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Enhanced photocatalytic performance of ZnO under visible light by co-doping of Ta and C using hydrothermal method

RSC Adv., 2024, 14,12954-12965
DOI: 10.1039/D4RA00579A, Paper
Open Access
Thi Viet Ha Luu, Hong Yen Xuan Nguyen, Quoc Thang Nguyen, Quang Bac Nguyen, Thi Ha Chi Nguyen, Ngoc Chuc Pham, Xuan Dung Nguyen, Trung Kien Nguyen, Ngoc Nhiem Dao
C, Ta-co-doped ZnO nanoparticles (Eg = 2.88 eV), prepared by hydrothermal method, were used as a photocatalyst under visible light to remove organic contaminants in aquatic environments.
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Highly homogeneous and stable single-walled carbon nanotubes dispersion modified by polyvinylpyrrolidone and alkanolamine in water

RSC Adv., 2024, 14,12947-12953
DOI: 10.1039/D4RA01614A, Paper
Open Access
Minghua Li, Shujun Yu, Xiting Fang, Zhiqiang Du, Xiaojin Ge
An easy green non-covalent surface functionalization of pristine SWCNT was carried out by using ball grinding technology, resulting in the formation of a highly homogeneous and stable PA-SWCNTs dispersion reported firstly in water.
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no

Antioxidant-rich brilliant polymeric nanocomposites for quick and efficient non-enzymatic hydrogen peroxide sensor

RSC Adv., 2024, 14,13142-13156
DOI: 10.1039/D4RA01768D, Paper
Open Access
M. S. Hashem, Hend S. Magar, Asmaa M. Fahim, Rokaya A. Sobh
New polymeric nanocomposites with metal oxide nanoparticles enhance electrical impedance ratings, offer energy storage and supercapacitors, and enable rapid creation of hydrogen peroxide sensors through microemulsion polymerization.
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no

Exploring the synthetic potential of epoxide ring opening reactions toward the synthesis of alkaloids and terpenoids: a review

RSC Adv., 2024, 14,13100-13128
DOI: 10.1039/D4RA01834F, Review Article
Open Access
Madiha Hanif, Ameer Fawad Zahoor, Muhammad Jawwad Saif, Usman Nazeer, Kulsoom Ghulam Ali, Bushra Parveen, Asim Mansha, Aijaz Rasool Chaudhry, Ahmad Irfan
Epoxides are oxygen containing three-membered heterocycles which can undergo ring opening reactions. These reactions have been significantly employed in the synthesis of alkaloids and terpenoids-based natural products.
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Self-supplying Cu2+ and H2O2 synergistically enhancing disulfiram-mediated melanoma chemotherapy

RSC Adv., 2024, 14,13180-13189
DOI: 10.1039/D4RA01075B, Paper
Open Access
Yingqian Gao, Xiaojun Cai, Weijuan Zou, Xiuzhen Tang, Lixian Jiang, Junnian Hao, Yuanyi Zheng, Xinhua Ye, Tao Ying, Ao Li
Disulfiram (DSF) can target and kill cancer cells by disrupting cellular degradation of extruded proteins and has therefore received particular attention for its tumor chemotherapeutic potential.
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no

A surface-independent bioglue using photo-crosslinkable benzophenone moiety

RSC Adv., 2024, 14,12966-12976
DOI: 10.1039/D4RA01866D, Paper
Open Access
Yue Shi, Xuelian Tao, Ping Du, Paul Pasic, Lars Esser, Hsien-Yeh Chen, Helmut Thissen, Peng-Yuan Wang
The UV-crosslinkable benzophenone (BP) “bio-glue” efficiently crosslinks with various surfaces and biomolecules. The beauty of this bio-glue lies in its simplicity and broad applicability, requiring no sophisticated equipment or reaction conditions.
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no

Expression of concern: Facile route to synthesize Fe3O4@acacia–SO3H nanocomposite as a heterogeneous magnetic system for catalytic applications

RSC Adv., 2024, 14,13016-13016
DOI: 10.1039/D4RA90043J, Expression of Concern
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Reza Taheri-Ledari, Mir Saeed Esmaeili, Zahra Varzi, Reza Eivazzadeh-Keihan, Ali Maleki, Ahmed Esmail Shalan
The content of this RSS Feed (c) The Royal Society of Chemistry




no

Grind, shine and detect: mechanochemical synthesis of AIE-active polyaromatic amide and its application as molecular receptor of monovalent anions or nucleotides

RSC Adv., 2024, 14,13227-13236
DOI: 10.1039/D4RA02129K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jakub S. Cyniak, Artur Kasprzak
The mechanochemical synthesis of AIE-active amide, as well as the application of the title compound as molecular receptor of monovalent anions and nucleotides, are described.
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Formation of H-bonding networks in the solid state structure of a trinuclear cobalt(III/II/III) complex with N2O2 donor Schiff base ligand and glutaric acid as bridging co-ligand: synthesis, structure and DFT study

RSC Adv., 2024, 14,13200-13208
DOI: 10.1039/D3RA07697K, Paper
Open Access
Sovana Maity, Sudip Bhunia, Michael G. B. Drew, Rosa M. Gomila, Antonio Frontera, Shouvik Chattopadhyay
Formation of hydrogen bonding network in a trinuclear linear mixed-valence centrosymmetric cobalt(III)–cobalt(II)–cobalt(III) complex has been analyzed using DFT calculations.
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1D hollow tubular/2D nanosheet hybrid dimensional porous carbon prepared by one-step carbonization using natural minerals as templates for supercapacitors

RSC Adv., 2024, 14,13190-13199
DOI: 10.1039/D4RA01873G, Paper
Open Access
Fangfang Liu, Chao Zhang, Weiwei Huang, Lei Chen, Yuanshuang Wang, Jinan Niu, Xiuyun Chuan
1D hollow tubular/2D nanosheet hybrid dimensional porous carbon was synthesized through one-step carbonization using 1D fibrous brucite and 2D layered magnesium carbonate hydroxide as templates.
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A multi-channel microfluidic platform based on human flavin-containing monooxygenase 3 for personalised medicine

RSC Adv., 2024, 14,13209-13217
DOI: 10.1039/D4RA01516A, Paper
Open Access
Melissa De Angelis, Silvia Schobesberger, Florian Selinger, Viktor Laurin Sedlmayr, Martin Frauenlob, Orsola Corcione, Shiman Dong, Gianfranco Gilardi, Peter Ertl, Sheila J. Sadeghi
A microfluidic platform with immobilized human flavin-containing monooxygenase for high-throughput screening of drugs with relevance to personalised medicine.
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no

Tight-binding model describes frontier orbitals of non-fullerene acceptors

Mol. Syst. Des. Eng., 2024, 9,382-398
DOI: 10.1039/D3ME00195D, Paper
Vishal Jindal, Michael J. Janik, Scott T. Milner
HOMO and LUMO of conjugated molecules as superposition of HOMO and LUMO of individual moieties.
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no

Mesoporous degradable chitosan-based monoliths: synthesis and applications toward water purification

Mol. Syst. Des. Eng., 2024, 9,399-408
DOI: 10.1039/D3ME00180F, Paper
Jyoti Devi Katiyar, Subrata Chattopadhyay
A synthetic strategy is presented for the preparation of degradable chitosan based functional porous polymer monoliths with tunable surface area, which are capable to efficiently remove multiple pollutants from water.
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Two-state nanocomposite based on symmetric diblock copolymer and planar nanoparticles: mesoscopic simulation

Mol. Syst. Des. Eng., 2024, 9,409-422
DOI: 10.1039/D3ME00176H, Paper
Maxim Malyshev, Daria Guseva, Pavel Komarov
A method for controlling the distribution and orientation of 2D fillers in the copolymer matrix is presented.
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Hard carbon derived from Physalis alkekengi L. husks as a stable anode for sodium-ion batteries

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00007B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Liying Liu, Henry R. Tinker, Yusheng Wu, Jiaqi Lv, Laishi Li, Yingjiao Fang, Yuhan Wu, Yang Xu
Physalis alkekengi L. husk-derived hard carbon is firstly investigated as the anode of sodium-ion batteries and demonstrates the great possibility of practical application.
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no

DNA nanostar structures with tunable auxetic properties

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D3ME00202K, Paper
Open Access
Yancheng Du, Ruixin Li, Anirudh S. Madhvacharyula, Alexander A. Swett, Jong Hyun Choi
A nanoscale metastructure with tunable auxetic properties is constructed with DNA origami. This DNA nanostar structure can reconfigure in two orientations that can lead to distinct negative Poisson's ratios.
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Kanoh: A railway station that’s off the beaten track

Kanoh, on the world heritage site Kalka-Shimla Line in Himachal Pradesh, has no roads, only train tracks




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No longer just forest residue

Women in HP are becoming financially independent thanks to pine needles




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This one is an innovative ‘stitches to riches’ story

How quilting discarded clothes is being used to empower women




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Many tunnels, no water

Construction of tunnels to connect what will be the world’s tallest railway bridge in Jammu and Kashmir’s Reasi district has left scores of villages without water




no

Reaping a knowledge-enabled harvest

A joint project educating Uttar Pradesh farmers on sustainable agriculture practices has helped improve output




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Where technology yields not microchips but sun-dried chips

The Women’s Technology Park in Salem is turning rural women into entrepreneurs, through sustainable schemes




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Working with pride, not prejudice

A recent job fair for the LGBTI community attracted people from cities and small towns




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Not a day’s medicine missed

How Project Ahana reached out to the HIV-positive community during the lockdown




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With no stable income, their earnings have bolted

Covid-19 has meant no tourists or joy rides at the Ridge in Shimla, leaving horse owners in penury




no

No ifs, just butts

A young entrepreneur turns cigarette waste into finished products




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A true digital revolution or ‘exclusion through technology’?

Lack of smartphones and poor connectivity have severely cramped internet outreach in Manipur during the ongoing pandemic




no

School’s out for those not connected

Online education during the pandemic blacks out marginalised students in Odisha’s rural districts




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Announcing updates to p5.js

A fresh upgrade to p5.js We’re excited to announce our work with p5.js to set the tech stack and rebuild their incredible website, supported by The Processing Foundation. The Processing Foundation is a rad organization that has helped folks in the visual arts improve their software literacy for over a decade. p5.js is an open-source […]




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Israeli Strikes Kill 46 People In The Gaza Strip And 33 In Lebanon, Medics Say

In Lebanon, large explosions shook Beirut's southern suburbs — an area known as Dahiyeh, where Hezbollah has a significant presence — soon after the Israeli military issued evacuation warnings for 11 houses there.




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Polymerization of isoprene and butadiene with unparalleled stereoselectivity catalysed by rare-earth metal cationic species bearing a novel tridentate ligand

Polym. Chem., 2024, 15,4255-4263
DOI: 10.1039/D4PY00781F, Paper
Xiuling Wang, Yang Wang, Zhonglei Qin, Liying Shen, Xiaochao Shi
Phenylthiol-functionalized rare-earth metal cationic species showed unparalleled stereoselectivity in the polymerization of isoprene and butadiene to respectively produce cis-1,4-polyisoprene and trans-1,4-polybutadiene.
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no

A facile and versatile platform for preparing uniform π-conjugated nanofibers with controlled length and varying shells

Polym. Chem., 2024, 15,4231-4243
DOI: 10.1039/D4PY00979G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Bo Xiang, Hongluo Wu, Rang Chen, Xiaoyu Huang, Guolin Lu, Chun Feng
A versatile and facile platform is developed for the generation of uniform π-conjugated nanofibers with controlled length and varying shells by the combination of pentafluorophenyl ester chemistry and a self-seeding strategy.
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no

Mechanical properties and molecular adhesion exhibited by inorganic–organic composite elastomers

Polym. Chem., 2024, 15,4196-4203
DOI: 10.1039/D4PY00879K, Paper
Naoki Yamashita, Ryohei Ikura, Kenji Yamaoka, Nobu Kato, Masanao Kamei, Kentaro Ogura, Minoru Igarashi, Hideo Nakagawa, Yoshinori Takashima
Organic–inorganic composite elastomers with reversible cross-links formed by β-cyclodextrin and adamantane (Ad) were prepared. Excess Ad units improve the mixability of polydimethylsiloxane and poly(ethyl acrylate) to increase the healing ratio.
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Versatile poly(N-vinylcaprolactam)-grafted-hydroxypropyl cellulose polymers with tailored thermo- and pH-responsive properties via sustainable organocatalyzed atom transfer radical polymerization

Polym. Chem., 2024, 15,4244-4254
DOI: 10.1039/D4PY00931B, Paper
Muhammad Asif Iqbal, Asif Mahmood, Waheed Al-Masry, Chan Ho Park, Sadaf Ul Hassan, Toheed Akhter
This study explores the synthesis of dual pH- and thermo-responsive poly(N-vinylcaprolactam)-grafted-hydroxypropyl cellulose (PNVCL-g-HPC) polymers via visible-light-driven, metal-free organocatalyzed atom transfer radical polymerization (O-ATRP).
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Heterogenous catalysis for oxygen tolerant photoredox atom transfer radical polymerization and small-molecule dehalogenation

Polym. Chem., 2024, 15,4264-4280
DOI: 10.1039/D4PY00899E, Paper
Open Access
Kriti Kapil, Mingkang Sun, Ting-Chih Lin, Hironobu Murata, Grzegorz Szczepaniak, Khidong Kim, Stephen DiLuzio, Jaepil Jeong, Mitchell Baumer, Stefan Bernhard, Tomasz Kowalewski, Krzysztof Matyjaszewski
Heterogeneous photocatalysts (PCs) have garnered attention for their sustainability and cost-effectiveness.
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Materials designed to degrade: structure, properties, processing, and performance relationships in polyhydroxyalkanoate biopolymers

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00623B, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jessica N. Lalonde, Ghanshyam Pilania, Babetta L. Marrone
A materials tetrahedron framework is applied to PHA biopolymers to highlight design challenges and frame potential future research exploring structure, property, processing, and performance relationships.
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Self-healable, reprocessable and anti-flammable eugenol-derived covalent adaptable thermosets based on dynamic covalent boronic esters and thiol–ene click chemistry

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00684D, Paper
Haoxin Niu, Yu Li, Ping Zhang, Wenwen Guo, Xin Wang, Yuan Hu
Self-healable and reprocessable eugenol-derived covalent adaptable thermosets were fabricated via dynamic covalent boronic esters and thiol–ene click chemistry.
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The CF3TMS adduct of anthraquinone as a monomer for making polymers with potential as separation membranes

Polym. Chem., 2024, 15,4312-4318
DOI: 10.1039/D4PY01002G, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kim Jiayi Wu, John M. Tobin, Anli Ji, Yang Shi, Chunchun Ye, Gary S. Nichol, Alessio Fuoco, Mariagiulia Longo, Johannes C. Jansen, Neil B. McKeown
The CF3TMS adduct of anthraquinone reacts with diphenyl ether via a superacid-catalysed step-growth polymerisation to give a polymer (BTFMA-DPE) with promise for making gas separation membranes.
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Synthesis of Asymmetric Imine Polymers for Highly Selective Sorting of Semiconducting Single-Walled Carbon Nanotubes by Two in One Strategy

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00607K, Paper
Ying Zhang, Yu Li, Yuchi Wan, Jun-Hao Wang, Yunzhen Chang, Sheng Zhu, Lan Bai, Yu Cao, Xuelei Liang, Gaoyi Han
By two in one strategy, we get three polymers of fluorene derivative with asymmetric structure functionalized with two types of arenes with different orientation and electronic properties. The polymers are...
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An efficient and economical degradation strategy for epoxy thermoset based on low cost transesterification catalyst

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01137F, Paper
Zhijun Yang, Shuhan Zhang, Huan Liang, Enjian He, Yixuan Wang, Ting Lei, Zhicheng Wu, Qiulin Chen, Fusheng Zhou, Yen Wei, Yan Ji
Epoxy thermoset materials are widely used in the field of electrical engineering, including gas-insulated enclosed switches and drytype transformers. It is a challenge to degrade and recycle traditional epoxy thermoset,...
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Functionalization of nano-objects in living anionic polymerization-induced self-assembly and their use for improving thermal properties of epoxy resins

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY01008F, Paper
Guicun Guo, Jiali Wu, Jingwei Zhang, Peng Zhou, Ding Shen, Penghan Li, Guowei Wang
Using LAPISA or LAPICA, stabilized PDVB@(PI-b-PS) and PDVB@(PI-b-PS/PS) nano-objects were prepared, functionalized and used as additives for epoxy resin, providing improved Tgs, integrated interfaces, uniform distributions, and scalable applications.
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no

[Ru]-Catalyzed Olefin Metathesis and Ethenolysis for the Synthesis and Recycling of Bio-Based Polycarbonates and Polycyanurates

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00940A, Paper
Dana M. Pinson, Francesca D. Eckstrom, Gregory S. Ostrom, K. Randall McClain, Lawrence Baldwin, Benjamin Grant Harvey
Eugenol, an abundant, naturally occurring phenolic compound, was converted into a thermoplastic polycarbonate by olefin metathesis followed by interfacial polymerization with triphosghene. This resulted in polymers with Mn ranging from...
The content of this RSS Feed (c) The Royal Society of Chemistry




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A novel amine-first strategy suitable for preparing both functional and engineering bio-polyamides: furfurylamine as the sole furan source for bisfuranic diamine/diacid monomers

Polym. Chem., 2024, 15,4433-4446
DOI: 10.1039/D4PY00567H, Paper
Hong-Hui Shu, Yun Liu, Sheng-Li Han, Xiu-Qin Fang, Chang Wang, Cheng-Mei Liu
Biomass-based polyamides (bioPAs) are renewable materials that are viable alternatives to petroleum-based polyamides in the engineering field.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Acid-labile and non-degradable cross-linked star polymer model networks by aqueous polymerization for in situ encapsulation and release

Polym. Chem., 2024, 15,4454-4464
DOI: 10.1039/D3PY00677H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Gavin Irvine, Stuart Herron, Daniel W. Lester, Efrosyni Themistou
Aqueous RAFT polymerization for the preparation of degradable and non-degradable cross-linked star polymer model networks, in situ dye encapsulation and release.
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Enhanced mechanical properties of acrylate and 5-vinyl-2-norbornene-based ethylene terpolymers: rational design and synthesis using remotely modulated phosphine–sulfonate palladium complexes

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00722K, Paper
Yong-Qing Li, Gui-Ping Cao, Yu-Cai Cao
From a practical perspective, it is important to maintain or increase the mechanical properties of functional ethylene copolymers to those of nonpolar polyethylene (PE).
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Bisbenzothieno[b]-fused BODIPYs in panchromatic photoinitiating for the free radical and cationic photopolymerization and application in 3D printing

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00926F, Paper
Yangyang Xu, Wenlong Tang, Hui Deng, Jianjun Zhang, Zhongquan Zhu, Changjiang Yu, Haiguang Zhu, Ke Sun, Jiazhu Li, Jacques Lalevée
Abstract: Polymerization reactions induced by lights occupy an increasing share in the area of polymer synthesis; however, the effective photopolymerization under visible light emitting diodes (LEDs) rather than UV still...
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Fully Bio-Based Acetal Diepoxy Monomers: High Modulus, Good Thermal Stability and Readily Degradability

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01038H, Paper
Zidie Song, Li Liu, Pengbo Zhang, Kangle Xue, Zibo Hua, Tao You, Yiqi Wu, Hong Cui, Zhen Hu, Yudong Huang
Degradable epoxy resins are designed to address the environmental pollution caused by traditional epoxy resins. However, incorporating the degradability of dynamic covalent bonds in the design of degradable resins often...
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Reversible aminolysis: a new concept for postpolymerization modification

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00827H, Communication
Koki Kasai, Hideki Amii, Ryohei Kakuchi
Efficient yet reversible aminolysis postpolymerization modification reactions.
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Mesomorphic and photochromic luminescent behaviour of side-chain liquid crystalline polymers containing di-substituted cyanostilbene groups with the different number of alkyl tail chain

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00889H, Paper
Juan Luo, Juan Wang, Junde Zhang, Huizi Cao, Xiaofang Chen
In this work, side-chain luminescent liquid crystalline polymers (SCLLCPs) that contain di-substituted cyanostilbene (CS) groups with the different substituted number of terminal alkyl chain, which are PNB-Z-4, PNB-Z-34, and PNB-Z-345,...
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Diversified synthesis of poly(sulfonyl isourea)s by multicomponent polymerizations of isocyanides, sulfonyl azides, and alcohols/phenols

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00953C, Paper
Dongyang Fan, Fenggang Chen, Dong Wang, Ting Han, Ben Zhong Tang
A novel multicomponent polymerization strategy using diverse monomer combinations of isocyanides, sulfonyl azides, and alcohols/phenols was developed to synthesize thermally and morphologically stable and heteroatom-rich poly(sulfonyl isourea)s.
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