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Recent advances in discrete Cu complexes for enhanced chemodynamic therapy

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02380C, Frontier
Zhao-Guo Hong, Liangliang Zhang, Hong Liang, Fu-Ping Huang
Since the concept of metal ion stimulation-mediated chemodynamic therapy was proposed by Bu and Shi 's group in 2016, increasing attention has been directed toward fabricate efficient, safe and stable...
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Investigating the formation of metal nitride complexes employing a tetradentate bis-carbene bis-phenolate ligand

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT01765J, Paper
Romain Kunert, Diego Martelino, Samyadeb Mahato, Nicholas Hein, Jason Pulfer, Christian Philouze, Olivier Jarjayes, Fabrice Thomas, Tim Storr
The synthesis of MnV and CrV nitride complexes of a pro-radical tetradentate bis-phenol bis-N-heterocyclic carbene ligand H2LC2O2 were investigated. Employing either azide photolysis of the MnIII precursor complex MnLC2O2(N3) or...
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Development of Polyoxometalate-loaded MOF for Heterogeneous Catalysis and Enhanced Dye Adsorption

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02645D, Paper
Ketan Maru, Sarita Kalla, Ritambhara Jangir
The study focuses here on the enhancement of MIL-117 functionality by incorporating well-known polyoxometalate (POM); tetrabutylammonium octamolybdate [(n-C4H9)4N]4[Mo8O26]. Using an encapsulation method with conventional heating, Mo8O264- anions were first time...
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Design and theoretical analysis of a tunable bifunctional metasurface absorber based on vanadium dioxide and photoconductive silicon

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02563F, Paper
Changfeng Fu, Xinke Wang, Yicheng Zhang, Jiaxin Ju, Wei Fan, Xiaobo Yan, Lianfu Han
A bifunctional metasurface absorber based on vanadium dioxide (VO2) and photoconductive silicon (PSi) is proposed, which can be switched from dual- to single-broadband absorption by VO2, and the absorptivity is tunable by varying σPSi.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Stable homogeneous silver(I) catalysts for the highly efficient cycloaddition of azides onto terminal alkynes in water

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02825B, Communication
Meysam Kakavand, Anna Kozakiewicz, Abdollah Neshat
To develop stable and efficient silver(I) catalysts and evaluate the role of sulfur and phosphorus donor ligands in the catalytic cycloaddition of selected organic azides and alkynes (AAC), a series...
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Co-doping regulation on Ni-based electrocatalysts to adjust the selectivity of oxygen reduction reaction for Zn–air batteries and H2O2 production

Dalton Trans., 2024, 53,17819-17828
DOI: 10.1039/D4DT01625D, Paper
Songhan Hu, Kai Wang, Xinxin Xu, Qiang Wang
Two Ni-based electrocatalysts with different ORR selectivity were synthesized from a NiMOF, which show promising prospects in Zn–air batteries and H2O2 production.
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Molecular Fe(II)–Ln(III) dyads for luminescence reading of spin-state equilibria at the molecular level

Dalton Trans., 2024, 53,17756-17765
DOI: 10.1039/D4DT01868K, Frontier
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Timothée Lathion, Neel Deorukhkar, Charlotte Egger, Homayoun Nozary, Claude Piguet
Efficient and easy lanthanide(III)-based luminescence reading of iron(II) spin-state equilibria presents an attractive challenge, owing to the delicate combination of the primogenic effect and the Fermi golden rule.
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Advances in metal–organic frameworks for optically selective alkaline phosphatase activity monitoring: a perspective

Dalton Trans., 2024, 53,17742-17755
DOI: 10.1039/D4DT01727G, Perspective
Eduarda Andrade, Filipe A. Almeida Paz, Flávio Figueira
MOFs can play three essential roles in ALP monitoring: they can serve as fluorescent probes, function in oxidation or peroxidation mechanisms, or combine both processes.
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Asymmetric magnetic nanosnowman loaded with AgPd nanocage toward NIR-enhanced catalytic activity

Dalton Trans., 2024, 53,17864-17879
DOI: 10.1039/D4DT02425G, Paper
Jie Jin, Haoran Li, Hongfa Wang, Qunling Fang, Yunqi Xu, Weili Kong, Xia Chen, Ken Cham-Fai Leung, Hailong Wang, Shouhu Xuan
An asymmetric Fe3O4@AgPd/PDA nanosnowman embedded with an AgPd nanocage shows significantly enhanced catalytic activity under near-infrared (NIR) light.
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Theoretical study on the concerted catalysis of Ir/Ni for amino radical transfer for C(sp2)–C(sp3) bond formation

Dalton Trans., 2024, 53,18047-18053
DOI: 10.1039/D4DT02567A, Paper
Hui Li, He Zheng
Insights from DFT calculations into the synergistic Ir/Ni catalysis method for the synthesis of C(sp2)–C(sp3) bonds through an amino radical transfer (ART) strategy to generate alkyl radicals.
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The role of the stabilizing/leaving group in palladium catalysed cross-coupling reactions

Dalton Trans., 2024, 53,18013-18020
DOI: 10.1039/D4DT02533D, Paper
Open Access
Lorenzo Palio, Francis Bru, Tommaso Ruggiero, Laurens Bourda, Kristof Van Hecke, Catherine Cazin, Steven P. Nolan
Despite the widespread use of well-defined PdII complexes as pre-catalysts for cross-coupling processes, the role of the throw-away ligand is still underexplored.
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An acidity-triggered aggregation nanoplatform based on degradable mesoporous organosilica nanoparticles for precise drug delivery and phototherapy of focal bacterial infection

Dalton Trans., 2024, 53,17893-17901
DOI: 10.1039/D4DT02111H, Paper
Yunhan Huang, Wei Guo, Xinyu Wang, Jingrui Chang, Bo Lu
An acidity-triggered aggregation antibacterial nanoplatform based on biodegradable mesoporous organic silica nanoparticles, is reported. It enables precise drug release and spatial accuracy for photodynamic therapy and photothermal therapy.
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Synthesis and relaxivity of gadolinium-based DOTAGA conjugated 3-phosphoglycerate

Dalton Trans., 2024, 53,17777-17782
DOI: 10.1039/D4DT02766C, Communication
Open Access
Andrew R. Brotherton, Shifa Noor Mohamed, Thomas J. Meade
A Gd-DOTAGA based MR contrast agent conjugated to 3-phosphoglycerate for enhanced relaxivity and investigation into its metabolism.
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Recent Advances in Syntheses and Emerging Applications of 2D Borophene based Nanomaterials with a Focus on Supercapacitors

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02573C, Frontier
Prashanta Pal, Mahasweta Nandi
Two dimensional (2D) nanosheet of boron i.e. borophene, triggered interest in progressive research as a result of the vast field of opportunities to explore, from its innovative synthetic techniques to...
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Detailed mechanism of DNA/RNA nucleobase substituting bridging ligand in diruthenium (II,III) and dirhodium (II,II) tetraacetato paddlewheel complexes: Protonation of the leaving acetate is crucial

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02621G, Paper
Open Access
Iogann Tolbatov, Tiziano Marzo, Paolo Umari, Diego La Mendola, Alessandro Marrone
Paddlewheel complexes of bimetallic scaffolds are emerging metallic agents in the bioinorganic chemistry landscape. In the most commonly employed construct, these complexes are decorated by carboxylate moiety, prompting their possible...
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Ball badminton days

In the early 1980s, local clubs in Mysuru used to conduct round-robin tournaments of the game




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Take the road less travelled

Doing easy things is wired into our psyche, but that is not enough




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Rising stars: Sadie Witkowski and Michael Graw

Interview with early-career scientists in psychology and oceanography




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Enhancing radiotherapy with MRI

Bas Raaymakers describes how MRI can help target tumours with improved accuracy




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D’Cunha report on COVID ‘scam’ adds more heat to bypoll campaign

While Yediyurappa denied the allegation and called it ‘politically motivated’, Chief Minister Siddaramaiah, quoting The Hindu report, said it vindicated their earlier stand




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Karnataka byelection: It is a proxy war between Lad and Reddy in mineral-rich Sandur

Though Sandur has been the hotbed of mining activities, often hitting the headlines for illegal mining, this issue is barely resonating in the campaign




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Meeting on Nirmala Tungabhadra Abhiyana organised in Shivamogga




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BJP made money from heaps of dead bodies during COVID-19, claims Dinesh Gundu Rao




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KSRTC plans to launch Ashwamedha AC buses within 100-km radius of Bengaluru

In contrast to regular Ashwamedha buses, the AC version will be smaller, fully air-conditioned, and equipped with comfortable seating, and amenities like charging ports 




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Tunga Aarati held in Shivamogga as part of campaign to clean river Tungabhadra

Shivamogga MLA S.N. Channabasappa appreciated the efforts of people and students involved in the padayatra from Sringeri to Harihar as part of a campaign to keep the river clean




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Karnataka Ministers seek action against Union Minister Pralhad Joshi for ‘agent’ comment on retired high court judge Michael D’Cunha

The two Ministers told the Governor that Mr. Joshi made a deliberate attempt to politicise and taint a constitutionally sanctioned inquiry, betraying public trust in the process




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Activists demand that govt. grant land to landless, instead of encroachers on contract

They also urged the State government to recover the hundreds of acres of land encroached upon by private company estates in the Malnad region




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Yaduveer flays DKS for his remarks on Bandipur night traffic ban




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BMTC driver assaulted over alleged road rage




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All roads lead to Channapatna on last day of public campaign




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Ragi, paddy procurement under MSP to start soon in Mysuru

MSP for ragi has been fixed at ₹4,290 a quintal while for paddy, the MSP is ₹2,300 a quintal; farmers must register on the FRUITS portal to use the facility




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Rise in rent of paddy harvesting machines worries farmers




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Farmers in Yadgir district sow groundnut as major crop for rabi season




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Effective development of human resources facilitates growth: Pralhad Joshi




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Don’t reduce quantum of advance, Minister Shivanand Patil tells NABARD




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Farmers demand revocation of decades-old waqf notices




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Vinicius 'tricks' Real Madrid to win!

Real Madrid forward Vinicius Jr scored a hat-trick to help the LaLiga champions snap a two-game winless run in all competitions.




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PIX: Real Sociedad shock Barcelona

Barcelona suffered a shock 1-0 LaLiga defeat at Real Sociedad on Sunday that ended their seven-match winning streak in all competitions.




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Solution-focused brief therapy with clients managing trauma [electronic resource] / Adam Froerer, Jacqui von Cziffra-Bergs, Johnny Kim, Elliott Connie.

New York, NY : Oxford University Press , 2018.




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Sacred cow, mad cow : a history of food fears / Madeleine Ferrières ; translated by Jody Gladding

New York : Columbia University Press, c2006




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Pandemonium : bird flu, mad cow disease, and other biological plagues of the 21st century / Andrew Nikiforuk

Toronto : Viking Canada ; New York, NY : Penguin Group (USA), 2006




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Your stone-age brain in the screen age [electronic resource] : coping with digital distraction and sensory overload / Richard E. Cytowic.

Cambridge, Massachusetts : The MIT Press, [2024]




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A parade of patriotism



  • T E Raja Simhan

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People have seen our work... Devendra Fadnavis exudes confidence in Mahayuti alliance retaining power in Maharashtra




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Maha: Malad residents saving money on medicines, courtesy Jan Aushadhi Kendras




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Maharashtra: Malad residents saving money on medicines, courtesy Jan Aushadhi Kendras




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Jan Aushadhi Kendras in Maharashtra: Bringing relief with low cost medicines




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Padmini Kolhapure, Shreyas Talpade urge people to vote in Maharashtra Assembly elections




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8 parties in tough fight on Mumbai's 36 seats ahead of civic body polls




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Ranji Trophy | Denish and Purkayastha give Assam the first-innings lead against TN

The captain’s 173-run association with Sibsankar for the fourth wicket turns the tide the hosts’ way; Pradosh picks up three wickets