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Reversible on–off switching of a single-chain magnet via single-crystal-to- single-crystal transition- and light-induced metal-to-metal electron transfer

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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI01691B, Research Article
Meng-Jia Shang, Han-Han Lu, Qiang Liu, Ren-He Zhou, Hui-Ying Sun, Zhen Shao, Liang Zhao, Yin-Shan Meng, Tao Liu
The development of single-chain magnets with reversible and adjustable properties is of great significance for achieving high-density information storage and switching devices with multi-stimuli responsiveness whilst remains a challenging task....
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Fe3O4-decorated MXene for the effective removal of 133Ba and 137Cs: synthesis, characterization, and optimization via response surface methodology (RSM)

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Inorg. Chem. Front., 2024, 11,7860-7871
DOI: 10.1039/D4QI00404C, Research Article
Shalu Atri, Vipul Vilas Kusumkar, Süleyman İnan, Maros Gregor, Tomas Roch, Maria Caplovicova, Michal Galambos, Eva Viglasova, Gustav Plesch, Martin Motola, Olivier Monfort
The potential activity of Fe3O4 decorated MXenes in the removal of highly toxic 133Ba and 137Cs using a radioactive indicator method.
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High-efficiency tunable self-trapped exciton emission in one-dimensional β-Cs3Cu2Br5via Ag alloying for optoelectronic applications

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Inorg. Chem. Front., 2024, 11,7793-7802
DOI: 10.1039/D4QI00970C, Research Article
Xin Xu, Zhongyi Wang, Qingkun Kong, Siping Liu, Ruiling Zhang, Xiaojing Liu, Keli Han
Metastable 1D β-Cs3Cu2Br5 synthesized by rapid cooling could be stabilized by Ag+. Ag-alloyed samples exhibit tunable emission from blue-greenish to yellow, which is attributed to different degrees of lattice distortion regulated by Ag+.
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Exchange of equatorial ligands in protein-bound paddlewheel Ru25+ complexes: new insights from X-ray crystallography and quantum chemistry

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Inorg. Chem. Front., 2024, 11,7803-7811
DOI: 10.1039/D4QI01846J, Research Article
Open Access
Aarón Terán, Francesca Fasulo, Giarita Ferraro, Ana Edilia Sánchez-Peláez, Santiago Herrero, Michele Pavone, Ana Belén Muñoz-García, Antonello Merlino
The reactivity of [Ru2Cl(D-p-CNPhF)(O2CCH3)3]n (D-p-CNPhF− = N,N'-bis(4-cyanophenyl)formamidinate) with the model protein RNase A has been investigated by X-ray crystallography and Quantum Chemistry.
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Al-alkyl borate salt cocatalysts for olefin polymerization: exploration of N-donor ligand variations

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Inorg. Chem. Front., 2024, 11,7872-7885
DOI: 10.1039/D4QI01874E, Research Article
Open Access
Gaia Urciuoli, Francesco Zaccaria, Cristiano Zuccaccia, Roberta Cipullo, Peter H. M. Budzelaar, Leonardo Tensi, Antonio Vittoria, Christian Ehm, Alceo Macchioni, Vincenzo Busico
The stability and reactivity of {[iBu2(L)Al]2(μ-H)}+[B(C6F5)4]− (AlHAl), recently identified as a promising cocatalyst for olefin polymerization, can be modulated by varying the structure of the neutral N-donor (L).
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Realizing efficient broadband near-infrared emission under blue light excitation in Sb3+-doped zero-dimensional organic tin(IV)-based metal halides via coordination structure modulation

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Inorg. Chem. Front., 2024, 11,7979-7990
DOI: 10.1039/D4QI01904K, Research Article
Bao Ke, Hui Peng, Yongqi Yang, Chengzhi Yang, Shangfei Yao, Arfan Bukhtiar, Qilin Wei, Jialong Zhao, Bingsuo Zou
Here, we report a new NIR emitter of Sb3+-doped tin(IV)-based metal halides via coordination structure modulation, which can exhibit bright broadband NIR emission under blue light excitation with a PLQY of 33.2%.
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Tuning the phototherapeutic activity of Pt(IV) complexes for bladder cancer via modification of trans N-heterocyclic ligands

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Inorg. Chem. Front., 2024, 11,7898-7909
DOI: 10.1039/D4QI01765J, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Huayun Shi, Guy J. Clarkson, Peter J. Sadler
The photochemotherapeutic activity of diazido Pt(IV) complexes towards bladder cancer, a common cancer with expensive treatment, has been tuned via modification of trans N-heterocyclic ligands, to give a candidate for preclinical development.
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Pyridyl–triazole ligands enable in situ generation of a highly active dihydride iridium(III) complex for formic acid dehydrogenation

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Inorg. Chem. Front., 2024, 11,7921-7929
DOI: 10.1039/D4QI01818D, Research Article
Miriam Abán, J. Marco Cuenca, Irene Embid, Alba de Toro, Pilar Gómez-Sal, Ernesto de Jesús, Marta Valencia, Cristina G. Yebra
[CpIr(CO)H2] efficiently catalyses formic acid dehydrogenation, forming in situ from pyridyl-triazole pre-catalysts [Cp*Ir(k2-NN)(Cl)][OTf]. Neat formic acid is dehydrogenated with a TON of up to 26876 and a TOF exceeding 10700 h−1.
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Highly defective and conductive Cu-doped 1T/2H-MoS2 nanosheets as high-capacity cathode materials for enhanced magnesium-ion storage

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Inorg. Chem. Front., 2024, 11,7831-7842
DOI: 10.1039/D4QI02064B, Research Article
Ao Xu, Yan Liu, Jiahui Wang, Yijing Wang, Fuyi Jiang, Yanli Zhou
Limited by the poor electronic conductivity and strong interaction between Mg2+ and MoS2, the 2H phase of MoS2 as a cathode material exhibits low capacity and poor rate capability.
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Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds

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Inorg. Chem. Front., 2024, 11,7756-7774
DOI: 10.1039/D4QI02232G, Review Article
Hangwei Jia, Xueling Hou, Shilie Pan
The calculated polarizability anisotropy, hyperpolarizability and HOMO–LUMO gap of optically active groups.
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Shooting short-wavelength nonlinear optical materials with targeted balance performances in hydroxyborates through first-principles high-throughput screening

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Inorg. Chem. Front., 2024, 11,7843-7852
DOI: 10.1039/D4QI02234C, Research Article
Chenxu Li, Abudukadi Tudi, Huanhuan Cheng, Qingyu Liu, Zhihua Yang, Shilie Pan
High-throughput screening of 222 hydroxyborates identified three as promising short-wavelength ultraviolet nonlinear optical. with phase-matching second harmonic generation capacity extending to the solar blind region (200–280 nm).
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Metal–organic framework micro-nano reactors as armour of Escherichia coli for hydrogen production in air

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Inorg. Chem. Front., 2024, 11,8070-8077
DOI: 10.1039/D4QI02119C, Research Article
Yun Fan, Junyang Yan, Siyao Zhang, Ruifa Su, Baoli Zha, Weina Zhang
The MOF shell of an E. coli@ZIF-8 micro–nano reactor, used as armour for E. coli, not only protects the internal E. coli and improves its survival rate, but also delays the transport of oxygen to enable E. coli to produce hydrogen in air.
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Active molecular units in metal organic frameworks for artificial photosynthesis

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Inorg. Chem. Front., 2024, 11,7682-7755
DOI: 10.1039/D4QI01363H, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Subrata Mandal, Sahar Yoosefi, Alexander K. Mengele, Sven Rau, Andrea Pannwitz
Metal–organic frameworks (MOFs) integrate photoactive and catalytic entities within a 3D structure. This review classifies photocatalytic MOFs by photosensitizer and catalyst localization and their roles in artificial photosynthesis.
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Ru-anchoring Co-MOF-derived porous Ru-Co3O4 nanomaterials for enhanced oxygen evolution activity and structural stability

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Inorg. Chem. Front., 2024, 11,8139-8145
DOI: 10.1039/D4QI02061H, Research Article
Nan Li, Lujiao Mao, Yuting Fu, Haoran Wang, Yuchang Shen, Xuemei Zhou, Qipeng Li, Jinjie Qian
This study demonstrates a new approach for Ru-anchoring CoOF-1-derived porous Ru-Co3O4 nanomaterials with high activity and durability, showcasing great potential in the field of practical energy storage and conversion.
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Critical metal recovery from spent lithium-ion batteries’ leaching solution using electrodialysis technologies: strategies and challenges

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Inorg. Chem. Front., 2024, 11,7775-7792
DOI: 10.1039/D4QI01978D, Review Article
Tianshu Zhang, Yijun Qian, Changyong Zhang, Tao Qian, Chenglin Yan
This review overviews the recent advances in electrodialysis (ED) in extracting critical metals from spent battery leachate. In addition, strategies and challenges regarding ED techniques toward battery recycling are pointed out.
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Correction: Unexpected in crystallo reactivity of the potential drug bis(maltolato)oxidovanadium(IV) with lysozyme

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Inorg. Chem. Front., 2024, 11,8147-8147
DOI: 10.1039/D4QI90073A, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Maddalena Paolillo, Giarita Ferraro, Irene Cipollone, Eugenio Garribba, Maria Monti, Antonello Merlino
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Hierarchical FeCo LDH/NiSe heterostructure electrocatalysts with rich heterointerfaces for robust water splitting at industrial-level current density

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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02426E, Research Article
Weiwei Han, Wenyi Wang, Jiahong Liao, Yi He, Xingwang Zhang, Chunlin Yu
Sustainable hydrogen production by electrocatalytic water splitting is a promising energy storage technology yet challenging due to the sluggish kinetics of the oxygen evolution reaction (OER). Rationally designed robust and...
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Naphthalene diimide-based crystalline hybrid photochromic materials: Structural types, photochromic mechanism, and applications

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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02653E, Review Article
Li Li, Jian-Ge Zeng, Ning-Ning Zhang, Yu Yang-Tao, Shu-Hao Li, Yang Hua
The multifunctional stimuli-responsive photochromic materials significantly expand their application fields, including molecular switching, information storage and encryption, detection and sensing, etc. 1,4,5,8-naphthalenediimides (NDIs) have been widely used for the construction...
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Tunable luminescence via Cr3+–Yb3+/Nd3+ energy transfer in Cr3+ and Yb3+/Nd3+ coactivated NIR phosphors for non-destructive analysis

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02260B, Research Article
Open Access
Xiaowei Zhang, Dashuai Sun, Pengcheng Luo, Luhui Zhou, Zheng Lu, Jia Liu, Congcong Fan, Xinyu Ye, Hongpeng You
Novel high-efficiency near-infrared phosphors with tunable luminescence via Cr3+–Yb3+/Nd3+ energy transfer for non-destructive analysis.
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Ammonia and formate cosynthesis via nitrate electroreduction combined with methanol electrooxidation over nitrogen-doped carbon-encapsulated nickel iron phosphide

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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02350A, Research Article
Zongyi Wang, Jiuli Chang, Zhiyong Gao
Nitrate–methanol co-electrolysis by the pairwise cathodic NO3RR and anodic MOR is a viable way to coproduce ammonia (NH3) and formate via gentle, sustainable and energy-saving “E-refining” and “E-reforming” means.
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Pentagonal-bipyramidal Dysprosium(III) complexes with two apical phosphine oxide ligands and equatorial pentadentate N3O2 Schiff-base ligands: Breakdown of the apical magnetic axiality by strong equatorial crystal field†

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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02262A, Research Article
Tamara A. Bazhenova, Vyacheslav Kopotkov, Denis V. Korchagin, Elena Yureva, Michael V. Zhidkov, Alexey I Dmitriev, Ilya Yakushev, N. N. Efimov, Konstantin Andreevich Babeshkin, Vladimir Sergeevich Mironov, Eduard B. Yagubskii
A series of three new seven-coordinate pentagonal-bipyramidal (PBPY-7) Dy(III) complexes [Dy(LCH3)(Cy3PO)2]ClO4∙CH3CN (1), [Dy(L2(t-Bu))(Ph3PO)2]ClO4∙0.63C2H5OH (2), [Dy(LOCH3)(Ph3PO)2]ClO4∙2H2O (3) including various chelating pentadentate ligands with a [N3O2]2− binding node in the equatorial plane,...
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The use of single metal atoms-based photocatalysts for the production of ammonia through photocatalytic nitrogen fixation

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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02449D, Review Article
Ping Zhang, Yongchong Yu, Reyila Tuerhong, Xinyu Du, Keyi Chai, Xiaoping Su, Qiong Su, Shujuan Meng, Lijuan Han
The conventional synthetic ammonia industry is characterized by its high energy consumption, necessitating the exploration of a new environmentally sustainable method for NH3 synthesis. A prospective alternative to the Haber-Bosch...
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Nanoscale sorting of extracellular vesicles via optically-induced dielectrophoresis on an integrated microfluidic system

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Lab Chip, 2024, 24,1965-1976
DOI: 10.1039/D3LC01007D, Paper
Wei-Jen Soong, Chih-Hung Wang, Chihchen Chen, Gwo-Bin Lee
We devised an innovative method for automated sorting of extracellular vesicles (EVs) employing optically-induced dielectrophoresis on an integrated microfluidic chip. EVs of three distinct size categories could be isolated in 1 h at a purity of 86%.
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Capturing of extracellular vesicles derived from single cells of Escherichia coli

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Lab Chip, 2024, 24,2049-2057
DOI: 10.1039/D3LC00707C, Paper
Open Access
Fumiaki Yokoyama, André Kling, Petra S. Dittrich
A microdevice with narrow winding channels is introduced to trap and culture single bacterial cells. It is used to study growth patterns of the cells and to monitor secretion of extracellular vesicles under treatment with an antibiotic drug.
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Wearable intelligent sweat platform for SERS-AI diagnosis of gout

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Lab Chip, 2024, 24,1996-2004
DOI: 10.1039/D3LC01094E, Paper
Zhaoxian Chen, Wei Wang, Hao Tian, Wenrou Yu, Yu Niu, Xueli Zheng, Shihong Liu, Li Wang, Yingzhou Huang
A wearable intelligent SERS platform enables the sensitive detection of UA (0.1 μM) in sweat for AI diagnosis of gout.
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Multifunctional cardiac microphysiological system based on transparent ITO electrodes for simultaneous optical measurement and electrical signal monitoring

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Lab Chip, 2024, 24,1903-1917
DOI: 10.1039/D3LC00908D, Paper
Zhangjie Li, Kai Niu, Chenyang Zhou, Feifan Wang, Kangyi Lu, Yijun Liu, Lian Xuan, Xiaolin Wang
We developed a multifunctional cardiac microphysiological system on transparent electrodes, enabling simultaneous electrical signal monitoring and optical observations of cardiac tissue, holding promise for applications in cardiac drug development.
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SeParate: multiway fluorescence-activated droplet sorting based on integration of serial and parallel triaging concepts

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Lab Chip, 2024, 24,2107-2121
DOI: 10.1039/D3LC01075A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Wannes Verbist, Jolien Breukers, Sapna Sharma, Iene Rutten, Hans Gerstmans, Lotte Coelmont, Francesco Dal Dosso, Kai Dallmeier, Jeroen Lammertyn
A novel platform, called SeParate, enabling accurate multiplex droplet sorting by integrating serial and parallel sorting principles for three model systems with increasing complexity and intra-subpopulation variation in fluorescence intensities.
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Droplet microfluidic system for high throughput and passive selection of bacteria producing biosurfactants

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Lab Chip, 2024, 24,1947-1956
DOI: 10.1039/D3LC00656E, Paper
Open Access
Klaudia Staskiewicz, Maria Dabrowska-Zawada, Lukasz Kozon, Zofia Olszewska, Lukasz Drewniak, Tomasz S. Kaminski
Novel microfluidic technique for functional selection of biosurfactant-producing microorganisms. Single bacterial cells are encapsulated into picoliter droplets for clonal cultivation and passively sorted at high throughput by interfacial tension.
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Spatially controlled diffusion range of tumor-associated angiogenic factors to develop a tumor model using a microfluidic resistive circuit

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Lab Chip, 2024, Advance Article
DOI: 10.1039/D3LC00891F, Paper
Yu-Hsiang Hsu, Wen-Chih Yang, Yi-Ting Chen, Che-Yu Lin, Chiou-Fong Yang, Wei-Wen Liu, Subhashree Shivani, Pai-Chi Li
The DC-MPS device uses a velocity V-clamp to create a partition with a steep concentration gradient for simultaneously developing vasculogenic vessels and a tumor. It enables vessel–tumor interaction to develop a tumor model with angiogenic vessels.
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Detection and Identification of Single Ribonucleotide Monophosphates using a Dual In-Plane Nanopore Sensor Made from a Thermoplastic via Replication

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Lab Chip, 2024, Accepted Manuscript
DOI: 10.1039/D3LC01062G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Steven A. Soper, Chathurika Rathnayaka, Indu Chandrasoma, Junseo Choi, Katie Childers, Maximillian Chibuike, Khurshed Akabirov, Farhad Shiri, Adam R Hall, Collin J McKinney, Matthew David Verber, Sunggook Park
We report the generation of ~8 nm dual in-plane pores fabricated in a thermoplastic via nanoimprint lithography (NIL). These pores were connected in series with nanochannels, one of which served...
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Screening for Urothelial Carcinoma Cells in Urine Based on Digital Holographic Flow Cytometry through Machine Learning and Deep Learning Method

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Lab Chip, 2024, Accepted Manuscript
DOI: 10.1039/D3LC00854A, Paper
Lu Xin, Xi Xiao, Wen Xiao, Ran Peng, Hao Wang, Feng Pan
The incidence of urothelial carcinoma continue to rise annually, particularly among the elderly. Prompt diagnosis and treatment can significantly enhance patient survival and quality of life. Urine cytology remains a...
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Opto-combinatorial indexing enables high-content transcriptomics by linking cell images and transcriptomes

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Lab Chip, 2024, 24,2287-2297
DOI: 10.1039/D3LC00866E, Paper
Arata Tsuchida, Taikopaul Kaneko, Kaori Nishikawa, Mayu Kawasaki, Ryuji Yokokawa, Hirofumi Shintaku
We introduce a simple integrated analysis method that links cellular phenotypic behaviour with single-cell RNA sequencing by utilizing a combination of optical indices from cells and hydrogel beads.
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A microfluidic model to study the effects of arrhythmic flows on endothelial cells

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Lab Chip, 2024, 24,2347-2357
DOI: 10.1039/D3LC00834G, Paper
Austin Lai, Adam Hawke, Mokhaled Mohammed, Peter Thurgood, Gianmarco Concilia, Karlheinz Peter, Khashayar Khoshmanesh, Sara Baratchi
We created a versatile microfluidic system for studying the effect of arrhythmic flow patterns on endothelial cells in vitro. This system provides unique opportunities to identify the molecular machineries that control endothelial biology in response to arrhythmia.
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Reproducible generation of human liver organoids (HLOs) on a pillar plate platform via microarray 3D bioprinting

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Lab Chip, 2024, Accepted Manuscript
DOI: 10.1039/D4LC00149D, Paper
Sunil Shrestha, Vinod Kumar Reddy Lekkala, Prabha Acharya, Soo-Yeon Kang, Manav Goud Vanga, Moo-Yeal Lee
Human liver organoids (HLOs) hold significant potential for recapitulating the architecture and function of liver tissues in vivo. However, conventional culture methos of HLOs, forming Matrigel domes in 6-/24-well plates,...
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Kinetics of the valorization of hexoses with Sn-USY catalysts in methanolic media: glycosidation vs. retroaldol cleavage

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00307A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
J. M. Jimenez-Martin, M. El Tawil-Lucas, C. García-Jerez, J. Moreno, A. García, B. Hernández, J. Iglesias
Two operational regions in the transformation of hexoses have been revealed by experimental and kinetic analysis: glycosidation and retroaldol cleavage at low and high temperatures, respectively.
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The graph automorphism group of the dissociation microequilibrium of polyprotic acids

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React. Chem. Eng., 2024, 9,2925-2937
DOI: 10.1039/D4RE00271G, Paper
Nicolás Salas, Justin López, Carlos A. Arango
Effect of permutations σ12,0 and σ21 on graph G2.
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Optimization of reaction parameters for the synthesis of natural aroma esters by factorial design

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React. Chem. Eng., 2024, 9,2994-3002
DOI: 10.1039/D4RE00265B, Paper
Open Access
Adrian Ioan Dudu, Csaba Paizs, Monica Ioana Toşa
In this study, the synthesis of aroma esters by the direct esterfication of carboxylic acids with aromatic alcohols mediated by lipase B from Candida antarctica encapsulated in a sol–gel matrix in a solvent-free system is presented.
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Current research status on the structural properties and modification of LiFePO4 cathode materials

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React. Chem. Eng., 2024, 9,2830-2845
DOI: 10.1039/D4RE00263F, Review Article
Guo Xiaoying, Bao Yuanyuan, Li Wei, Zhao Siqin, Huang Chao
With the current global economy developing at a rapid pace, research into lithium-ion batteries has become a focal point in many major areas.
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Bayesian-optimization-based design of highly active and stable Fe–Cu/SSZ-13 catalysts for the selective catalytic reduction of NOx with NH3

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React. Chem. Eng., 2024, 9,3029-3037
DOI: 10.1039/D4RE00327F, Paper
Sanha Lim, Hwangho Lee, Hyun Sub Kim, Jun Seop Shin, Jong Min Lee, Do Heui Kim
Bayesian optimization approach facilitates an efficient optimization of multi-components catalyst for NH3-SCR reaction.
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Kinetic analysis of kraft lignin conversion via the Fenton process: process optimization and stochastic modelling

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00401A, Paper
Lucas Ramos, Giovani Maltempi-Mendes, Adriano Francisco Siqueira, Diovana Aparecida dos Santos Napoleão, Anuj Kumar Chandel
Lignin conversion through an advanced oxidative process.
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Two-temperature model of the non-thermal chemical dissociation of CO2

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00300D, Paper
Q. Shen, A. Pikalev, F. J. J. Peeters, J. Gans, M. C. M. van de Sanden
A two-temperature model with a vibrational temperature different from the gas temperature is presented for the decomposition of CO2.
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Unveiling the dynamic CO2 capture performance of MgO promoted with molten salts and CaCO3 via fixed bed reactor experiments

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00432A, Paper
Open Access
Theodoros Papalas, Andy N. Antzaras, Angeliki A. Lemonidou
MgO promoted with molten alkali salts and CaCO3 displayed efficient CO2 capture activity in a fixed bed reactor, attaining 75% CO2 removal at 275 °C and stable cyclic performance, with the promoters providing an alternative carbonation mechanism.
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CO2 hydrogenation to light olefins over Fe–Co/K–Al2O3 catalysts prepared via microwave calcination

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00428K, Paper
Nutkamaithorn Polsomboon, Thanapha Numpilai, Kulpavee Jitapunkul, Kajornsak Faungnawakij, Metta Chareonpanich, Xingda An, Le He, Günther Rupprechter, Thongthai Witoon
Microwave calcination optimizes the Fe–C/Fe3O4 ratio to 0.34, enhancing CO2 conversion and light olefin yield.
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Removal of gaseous Hg0 by Cl-loaded carbonaceous material prepared from rice husk

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00414K, Paper
Naoto Tsubouchi, Momone Yoshizawa, Javzandogole Bud, Yuuki Mochizuki
The main objective of this study was to investigate the removal of gaseous Hg0 from the residue obtained during the chlorination of rice husk char to recover silica.
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Synthesis of ethylphenols and xanthenes via reaction of calcium carbide and phenol: experimental and theoretical studies

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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00397G, Paper
Xin Liu, Yuxin Yan, Zhenyu Liu, Qingya Liu
A novel synthesis of xanthenes and ethylphenols by the reaction of phenol with CaC2 without catalysts and solvents.
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Ammonia Decomposition over Low-loading Ruthenium Catalyst Achieved through “Adiabatic” Plasma Reactor

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React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4RE00509K, Paper
Minhazur Rahman Shawon, Chinwendu Umeojiakor, Anthony Griffin, Jeffrey S. Aguinaga, Jiachun Wu, Derek Patton, Zhe Qiang, Hossein Toghiani, Yizhi Xiang
Electrified catalytic processes for ammonia (NH3) decomposition have been considered as essential technologies for distributed COx-free hydrogen production. Here we show that efficient NH3 decomposition can be achieved over low-loading...
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Trapping bond exchange phenomenon revealed for off-stoichiometry cross-linking of phase-separated vitrimer-like materials

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Soft Matter, 2024, 20,2961-2968
DOI: 10.1039/D4SM00074A, Paper
Takumi Kito, Mikihiro Hayashi
Unusual relaxation and creep properties by the trapping bond exchange phenomenon is revealed for vitrimer-like materials with bond exchangeable domains of quaternized pyridines, in the special case of off- stoichiometric cross-linking condition.
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Self-adhesion of uncrosslinked poly(butadiene-co-acrylonitrile), i.e. nitrile rubber, an inhomogeneous and associative polymer

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Soft Matter, 2024, 20,2978-2985
DOI: 10.1039/D3SM01630G, Paper
Valentine Hervio, Annie Brûlet, Costantino Creton, Gabriel E. Sanoja
The precursor of NBR, poly(acrylonitrile-co-butadiene), experiences thermodynamic forces for self-assembly and kinetic barriers for processing. We introduce three strategies to overcome such barriers and enable polymer self-adhesion in the bulk.
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Correction: Fabricating multi-scale controllable PEDOT:PSS arrays via templated freezing assembly

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Soft Matter, 2024, 20,3021-3021
DOI: 10.1039/D4SM90038C, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yang Lin, Junqiang Mao, Qingrui Fan, Jianjun Wang
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The fractal geometry of polymeric materials surfaces: surface area and fractal length scales

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Soft Matter, 2024, 20,3082-3096
DOI: 10.1039/D3SM01497E, Paper
Open Access
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H. Eduardo Roman, Federico Cesura, Rabia Maryam, Igor Levchenko, Katia Alexander, Claudia Riccardi
Non-treated (NT) and plasma-treated (PT) polymeric surfaces display self-affine fractal scaling. The plasma increases both the surface area and the fractal length scales, helping the design of PT interfaces with larger surface areas at the nm scale.
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