Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00042K, Research Article

Xuan Zhang, Qi Teng, Yanru Ren, Baitong Wei, Chen-Ho Tung, Zhenghu Xu
A Rh-catalyzed neighboring group-directed asymmetric [2 + 2 + 2] cycloaddition of 1,6-diynes and ynamides to generate C–N axially chiral indole derivatives has been developed.
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Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00072B, Research Article

Zhi Yang, Hanlin Chen, Linxi Wan, Xinyi Feng, Lingshuang Ma, Pei Tang, Fen-Er Chen
A sustainable synthesis method was developed for long-acting local anesthetics, ropivacaine and levobupivacaine, using both batch and continuous flow processes via asymmetric hydrogenation.
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Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00002A, Research Article

Shu Li, Zhi-Hong Dong, Si-Yu Dan, Mei-Jun Zheng, Teng Long, Jie Zhan, Qing Zhou, Wen-Dao Chu, Quan-Zhong Liu
A chiral bifunctional Brønsted base-catalyzed enantioselective [3 + 2] cycloaddition of D–A cyclopropanes and azadienes is reported. The protocol features broad substrate scope, mild reaction conditions and high functional group tolerance.
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Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00358F, Research Article

Shan Wang, Long Li, Yifei Zheng, Luqing Li, Yingcheng Wang, Fangzhi Peng, Zhihui Shao
Chiral spiropyrazolones were constructed through Pd-catalyzed asymmetric sequential hydroalkylation of 1,3-enynes. Four stereoisomers could be obtained through substrate control and chiral ligand control.
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Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00500G, Research Article

Open Access

  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

Sayan Sarkar, Michael Böck, Agnes Uhl, Aleksandr Agafontsev, Jürgen Schatz, Evgeny A. Kataev
Self-assembly of triangulenium dyes bearing C3-C8 substituents and their interaction with aromatic compounds and cyclophanes were studied in solution.
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Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00246F, Research Article

Jian Ji, Xuwen Chen, Zongjing Hu, Cong Guan, Jinhua Liu, Yaqi Deng, Shunying Liu
Iodine-catalyzed 1,2-thio (seleno)amination of alkenes via direct N- and C-centered radical cross-coupling was established to elicit highly regioselective β-triazolized thioalkyl compounds.
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Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO00453A, Research Article

Shang-Shi Zhang, Jiaohang Wei, Wen-Xuan Zou, Qiong Hu, Mei-Zhu Bao, Dan-Ting Shen, Lin Xiao, Jia-Lin Song, Xiang Liu
The synthesis of unsymmetrical α,α-O,O-substituted ketones via O-H double insertion is appealing but remains constrained due to the lack of compatible coupling partners or uncontrollable selectivity. Herein, we present a...
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Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00184B, Research Article

Jingchuan Lin, Yu Zhang, Jinxin Wang, Xinyu Han, Shenglan Zhu, Tong Li, Yanping Zhu, Wei-Dong Zhang
Herein, we describe a non-covalent complex-mediated epoxidation strategy that can yield highly selective central spiro-epoxides by irradiation with visible light without the need for catalyst addition.
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Org. Chem. Front., 2024, 11,2208-2214
DOI: 10.1039/D4QO00121D, Research Article

Lei Zhang, Kun Wan, Huanhuan Wang, Mengyao Wang, Ao Cui, Xin Huang, Bo Peng
A facile synthesis of benzothiophenes from readily available aryl sulfoxides and allenenitriles has been established through sulfonium-rearrangement triggered cyclization.
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Org. Chem. Front., 2024, 11,2201-2207
DOI: 10.1039/D4QO00125G, Research Article

Pengtao Yang, Dingguo Song, Lingxin Chen, Xianghua Zhao, Yirui Chen, Feiyang Shen, Fei Ling, Weihui Zhong
Highly reactive and highly stereoselective asymmetric hydrogenation of α-F-β-ketone amides (esters) via Ir/f-diaphos-catalyzed dynamic kinetic resolution is reported.
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Org. Chem. Front., 2024, 11,2178-2181
DOI: 10.1039/D4QO00269E, Research Article

Vojtěch Dočekal, Mohand Melaimi, Simona Petrželová, Jan Veselý, Xiaoyu Yan, Guy Bertrand
Chiral NHCs have found numerous applications as ligands for transition metals and in their own right for asymmetric catalysis. We report a synthetic route from L-malic acid to enantiopure 1,2,3-triazoliums with the chiral center in a fused ring.
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Org. Chem. Front., 2024, 11,2313-2318
DOI: 10.1039/D4QO00116H, Research Article

Zhehui Xu, Jianyang Dong, Geyang Song, Fuqiang Kong, Gang Li, Dong Xue
The selective synthesis of primary arylamines and diarylamines via coupling reactions with ammonia as a nitrogen source is still challenging.
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Org. Chem. Front., 2024, 11,2326-2331
DOI: 10.1039/D4QO00064A, Research Article

Ting-Peng Li, Shuixiu Su, Jia-Huan Shen, Meng Zang, Yang-Zi Liu, Quannan Wang, Wei-Ping Deng
An efficient approach for the construction of non-fused azepines in good yields with high enantioselectivity via Pd-catalyzed asymmetric [4 + 3] cycloaddition was developed.
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Org. Chem. Front., 2024, 11,2149-2154
DOI: 10.1039/D4QO90025A, Profile

This profile article showcases researchers who have contributed an article to the Organic Chemistry Frontiers Emerging Investigator Series.
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Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00351A, Research Article

Fei Liu, Fengqing Wang, Qin Li, Bingbing Dai, Weiguang Sun, Jianguo Li, Chunmei Chen, Yonghui Zhang, Hucheng Zhu
Lovastatin derivatives aculeatones A–F (1–6) with lipid-lowering activity were isolated from Aspergillus aculeatus. 1 and 2 represent the first examples with a 6/6/3-tricyclic scaffold and the biomimetic formation of 1 was achieved starting from 3.
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Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO00463A, Research Article

Zhong Zhang, Sirui Wu, Yuqiao Zhou, Bao-Lin Li, Siyue Xiao, Xiaohu Zhao, Zhipeng Yu
An unusual visible light-induced [1, 3]-Brook rearrangement of α-ketoacylsilanes for cascade cyclization with 1,3,5-triazinanes and C,N-cyclic azomethine imines has been developed under catalyst-free and mild reaction conditions. The strategy offers...
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Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00402G, Research Article

Mengyu Gao, Corinne Gosmini
Different allylbenzyl derivatives are synthesized by Co-catalyzed reductive cross-coupling from functionalized benzyl Katritzky pyridinium salts and various allylic acetates, ethers or carbonates in moderate to good yields under mild conditions.
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Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D3QO02101G, Research Article

Yuqing Fu, Yijia Leng, Haotong Bai, Jiaxi Xu, Ning Chen
A highly regioselective oxidative cleavage method has been developed for the synthesis of α,β-unsaturated nitriles from unsymmetric conjugated dienes. This transformation selectively cleaved the terminal C=C double bond, providing moderate...
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Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00356J, Research Article

Bohao Zhang, Sifan He, Na Dong, Antong Zhu, Haojie Duan, Dunjia Wang, Yao Zhou
An unprecedented metal-free divergent cyclization reaction of benzo[c][1,2]dithiol-3-ones with hexahydro-1,3,5-triazines to assemble six- and eight-membered N-containing heterocycles has been developed.
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Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO00506F, Research Article

Chen Chen, Xiao-Xu Zhang, Zi-Yi Wang, Chunjie Ni, Bolin Zhu
We reported a Pd/NBE cooperative catalyzed ortho C−H methylation and trideuteromethylation of arylthianthrenium salts, enabling the efficient synthesis of a wide variety of (trideutero)methylated arenes in moderate to good yields....
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Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00411F, Research Article

Lulu Liu, Jiaqi Hou, Yingying Ma, Hongwei Wang, Yu Zhong, Fangcan Liang, Luyao Wang, Qingling Wang, Ji-Quan Liu, Wen-Hua Xu, Dianhu Zhu
Selective reductive disulfuration of alkyl halides with di/trithiosulfonate reagents was developed through ligand regulation, with key features of broad substrate scope, good tolerance and excellent selectivity to disulfides over trisulfides.
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Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00322E, Research Article

Zhi Yang, Shangxian Luan, Linxi Wan, Jingxi Chen, Xiaofang Wei, Pei Tang, Fen-Er Chen
An iridium-catalyzed asymmetric hydrogenation of 2-esteryl-5-hydroxypyridinium salts is reported, providing chiral cis-5-hydroxypiperidine-2-carboxylates in excellent yields with high levels of enantioselectivities and diastereoselectivities.
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Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03529A, Paper

Open Access

  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.

Xiao Kun Lu, Wenxin Zhang, Brianna N. Ruggiero, Linsey C. Seitz, Jiaqi Li
Our electrochemical production uses carbon-free rocks, water electrolysis, and CO₂ capture/circulation for carbon-neutral/negative cement and green H₂, turning cement from the second-largest industrial CO₂ emitter to a gigaton-scale CCUS enabler.
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Chem. Educ. Res. Pract., 2024, Advance Article
DOI: 10.1039/D4RP00105B, Paper

Jean-Baptiste Ndagijimana, Jeannette Musengimana, Henriette Mushimiyimana, Evode Mukama, Olivier Habimana, Paulin Manirakiza, Jean Claude Dushimimana, Jean Pierre Alpha Munyaruhengeri, Samia Khan, Elizabeth Lakin
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J. Mater. Chem. A, 2024, 12,9173-9183
DOI: 10.1039/D3TA07512E, Paper

Ahsanul Kabir, Victor Buratto Tinti, Simone Santucci, Maxim Varenik, Samuel Griffiths, Sebastian Molin, Igor Lubomirsky, Vincenzo Esposito
Oxygen-defective metal oxides, e.g., acceptor-doped CeO₂, demonstrate exceptionally large electrostrictive responses compared to state-of-the-art electromechanically active ceramic materials.
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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00237G, Paper

Sanjit Mondal, Gabriel Mark, Ayelet Tashakory, Michael Volokh, Menny Shalom
A polymeric carbon nitride layer with controlled directionality, morphology, and nitrogen defects serves as a photoanode to allow photoelectrochemical (PEC) water-splitting and benzylamine oxidation.
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J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00244J, Paper

Open Access

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Jiani Li, Lubing Wang, Jun Xu
Lithium plating is considered an undesirable side reaction due to its potential to induce capacity fade and pose safety concerns in Li-ion batteries. The timely detection of lithium plating onset...
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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00438H, Paper

Hongyuan Shang, Xiaofei Zhang, Aiping Zhang, Jinwen Du, Ruiping Zhang
This study rationally designs a ternary thermoelectric nanocatalyst PtTeCu nanorod for the accurate detection of hydrogen sulfide in biomedical applications.
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J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00629A, Paper

Xintao Long, Yizhou Liu, Dongxin Wang, Yihang Nie, Xiaoyong Lai, Dan Luo, Xin Wang
Zinc ion batteries are expected to be the next generation of rechargeable aqueous metal ion batteries, but their application is limited by its severe dendrite growth caused by inhomogeneous plating...
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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01240B, Paper

Qiong Wan, Jiaxun Zhang, Xuan Liu, Huizhi Li, Abdullah, Taotao Ren, Qiyuan Liu, Yongheng Xu, Jia Liu, Jicheng Liu, Bingqing Yao, Yiyun Fang, Xinzhe Li, Chi He
Atomic restructuring in Pd/Fe₂O₃ catalysts weakens Pd binding to chemisorbed 4-aminophenylacetylene and hydrogen intermediates, boosting conversion and selectivity in 4-aminophenylacetylene semi-hydrogenation, surpassing Pd/C and other catalysts.
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J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00867G, Paper

Kunjie Lou, Yizheng Bao, Jun Chai, Jiyue Wu, Yanshuang Hao, Shaozheng Zhang, Genshui Wang
With the rapid growth of energy storage capacitors in advanced power systems, the pursuit of lightweight is gradually important despite the urgent need for device miniaturization. To reduce the weight...
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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00240G, Paper

Laijun Liu, Kaiyuan Chen, Dawei Wang, Manuel Hinterstein, Anna-Lena Hansen, Michael Knapp, Biaolin Peng, Xianran Xing, Yuanpeng Zhang, Jing Kong, Abhijit Pramanick, Mads Ry Vogel Jørgensen, Frederick Marlton
Local structure information of relaxor ferroelectrics is key to a clear understanding of their structure–property relationships. The size of polar nanoregions is determined based on the local atomic displacement and dielectric response.
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J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00618F, Paper

Chao Li, Lijiang Guan, Jin Zhang, Cheng Cheng, Zhaoqi Guo, Zhihong Tian, Li-Ming Yang, Shangbin Jin
Covalent triazine frameworks (CTFs) of designable nitrogen-rich structures, which can form Schottky Junction with Pt nanoparticles, have been extensively studied in photocatalysis. However, how to tune the interaction inside the...
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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07120K, Communication

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Marina I. Schönherr, Patricia I. Scheurle, Laura Frey, Marta Martínez-Abadía, Markus Döblinger, Andre Mähringer, Dominik Fehn, Lena Gerhards, Irina Santourian, Alfred Schirmacher, Tatjana Quast, Gunther Wittstock, Thomas Bein, Karsten Meyer, Aurelio Mateo-Alonso, Dana D. Medina
A novel electrically conducting cubic mesoporous metal–organic framework (MOF), consisting of hexahydroxy-cata-hexabenzocoronene (c-HBC) and Fe^III ions is presented.
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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00921E, Paper

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Rhys Montecillo, Cheng-Sao Chen, Kuei-Chih Feng, R. R. Chien, Pin-Yi Chen, Chi-Shun Tu
A high-configuration entropy results in the formation of grain boundaries and nanoclusters, which act as barriers for enhancing breakdown strength and energy-storage capability.
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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01475H, Paper

Mitsuharu Chisaka, Jubair A. Shamim, Wei-Lun Hsu, Hirofumi Daiguji
A platinum group metal-free S-doped TiN-supported N, P, S-tridoped TiO₂ catalyst with anatase/rutile TiO₂ hetero-phase junctions is revealed to display a high durability against fuel cell startup/shutdown cycles not to lose its anion dopants.
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J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01317D, Paper

Zihan Wang, Yue Sun, Shenglong Wang, Da Xiong, Guo Tian, Longchao Huang, Boling Lan, Long Jin, Weiqing Yang, Weili Deng
ZnO is a performance-rich material due to its unique coupling of piezoelectricity and semiconductor properties. However, the intrinsic piezoelectric screening effect of ZnO weakens the electromechanical conversion efficiency and greatly...
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J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00988F, Paper

Caiyuan Zhao, Haixia Wang, Lang Li, Liping Liu, Xinrui Cui, Haifeng Shi
A series of sulfonated poly(ether ether ketone) (SPEEK) hybrid membranes (SPEEK/NF) with a constant 1 wt% complexed nanofillers (NF) comprising of UiO-66-NH2 and sulfonated graphitic carbon nitride (s-g-C3N4) are prepared...
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