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Drug-delivery and biological activity in colorectal cancer of a supramolecular porous material assembled from heptameric chromium-copper-adenine entities

J. Mater. Chem. B, 2024, 12,11156-11164
DOI: 10.1039/D4TB01521E, Paper
Sandra Mena-Gutiérrez, Ekain Maiza-Razkin, Jon Pascual-Colino, Marcos J. Araúzo-Bravo, Garikoitz Beobide, Oscar Castillo, Ainara Castellanos-Rubio, Daniela Gerovska, Antonio Luque, Sonia Pérez-Yáñez
Supramolecular metal-organic porous materials as drug delivery systems, modulation of the release kinetics using cholesterol as pore blocking agent and its impact on colorectal cancer cell cultures: cytotoxicity and RNA-seq transcriptomics studies.
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Extracellular matrix mimetic supramolecular hydrogels reinforced with covalent crosslinked mesoporous silica nanoparticles

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB00499J, Paper
Open Access
Aygül Zengin, Shahzad Hafeez, Pamela Habibovic, Matthew Baker, Sabine van Rijt
Here we present a promising strategy to create hybrid, biomimetic supramolecular injectable hydrogels reinforced covalent crosslinked mesoporous silica nanoparticles for tissue engineering applications.
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Jhalak's GLAMOROUS Stars Are Ready To Dance!

If these celeb sightings are anything to go by, the 10th edition of Jhalak Dikhhla Jaa is going to be a visual delight.




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'I was the dangerous person in Bigg Boss'

'They voted me out as they realised that I am not a meethi choori, but a teeki one.'




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A composite of pineapple leaf-derived porous carbon integrated with ZnCo-MOF for high-performance supercapacitors

Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP02882A, Paper
Xiaoxiao Ma, Yunfan Bai, Shuangli Chen, Zhixian He, Pingping Wu, Yabing Qi, Sijing Zhang
Pineapple leaf-derived biochar (PLB) served as a carrier for ZnCo-MOF in the preparation of ZnCo-MOF@PLB-800. The porous structure of PLB reduced ZnCo-MOF aggregation, enhancing electron transfer and the conductivity of the electrode material.
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Catalytic applications of organic–inorganic hybrid porous materials

Chem. Commun., 2024, 60,13325-13335
DOI: 10.1039/D4CC04284K, Feature Article
Maodi Wang, Huicong Dai, Qihua Yang
Insights into the synergistic effects of different active sites of organic–inorganic hybrid porous materials for thermal- and photo-catalysis were discussed.
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Sb nanoparticles embedded uniformly on the surface of porous carbon fibres for high-efficiency sodium storage

Chem. Commun., 2024, 60,13428-13431
DOI: 10.1039/D4CC04806G, Communication
Yafei Zhao, Kai Xue, Xinyu Liu, Zhiyuan Gao, Junhao Zhang, Yuanjun Liu, Xiangjun Zheng, ZhongYao Duan, Qianqian Fan, Xingmei Guo
Sb nanoparticles (∼5 nm) are embedded uniformly on the surface of carbon fibers to prepare Sb NPs–SCFs, which exhibit excellent sodium storage with a stable capacity of 381.9 mA h g−1 at 1.0 A g−1 after 200 cycles, due to their unique structure.
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Bipyridine-based conjugated microporous polymers for boosted photocatalytic U(VI) separation

Chem. Commun., 2024, 60,13348-13351
DOI: 10.1039/D4CC04456H, Communication
Yun Xie, Zifan Li, Chenchen Liu, Qiming Song, Yunhai Liu, Zhibin Zhang, Bin Han
Incorporating bipyridine (BPY) units into conjugated microporous polymers (CMPs) boosts exciton dissociation, charge separation, and oxidation capacity, thereby exhibiting an admired U(VI) separation rate under sacrificial agent-free conditions.
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Ultrafine PtCo alloy nanoparticles integrated into porous N-doped nanosheets for durable oxygen reduction reaction

Chem. Commun., 2024, 60,13432-13435
DOI: 10.1039/D4CC04661G, Communication
Baoliang Chen, Lei Zhao, Zhaozhao Zhu, Pei Xiong, Zhao Li, Jun Song Chen, Lanlan Li, Rui Wu
The PtCo–CoNC–P catalyst, featuring sub-3 nm small-size PtCo alloy nanoparticles integrated into a porous nitrogen-doped nanosheet, exhibits exceptional durability after 30 000 cycles of accelerated durability tests.
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Crafting porous nanoscaled architecture as a potential frontier for drug delivery

Mol. Syst. Des. Eng., 2024, 9,1085-1106
DOI: 10.1039/D4ME00098F, Review Article
Koyeli Girigoswami, Pragya Pallavi, Agnishwar Girigoswami
Porous nanostructures exhibit remarkable nanoplatforms for payload delivery to diseased cells with high loading capacity, favorable release profiles, improved hemocompatibility, biocompatibility, and safe clearance after biodegradation.
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Generous debtors!




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Effect of ammonia addition on dispersion and activity of supported copper species on porous silica-alumina hollow spheres for catalytic decomposition of nitrous oxide

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ00808A, Paper
Tetsuo Umegaki, Takeru Nakamura, Yoshiyuki Kojima
This work investigated influence of ammonia addition in the immersion process of active species on dispersion and activity of copper supported porous hollow silica-alumina spheres catalysts for decomposition of nitrous...
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Metal–organic framework-derived mesoporous Co3O4 with high specific surface area for enhanced xylene sensing

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ01096E, Paper
Liwen Wang, Guanghui Zhang, Ruishu Zhang, Siqi Yang, Wenjuan Huang, Xiangbai Chen
Co3O4 hollow polyhedra have a high specific surface area and mesoporous structure. The Co3O4 gas sensor has excellent sensing performance and selectivity for xylene.
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Mesoporous carbon hollow spheres loaded with Fe/Fe3C as efficient solar vapour generation materials

New J. Chem., 2024, 48,7168-7175
DOI: 10.1039/D4NJ00424H, Paper
Jianfeng Gao, Hui Zhang, Zhaoshun Zhang, Changcheng Lin, Qun Yang, Shiwei Shi, Xueqin Zuo, Shaowei Jin, Guang Li
An evaporator has two major advantages: excellent interfacial evaporation efficiency and organic pollution treatment capacity.
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3D interconnected polymer/mesoporous silica nanoparticle hybrid materials with hierarchical macro/meso-structures for heavy metal adsorption

New J. Chem., 2024, 48,7503-7516
DOI: 10.1039/D3NJ05887E, Paper
Jae-Seo Park, Young Sunwoo, Debabrata Chakraborty, Chamila Gunathilake, Yanhai Du, Eun-Bum Cho
This work offers nanohybrid structures for heavy metal ion adsorption from water, which include a unique 3D cross-linked structure that combines organic polymer chains with mesoporous materials to improve adsorption efficiency.
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Design of Fe and N co-decorated biomass-derived hierarchical porous carbon frameworks with boosted oxidase-like activity for hydroquinone detection

New J. Chem., 2024, 48,7197-7204
DOI: 10.1039/D4NJ00509K, Paper
Han Zhang, Xiaodan Qi, Zhifei Wang, Lihua Jin, Yehua Shen
An Fe and N co-decorated biomass-derived porous carbon framework with boosted oxidase-like activity was prepared and applied to sensitive hydroquinone detection.
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Evaluation of adsorption and degradation performance of lanthanum modified mesoporous carbon nitride composite materials for tetracycline wastewater

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ00864B, Paper
Zhiqiang Wu, Yueyi Li, Pengxi Jiang, Sisi Ma, Wenfei Dong, Hongjian Zhao, Enke Feng, Xuming Wang
The lanthanum modified mesoporous graphite nitride carbon composites (La-g-C3N4) were synthesized using a thermal shrinkage polymerization method. The samples underwent characterization through the X-ray diffraction (XRD), the fourier transform infrared...
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A robust dual-network hydrogel electrolyte coupled with a porous carbon material for flexible quasi-solid-state zinc ion hybrid supercapacitors

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00310A, Paper
Chenchen Ji, Xinhong Lin, Yang Hong, Junfeng Liu, Aoteng Liu, Yijia Yao, Sicheng Liu, Hongyu Mi
A hydrogel electrolyte was designed by constructing a multi-crosslinked network. The quasi-solid-state ZHSC based on the hydrogel electrolyte and HSSPC delivers a high specific capacity, high energy/power densities, and good cycle stability.
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Co-transport of ferrihydrite–organic matter colloids with Sb(V) in saturated porous media: implications for antimony mobility

Environ. Sci.: Nano, 2024, 11,1462-1476
DOI: 10.1039/D3EN00701D, Paper
Wenjian Mao, Dengjun Wang, Pan Wu, Jian Zhu, Peng Liao, Kaidi Lai, Zihan Ding, Yuqin Zhang, Zhongxu He, Ruyi Zheng, Yonglin Chen
Schematic diagram of the mechanism of Fe–NOM–Sb(V) colloids formation and transport in the natural environment.
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Sulfur-doped porous carbon sheets embedded with rich iron sites for 1O2 dominated peroxymonosulfate activation

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00971H, Paper
Yadan Song, Yalong Liu, Yangju Li, Haipeng Hu, Kexin Huang, Zhe Zhang, Zhongxian Li, Wanning Cao, Kai Jiang, Dapeng Wu
Porous carbon films co-doped with iron, nitrogen, and sulfur were synthesized via a one-step pyrolysis process, which have multiple active sites and can produce bulk 1O2 through PMS activation, which is effective in phenol degradation.
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Co-transport of polybromodiphenyl ethers and soil nanoparticles in saturated porous media: implications for the risks of polybromodiphenyl ether spreading in groundwater

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00086B, Paper
Jiameng Liu, Tianchi Cao, Lin Duan, Shengkai Xu, Min Li, Tong Zhang, Wei Chen
This study demonstrates that PBDEs attached to soil nanoparticles can be highly mobile in saturated porous media, providing important insights on risk assessment of PBDEs contamination.
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Thermal fluctuation-induced selective CO2 uptake of seemingly nonporous N,C-protected dipeptide crystals as elucidated by in situ X-ray crystallographic analysis

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01018J, Paper
Kazuaki Yamanaka, Ryusei Oketani, Yuya Mori, Takashi Sato, Seiji Tsuzuki, Hiroki Takahashi, Hirohito Tsue
A novel N,C-protected dipeptide deposited nonporous but yet CO2-sorbing molecular crystals, of which the CO2 sorption state was disclosed.
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On an adventurous quest




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‘Samajavaragamana’ movie review: Sree Vishnu and Naresh shine in this humorous family drama

Director Ram Abbaraju’s ‘Samajavaragamana’ offers plenty of laughs that override the film’s shortcomings. Sree Vishnu and Naresh are a riot




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Electrolyte-dependent HER activity of mesoporous iron-based ZIF-67 leaf-like nanosheets

Mater. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QM00822G, Research Article
Muhammad Faisal Iqbal, Mengjiao Li, Tao Xu, Junchao Lou, Weitao Wang, Jing Zhang, Enlai Hu, Pan Xu
Owing to its greater specific surface area and electrical conductivity, mesoporous nature and leaf-like structure, Fe@ZIF-67-2 showed an overpotential of 45 mV and a Tafel slope of 32 mV dec−1 along with a TOF of 129.35 ms−1 in 1 M KOH.
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Autocomplete Interview - Cole Sprouse Answers the Web's Most Searched Questions

Cole Sprouse takes the WIRED Autocomplete Interview and answers the internet's burning questions about himself. What color are Cole Sprouse's eyes? When did Cole start doing photography? How can you tell the difference between Cole and his brother, Dylan? Cole answers all these questions and much more.




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How a Vet Performs Dangerous Surgeries on Wild Animals

Wildlife veterinarian Romain Pizzi performed the first brain surgery on a bear as well as the first keyhole appendix surgery on an orangutan. He's also anesthetized hundreds of seals. Using hours of his own self-shot footage, let's take a look at how Romain prepares and performs these amazing wildlife surgeries. Director: Anna O'Donohue Director of Photography: Steven Cassidy Editor: Parker Dixon Expert: Romain Pizzi Producer: Katherine Wzorek Line Producer: Joseph Buscemi Associate Producer: Samantha Vélez Production Manager: Eric Martinez Production Coordinator: Fernando Davila Camera Operator: Aidan Black Audio: Simon Tomlinson Production Assistant: Charles Marks Post Production Supervisor: Alexa Deutsch Post Production Coordinator: Ian Bryant Supervising Editor: Doug Larsen Assistant Editor: Diego Rentsch




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Effects of hydrothermal etching and conversion on photocatalytic hydrogen evolution and overall water splitting with nanoparticulate and mesoporous TiO2 and SrTiO3/TiO2 composites

J. Mater. Chem. A, 2024, 12,30768-30782
DOI: 10.1039/D4TA03416C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lion Schumacher, Jana Timm, Roland Marschall
Hydrothermal treatment of mesoporous photocatalysts in diluted NaOH solution or H2O might be a simple and promising strategy to improve photocatalytic activities in general, as we show for TiO2 and SrTiO3/TiO2 composites.
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An all-fibrous, permeable, adhesive, and stretchable self-powered electronic skin for sign language recognition

J. Mater. Chem. A, 2024, 12,30298-30308
DOI: 10.1039/D4TA05825A, Paper
Fan Chen, Xian Song, Jingjing Fu, Jiaheng Liang, Junhua Zhou, Jiehua Cai, Yufei Zhang, Mengjia Zhu, Yichun Ding, Jinxing Jiang, Zijian Chen, Youchao Qi, Zhihao Zhou, Qiyao Huang, Yingying Zhang, Zijian Zheng
An all-fibrous self-powered electronic skin that offers textile-like breathability, intrinsic stretchability, skin adhesion, biocompatibility, and good sensing performance for real-time gesture recognition assisted by machine learning.
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An azo-receptor immobilized mesoporous honeycomb silica framework as a solid-state chromogenic sensor for capturing ultra-trace cadmium ions from environmental/industrial samples

J. Mater. Chem. A, 2024, 12,30567-30581
DOI: 10.1039/D4TA04574B, Paper
Anju P. Veedu, Balasurendran Jeyakumar, Akhila Maheswari Mohan, Satheesh Kuppusamy, Pitchaiah K. Chinaraga, Manjula Muthurathinam, C. V. S. Brahmananda Rao, Sivaraman Nagarajan, Prabhakaran Deivasigamani
A solid-state naked-eye sensor composed of a mesoporous honeycomb structured silica monolith impregnated with a DMTHBD receptor offers a simple, rapid and eco-benign approach for the selective sensing of trace Cd2+, with brilliant color transitions.
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Rational engineering and synthesis of pyrene and thiazolo[5,4-d]thiazole-functionalized conjugated microporous polymers for efficient supercapacitor energy storage

J. Mater. Chem. A, 2024, 12,30508-30521
DOI: 10.1039/D4TA05908E, Paper
Abdul Basit, Yang-Chin Kao, Yasser A. El-Ossaily, Shiao-Wei Kuo, Mohamed Gamal Mohamed
The Py-Th-TzTz CMP was synthesized through a Schiff base reaction and exhibited a decomposition temperature (Td10) of 352 °C. In a three-electrode system, it demonstrated a specific capacitance of 652 F g−1.
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Vertical Macroporous Chitosan Aerogel Adsorbents for Simple and Efficient Enhancement of Atmospheric Water Harvesting and Air Dehumidification

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA07005D, Paper
Zhiguang Guo, Changhui Fu, Yuxuan He, Anhui Yu, Guangyi Tian, Danyan Zhan, Huimin Zhang
Adsorption-based atmospheric water harvesting (SAWH) has become one of the effective methods to extract water from the air in arid regions due to its high efficiency and low energy consumption....
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Dangerous ‘influencers’

The likes of Andrew Tate capitalise on the insecurities of young people




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Cuprous-based layered single-crystalline scintillators for X-ray detection and imaging

J. Mater. Chem. C, 2024, 12,17587-17594
DOI: 10.1039/D4TC03080J, Paper
Yuke Zhao, Danping Chen, Haitao Tang, Hailin Liu, Yong Liu, Yangyang Dang, Qianqian Lin
A new metal halide single crystal (C6H10N2)2Cu2I3(PO2)3 was demonstrated. The optical and X-ray properties of (C6H10N2)2Cu2I3(PO2)3 were fully characterized and evaluated, which demonstrated great potential for X-ray detection and imaging.
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Multidimensionally ordered mesoporous intermetallics: Frontier nanoarchitectonics for advanced catalysis

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D4CS00484A, Tutorial Review
Hao Lv, Ben Liu
This perspective summarizes recent progress in rational design and synthesis of multidimensionally ordered mesoporous intermetallics, and propose new frontier nanoarchitectonics for designing high-performance functional nanocatalysts.
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Lignin-based porous carbon adsorbents for CO2 capture

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D4CS00923A, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Daniel Barker-Rothschild, Jingqian Chen, Zhangmin Wan, Scott Renneckar, Ingo Burgert, Yong Ding, Yi Lu, Orlando J. Rojas
This review covers the state-of-the-art in the production of lignin-based carbon adsorbents for CO2 capture, discussing lignin chemistry and properties, traditional synthesis approaches to emerging methods, and fundamentals for rational design.
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UN Report Warns Nitrous Oxide Emissions Threaten Climate Goals And Public Health Urgently

A new UN report highlights the urgent need to address nitrous oxide emissions, which are accelerating climate change, harming the ozone layer, and posing serious health risks.




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Hierarchical porous dual-mode thermal management fabrics achieved by regulating solar and body radiations

Mater. Horiz., 2024, 11,1760-1768
DOI: 10.1039/D3MH01938A, Communication
Chuntao Lan, Jia Meng, Chongxiang Pan, Luyao Jia, Xiong Pu
A PTM fabric with cooling and heating abilities is achieved by simultaneously regulating solar and body radiations. The hierarchical porous fabric is suitable for various scenarios (e.g., indoors/outdoors, summer/winter, low/high latitude areas).
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Construction of hierarchical porous and polydopamine/salicylaldoxime functional zeolite imidazolate framework-8 via controlled etching for uranium adsorption

Mater. Horiz., 2024, Accepted Manuscript
DOI: 10.1039/D3MH02108D, Communication
Kai Tuo, Jin Li, Yi Li, Chuyao Liang, Cuicui Shao, Weifeng Hou, Zhijian Li, Shouzhi Pu, Chunhui Deng
Efficient uranium extraction from seawater is critical for developing the nuclear industry. Herein, a polydopamine/salicylaldoxime decorated hierarchical zeolite imidazolate framework-8 (H-PDA/SA-ZIF-8) is constructed by using a controlled etching process. Benefiting...
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Engineering a hollow bowl-like porous carbon-confined Ru–MgO hetero-structured nanopair as a high-performance catalyst for ammonia borane hydrolysis

Mater. Horiz., 2024, 11,2032-2040
DOI: 10.1039/D3MH01909H, Communication
Jialei Yang, Zhenyu Yang, Jiafu Li, Hao Gang, Donghai Mei, Dongming Yin, Ruiping Deng, Yifeng Zhu, Xingyun Li, Ning Wang, Sameh M. Osman, Yusuke Yamauchi
A sub-nano interfacial catalytic structure is orchestrated by tailor-designing a hollow bowl-like porous carbon-confined Ru–MgO hetero-structured nanopair as a high-performance catalyst for ammonia borane hydrolysis.
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Exploring the Mpemba effect: a universal ice pressing enables porous ceramics

Mater. Horiz., 2024, 11,1899-1907
DOI: 10.1039/D3MH01869E, Communication
Open Access
Xiaodan Yang, Yao Shan, Ying Hong, Zhuomin Zhang, Shiyuan Liu, Xiaodong Yan, Xuetian Gong, Guangzu Zhang, Zhengbao Yang
A unique technique of “ice and fire” is proposed, that is, manipulation of force via water freezing (ice) and high-temperature sintering (fire) to fabricate ideal porous ceramics.
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Correction: Exploring the Mpemba effect: a universal ice pressing enables porous ceramics

Mater. Horiz., 2024, 11,2041-2042
DOI: 10.1039/D4MH90030H, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xiaodan Yang, Yao Shan, Ying Hong, Zhuomin Zhang, Shiyuan Liu, Xiaodong Yan, Xuetian Gong, Guangzu Zhang, Zhengbao Yang
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Rouse Hill Times [electronic journal].

News Ltd Australia




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Productivity Dispersion and Persistence Among the World's Most Numerous Firms [electronic journal].

National Bureau of Economic Research




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Rapid Joule heating synthesis of Ni doped into porous honeycomb C3N4 with greatly improved photocatalytic H2 production

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00225C, Research Article
Zehui Zhao, Guangmin Ren, Zisheng Zhang, Xiangchao Meng, Zizhen Li
Photocatalytic water splitting is one of the sustainable and environmentally-friendly methods for producing hydrogen.
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NH3 plasma-etching-derived porous N-doped carbon nanotubes with FeP nanoparticles and intrinsic carbon defects for boosting oxygen reduction in rechargeable Zn–air batteries

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00182F, Research Article
Bing Chen, Minjie Zhou, Na Zhang, Xianglin Deng, HaiHua Yang
The formation of intrinsic carbon defects and phase engineered FeP nanoparticles regulated by NH3 plasma etching significantly enhanced the oxygen reduction reaction performance of N-doped carbon nanotubes.
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Solar heating catalytic formic acid dehydrogenation by graphene-porous foam-supported tungsten nitride nanoparticles

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00590B, Research Article
Jiarong Chang, Tianhua Hao, Cuncai Lv, Maoyu Xu, Deyi Zhang, Linjie Gao, Shangbo Ning, Yaguang Li, Jinhua Ye
WN/Gr PF exhibits significant solar heating catalytic formic acid dehydrogenation and the rate exceeds those of other reported photocatalysts.
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Porous liquids: an integrated platform for gas storage and catalysis

Chem. Sci., 2024, 15,17720-17738
DOI: 10.1039/D4SC04288C, Perspective
Open Access
Errui Li, Kevin M. Siniard, Zhenzhen Yang, Sheng Dai
In this perspective, recent discoveries in the integration of gas storage and catalysis by leveraging PL platforms have been summarized, highlighting the unique features different from those of traditional homogeneous or heterogeneous procedures.
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Direct detection of dithiocarbamate fungicides by SALDI/MS using porous TiC ceramic powder as a substrate

Anal. Methods, 2024, Advance Article
DOI: 10.1039/D3AY01533E, Paper
Hiroshi Moriwaki, Issey Osaka, Kotaro Hashimoto, Osamu Yamada
Direct detection of dithiocarbamate fungicides (DTCs) has been achieved by SALDI/MS using porous titanium carbide (TiC) ceramic powder as a substrate.
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