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ad Advances, opportunities, and challenges in methods for interrogating the structure activity relationships of natural products By pubs.rsc.org Published On :: Nat. Prod. Rep., 2024, 41,1543-1578DOI: 10.1039/D4NP00009A, Review Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Christine Mae F. Ancajas, Abiodun S. Oyedele, Caitlin M. Butt, Allison S. WalkerThis review highlights methods for studying structure activity relationships of natural products and proposes that these methods are complementary and could be used to build an iterative computational-experimental workflow.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ad Estimating the extent of adulteration of the popular herbs black cohosh, echinacea, elder berry, ginkgo, and turmeric – its challenges and limitations By pubs.rsc.org Published On :: Nat. Prod. Rep., 2024, 41,1604-1621DOI: 10.1039/D4NP00014E, Review Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Nilüfer Orhan, Stefan Gafner, Mark BlumenthalThis review article focuses on the challenges and limitations of estimating the prevalence of adulteration in preparations made from black cohosh, echinacea, elder berry, ginkgo, and turmeric.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ad Highly stable chiral Cr(III)-based metal–organic frameworks for enantioadsorption separation of aromatic alcohols By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,1998-2006DOI: 10.1039/D4QI00113C, Research ArticleMengna Li, Benlai Wu, Maochun HongHighly stable Cr-HMOFs Cr-HMOF-1 and Cr-HMOF-2 were synthesized for the first time directly using enantiomerically pure chiral ligands, showing excellent enantioselective separation performance for aromatic alcohol racemates.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ad Te doped 1T/2H-MoSe2 nanosheets with rich defects as advanced anode materials for high-rate sodium ion half/full batteries By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2017-2028DOI: 10.1039/D4QI00259H, Research ArticleZhiqi Li, Jiawen Yan, Qiming Li, Ao Xu, Jianchao Sun, Yijing Wang, Xiaoyu Zhang, Xueqin Sun, Fuyi Jiang, Yanli ZhouMoSe2 with a two-dimensional layer-like structure has been considered a promising anode material for sodium-ion batteries (SIBs) on account of its high capacity and rich reserves on Earth.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ad Combination of dimensional reduction and active site addition strategies for preparing unique {RE9}-cluster-based MOFs: efficient CO2 fixation and Knoevenagel condensation By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2071-2080DOI: 10.1039/D3QI02527F, Research ArticleYing Zhao, Dan Wu, Yidan Qiao, Guo-Ping Yang, Lu-Fang Ma, Yao-Yu WangA series of 2D {RE9}-cluster-based rare-earth MOFs were built by dimensional reduction and active site addition strategies. They exhibit excellent catalytic activity in CO2 fixation and Knoevenagel condensation under mild conditions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ad Sodium ion pre-intercalation regulates the electron density and structural stability of vanadium oxide nanowires for Ca–ion batteries By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00218K, Research ArticleHuajie Feng, Yize Wang, Wenda Qiu, Zixi Liu, Yaping Tao, Xihong LuBenefiting from the abundant resource, low cost, and high operating potential, calcium–ion batteries (CIBs) have attracted great attention as emerging energy storage devices over lithium-based systems.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ad Adhesion, stability, structural and electronic properties of perovskite/BaWO4 heterostructures: first-principles and experimental characterizations By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00231H, Research ArticleYao Guo, Shiding Zhang, Zhaoyu Zhang, Yuanbin Xue, Jianxin Li, Haixiang Song, Yuhua Wang, Qing ShenThe interfacial behavior and mechanism of the CsPbBr3/BaWO4 and MAPbBr3/BaWO4 heterostructures have been extensively investigated by a combined first-principles and experimental analysis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ad Modulating Mn self-reduction and multimodal luminescence in CaSb2O6 through La3+ doping for quadruple-mode dynamic anti-counterfeiting and optical temperature sensing applications By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00493K, Research ArticleFenzhong Long, Lu Xie, Jiawei Fu, Kaian Shan, Huihui Fei, Xinmin ZhangThe co-doping La3+strategy was employed to modulate Mn self-reduction and multimodal luminescence in CaS2O6:Mn. CaS2O6:Mn has potential application in optical anti-counterfeiting and high-sensitivity temperature sensing applications.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ad Synergistic role of hydrogen bonding and band degeneracy leads to enhanced X-ray detection in HPIP-(NH4)0.7Cs0.3Br3·H2O perovskites By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00272E, Research ArticlePengxiang Dong, Chensheng Lin, Xin Zhao, Yicong Lv, Ning Ye, Min LuoThis work shows the innovative introduction of Cs+ into molecular perovskites to co-occupy with NH4+, synthesis of the HPIP-(NH4)0.7Cs0.3Br3·H2O perovskite, and fabrication of an X-ray detector with excellent overall performance and superior environmental stability.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ad Rational design for broad near-infrared emission from a two-sited Rb2LiAlF6:Cr3+ phosphor with high efficiency and thermal stability for spectroscopic applications By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00429A, Research ArticleSong Qing, Jing Wan, Tao Yang, Qiang Zhou, Yayun Zhou, Zhengliang Wang, Dawei Wen, Mingmei WuA comparative investigation of broadband near-infrared luminescence from two different occupation sites in Rb2LiAlF6:Cr3+ with high efficiency and excellent thermal stability.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ad Controlling the structural and adsorption features of polyoxovanadate-based metal–organic clusters by adjustable template effect By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00254G, Research ArticleYan-Hu Wang, Ke-Wei Tong, Chao-Qin Chen, Jing Du, Guo-Ping Yang, Peng YangAn adjustable template effect was employed to activate the evolution of polyoxovanadate-based metal–organic clusters, resulting in unprecedented structural archetypes as well as customized dye and iodine adsorption features.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ad Efficient doped and non-doped light-emitting diodes based on a TADF-emitting Cu4Br4 cluster By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00210E, Research ArticleXin Lu, Shao-Jie Wu, Ya-Shu Wang, Shan-Yue Wei, Lingyi Meng, Xi-He Huang, Xu-Lin Chen, Can-Zhong LuA sublimable Cu4Br4 cluster, chelated by bidentate N^P ligands with a donor–acceptor configuration, realizes highly efficient doped and non-doped cluster light-emitting diodes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ad Porphyrin-based MOFs for photocatalysis in water: advancements in solar fuels generation and pollutants degradation By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2212-2245DOI: 10.1039/D3QI01996A, Review Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Fangbing Liu, Irene Rincón, Herme G. Baldoví, Amarajothi Dhakshinamoorthy, Patricia Horcajada, Sara Rojas, Sergio Navalón, Alexandra FateevaThis review highlights the recent advances in the photocatalytic applications of porphyrin-based MOFs in aqueous environments for solar fuel generation and water remediation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ad Three in one: a cadmium bismuth vanadate NLO crystal exhibiting a large second-harmonic generation response and enhanced birefringence By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2384-2391DOI: 10.1039/D4QI00261J, Research ArticleShuya Liu, Conggang Li, Jinmiao Jiao, Yuheng She, Tinghui Zhang, Dianxing Ju, Ning Ye, Zhanggui Hu, Yicheng WuA novel vanadate NLO crystal Cd2BiVO6 was synthesized through spontaneous crystallization, exhibiting a large SHG response, an enhanced birefringence and a wide transmittance range.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ad sp2–sp cross-carbanion coupling at a rare-earth center leading to the formation of carbon–carbon double bonds By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2312-2318DOI: 10.1039/D4QI00178H, Research ArticleZhengqi Chai, Ze-Jie Lv, Wei Liu, Jinxiao Yang, Junnian Wei, Wen-Xiong ZhangThe reaction of rare-earth azametallacyclopentadienes with terminal alkynes provides rare-earth metallacycles with cumulated double bonds in three steps: alkynyl C–H bond activation, sp2–sp cross-carbanion coupling and subsequent isomerization.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ad Energetic copper(II) quadridentate chelate: a novel green laser-sensitive primary explosive By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00489B, Research ArticleQi Zhang, Ruibing Lv, Ying Wang, Zhenghang Luo, Pengyang Pan, Tingwei Wang, Quancheng LiuA copper(II)-based quadridentate chelate [Cu(BNATE)·2H2O] has been prepared and systematically studied. It has excellent near-infrared laser sensitivity and detonation performance, and low mechanical sensitivity.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ad Homochiral Dy2 single-molecule magnets with strong magneto-optical Faraday effect and strong third-harmonic generation By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI00691G, Research ArticleCai-Ming Liu, Rong Sun, Xiang Hao, Xi-Li Li, Bingwu WangFour pairs of homochiral Dy2 complexes were directionally prepared using homochiral β-diketone ligands {D-Htfc/L-Htfc = (+)/(−)-3-trifluoroacetyl camphor, D-Hpfc/L-Hpfc = 3-(perfluorobutyryl)-(+)/(−)-camphor} and hydrazone Schiff base bridging ligands {H2L1 = (E)-N'-(2-hydroxy-3-methoxybenzylidene)pyrazine-2-carbohydrazide, H2L2...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ad Radiochromic Semiconductive MOF with High Sensitivity and Fast Photochromic Response for Dual-mode X-ray Direct Detection By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI00771A, Research ArticleXuying Yu, Jia-Rong Mi, Qiu-Pei Qin, Xin-Ping Fang, Yong-Fang Han, Li-Zhen Cai, Ming-Sheng Wang, Guo-Cong GuoX-ray direct detectors, which may directly convert X-rays into electrical signals through semiconductors, are highly desirable for early cancer screening and other applications. Prevailing commercial amorphous Se detectors still suffer...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ad Large enhancement of electrochemical biomass oxidation by optimizing the competitive adsorption of HMF and OH− on doped CoOx By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00519H, Research ArticleTianqi Nie, Guihao Liu, Ziheng Song, Tianyang Shen, Xiaoliang Sun, Tianrui Yu, Sha Bai, Lirong Zheng, Yu-Fei SongBy doping transition metals into CoOx, we can regulate the deintercalation capacity of OH−. The CoCuOx with enriched oxygen vacancies allowed the optimization of the competitive adsorption between HMF and OH−, and accelerated the kinetics of HMFOR.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ad Advances in technical strategies for monitoring the reduction of platinum(IV) complexes By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00459K, Review Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Shu Chen, Qiyuan Zhou, Ka-Yan Ng, Zoufeng Xu, Weikang Xu, Guangyu ZhuThe reduction of Pt(IV) complexes can be monitored by various analytical techniques. These techniques hold significant promise in elucidating the mechanisms of Pt(IV) prodrug activation, aiding in the rational design of novel Pt(IV) prodrugs.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article