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Progress and perspectives on iron-based electrode materials for alkali metal-ion batteries: a critical review

Chem. Soc. Rev., 2024, 53,4154-4229
DOI: 10.1039/D3CS00819C, Review Article
Junzhe Li, Chao Wang, Rui Wang, Chaofeng Zhang, Guanjie Li, Kenneth Davey, Shilin Zhang, Zaiping Guo
This review critically evaluates recent advances in iron-based electrode materials and applications in alkali metal ion batteries, covering chemical synthesis, structural design, and modification strategies, with insights into future directions.
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The mechanism of water oxidation using transition metal-based heterogeneous electrocatalysts

Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS01031G, Review Article
Shujiao Yang, Xiaohan Liu, Sisi Li, Wenjie Yuan, Luna Yang, Ting Wang, Haoquan Zheng, Rui Cao, Wei Zhang
The oxygen evolution reaction (OER) mechanisms using transition metal-based electrocatalysts are instrumental in providing novel insights into both natural and artificial energy conversion processes.
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Karthi’s brace helps Secretariat share honours with Odisha

In the second match of the day, former champion BPCL edged out Hockey Unit of Tamil Nadu 2-1




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Odisha impresses with win over NCOE; IOC drubs Central Secretariat




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Railways retains the title after fighting win over IOC




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CBSE asks schools to share details of amenities, fees

Even safety measures and educational qualification of their teaching staff will have to be disclosed




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Principal Secretary to inspect State-run schools, hostels in Andhra Pradesh

The implementation of State flagship programmes in the government schools and hostels to be the focus of the inspection.




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Zirconium metal–organic framework photocatalysis with TEMPO for blue light-powered aerobic sulfoxidation

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05173D, Communication
Bing Zeng, Yuexin Wang, Kanghui Xiong, Keke Zhang, Siyu Zhang, Xianjun Lang
A catalytic amount of TEMPO, mobile in the reaction medium, enhances the hole transfer of NU-1003 photocatalysis for blue light-powered oxidation of organic sulfides with O2.
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Functional metal–organic frameworks derived electrode materials for electrochemical energy storage: a review

Chem. Commun., 2024, 60,13292-13313
DOI: 10.1039/D4CC04086D, Highlight
Basree, Arif Ali, Khusboo Kumari, Musheer Ahmad, Ganesh Chandra Nayak
Pristine MOFs and their derivatives have been proven for supercapacitor as well as energy storage due to their versatile features like huge specific surface area, high porosity, redox active metal centre, high thermal stability, and so on.
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Enhancing the performance of ionic conductivity for solid-state electrolytes: an effective strategy of injecting lithium ions within anionic metal–organic frameworks

Chem. Commun., 2024, 60,13416-13419
DOI: 10.1039/D4CC04515G, Communication
Lu Shi, Xin Wang, Zhiliang Liu
An ionotropic MOF (Li+[Cu-BTC]) with lithium ions in the pores of the lattice was synthesized, which displays outstanding lithium ionic conducting properties over a wide temperature range.
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Rapid and sensitive detection of vanillylmandelic acid based on a luminescent fourteen-metal Tb(III) planar nanocluster

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC03667K, Communication
Yanheng Meng, Shiqing Wang, Xiaoli Lv, Xianfeng Huang, Wei-Bing Zhang, Xiaojun Wu, Desmond Schipper, Xiaoping Yang
A 14-metal Tb(III) nanocluster with four CO32- anions as templates was constructed for the quantitative and qualitative detection of vanillylmandelic acid (VMA) with high sensitivity and selectivity. The luminescence response...
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Metal-free photocatalysts with charge-transfer excited states enable visible light-driven atom transfer radical polymerization

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04470C, Communication
Yuchen Huang, Yangxin Liu, Yingde Yan, Yanjun Gong, Yifan Zhang, Yanke Che, Jincai Zhao
Photoredox-catalyzed atom transfer radical polymerization (O-ATRP) offers powerful tools for the precise control of polymer synthesis. Metal-free photocatalysts are particularly desirable due to their high level of control in O-ATRP...
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Ceria-based supported metal catalysts for the low-temperature water-gas shift reaction

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04072D, Feature Article
Xin-Pu Fu, hui zhao, Chun-Jiang Jia
Water-gas shift (WGS) reaction is a crucial step for the industrial production of hydrogen or upgrading hydrogen generated from fossil or biomass sources by removing the residual CO. However, current...
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Li2NbHO2: a new transition-metal oxyhydride with rock-salt-type structure

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05503A, Communication
F Takeiri, Keiko KUSUMOTO, Kosuke Kawai, Hiroshi Yaguchi, Takashi Saito, Kazuhiro Mori, Saburo Hosokawa, Masashi Okubo, Genki Kobayashi
Transition-metal oxyhydrides are an emerging class of functional materials; however, the known compounds have mostly been limited to perovskite-type structures. Here, we successfully synthesized Li2NbHO2, the first example of a...
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Catalytic Ethynylation of Formaldehyde for Selective Propargyl Alcohol Production Using the Copper Metal Organic Framework HKUST-1

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D3NJ06001B, Paper
Wanxi Yang, Wencai Peng, Han Li, Jin Mao, Liqiang Qian, Qingyu Zhang
HKUST-1 with high crystallinity has been successfully synthesized by solvothermal method using Cu(NO3)2·3H2O as a copper source, 1,3,5-benzenetricarboxylic acid as organic ligand, and N,N-dimethylformamide as solvent. HKUST-1 exhibited a typical...
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Metal–organic frameworks constructed using acid–base mixed ligands, carboxylic acids and N-containing chalcone, and their catalytic performance for Knoevenagel condensation

New J. Chem., 2024, Advance Article
DOI: 10.1039/D3NJ05164A, Paper
Limin Cheng, Junyong Zhang, Caihong Zhan, Hao Xu, Chunhua Gong, Jingli Xie
MOF materials constructed using acid–base mixed ligands serve as efficient and economical porous heterogeneous catalysts for Knoevenagel condensation.
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Metal–organic framework-derived mesoporous Co3O4 with high specific surface area for enhanced xylene sensing

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ01096E, Paper
Liwen Wang, Guanghui Zhang, Ruishu Zhang, Siqi Yang, Wenjuan Huang, Xiangbai Chen
Co3O4 hollow polyhedra have a high specific surface area and mesoporous structure. The Co3O4 gas sensor has excellent sensing performance and selectivity for xylene.
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3D interconnected polymer/mesoporous silica nanoparticle hybrid materials with hierarchical macro/meso-structures for heavy metal adsorption

New J. Chem., 2024, 48,7503-7516
DOI: 10.1039/D3NJ05887E, Paper
Jae-Seo Park, Young Sunwoo, Debabrata Chakraborty, Chamila Gunathilake, Yanhai Du, Eun-Bum Cho
This work offers nanohybrid structures for heavy metal ion adsorption from water, which include a unique 3D cross-linked structure that combines organic polymer chains with mesoporous materials to improve adsorption efficiency.
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Nanopolyhedral Zn/Fe-NC derived from bimetallic zeolitic imidazole frameworks as an efficient catalyst for the oxygen reduction reaction in an air-cathode microbial fuel cell

New J. Chem., 2024, 48,7092-7101
DOI: 10.1039/D3NJ05279F, Paper
Qianwu Wang, Jingzhao Lu, Songlin Liu, Boqu Yu, Bolong Liang
The synergistic effect of Zn, N and moderate Fe doping enhances the ORR performance. The maximum power density of the Zn/Fe-NC-0.5 MFC is 1954 ± 20 mW m−2.
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Performance analysis and structure characterization of polylactic acid modified with three flame retardants

New J. Chem., 2024, 48,7469-7479
DOI: 10.1039/D3NJ05967G, Paper
Zhu Yuqin, Wang Di, Guo Zhongliang, Wen Huiying
Three flame retardant composites were prepared by incorporating flame retardants (FRs), including triphenyl phosphate (TPP), polysiloxane (PSQ) and phosphite functionalized polysiloxane (PPSQ), respectively into a polylactic acid (s/PLLA) matrix.
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Enhanced photocatalytic activity of carbon nitride nanosheets with alkali metal ion doping

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01210K, Paper
Xinhang Sun, Gang Zhao, Songyuan Li, Mingju Huang, Junhui Liu
Photocatalytic degradation of pollutants is one of the most promising strategies for addressing environmental issues associated with wastewater from textile and other dyeing industries. Graphitic carbon nitride (g-C3N4) has emerged...
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Catalytic oxidative desulfurization performance of a modified nano-sized β zeolite loaded with different structural polyoxometalates

New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00214H, Paper
Jinhong Li, Haonan Li, Zhimei Song, Ying Guo, Mengxiao Tai, Mei Han, Xinyao Wang, Lidong Chen, Dongmei Ren
HPW/β-T+S has the best desulfurization activity among the composite catalysts supported by polyoxometalates with different structures.
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Critical role of dissolved oxygen and iron–copper synergy in dual-metal/char catalyst systems

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00911D, Paper
Yang Luo, Hong Li, Hailan Yang, Zhiming Yang, Chuang Li, Shaoheng Liu, Qiang Chen, Weihua Xu, Wei Zhang, Xiaofei Tan
The critical role of dissolved oxygen and iron–copper synergy in dual-metal/char catalyst system was studied.
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Highly radiation-resistant Al-MOF selected based on the radiation stability rules of metal–organic frameworks with ultra-high thorium ion adsorption capacity

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00076E, Paper
Xiaofan Ding, Zhanjun Zhang, Xinyan Li, Ke Ma, Tiantian Jin, Zhaoning Feng, Tian Lan, Jing Zhao, Songtao Xiao
Al-MOF synthesized based on MOF irradiation stability rules exhibits high stability against β-irradiation and ultra-high thorium adsorption capacity, which proves its huge potential application value in the field of radionuclide adsorption.
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Green Chemistry: Advancing Planetary Phosphorus Sustainability through the Synergy of Graphene Oxide Modified with Magnetic Nanoparticles (M@GO) for Extracting Tertiary Effluent Phosphorus in Sewage Treatment Plants.

Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D3EN00859B, Paper
Open Access
Andrea Muñoz-Garcia, Pablo Montoro Leal, María Mar López Guerrero, Carlos Vereda-Alonso, Elisa Vereda Alonso
Securing the enduring sustainability of global phosphorus (P) utilization has become a key societal priority. The application of green chemistry and green engineering presents an opportunity to mitigate these challenges...
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Biogenic synthesis of dual-emission chlorophyll-rich carbon quantum dots for detection of toxic heavy metal ions – Hg(II) and As(III) in water and mouse fibroblast cell line NIH-3T3

Environ. Sci.: Nano, 2024, 11,1636-1653
DOI: 10.1039/D3EN00789H, Paper
Ravi Pratap, Nurul Hassan, Monika Yadav, Saurabh Kumar Srivastava, Shilpi Chaudhary, Anita Kamra Verma, Jayeeta Lahiri, Avanish S. Parmar
Due to the excessive residues and serious adverse effects, it is urgent to develop an efficient method to detect Hg2+ and As3+ in drinking water to protect human health.
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Understanding the active sites and associated reaction pathways of metal-free carbocatalysts in persulfate activation and pollutant degradation

Environ. Sci.: Nano, 2024, 11,1368-1393
DOI: 10.1039/D3EN00988B, Critical Review
Huawen Hu, Dongchu Chen, Yaoheng Liang, Wenyi Wang, Yinlei Lin, Xuejun Xu, Xiaowen Wang, Kun Wang, Yuyuan Zhang, Jian Zhen Ou
Environmental remediation based on peroxomonosulfate- and peroxydisulfate-activation-enabled radical/non-radical oxidation has gained growing interest due to the strong oxidation power, long life of reactive oxygen species, and wide pH adaptability.
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Selective metal recovery by mucin: turning gold from wastewater into a peroxymonosulfate-activated catalyst

Environ. Sci.: Nano, 2024, 11,1487-1498
DOI: 10.1039/D3EN00699A, Paper
Open Access
Shira Gavriely, Shachar Richter, Ines Zucker
This study explores mucin's ability to selectively recover gold (Au) from metal wastewater. The Au, in the form of a nanoparticle, was utilized in peroxymonosulfate activation for the degradation of bisphenol A.
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Doped carbon dots affect heavy metal speciation in mining soil: changes of dissimilated iron reduction processes and microbial communities

Environ. Sci.: Nano, 2024, 11,1724-1739
DOI: 10.1039/D3EN00823A, Paper
Xinyi Huang, Shaobo Liu, Xuanming Liu, Xiaofei Tan, Shuai Guo, Mingyang Dai, Qiang Chen, Gaobin Chen, Chenzhi Feng
Carbon dots (CDs) inevitably accumulate in soils due to their widespread use, affecting soil enzyme activities and microbial community structure.
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Correction: Nano-pelargonidin modulates p53/PARP/HSP 90/XRCC1 signaling axis to combat cypermethrin-induced genotoxicity and metabolic dysfunction in fish: a molecular docking predicted in vivo approach

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN90017K, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Priyanka Sow, Sudatta Dey, Rishita Dey, Asmita Samadder, Sisir Nandi, Debojyoti Tarafdar, Anisur Rahman Khuda-Bukhsh
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Polymeric polyiodo-chlorotellurates(IV): new supramolecular hybrids in halometalate chemistry

CrystEngComm, 2024, 26,2018-2024
DOI: 10.1039/D4CE00088A, Paper
Nikita A. Korobeynikov, Andrey N. Usoltsev, Maxim N. Sokolov, Alexander S. Novikov, Sergey A. Adonin
Reaction between TeO2 and I2 in HCl afforded a series of supramolecular hybrids Cat2{[TeCl6](I2)} (1–5) where diiodine fragments are linked to [TeCl6]2− octahedra via halogen bonds (XB).
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Two multifunctional Dy(III)-based metal–organic frameworks exhibiting proton conduction, magnetic properties and second-harmonic generation

CrystEngComm, 2024, 26,2033-2042
DOI: 10.1039/D4CE00065J, Paper
Ya-Qing Liao, Tian-Zheng Xiong, Kang-Le Xie, Huan Zhang, Jun-Jie Hu, He-Rui Wen
Two novelty Dy-MOFs were synthesized using H4DTTP-2OMe ligand. MOF 1 displays a more superior proton conductivity, field-induced single molecule magnets behavior and obvious second-order nonlinear optical properties.
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Extended isomerism in heteronuclear metal-organic frameworks: synthetic strategies and crystal structures of lanthanide-cobalt-oxydiacetate systems

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00168K, Paper
Fernando Igoa, Agustín López Cabrera, Javier Gonzalez-Platas, Leopoldo Suescun, Carlos Kremer, Julia Torres
Here, we present the synthesis and crystal structure of a series of heteronuclear metal-organic frameworks, which consists of cobalt(II) and lanthanide(III) ions or yttrium(III), connected by oxydiacetato (oda2-) as ligand....
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Metal–organic polyhedron from a flexible tetrakis(thiobenzyl-carboxylate)-tetrathiafulvalene

CrystEngComm, 2024, 26,2072-2077
DOI: 10.1039/D3CE01251D, Paper
Yohan Cheret, Narcis Avarvari, Nicolas Zigon
Wiggle, wiggle… Stay! A redox-active tetrakis(thiobenzyl-carboxylate)-TTF with a high degree of flexibility stands still in a self-assembled cage upon complexation with Cu(II).
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Enantioselective enrichment of chiral 1-phenylethanol in the camphor-based chiral metal–organic framework CFA-22

CrystEngComm, 2024, 26,2051-2055
DOI: 10.1039/D4CE00181H, Communication
Richard Röβ-Ohlenroth, Katharina Knippen, Maryana Kraft, Dirk Volkmer
The novel enantioselective CFA-22 metal–organic frameworks were successfully developed and investigated for chiral adsorption separation of e.g. racemic 1-phenylethanol.
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Crystal growth and spontaneous polarization mechanism of polar metal borate halides: Mn3B7O13Cl

CrystEngComm, 2024, 26,2060-2064
DOI: 10.1039/D4CE00060A, Communication
Haodong Li, Duo Zhang, Jiesen Guo, Qiangqiang Wang, Yuxin Ma, Munan Hao, Yuetong Wu, Fanshu Meng, Tianming Liu, Yibo Xu, Xu Chen, Changchun Zhao, Dezhong Meng, Zhiyuan Zheng, Ruijin Sun
High-quality single crystals of Mn3B7O13Cl have been successfully synthesized, to unravel the elusive mechanism behind its spontaneous polarization.
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Ionic liquid-functionalized metal organic frameworks and their composite membranes for enhanced proton transport

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00186A, Highlight
Jeong Hwa Song, Seyoung Koo, Dong Won Kang
Post-synthetic modification is gaining prominence as a highly effective strategy for enhancing the functionality of porous materials without significant structural changes. Recently, there is growing interest in research focusing on...
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Noble-metal-free bimetallic nitride decorated CdS nanorods for photocatalytic hydrogen generation

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00216D, Paper
Lu Chen, Yu Zou Xia, Jiale Shi, Xiaohui Huang, Xiyao Liu, Guiyang Yan, Renkun Huang
Developing highly active and stable non-noble-metal cocatalyst-decorated semiconductors is desirable for the practical application of photocatalysis, which remains an open question. Herein, we report transition-metal nitride (Ni3FeN) loaded cadmium sulfide...
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A stable metal azolate framework with rare nonintersecting one-/two-dimensional pore channels

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00318G, Communication
Heng Yi, Mu-Yang Zhou, Le Ye, Xiao-Tong Lu, Dong-Dong Zhou, Jie-Peng Zhang
It is challenging to design and synthesize stable crystalline structures with heterogeneous pores. Herein, we design and synthesize a new azole ligand with rich aromatic moieties and trifluoromethyl groups, and...
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Meta Verified is now available in India at ₹699

Meta Verified is available for direct purchase on Instagram or Facebook.




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Meta launches more parental supervision tools for Instagram. Is it enough?

Many of the features require minors and their parents to opt in, raising questions about how effective the measures are




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Meta explains how AI influences Facebook and Instagram feeds

Meta is also expanding ‘Why Am I Seeing This?’ feature in Instagram and Facebook Reels.




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Meta takes aim at Twitter with the launch of Threads

Threads passes 5 million sign ups in four hours: CEO Zuckerberg




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Meta Threads is live now. Here’s how to register

Threads gains about 10 million signups within seven hours of the roll out




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Meta’s Threads rolls out, Mark challenges Elon with first Twitter post in decade

Mark challenges Elon with Twitter post




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Twitter threatens to sue Meta over Threads: report

Meta, which launched Threads on Wednesday, looks to take on Elon Musk's Twitter by taking advantage of Instagram's billions of users




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Meta’s Threads draws millions seeking a Twitter alternative

On Threads, people can post text and links and reply to or repost messages from others




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Why Meta’s Threads app is the biggest threat to Twitter yet

In less than 24 hours, Threads attracted some 30 million users




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Ex-Twitter CEO Jack Dorsey takes a dig at Meta over Threads

Threads app received about 30 million signups as of Thursday morning