A porous silica material in which silica particles are connected to one another three-dimensionally, wherein: the porous silica material includes a through hole including first pores smaller than a mean free path of an air, and second pores larger than the first pores; the porous silica material has a density of 100 kg/m3 or more and 300 kg/m3 or less; and an isobutyl group is bound to silicon of silica of the silica particles.

Process for obtaining lithium carbonate directly from the mineral containing silicium, aluminum, lithium and other metal oxides without the need to dissolve previously all oxides in sulphuric acid or alkaline hydroxides at high temperatures and pressures, by using carbon dioxide and water at supercritical or near supercritical conditions acting directly on the fine powder of the mineral.

Provided is an aggregate of carbon nanotubes wherein a mixture of 10 mg of aggregate of carbon nanotubes, 30 mg of sodium polystyrene sulfonate and 10 mL of water is subjected to ultrasonic homogenizer treatment, subsequently subjected to centrifugal treatment at 20000 G, then 9 mL of supernatant is sampled, and the content of aggregate of carbon nanotubes in the supernatant is 0.6 mg/mL or more. The aggregate of carbon nanotubes of the present invention can provide a dispersion of an aggregate of carbon nanotubes having a high concentration through very good dispersibility.

A system and method for manufacturing carbon nanotubes using chemical vapor deposition. The system has a first chamber comprising at least one cathode and at least one anode, a gas supply source, at least one activation energy source, at least one alignment energy source, a second chamber situated within said first chamber, said second chamber comprising: a target growth plate, comprising a catalyst and a substrate, a second cathode configured to support said target growth plate, a movable platform configured to support said second cathode, and a gas permeable barrier vertically opposed from said second cathode.

The invention relates to a process and apparatus for recovering sulfur (9). In a sour gas scrubbing apparatus (S) comprises a scrubbing part (SP) and a regeneration part (RP), wherein sulfur components and carbon dioxide are selectively removed from a crude synthesis gas (2) with the aid of a circulating scrubbing agent (3). A sulfur-containing gas fraction (8) produced during the regeneration of loaded scrubbing agent is supplied to a sulfur recovery system (SR) in which an off-gas (10) comprising carbon dioxide and also sulfur components is formed. The off-gas is hydrogenated (H) and subsequently subjected to a gas scrubbing operation (Z). The hydrogenated off-gas (12) is scrubbed, independently of the crude synthesis gas (2), and scrubbing agent (13) removed from the scrubbing agent circuit of the sour gas scrubbing apparatus (S) is used to scrub out sulfur components from the hydrogenated off-gas (12).

The present invention provides a catalyst for generating hydrogen containing at least one composite metal selected from the group consisting of a composite metal of platinum and nickel and a composite metal of iridium and nickel, the catalyst being used in a decomposition reaction of at least one compound selected from the group consisting of hydrazine and a hydrate thereof; and a method for generating hydrogen, including contacting the catalyst for generating hydrogen with at least one compound selected from the group consisting of hydrazine and a hydrate thereof. According to the invention, hydrogen can be efficiently generated with improved selectivity in the method for generating hydrogen that utilizes the decomposition reaction of hydrazine.

The present invention relates to an organotemplate-free synthetic process for the production of a zeolitic material comprising YO2 and X2O3, wherein said process comprises the steps of (1) preparing a mixture comprising seed crystals, one or more sources for YO2, one or more sources for X2O3, and one or more solvents;(2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material comprising YO2 and X2O3 as a crystallization product; wherein Y is a tetravalent element, and X is a trivalent element, and wherein at least a portion of the mother liquor obtained in step (2) is recycled to step (1) as a source for YO2, optionally after concentration of the mother liquor.

The invention relates to a catalytic reactor including: at least one first architecture/microstructure including a ceramic and/or metal cellular architecture having a pore size of 2 to 80 ppi and a macroporosity of more than 85%, and a microstructure having a grain size of 100 nm to 5 microns, and skeleton densification of more than 95%, and a catalytic layer; and at least one second architecture/microstructure including a spherical or cylindrical architecture having a pore size of 0.1 to 100 μm and a macroporosity of less than 60%, and a microstructure having a grain size of 20 nm to 10 μm and a skeleton densification of 20% to 90%, and a catalytic layer; the first and second architecture/microstructure being stacked inside said reactor.

The present invention is directed to a hybrid process using ion exchange resins in the selective recovery of nickel and cobalt of leaching effluents that is comprised of the steps of processing (1) the laterite ore (M), which is then treated through leaching (2) (either atmospheric or under pressure), considering solutions from the solid-liquid separation step of existing plants already in operation (2) as well, in a way that the downstream process comprises an ion exchange hybrid circuit, wherein the first ion exchange step (3) with resins (Re) exhibits specific selectivity conditions for the removal of iron, aluminum and copper and an increased pH, and the second ion exchange step (4) allows the removal of nickel and cobalt.

A system and method scrub a vapor. In embodiments, a vacuum truck scrubber system includes a liquid vat, a first carbon canister, a second carbon canister, and a third carbon canister. The first carbon canister and the second carbon canister each contain carbon. The liquid vat is connected to the first carbon canister. The first carbon canister is connected to the second carbon canister. A vapor having contaminants is fed to the liquid vat and is introduced from the liquid vat to the first carbon canister wherein a portion of the contaminants is removed from the vapor. The vapor is introduced from the first carbon canister to the second carbon canister wherein another portion of the contaminants is removed. The vacuum truck scrubber system also includes a monitoring system for reading and recording of sample measurements in the first carbon canister, the second carbon canister and the third carbon canister.

A ferrous sulfide suspension that includes at least FeSm and Al(OH)3 and which can be used to reduce mercury emissions in flue gases. Through a combination of complex chemical reactions, precipitation, co-precipitation, and surface adsorption the ferrous sulfide suspension of the present invention effectively removes mercury from gaseous streams while concurrently preventing mercury re-emission.

An exhaust system for a compression ignition engine comprising an oxidation catalyst for treating carbon monoxide (CO) and hydrocarbons (HCs) in exhaust gas from the compression ignition engine, wherein the oxidation catalyst comprises: a platinum group metal (PGM) component selected from the group consisting of a platinum (Pt) component, a palladium (Pd) component and a combination thereof; an alkaline earth metal component; a support material comprising a modified alumina incorporating a heteroatom component; and a substrate, wherein the platinum group metal (PGM) component, the alkaline earth metal component and the support material are disposed on the substrate.

Described are catalyst compositions, catalytic articles, exhaust gas treatment systems and methods that utilize the catalytic articles. The catalyst composition comprises a washcoat including a zeolite, refractory metal oxide support particles, and a platinum group metal supported on the refractory metal oxide support particles. Greater than 90% of the refractory metal oxide particles supporting PGM have a particle size greater than 1 μm and a d50 less than 40 microns.

A CO2 amine scrubbing process uses an absorbent mixture consisting of an alkanolamine CO2 sorbent in combination with a non-nucleophilic base. The alkanolamine has oxygen and nitrogen sites capable of nucleophilic attack at the CO2 carbon atom. The nucleophilic addition is promoted in the presence of the non-nucleophilic, relatively stronger base, acting as a proton acceptor. The non-nucleophilic base promoter, which may also act as a solvent for the alkanolamine, can promote reaction with the CO2 at each of the reactive hydroxyl and nucleophilic amine group(s) of the alkanolamines. In the case of primary amino alkanolamines the CO2 may be taken up by a double carboxylation reaction in which two moles of CO2 are taken up by the reacting primary amine groups.

A method for extending the service life of a Collective Protection (CP) filter includes: providing at least one CP filter comprising a filter bed; and passing an airstream through a guard bed configured to protect the filter bed by removing one or more of airborne contaminants and battlefield contaminants. An apparatus for extending the service life of a CP filter includes: a CP filter comprising a filter bed; and a guard bed configured to protect the filter bed by removing one or more of airborne contaminants and battlefield contaminants.

An object the invention is to provide a phosphorus pentafluoride producing process wherein phosphorus pentafluoride is separated/extracted from a pentavalent phosphorus compound or a solution thereof, or a composition obtained by allowing the pentavalent phosphorus compound or the solution thereof to react with hydrogen fluoride, thereby producing phosphorus pentafluoride; and a phosphate hexafluoride producing process wherein the resultant phosphorus pentafluoride is used as raw material to produce a phosphate hexafluoride high in purity. The present invention relates to a process for producing phosphorus pentafluoride, wherein a carrier gas is brought into contact with either of the following one: a pentavalent phosphorus compound, a solution thereof, or a solution in which a composition obtained by allowing the pentavalent phosphorus compound or the solution thereof to react with hydrogen fluoride is dissolved, thereby a phosphorus pentafluoride is extracted into the career gas.

A storage material for obtaining H-silanes which is present in the form of a hydrogenated polysilane (HPS), as a pure compound or as a mixture of compounds having on average at least six direct Si—Si bonds, the substituenis of which predominantly consist of hydrogen and in the composition of which the atomic ratio of sabstitueot to silicon is at least 1:1.

An apparatus for producing disilane through pyrolysis of monosilane, includes: a monosilane pyrolysis unit; a solid particle removal unit which removes solid particles generated in the pyrolysis unit; a condensing unit which liquefies and collects unreacted monosilane, and disilane and higher silanes with three (3) to seven (7) silicon atoms as pyrolysis products excluding hydrogen from a gas with the solid particles removed; a first separation unit which separates monosilane from a mixture of the liquefied unreacted monosilane, disilane and higher silanes; and a second separation unit which separates disilane and higher silanes from the mixture with the monosilane removed. In accordance with the present disclosure, disilane can be produced economically and efficiently with high purity through pyrolysis of monosilane.

Process for preparing hydrocyanic acid by catalytic dehydration of gaseous formamide, wherein the dehydration of formamide is coupled with an exothermic reaction by the reactor used in the dehydration comprising two separate fluid paths which are separated by a common reactor wall, with one fluid path being provided for the dehydration of formamide and the second fluid path being provided for the exothermic reaction.

This invention relates to a method for the preparation of lithium carbonate from lithium chloride containing brines. The method can include a silica removal step, capturing lithium chloride, recovering lithium chloride, supplying lithium chloride to an electrochemical cell and producing lithium hydroxide, contacting the lithium hydroxide with carbon dioxide to produce lithium carbonate.

This invention relates to a method for the preparation of lithium carbonate from lithium chloride containing brines. The method can include a silica removal step, capturing lithium chloride, recovering lithium chloride, supplying lithium chloride to an electrochemical cell and producing lithium hydroxide, contacting the lithium hydroxide with carbon dioxide to produce lithium carbonate.

The present invention relates to an HPHT method for synthesizing single crystal diamond, wherein a single crystal diamond seed having an aspect ratio of at least 1.5 is utilized. Single crystal diamond seeds having an aspect ratio of at least 1.5 and synthetic single crystal diamond which may be obtained by the method recited are also described. The growth surface is substantially aligned along a or direction in the plane of the growth surface.

A process for the production of nano-structures is presented, involving providing a graphite flake comprising graphene layers; intercalating the graphite flake to form a graphite intercalation compound exhibiting Stage I, II or III intercalation; and exfoliating the graphite intercalation compound by exposing it to a temperature between about 1600° C. and about 2400° C. such that a plurality of individual graphene layers are separated from the graphite intercalation compound.

Embodiments presented herein relate generally to the formation of diamond-like carbon, forms of diamond-like carbon and/or carbon dioxide fixation.

One embodiment of the present invention is a unique fuel cell system. Another embodiment is a unique desulfurization system. Yet another embodiment is a method of operating a fuel cell system. Other embodiments include apparatuses, systems, devices, hardware, methods, and combinations for fuel cell systems and desulfurization systems. Further embodiments, forms, features, aspects, benefits, and advantages of the present application will become apparent from the description and figures provided herewith.

A disclosed thermal treatment apparatus includes a supporting member where plural substrates are supported in the form of shelves; a reaction tube that accommodates the supporting member within the reaction tube, and is provided with plural gas supplying pipes arranged in a side part of the reaction tube, thereby allowing a gas to flow into the reaction tube through the plural gas supplying pipes; and a first heating part that heats the plural substrates supported by the supporting member accommodated within the reaction tube, wherein the first heating part includes a slit that extends from a bottom end to a top end of the first heating part and allows the plural gas supplying pipes to go therethrough, and wherein an entire inner surface, except for the slit, of the heating part faces the side part of the reaction tube.

A production process for composite oxide expressed by a compositional formula: LiMn1-xAxO2, where “A” is one or more kinds of metallic elements other than Mn; and 0≦“x”

A three way catalyst includes an extruded solid body having by weight: 10-100% of at least one binder/matrix component; 5-90% of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more thereof; and 0-80% optionally stabilised ceria. The catalyst also includes at least one precious metal and optionally at least one non-precious metal, wherein: (i) the at least one precious metal is carried in one or more coating layer(s) on the body surface; (ii) at least one metal is present throughout the body and at least one precious metal is carried in one or more coating layer(s) on a body surface; or (iii) at least one metal is present throughout the body, is present in a higher concentration at a body surface, and at least one precious metal is carried in one or more coating layer(s) on the body surface.

The invention relates to a method for cleaning exhaust gases, in which an exhaust gas and a sorbent are combined in a fluidized bed reactor. In a subsequent filter system, solid matter is segregated, and thereafter, up to 99 per cent of the sorbent is re-channeled into the fluidized bed reactor, wherein the gas is subjected to a rotation around the flow axis in the fluidized bed reactor.

The present invention relates to a method for removal of SO2 from exhaust gas from a marine engine or a marine boiler of a ship. The exhaust gas from said marine engine or marine boiler is cooled and washed with seawater in a first scrubber section, and subsequently, in a second scrubber section, washed with circulating freshwater with an addition of an alkaline chemical. The circulating freshwater used for washing is warmer than the seawater used for cooling in the first scrubber section. The warmer freshwater is indirectly heat exchanged with cold seawater. The exhaust gas washed in the first scrubber section is passed via a demister unit before it is washed with circulating freshwater in the second scrubber section. The invention further relates to a corresponding scrubber system.

Provided is a catalyst article for simultaneously remediating the nitrogen oxides (NOx), particulate matter, and gaseous hydrocarbons present in diesel engine exhaust streams. The catalyst article has a soot filter coated with a material effective in the Selective Catalytic Reduction (SCR) of NOx by a reductant, e.g., ammonia.

In one embodiment, a catalyst for ozone oxidation of pollutant components dispersed in a gas is provided. The ozone oxidation catalyst has a porous body formed from a metal body, a ceramic, or polymeric fibers coated with metal. A catalytic noble metal composition is deposited on the surface of the porous body. The catalytic noble metal composition is formed from particles of a noble metal supported by a mesoporous molecular sieve.

Apparatus and method for removal of particles and VOC from an airstream, in which particles carried by the airstream are charged by a corona ionizer and then collected by an electrically enhanced filter downstream of the ionizer. A catalytic filter downstream of the electrically enhanced filter removes VOC as well as ozone generated by the ionizer.

Kinetically stable halogenated polysilanes include mixture of compounds having respectively at least four silicon atoms bound together, the substituents thereof comprising chlorine, and chlorine and hydrogen, and in the composition thereof, the atomic ratio of substituent to silicon is at least 1:1, wherein a) the kinetically stable halogenated polysilanes have a kinetically high stability in relation to oxidative splitting by chlorine, and the degree of conversion at temperatures of 120° C. within 10 hours with an excess of chlorine gas at 1013 hPa does not exceed 30 mol %, and b) the kinetically stable halogenated polysilanes have a percentage of branching points in the polysilane molecules of more than 8 mol %.

The present disclosure provides an apparatus for manufacturing a single crystal silicon ingot having a dual crucible for silicon melting which can be reused due to a dual crucible structure. The apparatus includes a dual crucible for silicon melting, into which raw silicon is charged, a crucible heater heating the dual crucible to melt the raw silicon into molten silicon, a crucible drive unit controlling rotation and elevation of the dual crucible, and a pull-up drive unit disposed above the dual crucible and pulling up a seed crystal dipped in the molten silicon to produce a silicon ingot. The dual crucible has a container shape open at an upper side thereof, and includes a graphite crucible having an inclined surface connecting an inner bottom and an inner wall, and a quartz crucible inserted into the graphite crucible and receiving the raw silicon charged into the dual crucible.

The present invention concerns a process for producing ammonia synthesis gas from the reforming of hydrocarbons with steam in a primary reformer (1) equipped with a plurality of externally heated catalytic tubes and then in a secondary reformer (2) together with an oxidant gas. In this process, the reaction of said hydrocarbons with said steam in said primary reformer (1) is performed at an operating pressure of at least 45 bar in the catalytic tubes and a flow of essentially pure oxygen or oxygen-enriched air is added to said secondary reformer as oxidant gas for substantially reforming together with said all the hydrocarbons content of said product gas exiting the primary reformer (1). In the case essentially pure oxygen is used as oxidant gas, a flow of nitrogen is added downstream the secondary reformer (2) to reach a N2/H2 molar ratio corresponding to or close to the stoichiometric ratio for ammonia synthesis. This process allows to obtain high synthesis gas production capacities and lower investment and energy costs.

System and method for sustainable economic development which includes hydrogen extracted from substances, for example, sea water, industrial waste water, agricultural waste water, sewage, and landfill waste water. The hydrogen extraction is accomplished by thermal dissociation, electrical dissociation, optical dissociation, and magnetic dissociation. The hydrogen extraction further includes operation in conjunction with energy addition from renewable resources, for example, solar, wind, moving water, geothermal, or biomass resources.

A method of preparing functionalized graphene, comprises treating graphene with an alkali metal in the presence of an electron transfer agent and coordinating solvent, and adding a functionalizing compound. The method further includes quenching unreacted alkali metal by addition of a protic medium, and isolating the functionalized graphene.

Providing a roaster that operates at temperatures in the range of 800° Celsius to 2000° Celsius with inert, optional oxidizing and reducing gases to treat graphite contaminated with radionuclides including tritium, carbon-14, and chlorine-36. The combination of temperatures and gases allow for the removal of most to substantially all the carbon-14 within the graphite while substantially limiting gasifying the bulk graphite.

Provided are a method for post-treatment of a carbonaceous material using dehydrocyclization, a carbonaceous material post-treated by the method, and a polymer composite material including the carbonaceous material. More particularly, provided are a method for post-treatment of a carbonaceous material using dehydrocyclization, including subjecting the carbonaceous material to dehydrocyclization at room temperature to heal structural defects in the carbonaceous material, while increasing the effective conjugated length of the carbonaceous material to improve the electrical conductivity thereof, as well as a carbonaceous material post-treated by the method and a polymer composite material including the carbonaceous material.

A semi-continuous process and system thereof, for the synthesis of a narrow particle size distribution Zeigler Natta procatalyst for use in the manufacture of polyolefins. The process comprises: (a) mixing a reaction mixture containing a titanium compound; (b) charging a first reactor with said reaction mixture; (c) removing excess reactants from said first reactor as a filtrate; (d) feeding said filtrate to at least one further reactor; and continuously removing excess reactants from said at least further reactor.

The present invention relates to a method of preparing a spherical mesoporous silica structure containing silver nanoparticles dispersed therein by adding a silver nitrate solution to an aqueous surfactant solution and performing a sol-gel process and to spherical mesoporous silica prepared thereby. The spherical mesoporous silica is cost-effective compared to a conventional method that uses silver nanoparticles as a raw material, because the silver nitrate solution that is inexpensive compared to silver nanoparticles is used. Also, the spherical mesoporous silica can be with high productivity in large amounts, and thus is easily commercialized. Moreover, because silver nanoparticles are incorporated into the pores of the mesoporous silica, the silver nanoparticles are used stably and do not change color and odor. In addition, the spherical mesoporous silica exhibits various additional effects, including far-infrared ray emission and deodorization, attributable to silica.

Provided is a method of producing a carbon catalyst having an improved activity. The method of producing carbon catalyst including a carbonization step of carbonizing raw materials containing an organic compound as a carbon source, a metal, and an electrically conductive carbon material to produce a carbonized material; a metal impregnation step of impregnating the carbonized material with a metal; and a heat treatment step of subjecting the carbonized material impregnated with the metal to a heat treatment.

Described is a process for preparing platinum-carbene complexes.

The present invention provides an alkali metal salt of fluorosulfonyl imide having favorable heat resistance and a reduced content of specific impurities and a water content, and provides a method for producing an alkali metal salt of fluorosulfonyl imide, which is capable of easily removing a solvent from a reaction solution. An alkali metal salt of fluorosulfonyl imide of the present invention is represented by the following general formula (I) and has a mass loss rate of 2% or less when the alkali metal salt of fluorosulfonyl imide is kept at 100° C. for 8 hours under an air current. A method for producing an alkali metal salt of fluorosulfonyl imide of the present invention comprises a step of concentrating a solution of the alkali metal salt of fluorosulfonyl imide by bubbling a gas into a reaction solution containing the alkali metal salt of fluorosulfonyl imide, and/or concentrating a solution of the alkali metal salt of fluorosulfonyl imide by thin layer distillation.

A portable, collapsible vending cart which can be used to vend disparate items in a variety of environments. The cart is adaptable to accommodate vendors of a wide variety of products, and provides an apparatus which is in compliance with most state regulations for vending carts. The cart is adapted to fit within the “security space” of a storefront, the space between a pull down security gate and the display window/entry point of the storefront. A locking mechanism extending from the vending cart is designed for secure locking engagement within the security space using infrastructure associated with the standard security gate.

An enclosure for enclosing a flat panel display for viewing that is substantially sealed and resistant to liquid ingress. The enclosure comprises a bezel, a substantially transparent front cover, and an enclosure housing. The bezel has a peripheral surface defining an enclosure area, an inner edge defining a display opening, and a rear surface. The substantially transparent front cover is operatively connected to the bezel and covers the display opening. The enclosure housing has a front opening and a flange disposed about and extending from the front opening. The bezel and the enclosure housing are joined together at a joining region that is substantially sealed and resistant to liquid ingress. The bezel, the front cover, and the enclosure housing define the enclosure, which is configured to receive a flat panel display therein.

A table top dishwasher comprises (a) a tub (10) for accommodating articles to be cleaned; (b) a water-tight hood (12) arranged over said tub (10), said hood comprising a fixed hood portion (14), an access opening (42), and a rotatable door (16) which is connected to the fixed hood portion so as to be rotatable between a raised opened position in which it exposes the access opening to provide access to the tub and a lowered closed position in which it closes the access opening and forms part of the water-tight hood; and (c) a gasket (44) which is attached to the fixed hood portion (14) or to the rotatable door (16) along an edge region of the access opening, wherein the fixed hood portion (14)or the rotatable door (16), respectively, comprises a plurality of mounting projections (46), and wherein the gasket comprises a plurality of apertures (54) in which the mounting projections are held by snap-fit connection.

An anesthesia workstation includes a sliding track system attached to the front of the anesthesia workstation for the mounting of one or more displays. The displays are horizontally slidable along the front of the anesthesia workstation along the sliding track. In addition, the sliding track system includes pivot points which enable outward pivoting of the displays up to 90 degrees. Sliding and pivoting of the displays is possible both independently and simultaneously. The sliding track system allows the anesthetist to slide and pivot the displays across the front of the workstation along the length of the track to the most preferable viewing position. Additional storage space is positioned within the anesthesia workstation behind the displays and becomes exposed and accessible when the displays are manipulated via the sliding track system.

A cabinet drawer includes a molded drawer floor having a central portion including at least one depression, each depression having a bottom wall and a sidewall having an inner surface and an outer surface. A flange extends outwardly from an upper edge of each depression. A plurality of webs extends outward from each depression outer surface for connection with a drawer slide system. A peripheral edge of the flange includes a plurality of deflectable tabs for coupling to a surrounding fence without the use of fasteners. The fence includes a skirt portion extending downward from the drawer floor flange to hide any drawer slide mechanism coupling the drawer floor to any underlying base.