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x Estimating the extent of adulteration of the popular herbs black cohosh, echinacea, elder berry, ginkgo, and turmeric – its challenges and limitations By pubs.rsc.org Published On :: Nat. Prod. Rep., 2024, 41,1604-1621DOI: 10.1039/D4NP00014E, Review Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Nilüfer Orhan, Stefan Gafner, Mark BlumenthalThis review article focuses on the challenges and limitations of estimating the prevalence of adulteration in preparations made from black cohosh, echinacea, elder berry, ginkgo, and turmeric.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Volatile organic compounds (VOCs) in terrestrial extreme environments: implications for life detection beyond Earth By pubs.rsc.org Published On :: Nat. Prod. Rep., 2024, Advance ArticleDOI: 10.1039/D4NP00037D, Review Article Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Claire A. Batty, Victoria K. Pearson, Karen Olsson-Francis, Geraint MorganThis review highlights how discovering and analysing VOCs in extreme environments on Earth can help identify biosignatures and unravel complex patterns in metabolic data that could help identify life on other planetary bodies.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Efficient catalysis of Knoevenagel condensation by 1D copper-containing heteropolyoxoniobate at room temperature By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,1993-1997DOI: 10.1039/D4QI00260A, Research ArticleYa-Kun Zuo, Yan-Ru Li, Yan-Qiong Sun, Xin-Xiong Li, Cai Sun, Shou-Tian ZhengA 1D copper-containing organic–inorganic hybrid heteropolyoxoniobate catalyst for efficient catalysis of Knoevenagel condensation at room temperature.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Carbon dots induce abundant oxygen vacancies in CeVO4 for promoting photocatalytic selective hydrogenation of functionalized nitroarenes By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2128-2135DOI: 10.1039/D4QI00002A, Research ArticleErnan Pang, Shijia Li, Jie Wu, Qing Chang, Ning Li, Jinlong Yang, Shengliang HuCarbon dots create the appropriate oxygen vacancies (OVs) in CeVO4 for the chemoselective hydrogenation of functionalized nitroarenes under light irradiation.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Defect-engineered WSxSe2−x nanocrystals anchored on selenized polyacrylonitrile fibers toward high-performance sodium/potassium-ion batteries with a wide working temperature range By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2164-2177DOI: 10.1039/D3QI02640J, Research ArticleFuyu Xiao, Jingran Zhang, Weiming Zhou, Yixing Fang, Xiaotong He, Wenbin Lai, Chuyuan Lin, Mingyang Ge, Haosen Fan, Qingrong Qian, Mingdeng Wei, Qinghua Chen, Lingxing ZengWSSe-Se@PAN was fabricated by the electrospinning route combined with selenization treatment. It exhibited a wide working temperature range for SIB/PIB applications.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Slow magnetization relaxation of a high-spin iron(III) in mayenite Ca12Al14O33 By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2098-2104DOI: 10.1039/D4QI00480A, Research ArticleTimur Z. Sharifullin, Alexander V. Vasiliev, Vladimir D. Dolzhenko, Sebastian Bette, Robert E. Dinnebier, Reinhard K. Kremer, Pavel E. KazinHigh-spin Fe3+ ion imbedded in the extended solid displays field-induced slow relaxation of magnetization with enhanced relaxation time values.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Structural isomerism-tuned magnetisation relaxation dynamics in lanthanide coordination complexes By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2116-2127DOI: 10.1039/D4QI00161C, Research ArticleSteen H. Hansen, Christian D. Buch, Stergios PiligkosControl of the composition of molecular magnetic materials by chemical modification leads to tuning of their magnetization dynamics. We show that two structural isomers display such differences with respect to each other and to their parent complex.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Combination of dimensional reduction and active site addition strategies for preparing unique {RE9}-cluster-based MOFs: efficient CO2 fixation and Knoevenagel condensation By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2071-2080DOI: 10.1039/D3QI02527F, Research ArticleYing Zhao, Dan Wu, Yidan Qiao, Guo-Ping Yang, Lu-Fang Ma, Yao-Yu WangA series of 2D {RE9}-cluster-based rare-earth MOFs were built by dimensional reduction and active site addition strategies. They exhibit excellent catalytic activity in CO2 fixation and Knoevenagel condensation under mild conditions.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Reasonable regulation of flexible sulfur-based bifunctional catalytic electrodes for efficient seawater splitting By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2152-2163DOI: 10.1039/D3QI02575F, Research ArticleFengjing Lei, Xunwei Ma, Xinyun Shao, Ziyan Fang, Yuqin Wang, Weiju HaoAn iron-regulated three-dimensional nano-conical, economical, and flexible Fe-NiS@HA electrode exhibiting high intrinsic activity is prepared by gentle one-step electroless plating for efficient, durable hydrogen production in alkaline seawater.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Sodium ion pre-intercalation regulates the electron density and structural stability of vanadium oxide nanowires for Ca–ion batteries By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00218K, Research ArticleHuajie Feng, Yize Wang, Wenda Qiu, Zixi Liu, Yaping Tao, Xihong LuBenefiting from the abundant resource, low cost, and high operating potential, calcium–ion batteries (CIBs) have attracted great attention as emerging energy storage devices over lithium-based systems.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Defect-rich Pd@PdOs nanobelts for electrocatalytic oxidation of ethylene glycol By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00319E, Research ArticleXianlong Wang, Xuewen Wei, Ruifan Zhang, Min Yan, Ranran Wei, Xiaoying Zhang, Zhaoyou Zhu, Yinglong Wang, Xinling Zhao, Shuli YinReasonable design and development of catalysts with specific components and morphologies can effectively improve the catalytic performance of nanomaterials.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Adhesion, stability, structural and electronic properties of perovskite/BaWO4 heterostructures: first-principles and experimental characterizations By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00231H, Research ArticleYao Guo, Shiding Zhang, Zhaoyu Zhang, Yuanbin Xue, Jianxin Li, Haixiang Song, Yuhua Wang, Qing ShenThe interfacial behavior and mechanism of the CsPbBr3/BaWO4 and MAPbBr3/BaWO4 heterostructures have been extensively investigated by a combined first-principles and experimental analysis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Facile access to tetra-substituted FeIIFeII biomimetics for the oxidized state active site of [FeFe]-hydrogenases By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00773E, Research ArticleXin-Ping Gao, Shu-Fen Bai, Yan-Lan Wang, Shuang Lü, Qian-Li LiThis study presents a convenient approach to obtain two distinct types of novel tetra-substituted Fe/Se salts through a dehalogenation reaction. The objective is to advance research in mimicking the FeIIFeII oxidation state in [FeFe]-H2ases.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x NH3 plasma-etching-derived porous N-doped carbon nanotubes with FeP nanoparticles and intrinsic carbon defects for boosting oxygen reduction in rechargeable Zn–air batteries By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00182F, Research ArticleBing Chen, Minjie Zhou, Na Zhang, Xianglin Deng, HaiHua YangThe formation of intrinsic carbon defects and phase engineered FeP nanoparticles regulated by NH3 plasma etching significantly enhanced the oxygen reduction reaction performance of N-doped carbon nanotubes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Synergistic role of hydrogen bonding and band degeneracy leads to enhanced X-ray detection in HPIP-(NH4)0.7Cs0.3Br3·H2O perovskites By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00272E, Research ArticlePengxiang Dong, Chensheng Lin, Xin Zhao, Yicong Lv, Ning Ye, Min LuoThis work shows the innovative introduction of Cs+ into molecular perovskites to co-occupy with NH4+, synthesis of the HPIP-(NH4)0.7Cs0.3Br3·H2O perovskite, and fabrication of an X-ray detector with excellent overall performance and superior environmental stability.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Large-scale fabrication of ZIF-derived electrocatalysts for industrial oxygen evolution By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00458B, Research ArticleLiangjun Chen, Zhuowen Huangfu, Xuelin Yang, Hang Lei, Zilong Wang, Wenjie MaiThis study presents a methodology that enables the development of efficient and scalable ZIF-derived electrocatalysts for industrial water electrolysis, resulting in significant time and energy savings.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Controlling the structural and adsorption features of polyoxovanadate-based metal–organic clusters by adjustable template effect By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00254G, Research ArticleYan-Hu Wang, Ke-Wei Tong, Chao-Qin Chen, Jing Du, Guo-Ping Yang, Peng YangAn adjustable template effect was employed to activate the evolution of polyoxovanadate-based metal–organic clusters, resulting in unprecedented structural archetypes as well as customized dye and iodine adsorption features.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Discovery of excellent ultraviolet nonlinear optical materials in chlorates and bromates with highly stereochemically active lone pairs By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00462K, Research ArticleChun-Li Hu, Qian-Qian Chen, Fang Kong, Jiang-Gao MaoThe long-neglected stereochemically active lone pair groups ClO3− and BrO3− are demonstrated to be important UV NLO functional motifs based on the fact that AClO3 and ABrO3 possess high SHG effects and short λPM and are promising UV NLO materials.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Yellow-Emissive Organic Copper(I) Halide Single Crystals with [Cu4I4] Cubane Unit as Efficient X-ray Scintillators By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Accepted ManuscriptDOI: 10.1039/D4QI00500G, Research ArticleQingzheng Kong, Xiaomei Jiang, Ying Sun, Jianguo Zhu, Xutang TaoRecently, low-dimensional copper(I)-based halide is considered as a potential substitute for lead-based counterpart due to its environmental friendliness, facile preparation and superior luminescence performances. In particular, as a representative of...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Integrating multiple regulatory strategies: phase, morphology and interface engineering to construct a hierarchical Ni2P–MoS2/rGO heterostructure catalyst for efficient oxygen reduction reaction By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00262H, Research ArticleXinyi Wang, Jing Jin, Zeyuan Gao, Li Hou, Xiwen Tao, Jing Wang, Yueqi Zhao, Faming GaoTwo-dimensional (2D) molybdenum disulfide (MoS2) with a large surface area and unique electronic properties has emerged as a promising noble metal-free catalyst for electrochemical energy storage/conversion applications.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Metal– and covalent organic frameworks for photocatalytic CO2 reduction coupled with H2O oxidation By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00304G, Review ArticleXiao-Xiang Zhou, Yongshi Ye, Qia-Chun Lin, Wei-Ming Liao, Jun HeIt outlines influencing factors of photocatalytic CO2 reduction coupled with water oxidation, along with catalytic mechanisms and performance enhancement strategies.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Achieving high-sensitivity dual-mode optical thermometry via phonon-assisted cross-relaxation in a double-perovskite structured up-conversion phosphor By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QI00395K, Research ArticleHouhe Dong, Zonghao Lei, Shikun Su, Wenhua Yang, Xuyang Zhang, Wenying Teng, Guangyue Zu, Bing Teng, Degao ZhongBy adjusting the phonon energy of the host crystal (Ca2+/Sr2+/Ba2+) LaLiTeO6:Yb3+, Tm3+ phosphor, combined with the cross-relaxation phenomenon, a high-sensitivity thermometer for dual-mode temperature measurement was constructed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Development of In–Cu binary oxide catalysts for hydrogenating CO2via thermocatalytic and electrocatalytic routes By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2319-2338DOI: 10.1039/D3QI02499G, Research Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Marco Pietro Mezzapesa, Fabio Salomone, Hilmar Guzmán, Federica Zammillo, Roberto Millini, Letizia Bua, Gianluigi Marra, Alessandra Tacca, Rosamaria Marrazzo, Nunzio Russo, Raffaele Pirone, Simelys Hernández, Samir BensaidCarbon dioxide (CO2) hydrogenation to obtain valuable chemicals and fuels via thermocatalysis or electrocatalysis is a promising and sustainable method for CO2 utilization.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Carboxylate trapping engineering to fabricate monodispersed dual-atom iron sites for efficient oxygen reduction By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2260-2271DOI: 10.1039/D4QI00124A, Research ArticleHailiang Chu, Yilong Wu, Shujun Qiu, Chunfeng Shao, Yongpeng Xia, Yongjin Zou, Baitao Li, Kai Dai, Lixian SunAtomically dispersed catalysts with dense accessible Fe–Fe binary active sites supported on hierarchically ordered porous N-doped carbon are prepared via a general carboxylate-assisted strategy and they display drastically enhanced ORR activity.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Selenium doping induced phase transformation and interlayer expansion boost the zinc storage performance of molybdenum disulfide By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2272-2280DOI: 10.1039/D4QI00344F, Research ArticleMengfan Niu, Wenli Xin, Lei Zhang, Min Yang, Yaheng Geng, Xilin Xiao, Hui Zhang, Zhiqiang ZhuThis work synthesized Se-doped MoS2 nanosheets as a cathode for aqueous zinc-ion batteries, and they exhibited largely improved electrochemical performance owing to their high content of the 1T phase (64%) and expanded interlayer spacing (0.65 nm).The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
x Solvent-modulated assembly of peptide and cerium functionalized gigantic {Mo120Ce6}2 dimers for high-efficiency photocatalytic oxidation By pubs.rsc.org Published On :: Inorg. Chem. Front., 2024, 11,2355-2364DOI: 10.1039/D4QI00339J, Research ArticleDexiang Zhou, Bingbing Li, Qixin Zhao, Xinyu Tang, Tingya Lan, Heyang Su, Guoping Yang, Weimin XuanTwo gigantic peptide and cerium functionalized {Mo120Ce6}2 dimers have been constructed via a solvent-modulated assembly and applied for effective photocatalytic aerobic oxidation of sulfides to sulfoxides.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article