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Biochar generator and associated methods

A biochar generator may include a pyrolysis chamber, a heater connected to the pyrolysis chamber and a biochar collection chamber in communication with the pyrolysis chamber. A biochar collection chamber sensor may sense a composition of the biochar collected in the biochar collection chamber to define a sensed composition of the biochar. A controller in electrical communication with the biochar collection chamber sensor may utilize the sensed composition of the biochar to dynamically alter conditions in the pyrolysis chamber to alter the composition of the biochar.




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Pyrolysis systems, methods, and resultants derived therefrom

A process for the controlled gasification of a carbonaceous feedstock includes pyrolizing the feedstock by conveying the feedstock through a retort surrounded by a plurality of successive heating chambers each comprising an axially adjustable chamber separation wall and each operated at a predetermined temperature, wherein a predetermined dwell time of the feedstock in each of the plurality of successive heating chambers is controlled by a conveyance rate of the feedstock through the retort and a position of each of the axially adjustable chamber separation walls to produce a gas product and a solid product. The gas product includes methane and noxious chemicals and the solid product includes carbon, and the pyrolizing step is controlled using feedback related to constituents of the gas product.




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System and method for recycling of carbon-containing materials

There is described a system and method for recycling carbon-containing material, in particular tires and plastics materials. The system includes a heating arrangement for anaerobically heating carbon containing material to produce carbon-containing gases. A condensing arrangement is also used to condense a proportion of the carbon-containing gases to provide condensed gases and non-condensed gases. In addition, a recirculating arrangement is provided for recirculating the non-condensed gases into the heating arrangement. Further systems and methods for pre- and post-processing of the carbon-containing material are also disclosed and products of the systems and methods are also described.




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Method of recovering energy

Described is an apparatus and method for recovery of energy and by-products from automobile and truck tires. The tires are heated in an oxygen poor environment, and the off gases are condensed to recover a liquid oil product and compressible natural gas. The tires are reduces to ash and steel, both of which can be feed streams for other processes. The apparatus includes a condenser with cooled plates, and oil recovery structures.




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Microwave assisted flash pyrolysis system and method using the same

The present invention provides a microwave assisted flash pyrolysis system to carry out microwave assisted flash pyrolysis in an industrial scale. The microwave assisted flash pyrolysis system comprises at least one microwave generator; a chamber comprises: at least one feedstock inlet, at least one baffle plate, a microwave-transparent rotating window, and at least one microwave inlet, at least one wet gas outlet, and at least one dry end product outlet. The present invention also provides a method using the same system to carry out microwave assisted flash pyrolysis.




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System and method for obtaining hydrocarbons from organic and inorganic solid waste

This invention relates to a system for obtaining hydrocarbons from organic or inorganic solid waste, wherein said system comprises: an inlet chamber, within which is a mixer assembly which mixes and conveys the waste through said chamber, which is also at ambient temperature, thus avoiding any thermal shock to the solid waste for processing; a dehydration chamber with a mixing assembly therein, and the upper part of this chamber contains an expansion chamber for promoting more efficient molecular breakdown; the thermal breakdown is carried out in two reactors which are operated at different temperatures, the first thermal disassociation reactor which has inside a mixer unit, and which in its upper part houses an expansion chamber, the second thermal breakdown reactor, therein has a mixer unit, and in the upper portion thereof houses an expansion chamber and at the top end thereof a vertical expansion tower; wherein the thermolytic steam is homogenized, a separator of heavy hydrocarbons, which does not require an additional cooling system, a multiple valve determines the temperature and oxygen content of the vapors and conveys them to the expansion tower in order to optimize the production of hydrocarbons, and to obtain a liquid hydrocarbon with high heating value.




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Process for conversion of organic, waste, or low-value materials into useful products

Methods and apparatus for processing of waste and low-value products to produce useful materials in reliable purities and compositions, at acceptable cost, without producing malodorous emissions, and with high energy efficiency are disclosed. In particular, multi-stage processes are disclosed to convert various feedstocks such as offal, animal manures, municipal sewage sludge, tires, and plastics, that otherwise have little commercial value, to useful materials including gas, oil, specialty chemicals, and carbon solids. Disclosed processes subject the feedstock to heat and pressure, separates out various components, then further applies heat and pressure to one or more of those components. Various materials produced at different points in the process may be recycled and used to play other roles within the process. Also disclosed are apparatus for performing multi-stage processes of converting waste products into useful materials, and at least one oil product that arises from the process.




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Method for the rapid pyrolysis of lignocellulose

Method for fast pyrolysis of lignocellulose including: mechanically comminuting the lignocellulose to lignocellulose particles; at least one of completely drying and preheating the lignocellulose particles; mixing the lignocellulose particles with heat transfer particles so as to provide a mixture; heating the heat transfer particles, prior to the mixing, to a temperature between 500° C. and 650° C.; and heating, in a pyrolysis reactor with oxygen excluded, the lignocellulose particles using the heat transfer particles so as to establish a temperature between 400° C. and 600° C. for 1 to 50 seconds and so as to react the lignocellulose particles so as to provide pyrolysis coke, pyrolysis condensate, and pyrolysis gas.




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Refractory oven doors and refractory oven door framing walls of a coke oven battery

A heat-resistant door device for closing a horizontal coke oven chamber is made of a refractory material, using a material containing silica or a material containing silica and aluminum oxides, in particular. The material has a low temperature expansion coefficient and it is thermally well insulating so that the door is not deformed and/or distorted during the coal carbonization process. The door device is built of a coke oven wall mainly located above the door and embracing the door as well as of a mobile door located underneath. Thereby less cold ambient air enters into the coke oven chamber and radiation losses are minimized. The door may be comprised of an ellipsoidal bulge by which the coke can be better pushed into the coking chamber. The oven wall embracing the oven door can also be made of a refractory material containing silica or of a material containing silica and aluminum oxides.




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Method and device for the positioning of operating units of a coal filling cart at the filling openings of a coke oven

The invention relates to a method of positioning service equipment of a coal-charging larry cart at charging ports of a coke oven, wherein a rail-guided larry cart is moved on the roof of a coke oven and is positioned at locations known by a machine control system and corresponding to charging ports in the oven roof in order to charge the oven chambers, and wherein then at least one piece of service equipment of the coal-charging larry cart is guided to the charging ports by horizontal biaxial positioning movements. According to the invention, an optical measurement method is used after each positioning of the larry cart to detect the coordinates of at least one marking that is applied to the oven roof and that has a fixed relationship with the center axis of a charging port within a measurement field that is predefined by the measurement method and to compare them with reference values that are stored in the machine control system for the marking. The deviations between the measured coordinates and the coordinates stored in the machine control system are determined for both axial directions. Differential values are then taken into account as correction values during the positioning movement of the piece of service equipment. The subject matter of the invention is furthermore formed by an apparatus for carrying out the described method.




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Process and apparatus for decomposition of polymer products including those containing sulphur such as vulcanised rubber tyres and recovery of resources therefrom

A method and apparatus for pyrolytic destruction of polymer products including whole vehicle vulcanised rubber tires is disclosed. The apparatus 111 has a reaction chamber 153 into which a tire can be placed, and immersed for pyrolytic decomposition in a molten alloy of zinc with a minor proportion of aluminium. The apparatus 111 has a heated reservoir 155 in which the alloy is maintained in a molten state, and from where it can be transferred to the reaction chamber 153 to immerse the tire. Fluid hydrocarbon byproducts are drawn off for condensation and recovery, and solid zinc sulphides are also recovered. Where steel belted tires are processed, carbon and steel residues are also recovered.




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System and method for recovering turpentine during wood material processing

A system, method and configuration for recovering turpentine during the manufacturing of wood chips, wood pellets or other substances that may include turpentine. In general, a turpentine recovery system is used to capture turpentine from exhaust of a dryer as wood chips are being dried. Advantageously, application of the various techniques disclosed herein can result in the recovery of turpentine that can then be sold to generate revenue and, may contribute to a reduction in the capital and operation costs for emission controls for the dryer exhaust.




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Thermal treatment of biomass

A biomass pyrolysis process is provided in which biomass feedstock is mixed with a heat carrier. The heat carrier at least partly comprises char. The ratio by weight of biomass to char is in the range 1:1 to 1:20. The process may be carried out by in a screw/auger pyrolysis reactor in which the solid feedstock components are conveyed along the reactor by a first screw. A second screw conveys at least a portion of the solid products of the biomass pyrolysis back to a heat transfer medium input port. Thus, the heat transfer medium includes char from the biomass pyrolysis.




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Bubbling bed catalytic hydropyrolysis process utilizing larger catalyst particles and smaller biomass particles featuring an anti-slugging reactor

This invention relates to a process for thermochemically transforming biomass or other oxygenated feedstocks into high quality liquid hydrocarbon fuels. In particular, a catalytic hydropyrolysis reactor, containing a deep bed of fluidized catalyst particles is utilized to accept particles of biomass or other oxygenated feedstocks that are significantly smaller than the particles of catalyst in the fluidized bed. The reactor features an insert or other structure disposed within the reactor vessel that inhibits slugging of the bed and thereby minimizes attrition of the catalyst. Within the bed, the biomass feedstock is converted into a vapor-phase product, containing hydrocarbon molecules and other process vapors, and an entrained solid char product, which is separated from the vapor stream after the vapor stream has been exhausted from the top of the reactor. When the product vapor stream is cooled to ambient temperatures, a significant proportion of the hydrocarbons in the product vapor stream can be recovered as a liquid stream of hydrophobic hydrocarbons, with properties consistent with those of gasoline, kerosene, and diesel fuel. Separate streams of gasoline, kerosene, and diesel fuel may also be obtained, either via selective condensation of each type of fuel, or via later distillation of the combined hydrocarbon liquid.




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Process for producing a renewable hydrocarbon fuel

A process for producing a renewable hydrocarbon fuel. The process can include providing a feed including a lignocellulosic material to a pyrolysis zone to produce a stream including a pyrolysis oil, providing the pyrolysis oil stream to a refining zone producing a refined stream, providing at least a portion of the refined stream to a reforming zone producing a stream including hydrogen, providing at least a portion of the hydrogen stream to the refining zone; and recovering the renewable hydrocarbon fuel from the refined stream.




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Removal of hydrogen sulfide as ammonium sulfate from hydropyrolysis product vapors

A system and method for processing biomass into hydrocarbon fuels that includes processing a biomass in a hydropyrolysis reactor resulting in hydrocarbon fuels and a process vapor stream and cooling the process vapor stream to a condensation temperature resulting in an aqueous stream. The aqueous stream is sent to a catalytic reactor where it is oxidized to obtain a product stream containing ammonia and ammonium sulfate. A resulting cooled product vapor stream includes non-condensable process vapors comprising H2, CH4, CO, CO2, ammonia and hydrogen sulfide.




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Disposal of electrical and electronic equipment

A method for disposing electrical and electronic equipment comprising plastic and metal components, the method comprising: melt processing the equipment and/or comminuted parts thereof to form a melt processed product; transferring the melt processed product into a vessel and heating the product using far infrared radiation such that it liberates volatile hydrocarbons and leaves behind non-volatile residue comprising metal; and collecting one or both of the volatile hydrocarbons and the non-volatile residue for subsequent use.




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Energy-efficient process and apparatus for drying feedstock

This invention presents a versatile and continuous drying technology that utilizes controlled heat combined with forced air supply for drying a feedstock. The dryer virtually divided top-down into different zones, each having definite heated air distribution rate to secure desired condition for drying of the feedstock. The heat source of the dryer is waste heat, either provided by the feedstock itself through exothermic heat generated by the feedstock or reclaimed waste heat or solar heat. The discharge system of the dryer is a fail-safe discharge system, which ensures equal residence time for the feedstock through all the zones. The synergic interaction of all these components along with recycling the heat through an efficient use of heat exchangers, optimized control of airflow rate and feedstock resident time, purifying the exhaust air and condensing the outlet vapor empowers the technology to function with minimum energy, minimum processing time, minimum environmental foot-print, minimum cost and with minimum operational cost.




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Waste processing

An apparatus (100) for processing waste material is provided which comprises a heat proof chamber (102), a hot gas inlet (106, 112) for heating the interior of the heat proof chamber (102), and a rotatable drum (118) for containing waste to be processed. The drum (118) has gaps (120) therein, is located within the heat proof chamber (102), and separated therefrom around its edge by a gap. The apparatus (100) is also provided with a drive (126, 128) for rotating the drum (118) at a speed such that, in use, waste material that is heat softened is centrifugally separated from the remainder of the waste and passes through the gaps (120) in the drum (118).




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Process control by blending biomass feedstocks

A process and system is disclosed for optimizing a key parameter of a biomass feedstock that enhances bio-oil production. The process and system involves optimizing the values of the key parameter in multiple biomass feedstocks by regulating their feed rates and blending those feedstocks to produce a cumulative biomass feedstock with an optimal value for the key parameter. The key parameter in the biomass feedstocks is measured and the feed rates of the multiple biomass feedstocks are adjusted in order to produce a cumulative biomass feedstock exhibiting optimal values for the desired key parameter. The key parameters can include compositional properties, such as lignin content or mineral content, and/or fluidization properties of the biomass materials, such as density, particle cohesion force, or particle size.




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Pyrolysis fuels and methods for processing pyrolysis fuels

Pyrolysis fuels and methods for processing pyrolysis fuel are provided. In one embodiment, a method of processing pyrolysis fuel converts biomass to pyrolysis fuel including pyrolysis oil and char particles. Also, the method includes resizing a portion of the char particles so that substantially all resized char particles have a largest dimension no greater than about 5 microns.




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Method for compacting coal in a manner suitable for coke oven chambers

A method for compacting coal in a manner suitable for coke oven chambers is described. The coal is initially compressed by means of a suitable compressing device into one or more coal cakes, and the obtained coal cakes are divided into compacted products by a cutting device. The compacted products are stacked on top of the each other such that they can be loaded into a coke oven chamber for coking. The compacted products enable the coke oven chambers to be loaded in a precise and a coal loss-free manner. The coal compacted products are easy to store.




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Pyrolysis process and products

A pyrolysis device and process to convert a carbonaceous feedstock to a carbon solid and pyrolysis gas, and processes for refining the resulting carbon solid and pyrolysis gases. The pyrolysis process may include introducing a carbonaceous feedstock into a pyrolysis processor having a vertical rotary tray processor, heating the feedstock to a temperature above about 790° F., removing a carbon material from a bottom of the pyrolysis processor, and removing a pyrolysis gas from a top of the pyrolysis processor.




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Processing organic materials

A method and an apparatus for pyrolysing a solid organic feed material are disclosed. Solid organic material is moved through a reaction chamber and exposed to a temperature profile within the chamber that dries and pyrolyses the organic material and releases water vapour and a volatile products gas phase. The water vapour phase and the volatile products gas phase are moved counter-current to the solid organic material so that the water vapour phase and condensable components of the volatile products gas phase condense in cooler upstream sections of the chamber and form a liquid water product and a separate liquid oil product. The liquid water product is discharged via an outlet along the length of the chamber and a dried and pyrolysed solid product is discharged from a downstream outlet in the chamber. The chamber includes a plurality of heat transfer members extending within the chamber and a supply of oxygen-containing gas for establishing and maintaining the temperature profile within the chamber.




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Process and device for fluidized bed torrefaction and grinding of a biomass feed for subsequent gasification or combustion

A process and a unit for fluidized bed torrefaction and grinding of particles of a biomass with a largest dimension of 2 cm to 5 cm, and which unit contains an envelope having a general shape of a sector having a) two substantially vertical walls delimiting that sector; and b) at least one inclined wall defining three zones, from bottom to top: a lower zone provided with a fluidization means, and provided with a grinder placed at the bottom of that zone; an intermediate zone (2) provided with a fluidization means; and an upper zone (3) provided with a fluidization means; and a pipe (11) for introducing the particles reaching into the unit to the level of the intermediate zone.




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Production of higher quality bio-oils by in-line esterification of pyrolysis vapor

The disclosure encompasses in-line reactive condensation processes via vapor phase esterification of bio-oil to decease reactive species concentration and water content in the oily phase of a two-phase oil, thereby increasing storage stability and heating value. Esterification of the bio-oil vapor occurs via the vapor phase contact and subsequent reaction of organic acids with ethanol during condensation results in the production of water and esters. The pyrolysis oil product can have an increased ester content and an increased stability when compared to a condensed pyrolysis oil product not treated with an atomized alcohol.




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Carbon-based durable goods and renewable fuel from biomass waste dissociation for transportation and storage

Techniques, systems, apparatus and material are described for generating renewable energy from biomass waste while sequestering carbon. In one aspect, a method performed by a reactor to dissociate raw biomass waste into a renewable source energy or a carbon byproduct or both includes receiving the raw biomass waste that includes carbon, hydrogen and oxygen to be dissociated under an anaerobic reaction. Waste heat is recovered from an external heat source to heat the received raw biomass waste. The heated raw biomass waste is dissociated to produce the renewable fuel, carbon byproduct or both. The dissociating includes compacting the heated raw biomass waste, generating heat from an internal heat source, and applying the generated heat to the compacted biomass waste under pressure.




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Method for producing individual compacts suitable for coke oven chambers by dividing a coal cake in a non-mechanical manner

A method for producing individual compacts made of coke and suitable for coke oven chambers by dividing a coal cake in a non-mechanical manner, wherein the coal cake is produced by a compression method according to the prior art and the coal cake is divided by non-mechanical, energy-supplying media, and the non-mechanical media supplying shearing energy are, for example, a laser beam, a high-pressure water jet, an abrasive-solid jet, an ultrasonic beam, a compressed-air jet, or a gas jet. By using the method, coal compacts can be produced from coal cakes without forming dust, without wearing out cutting tools, and with high precision.




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Method of increasing anhydrosugars, pyroligneous fractions and esterified bio-oil

The device and method are provided to increase anhydrosugars yield during pyrolysis of biomass. This increase is achieved by injection of a liquid or gas into the vapor stream of any pyrolysis reactor prior to the reactor condensers. A second feature of our technology is the utilization of sonication, microwave excitation, or shear mixing of the biomass to increase the acid catalyst rate for demineralization or removal of hemicellulose prior to pyrolysis. The increased reactivity of these treatments reduces reaction time as well as the required amount of catalyst to less than half of that otherwise required. A fractional condensation system employed by our pyrolysis reactor is another feature of our technology. This system condenses bio-oil pyrolysis vapors to various desired fractions by differential temperature manipulation of individual condensers comprising a condenser chain.




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Method for converting waste plastic to lower-molecular weight hydrocarbons, particularly hydrocarbon fuel materials, and the hydrocarbon material produced thereby

The method produces a hydrocarbonaceous fluid (a liquid mixture of hydrocarbons, or in other words a mixture of hydrocarbons which is liquid at ambient room temperature and atmospheric pressure), which functionally is a liquid hydrocarbon fuel, from a feed of waste plastic. The method can comprise the steps of: (step 1) melting a feed of substantially solid waste plastic in an aerobic atmosphere (for instance, air) whereby a waste-plastic melt is produced; (step 2) distilling at least a portion of the waste-plastic melt whereby a hydrocarbonaceous distillate is produced; and (step 3) collecting the hydrocarbonaceous distillate. That distillate is generally referred to above as a condensate. The method can include the step of comminuting the feed of substantially solid waste plastic into pieces substantially no greater than about 1.5 cm2 prior to step 1. The method can also include the step of adding an effective amount of a cracking catalyst to the waste plastic prior to step 2.




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Disposal method for entirely recycling solid refuse

A disposal method for entirely recycling solid refuse includes the following steps: sorting, crushing, drying, pressing with high pressure to shaped articles, producing charcoal from combustible refuse in high temperature and firing incombustible refuse in high temperature, at last cooling high temperature articles to obtain solid fuel with various shapes and bricks or board used for building. The method achieves entirely recycling house refuse, especial solid refuse. The method recycles solid refuse to obtain fuel and building material with economic value. The method is simple and its processing cost is low.




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Coking plant with flue gas recirculation

Improvement in carbonization in a carbonization furnace and simultaneous reduction in NOx emissions is achieved by recirculation of waste gas from a coking oven back to the oven chamber, the downcomers, or the sole channel system.




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Carbonization method and device

The invention relates to a method of manufacturing charcoal. It is characterized in that: first hot gases are generated by at least one heating means; its first gases are mixed with second gases in order to form a gas mixture; this mixture is sent into a charge of wood in order to generate therein a pyrolysis front; an overpressure is created between the upstream end and the downstream end of the charge so as to force this front to pass through it in one direction, namely from the upstream end to the downstream end; and third gases are recovered downstream of the charge, at least a first portion of said third gases, in the form of a stream of said second gases, is conveyed by a conveying means. The invention also relates to a device for implementing this method.




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Method for processing biomass

A method for processing biomass to produce biofuel includes decomposing lignocellulosic material into byproduct polymers that include lignin, decomposing the lignin into targeted chemical fragments, and chemically converting the targeted chemical fragments into a biofuel.




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Solids removal from bio-oil using biomass filter aid

A green process and system are disclosed for utilizing a biomass filter aid in the filtration of a bio-oil. The process comprises filtering a bio-oil containing residual solids from a conversion reaction in the presence of the biomass filter aid to produce a filtered bio-oil. The biomass filter aid facilitates efficient removal of residual solids from the bio-oil. The spent biomass filter aid containing the residual solids may be recycled as a conversion feedstock or used as a combustion heat source in the biomass conversion system.




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Coal processing to upgrade low rank coal having low oil content

A method of treating untreated low calorific coal containing moisture and organic volatiles includes feeding untreated coal to a dryer, and drying the coal. The dried coal is subjected to a pyrolyzing step where oxygen-deficient gases are brought into contact with the coal, thereby lowering the volatile content of the coal and producing a stream of pyrolysis effluent gases. The pyrolysis effluent gases are subjected to a separation process to separate lean fuel gases from liquids and tars, wherein the separation process removes less than about 20 percent of the pyrolysis effluent gases as the liquids and tars, with the remainder being the lean fuel gases. The lean fuel gases are returned to the dryer combustor, the pyrolyzer combustor, or the pyrolyzer.




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Depolymerizatin of plastic materials

A styrene monomer reclamation process and system is described. The styrene monomer reclamation process includes providing a waste plastic. The waste plastic includes styrenic polymers. The waste plastic is formed into polymer particles. At least a portion of the polymer particles are dissolved in a solvent to form a polymer stream. The dissolved polymer particles are depolymerized to form a styrene monomer stream.




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Carbon-based durable goods and renewable fuel from biomass waste dissociation

Techniques, systems, apparatus and material are disclosed for generating renewable energy from biomass waste while sequestering carbon. In one aspect, a method performed by a reactor to dissociate raw biomass waste into a renewable source energy or a carbon byproduct or both includes receiving the raw biomass waste that includes carbon, hydrogen and oxygen to be dissociated under an anaerobic reaction. Waste heat is recovered from an external heat source to heat the received raw biomass waste. The heated raw biomass waste is dissociated to produce the renewable fuel, carbon byproduct or both. The dissociating includes compacting the heated raw biomass waste, generating heat from an internal heat source, and applying the generated heat to the compacted biomass waste under pressure.




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Air proportioning system for secondary air in coke ovens depending on the vault vs. sole temperature ratio

A device for proportioning of secondary combustion air into the secondary air soles of coke oven chamber ovens is shown. The device is formed by a slide gate or a parallelepiped device or by plates moved by means of a thrust bar, the thrust bar being moved longitudinally in parallel to the coke oven chamber wall so that the plates move away from the secondary air apertures and open or close these. The thrust bar is moved by means of a positioning motor, with the power transmission being effected hydraulically or pneumatically. Via suitable measuring parameters, it is thus possible to optimize secondary heating so that heating is provided evenly from all sides, thus achieving an improvement in coke quality.




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Continuously converting biomass

Methods, devices and systems for continuously converting biomass are described herein. A device has a feed section for holding a moving bed of biomass, namely wood, having a drying section, a flame zone for degassing, and a, smolder zone for carbonizing the biomass into a solid converted product, namely charcoal. The device includes a tank for collecting the solid converted product arranged below a grate and coupled with the feed section in a gas-tight manner. The system comprising the device, a biogas plant and/or a combined heat and power plant conveys the liquid converted product, namely pyroligneous acid or acetic acid, to the biogas plant and/or the solid converted product, namely charcoal, to the combined heat and power plant.




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Selective temperature quench and electrostatic recovery of bio-oil fractions

A process for quenching, separating and collecting targeted components of a hot pyrolysis product stream from the pyrolysis of biomass is provided. The process utilizes sequential steps of rapid quenching and electrostatic precipitation comprising injecting a coolant comprising at least one of nitrogen, a noble gas and mixtures thereof into a hot pyrolysis vapor to selectively condense a first fraction of components from the hot pyrolysis vapor at a first predetermined temperature which is then collected by electrostatic precipitation in a first electrostatic precipitator at about the first predetermined temperature, where a wall temperature of the first electrostatic precipitator is maintained slightly higher than the first predetermined temperature. The sequential steps of coolant injection and collection are repeated at progressively cooler temperatures in order to selectively collect one or more fractions of the hot mixture.




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Ultrasonic microwave molecular vacuum distillation system for waste tires

A system for tire distillation including an upper chamber, a first conveyor configured to transport a tire through the upper chamber, a lower chamber located beneath the upper chamber, the lower chamber that includes an ultrasonic purge chamber configured to radiate the tire with ultrasonic radiation, a microwave radiation chamber configured to radiate the tire with microwave radiation, and a second conveyor configured to transport the tire from the ultrasonic purge chamber to the microwave radiation chamber. The system further includes a vacuum system configured to maintain an atmosphere in the ultrasonic purge chamber and the microwave radiation chamber under a vacuum wherein the tire is preheated during conveyance through the upper chamber from heat produced in the lower chamber.




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Reciprocating reactor and methods for thermal decomposition of carbonaceous feedstock

The present technology describes apparatus, systems, and methods for the thermal decomposition of carbonaceous feedstocks through continuous pyrolysis. A reciprocating reactor is described that includes an inner reactor pipe and an outer reactor pipe. The outer reactor pipe has a first portion that surrounds the inner reactor pipe forming an annulus space, and a second portion that extends beyond the inner reactor pipe and forms a turnaround zone. The inner reactor pipe defines an inner reactor zone that produces partially reacted carbonaceous feedstock, and the annulus space defines an outer reactor zone that produces product gases and solids.




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Method and device for processing plastic waste, especially polyolefins

A method for processing plastic waste, in particular polyolefins, and a device for processing plastic waste, in particular polyolefins, are used especially in the industrial utilization of plastic waste. The method consists in that a primarily refined charge after being fed into a reactor (6) is fluidized and cracked during forced progressive-rotational movement coinciding with heating. A gas-steam fraction obtained during a utilization process is continuously guided out to a cooling system whereas impurities are periodically guided out from the reactor (6) to a waste tank (22).




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Process for heat treatment of biomass with a coolant solid

A process for heat treatment of a solid, with a coolant solid, in which a stage for mixing the solid with the pre-heated coolant solid is carried out, with the coolant solid being a solid hydrocarbon. The solid hydrocarbon is ground, before the mixing stage with the solid, to obtain a solid hydrocarbon powder with a grain size of between 20 μm and 300 μm. The solid is ground, before the mixing stage with the coolant solid, to obtain solid pellets with a thickness of between 1 mm and 30 mm, a width of between 1 mm and 40 mm, and a length of between 1 mm and 100 mm. The mixing is carried out at a temperature of between 80° C. and 700° C.




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Fast pyrolysis catalytic cracking pipe for producing bio-oils

A pyrolyzer apparatus (i.e. a “cracking pipe”) comprises a first screen, a second screen, and a catalyst material positioned between the first and second screens. The pyrolyzer is structured so that feedstock is pyrolyzed and pyrolyzer-generated gas is drawn through the first screen, through the catalyst material, and then through the second screen in series. The gas may then be directed to other processing equipment so that bio-oil is extracted from the gas.




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Method to reduce heat radiation losses through coke oven chamber doors and walls by adapting the coal cake in height or density

A method for reducing the coking time in the oven area near the door or end wall and for improving coke quality and situation of emissions by compensating for radiation losses through coke oven chamber doors and end walls is described. This compensation is accomplished by varying the height of the coal cake in the environment of the frontal coke oven chamber doors. The variation is achieved both by increasing or decreasing the coal cake over part of the length or over the entire length of the coke oven chamber door. The reduction in the height of the coal cake can be generated by omission of coal or coal compacts, the increase in height can be accomplished by stacking of coal and pressing or adding of coal compacts, with it also being envisaged to omit the pressing cycle so as to obtain a recess with a lower coal cake density which also has less heat radiation.




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Controllable air ducts for feeding of additional combustion air into the area of flue gas channels of coke oven chambers

A device for feeding and controlling secondary air from secondary air ducts into flue gas channels of horizontal coke oven chambers is shown. The flue gas channels are located underneath the coke oven chamber floor on which coal carbonization is realized. The flue gas channels serve for combustion of partly burnt coking gases from the coke oven chamber. The partly burnt gases are burnt with secondary air, thus heating the coke cake also from below to ensure even coal carbonization. Secondary air comes from the secondary air ducts connected to atmospheric air and to the flue gas channels. Controlling elements are mounted in the connecting channels between the flue gas channels and secondary air ducts which can precisely control the air flow into the flue gas channels. Thereby, it is possible to achieve a much more regular heating and heat distribution in coke oven chambers. The actual controlling devices in the connecting channels can be formed by turnable pipe sections, wall bricks, or metal flaps. It is particularly advantageous to utilize a hump-like facility (tabouret) which sits in the secondary air ducts and which is comprised of a tabouret plate with a central opening that is slid under the corresponding embranchment to regulate the gas stream. The controlling mechanism can be actuated manually, electrically, or pneumatically. Thereby, the controlling device can also be automated.




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Device for loading printing plates on a plate cylinder of a rotary offset press

The loading device according to the invention comprises a magazine for receiving at least one printing plate and transferring it from the magazine to the plate cylinder. It also comprises at least one guide rail to guide a printing plate during transfer thereof by cooperation with a notch of a front edge of the printing plate, the notch sliding along the guide rail during the transfer.




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Solvent assisted method of microcontact printing

A method of microcontact printing comprises (a) providing an elastomeric stamp comprising a printing surface inked with an ink comprising surface-functionalizing molecules, (b) treating the inked printing surface of the stamp with solvent, and (c) contacting the treated inked printing surface of the stamp to a surface of a substrate. The printing surface of the stamp comprises a first relief pattern, or the surface of the substrate comprises a second relief pattern, or both of the surfaces comprise the relief patterns, and a pattern of surface-functionalizing molecules is transferred to the substrate according to one or both of the relief patterns.