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Asymmetric synthesis of (aza)flavanones by the evolution of CarOx ligands

Org. Chem. Front., 2024, 11,6444-6449
DOI: 10.1039/D4QO01345J, Research Article
Juan Yang, Wenlong Kong, Mingxin Chang, Jixing Lai, Shengkun Li
Amino-pyridine-oxazoline (NHPyOx) is conceived as an unprecedented model via the core-emulating optimization of CarOx ligands.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Sulfenylation of bioactive maleimides, acrylates and cyclohexenones under ambient organophotocatalysis

Org. Chem. Front., 2024, 11,6503-6509
DOI: 10.1039/D4QO01342E, Research Article
Debanjana Bag, Rajjakfur Rahaman, Anindya S. Manna, Subhasis Pal, Rajesh Nandi, Shobhon Aich, Narendra Nath Ghosh, Dilip K. Maiti
A novel visible light-induced sulfenylation of biologically important maleimides, acrylates and cyclohexenones has been developed using cheap and easily available organophotoredox catalyst Eosin Y with thiols under ambient conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A Stereoselective Organocatalyzed C-Glycosylation of Indole: Implications of Acceptor-Catalyst-Donor Interaction

Org. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QO01873G, Research Article
Lihuang Xie, Wenchao Liu, Zhenbo Guo, Qinbo Jiao, Xiaomin Shen, Tianfei Liu, Chunfa Xu
A stereoselective pyridinium hexafluorophosphate-catalyzed C-glycosylation of indole is presented, featuring the plausible formation of a catalyst-acceptor complex and a crucial H-bond between the indole N-H and the oxygen at C6...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Metal–ligand cooperation and synergistic palladium catalysis for the dual ligand system [2,2'-bipyridin]-6(1H)–one/PCy3: milder conditions for the undirected C–H arylation of arenes

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01877J, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Cintya Pinilla, Mario García-Zarza, Ana C. Albéniz
The mixture of Pd(OAc)2 and two ligands segregate into distinct active species working synergistically for the C–H arylation of simple arenes.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Hemilabile P,N-Ligand-Assisted Gold Catalyzed Hiyama Allylation to Access Allylarenes and 1,4-Dienes Derivatives

Org. Chem. Front., 2025, Accepted Manuscript
DOI: 10.1039/D4QO01879F, Research Article
Yuanhao He, Wanping Ma, Yu Zhong, Yanfei Hu, Mingou Li, Fen Zhao, Zhonghua Xia, Baomin Fan
Oxidant-free gold-catalyzed reactions are emerging as a novel synthetic tool for organic transformations. Here in, we reported a hemilabile P,N-ligand-assisted gold-catalyzed Hiyama cross coupling reaction of aryl and alkenyl iodides...
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Telangana Cyber Security Bureau conducts digital awareness campaign for senior citizens




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Telangana CID arrests two involved in pan-India job fraud racket




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Telangana pharmaceutical industries logged 97 major fire accidents in past decade: Fire Services Director-General Y. Nagi Reddy

The new government would like to decentralise and set up pharma villages, in 10 clusters, Special Chief Secretary Jayesh Ranjan said




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HYDRAA created fear among encroachers and big builders and not common people: Telangana CM




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When hope meets hurdles: stark reality of Telangana’s job market

The State’s job crisis has come back to haunt the Congress party, which rode to power last year on promises of employment. While local youth wait, worry, and exchange dreams about securing government jobs, short-term opportunities are drawing people from other States. This dynamic has transformed Telangana into a job magnet for outsiders but a desert for its own aspirants, reports Serish Nanisetti




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Cyberabad | Four arrested for vandalising Gandhi statue




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Telangana set to unveil new industrial sectoral policies 

Electric Mobility and Storage, Electronics, Life Sciences, Defence and Aerospace sectors to get new growth guiding documents as some existing policies have become outdated and those in other States are superior, senior official 




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Ugandan woman sentenced to 13 years RI for smuggling drugs to Hyderabad

The woman was caught attempting to smuggle 3,900 grams of heroin, worth ₹25 crore, to Hyderabad




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No more parties without permission: Telangana Excise Dept. to farmhouse owners




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Telangana Deputy CM seeks proposals for retaining wall to prevent monsoon flooding in Madhira




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Kishan Reddy slams Revanth government for failing farmers, challenges Rahul Gandhi to tour villages in Telangana




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Telangana govt. urged to release caste survey forms in English and Urdu




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Telangana delegation to embark on 3-day study tour in Karnataka for fisheries development




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Telangana State Cyber Security Bureau nabbed 165 cyber criminals involved in 795 cases in last six months

45% fraudsters are either graduates or post-graduates; indulge in crime due to peer pressure and for easy money, says data




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Bar an equal partner in the administration of justice: Telangana HC Chief Justice Alok Aradhe

Foundation of judicial system is faith and trust of litigants; steps will be taken soon to digitally serve summons in criminal cases in order to considerably reduce delays, says Telangana High Court Chief Justice




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Minister Ponnam Prabhakar urges caste associations to support ongoing comprehensive survey in Telangana




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Telangana’s Dhanalakota Vaikuntam Nakash’s journey with Cheriyal art

The 64-year-old artist adapts to the times to narrate stories in the 400-year-old Cheriyal artform in new mediums




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Modi’s parivar stands for division of people and Gandhi parivar works for country’s unity: Telangana CM Revanth

Referring to the lack of minority representation in his Cabinet, the Chief Minister attributed it to the absence of a Muslim MLA in Telangana




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Hyderabad commissioner restricts city-wide ban to vicinity of Telangana Secretariat

The new order comes into effect from November 11 until further notice, said the commissioner




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Telangana to repair 9,000 km of roads using advanced technology: Minister Komatireddy




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People’s committee slams BJP, BRS for ‘opposing’ caste survey in Telangana




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Three schoolgirls in Telangana tribal school hospitalised after suspected food poisoning, one critical

The girls, aged between 13 and 16, suffered acute gastroenteritis, dehydration, and kidney-related complications




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Telangana to set up four new drug testing labs




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An art showcase in Hyderabad heralds the power of Gandhi as a global icon in a pre-digital era

Give Peace Another Chance, artist Adarsh Baji’s series on view at Kalakriti art gallery in Hyderabad, doffs its hat to the life, times and ideology of Mahatma Gandhi ahead of his 154th birth anniversary




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The Complete to Planning Your Estate in Michigan: A Step-by-Step Plan to Protect Your Assets, Limit Your Taxes, and Ensure Your Wishes are Fulfilled for Michigan Residents

What happens to your estate after you are gone is very much within your control. Estate planning is not only for the wealthy; it is for everyone. It is simply the process of deciding where your assets are to be distributed after your death. For those people who wish to preserve their assets for designated […]




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Graphene-supported organoiridium clusters catalyze N-alkylation of amines via hydrogen borrowing reaction

RSC Adv., 2024, 14,35163-35171
DOI: 10.1039/D4RA06595F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tsun-Ren Chen, Siang-Yu Chiu, Wen-Jen Lee, Yi-Siou Tsai, Yu-Sheng Huang
Graphene-supported organic iridium clusters (GSOIC) exhibit excellent N-alkylation on various substrates under green processes.
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An exceptional water stable terbium-based metal–organic framework for selective detection of pesticides

RSC Adv., 2024, 14,35220-35226
DOI: 10.1039/D4RA06622G, Paper
Open Access
Ching-Ping Liu, Ting-En Lin, Jung-Chang Chiang, Bo-Jhen Chen, Po-Hsiu Chien, Su-Ying Chien, Gene-Hsiang Lee, Yen-Hsiang Liu, Kuang-Lieh Lu
The terbium-based metal–organic frameworks (Tb-MOFs) were synthesized successfully under hydrothermal conditions, which could maintain at least 90% of the emission intensity after storage in water for several months.
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DFT investigation of the mechanism and role of N-heterocyclic carbene (NHC) in constructing asymmetric organosilanes using NHC-catalyzed [4+2] cycloaddition reaction

RSC Adv., 2024, 14,35475-35489
DOI: 10.1039/D4RA03676J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Batoul Alipour
The mechanism and origin of stereoselectivity for the synthesis of asymmetric organosilanes using NHC are theoretically investigated.
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Harnessing the UiO-67 metal–organic framework for advanced detection of cadmium ions in water bodies

RSC Adv., 2024, 14,35618-35627
DOI: 10.1039/D4RA06811D, Paper
Open Access
Bhuvaneswari Selvaraj, Lakshmi Priya G., Selva Balasubramanian
Heavy metal ions are hazardous pollutants that pose serious threats to ecosystems and human health, making it imperative to detect and monitor their presence in water for environmental protection.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis and characterization of carbonyl functionalized organotellurium(IV) derivatives

RSC Adv., 2024, 14,35650-35656
DOI: 10.1039/D4RA06023G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Puspendra Singh, Mariya Khan, Andrew Duthie, Ray J. Butcher
Aryltellurium trichlorides, ArTeCl3 (Ar = C6H5, Ph; 4-Me-C6H4, p-Tol; 1-C10H7, 1-Nap; 2,4,6-Me3C6H2, Mes) react under mild conditions with acetylacetone/benzoylacetone to give carbonyl functionalized organotellurium(IV) derivatives.
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Cs2ZnCl4: a lead-free all-inorganic perovskite with a large dielectric permittivity

RSC Adv., 2024, 14,36253-36263
DOI: 10.1039/D4RA04755A, Paper
Open Access
Imen Romdhane, Asma Ajmi, Mohamed Ben Bechir, Regis Barille, Abdallah Ben Rhaiem
In recent years, inorganic perovskite materials based on metallic halides have attracted significant attention due to their non-toxicity and ease of synthesis, making them suitable for various applications.
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Bridge collapses in Bihar’s Kishanganj, fourth incident in State in eight days

A pillar of the bridge across the Mariya river could not withstand strong currents of the river whose water level rose due to heavy rainfall in the catchment areas of Nepal, said officials




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Rahul Gandhi likely to visit Ahmedabad on July 6

Rahul Gandhi will meet party workers and leaders who were ‘assaulted by BJP goons’, says Gujarat Congress chief 




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With four out of five NEET ‘solver gang’ arrests from the district, no easy answers in Nalanda

According to the police, the ‘solver gang’ is spread across Bihar, Jharkhand, Uttarakhand, Uttar Pradesh, and Gujarat




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Panel formed to monitor opening of treasury of Jagannath temple in Puri to meet on July 6

The last inventory of Ratna Bhandar was taken 46 years ago in 1978




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Rahul Gandhi to visit Ahmedabad on July 6

Rahul Gandhi will meet family members of Cong. workers arrested after clash with BJP members




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BJP government in Rajasthan takes over Gandhi Vatika Museum’s management

Conceptualised by the Gandhi Peace Foundation, the museum makes concerted efforts to keep the Gandhian philosophy relevant to the life and times of India




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Opposition slams Nitish Government over murder, alleged gang rape of Dalit minor in Bihar

While RJD leader Tejashwi Yadav said the morale of “state-protected criminals and rapists” has increased under the “patronage” of Nitish Kumar, the Congress demanded a speedy probe




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Outrage after minor girl’s gang rape in Assam

Some locals found her lying semi-conscious by the roadside on her way back home from tuition classes




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New link to Library Reorganization Blog

I've put a link to the new Library Reorganization Blog to our list of links (look on the right hand side). It appears that it is open for comments, whether named or anonymous.




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Sports science back-up provided to Indian athletes in Paris Games is unprecedented, says Gagan Narang

Narang said the sports science team, under the leadership of renowned sports injury expert Dr. Dinshaw Pardiwala, is a never-before support for the Indian athletes.




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Ugandan Olympic runner Cheptegei dies after being set on fire by boyfriend

The 2024 Paris Olympian was doused in petrol and set on fire by her boyfriend, making her the third female athlete to be killed in the country since 2021




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Multiple rocket launches identified from Lebanon since Yom Kippur fast began, says Israel

Israel shut down late on Friday afternoon for Yom Kippur, the Jewish Day of Atonement and the holiest day of the Jewish calendar




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Trump talks Xi, tariffs and aliens in freewheeling Joe Rogan podcast

The conversation stretched long enough that Trump ended up hours late for a rally in swing-state Michigan, where hundreds of supporters trickled out of the venue as temperatures dropped while waiting for him to arrive




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ISL | Super-sub Cummings does the trick for Mohun Bagan Super Giant