
Herein, a simple and efficient method for the oxidative dehydrogenation (ODH) of tetrahydro-β-carbolines, indolines and (iso)quinolines is described using a reusable, homogeneous cobalt-phthalocyanine photoredox catalyst in a biphasic medium.
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One-pot synthesis of 1,3-butanediol by 1,4-anhydroerythritol hydrogenolysis over a tungsten-modified platinum on silica catalyst

Green Chem., 2020, 22,2375-2380
DOI: 10.1039/D0GC00244E, Communication
Lujie Liu, Takehiro Asano, Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige
Chemical production of 1,3-butanediol from biomass-derived compounds was first reported by 1,4-anhydroerythritol hydrogenolysis over a Pt–WOx/SiO2 catalyst.
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Iridium-catalyzed orthogonal and regioselective synthesis of triazole disulfides in aqueous media under mild conditions

Green Chem., 2020, 22,2394-2398
DOI: 10.1039/D0GC00555J, Communication
Ming Li, Nan Zheng, Junhao Li, Yubin Zheng, Wangze Song
Triazole disulfides were prepared in water or biological media under mild conditions by orthogonal and regioselective Ir-catalyzed reactions.
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Mechanochemical synthesis of mixed metal, mixed linker, glass-forming metal–organic frameworks

Green Chem., 2020, 22,2505-2512
DOI: 10.1039/D0GC00546K, Paper
Michael F. Thorne, María Laura Ríos Gómez, Alice M. Bumstead, Shichun Li, Thomas D. Bennett
Methods to produce glass forming metal–organic frameworks (MOFs) rely on solvothermal syntheses which have high energy requirements, low yields and large teratogenic solvent usage. We present mechanochemical methods to overcome these issues.
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Double-metal cyanide as an acid and hydrogenation catalyst for the highly selective ring-rearrangement of biomass-derived furfuryl alcohol to cyclopentenone compounds

Green Chem., 2020, 22,2549-2557
DOI: 10.1039/C9GC04432A, Paper
Xiang Li, Qiang Deng, Lian Yu, Rui Gao, Zhikun Tong, Chenxi Lu, Jun Wang, Zheling Zeng, Ji-Jun Zou, Shuguang Deng
Herein, novel green synthetic routes to 4-hydroxy-2-cyclopentenone (HCP) and 2-cyclopentenone (CPE) from biomass-derived furfuryl alcohol via double-metal cyanide catalysis are proposed.
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Improving process efficiency of gold-catalyzed hydration of alkynes: merging catalysis with membrane separation

Green Chem., 2020, 22,2598-2604
DOI: 10.1039/D0GC00498G, Paper
Tahani A. C. A. Bayrakdar, Fady Nahra, Oihane Zugazua, Lies Eykens, Dominic Ormerod, Steven P. Nolan
In this report, we investigate the integration of a membrane separation protocol in line with the gold-catalyzed hydration of alkynes.
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Visible Light-Induced Aerobic Oxidation of Diarylalkynes to -Diketones Catalyzed by Copper-superoxo at Room Temperature

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00975J, Communication
Vaibhav Pramod Charpe, Arunachalam Sagadevan, Kuo Chu Hwang
We have developed the visible light induced simple copper(II) chloride catalyzed the oxidation of diarylacetylenes to -diketones by molecular oxygen at room temperature. The in-situ generated copper(II)-superoxo complex is a...
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Computer-aided Nanotoxicology: Risk Assessment of Metal Oxide Nanoparticles via nano-QSAR

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00933D, Paper
Jiakai Cao, Yong Pan, Yanting Jiang, Ronghua Qi, Beilei Yuan, Zhenhua Jia, Juncheng Jiang, Qingsheng Wang
Since the applications of nanomaterials have been expanded to serve as a therapeutic methodology, the cytotoxicity accompanying with the nanomaterials drew lots of attention during the therapeutic process. It is...
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Photocatalytic transfer hydrogenolysis of aromatic ketones using alcohols

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00732C, Paper
Hongji Li, Zhuyan Gao, Lijun Lei, Huifang Liu, Jianyu Han, Feng Hong, Nengchao Luo, Feng Wang
A mild method of photocatalytic deoxygenation of aromatic ketones to alkyl arenes was developed, which utilized alcohols as the green hydrogen donor. No hydrogen evolution during this transformation suggested a...
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Chemoselective O-formyl and O-acyl protection of alkanolamines, phenoxyethanols and alcohols catalyzed by nickel(II) and copper(II)-catalysts

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00520G, Paper
Rahul B. Sonawane, Swapnali R. Sonawane, Nishant K. Rasal, Sangeeta V. Jagtap
A crucial chemoselective O-formyl and O-acyl protection of alkanolamines, phenoxyethanols, and alcohols in the presence of amines catalyzed by Ni(II) and Cu(II) complexes with 8-hydroxyquinoline in a homogeneous medium is achieved.
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Degradation of poly(ethylene terephthalate) catalyzed by metal-free choline-based ionic liquids

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00327A, Paper
Yachan Liu, Xiaoqian Yao, Haoyu Yao, Qing Zhou, Jiayu Xin, Xingmei Lu, Suojiang Zhang
Glycolysis of PET is a prospective way for degradation of PET to its monomer bis(hydroxyethyl)terephthalate (BHET) which can be polymerized again to form new qualified PET materials, and hence provides possibilities for a permanent loop recycling.
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One-step catalytic amination of naphthalene to naphthylamine with exceptional yield

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00633E, Communication
Fang Hao, Xin Wang, Linfang Huang, Wei Xiong, Pingle Liu, Hean Luo
This is the first time to synthesize naphthylamine from one-step naphthalene amination by vanadium catalysts with high yield under mild condition. It could obtain ∼70% yield of naphthylamine, with major product of valuable 1,5-diaminonaphthalene.
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Nickel-catalyzed and Li-mediated regiospecific C–H arylation of benzothiophenes

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00917B, Paper
Yorck Mohr, Gaëlle Hisler, Léonie Grousset, Yoann Roux, Elsje Alessandra Quadrelli, Florian M. Wisser, Jérôme Canivet
A sustainable nickel-catalyzed direct C–H arylation of benzothiophenes, benzofuran and selenophene is reported for the first time.
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Mechanochemical Cleavage of Lignin Models and lignin via Oxidation and Subsequent Base-Catalyzed Strategy

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00372G, Paper
Weike Su, Chen Sun, Lei Zheng, Wenhao Xu, Alexandr V. Dushkin
Mechanochemical cleavage of lignin dimer model compounds to phenolic monomers has been developed via a two-step strategy under milling conditions. In the first step of this process, the secondary benzylic...
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Photocatalytic Hydrogen Atom Transfer: the Philosopher’s Stone for Late-Stage Functionalization?

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC01035A, Tutorial Review
Luca Capaldo, Lorenzo Lafayette Quadri, Davide Ravelli
An overview about the potentialities of photocatalytic Hydrogen Atom Transfer (HAT) for the Late-Stage Functionalization (LSF) of complex molecules is offered. The examined approach allows the smooth homolytic cleavage of...
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MOFs come up to scratch: an environmentally benign route to oxidative [4 + 2] cycloaddition on maleimides solely via MOFs in water

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00619J, Paper
Masoumeh Abbasnia, Mehdi Sheykhan, Mona Bahmani, Parvaneh Taghizadeh
The first Diels–Alder reaction of vinyl arenes with ene systems catalyzed by MOFs is reported.
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Tandem catalytic aromatization of volatile fatty acids

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00964D, Paper
Open Access
Egor V. Fufachev, Bert M. Weckhuysen, Pieter C. A. Bruijnincx
The transition towards a circular economy requires closing the carbon loop, e.g. by the development of new synthesis routes to valuable intermediates and products from organic-rich waste streams.
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Yb(OTf)3 and Visible Light Relay Catalyzed [3+2] Cycloaddition/[3,3]-Rearrangement/[4+2] Cycloaddition in One Pot to Prepare Oxazonine-Fused Endoperoxides

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00929F, Paper
Xiao-Pan Ma, Cai-Mei Nong, Yu-Feng Liang, Pei-Pei Xu, Xiu-Yun GUO, Cui Liang, Chengxue Pan, Gui-Fa SU, Dong-Liang Mo
We report a relay catalysis for the highly stereoselective synthesis of densely substituted oxazonine-fused endoperoxides in good yields. This domino reaction is based on a Yb(OTf)3 and visible light promoted...
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Microwave-assisted aqueous carbon–carbon cross-coupling reactions of aryl chlorides catalysed by reduced graphene oxide supported palladium nanoparticles

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00833H, Paper
Qingxiao Zhang, Zhan Mao, Kaixuan Wang, Nam Thanh Son Phan, Fang Zhang
Microwave-assisted reduced graphene oxide supported palladium nanoparticles can efficiently promote aqueous Ullmann and Suzuki coupling reactions of aryl chlorides.
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Functionalized magnetic nanosized materials for efficient biodiesel synthesis via acid–base/enzyme catalysis

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00924E, Critical Review
Anping Wang, Putla Sudarsanam, Yufei Xu, Heng Zhang, Hu Li, Song Yang
This critical review introduces the preparation methods, structural and performance control, protection, and functionalization of magnetic nanoparticles as easily recyclable and efficient heterogeneous catalysts for biodiesel synthesis.
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Metal-catalysed selective transfer hydrogenation of α,β-unsaturated carbonyl compounds to allylic alcohols

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00855A, Critical Review
Ronald Alvaro Alvaro Farrar Tobar, Andrea Dell'Acqua, Sergey Tin, Johannes G. de Vries
Allylic alcohols are highly important compounds which are used in a variety of processes. They can be obtained from α,β-unsaturated carbonyl compounds via stoichiometric or catalytic reductions. Catalytic transfer hydrogenation...
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Highly efficient oxidation of alcohols to carboxylic acids using a polyoxometalate-supported chromium(III) catalyst and CO2

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00388C, Paper
Ying Wang, ZhiKang Wu, Han Yu, Sheng Han, Yongge Wei
A green and highly efficient oxidation of alcohols to carboxylic acids using a polyoxometalate-supported chromium(III) catalyst and CO2.
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Catalytic C–C coupling of diazo compounds with arylboronic acids: using surface modified sewage sludge as catalyst

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00317D, Paper
Zhipeng Zhang, Yang Yu, Yuxing Xie, Timothy Hughes, Jun Xu, Fei Huang, He Huang
A green, mild and efficient synthesis of diarylmethines using sewage sludge-derived carbonaceous materials (SW) by perchloric acid catalyzed coupling reactions between diazo compounds and arylboronic acids was developed.
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Photoreforming of food waste into value-added products over visible-light-absorbing catalysts

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC01240H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Taylor Uekert, Florian Dorchies, Christian M. Pichler, Erwin Reisner
Food and mixed wastes are converted into H2 and organics over CdS and carbon nitride photocatalysts.
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Photochemical strategies for C–N bond formation via metal catalyst-free (hetero) aryl C(sp2)–H functionalization

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC01088J, Tutorial Review
Qing-Qing Kang, Wenfeng Wu, Qiang Li, Wen-Ting Wei
The development of efficient and mild methods to assemble C–N bonds represents an important and appealing goal in modern synthetic chemistry.
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Photochemical Synthesis of Acetals utilizing Schreiner’s Thiourea as the Catalyst

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC01135E, Paper
Open Access
Nikoleta Spiliopoulou, Nikolaos Nikitas, Christoforos G Kokotos
Acetalization of aldehydes is an area of great importance in Organic Chemistry for both synthetic and biological puproses. Herein, we report a mild, inexpensive and green photochemical protocol, where Schreiner’s...
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Catalyst-Free Photodecarbonylation of 2-Amine Benzaldehyde

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC01256D, Communication
Jingwei Zhou, Lamei Li, Songping Wang, Ming Yan, Wentao Wei
It is almost a consensus that decarbonylation of aldehyde group (-CHO) need to not only be mediated by transition metal catalysts, but also react under severe reaction conditions (high temperature...
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Catalytic production of 1, 4-Pentanediol from furfural in a fix-bed system under mild conditions

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00233J, Paper
QiaoYun Liu, Botao Qiao, Fei Liu, Leilei Zhang, Yang Su, Ai-Qin Wang, Tao Zhang
Furfural is one of the most important biomass-derived chemicals. Its large-scale availability calls for the exploration of new transformation routes for further valorization. Here we report on the direct, one-step...
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Solvent-free ageing reactions of rare earth element oxides: From geomimetic synthesis of new metal-organic materials towards a simple, environmentally friendly separation of scandium

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00454E, Paper
Igor Huskic, Mihails Arhangelskis, Tomislav Friščić
The development of cleaner methodologies for the separation and processing of rare earth elements, including scandium and yttrium, is of high importance to materials science and industry. Here, we explore...
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Archived Webinar - Talent Management - <i>How to Build a Successful Leadership Pipeline</i>

"today's session provided great insight to the importance of developing a formal program and continuous evaluation of the program"

- Susanne McCarroll, Human Resources



Webinar information current as of June 12, 2008

This archived webinar will help you learn techniques and strategies to ensure your company has the leadership it needs in the years ahead. With these skills you can help your business overcome the negativity caused by attrition of senior managers, address the anxieties of managers fast-tracked to senior roles, and tackle problems caused by the loss of intellectual capital and organizational memory. Our goal is to help you manage this transition with a clear strategy and organization.

Learn how to:  

  • Gain insight into your own negotiation style
  • Take necessary steps to effectively prepare for negotiation
  • Negotiate as part of a team
  • Read non-verbal communication
  • Develop skills to influence others
  • Employ key strategies to build trust and gain respect for your ideas
  • Overcome objections and resolve issues
  • Manage difficult interactions and build positive relationships

Speaker

Wayne Rawcliffe, B.A., B.Ed., MBA, CHRP, RODC, is the founder and principal consultant at Senga Consulting Inc. He is recognized for bringing humour, positive energy, creativity and a wealth of ideas to his work with clients in discovering and implementing measureable solutions. As a facilitator, instructor and coach Wayne’s clients benefit from over 25 years of organizational effectiveness experience in improving individual, team and organizational performance. Wayne has worked extensively with all levels of leadership in public, private and not for profit sector organizations to successfully develop and implement organizational improvement initiatives. As an active member of the business community, Wayne is involved with the Vancouver Board of Trade, BC Human Resource Management Association, Vancouver Enterprise Forum, BC Organizational Development Network, High Impact Network and the International Registry of Organizational Development Professionals and is a contributing editor of CCH Canadian Ltd. Ultimate HR Manual, Western Edition.

Format

The following is required to access the archived webinar:

  • Flash Player installed in your computer
  • an Internet connection
  • a sound card

This archived webinar will include:

  • PowerPoint presentation with slides
  • Speaker and facilitator voice-over pres

    If you would like more details about this product, or would like to order a copy online, please click here.




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Forensic psychology reconsidered : a critique of mental illness and the courts / David Polizzi, Matthew Draper

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New perspectives in forensic human skeletal identification / edited by Krista E. Latham, Eric J. Bartelink, Michael Finnegan




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Collateral damage : the impacts of my mother's mental illness on me / Cate Grace

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