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Heterogeneous iron-containing nanocatalysts – promising systems for selective hydrogenation and hydrogenolysis

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00086H, Minireview
Anastasiya A. Shesterkina, Leonid M. Kustov, Anna A. Strekalova, Vladimir B. Kazansky
Bimetallic catalytic systems Fe–Me (Pt, Pd, Cu) demonstrate synergy in the activity/selectivity pattern in reactions involving hydrogen: selective hydrogenation of CC bonds, NO2 and carbonyl groups and hydrogenolysis of C–O bonds.
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Insights into isothiourea-catalyzed asymmetric [3 + 3] annulation of α,β-unsaturated aryl esters with 2-acylbenzazoles:Mechani-sm, origin of stereoselectivity and switchable chemoselectivity

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00295J, Paper
Congcong Wang, Shi-Jun Li, Qiao-Chu Zhang, Donghui Wei, Lina Ding
Recently, isothiourea-catalyzed asymmetric [3 + 3] annulation reactions of α,β-unsaturated aryl esters with 2-acylbenzothiazole (or 2-acylbenzoxazole) were reported with switchable chemoselectivity to form either dihydropyridone or dihydropyrone, but predicting the...
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Photocatalytic hydrogen evolution over nickel cobalt bimetallic phosphate anchored graphitic carbon nitrides by regulation of d-band electronic structure

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00556H, Paper
Yuanzheng Zhang, Yunrong Dai, Lifeng Yin, Huihui Li, Xiang Chen, Bin Chen
Non-precious metal co-catalysts with high activity and stability are extremely desirable for economically viable photocatalytic molecular hydrogen (H2) evolution. Herein, nickel cobalt phosphate (NiCo-Pi) was introduced into graphitic carbon nitride...
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Surface reconstruction and effect of Ni-modification in the selective hydrogenation of 1,3-butadiene over Mo2C-based catalysts

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00402B, Paper
Qiuchen Yang, Rui Qiu, Xixi Ma, Ruijun Hou, Kening Sun
In the current study, Mo2C, NiMo2C, H-Mo2C and H-NiMo2C were synthesized to understand the effects of Ni modification and synthesis route. The catalysts were characterized by XRD, N2-physisorption, SEM, TEM,...
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Phosphorus-Doped Inverse Opal g-C3N4 for Efficient and Selective CO Generation from Photocatalytic Reduction of CO2

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00457J, Paper
xiaoyue huang, Wenyi Gu, Songchang Hu, Yan Hu, Liang Zhou, Juying Lei, Lingzhi Wang, Yongdi Liu, Jinlong Zhang
In this work, inverse opal (IO) structure construction and phosphorus doping were combined to modify carbon nitride (g-C3N4) for photocatalytic reduction of CO2. The inverse opal structure was fabricated by...
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Ligand photodissociation in Ru(II)–1,4,7-triazacyclononane complexes enhances water oxidation and enables electrochemical generation of surface active species

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/C9CY02575H, Paper
Hussein A. Younus, Nazir Ahmad, Ibrahim Yildiz, Serge Zhuiykov, Shiguo Zhang, Francis Verpoort
Ligand transformations involved in metal complexes during water oxidation (WO), such as ligand decomposition, partial oxidation, or complete dissociation have been reported, however, ligand photodissociation has not been reported yet.
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Stability of the ketyl radical as a descriptor in the electrochemical coupling of benzaldehyde

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00282H, Paper
Jacob Anibal, Arnav Malkani, Bingjun Xu
Electroreductive coupling is an emerging pathway for the renewable upgrading of biomass derived oxygenates. This work investigates electrochemical benzaldehyde reduction on Au, Cu, Pt and Pd using reactivity testing and in situ spectroscopy.
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Photocatalytic asymmetric epoxidation of trans-stilbene with manganese–porphyrin/graphene-oxide nanocomposite and molecular oxygen: axial ligand effect

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00441C, Paper
Elahe Ahadi, Hassan Hosseini-Monfared, Alex Spieß, Christoph Janiak
An efficient, visible light-driven manganese–porphyrin photocatalyst was developed for the asymmetric epoxidation of trans-stilbene by molecular oxygen under mild conditions.
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Interfacial Effect of Co4S3-Co9S8 Nanoparticles Hosted onto rGO Sheets Derived from Molecular Precursor Pyrolysis on Enhancing Electrochemical Behaviour†

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00564A, Paper
Mengmeng He, Linchao Zhu, Yanyan Liu, Hao Wen, Yunxia Hu, Baojun Li
The reasonable design and synthesis of Co-based compound with superior electrochemical activity and durability have aroused tremendous research interests. Herein, a simple molecular precursor pyrolysis strategy is proposed to fabricate...
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Selective synthesis of α-olefins by dehydration of fatty alcohols over alumina–thoria mixed catalysts

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00551G, Paper
Arif Ali, Chen Zhao
The selective and high-yield production of α-olefins by alcohol dehydration is challenging because the isomerization and polymerization olefin products are more thermodynamically stable. In this study, we prepared a physical...
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My own worst enemy / Scott Snyder, writer ; John Romita Jr., penciller ; Danny Miki, inker ; Dean White, colorist ; Steve Wands, letterer ; John Romita Jr., Danny Miki & Dean White, collection cover artists

Hayden Library - PN6728.B36 S697 2017




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Be prepared / Vera Brosgol ; color by Alec Longstreth

Hayden Library - PN6727.B7567 B4 2018




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Frankenstein: Junji Ito story collection / story & art by Junji Ito ; translation, Jocelyn Allen ; English adaptation, Nick Mamatas ; other stories translation & adaptation, Jocelyn Allen ; touch-up art & lettering, James Dashiell ; cover &

Barker Library - PN6790.J33 I73413 2018




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Mister Miracle / Tom King, writer ; Mitch Gerads, artist and colorist ; Clayton Cowles, letterer ; Mitch Gerads, collection cover art ; Nick Derington, original series cover art

Barker Library - PN6728.M53 K56 2019




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She-Hulk: the complete collection / writer, Charles Soule ; storytellers, Javier Pulido, Ron Wimberly ; color artists, Muntsa Vicente, Rico Renzi, Ron Wimberly ; letterer, VC's Clayton Cowles ; cover art, Kevin Wada ; assistant editor, Frankie Johnson

Barker Library - PN6728.S462 S7664 2018




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Sulfur dioxide signaling molecule-responsive polymeric nanoparticles

Biomater. Sci., 2020, 8,2300-2307
DOI: 10.1039/D0BM00276C, Paper
Ruru Li, Xiaoyu Huang, Guolin Lu, Chun Feng
A PEG45-b-PVPOP14 diblock copolymer with pendant levulinate-protected phenol groups exhibited a highly specific response toward sulfites.
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A fluorinated low-molecular-weight PEI/HIF-1α shRNA polyplex system for hemangioma therapy

Biomater. Sci., 2020, 8,2129-2142
DOI: 10.1039/D0BM00171F, Paper
Xiaoshuang Guo, Zihan Yuan, Yang Xu, Minyan Wei, Zhiwei Fang, Wei-En Yuan
RNAi technology targeting HIF-1α could benefit hemangioma therapy effectively and FPEI polyplexes which could inhibit the expression of HIF-1α at the translational level can provide a practicable strategy for clinical hemangioma treatment in the future.
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A disulfide based low molecular weight gel for the selective sustained release of biomolecules

Biomater. Sci., 2020, Advance Article
DOI: 10.1039/D0BM00508H, Paper
Nitin D. Bansode, Kotagudda Ranganath Sindhu, Chloe Morel, Murielle Rémy, Julien Verget, Claudine Boiziau, Philippe Barthélémy
Constructing biocompatible soft materials via supramolecular approaches remains an important challenge for in vivo applications.
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Naturally available hypericin undergoes electron transfer for type I photodynamic and photothermal synergistic therapy

Biomater. Sci., 2020, 8,2481-2487
DOI: 10.1039/D0BM00021C, Paper
Zhen Ke, Aize Xie, Jianjiao Chen, Zhenyuan Zou, Lei Shen, Yansong Dai, Dengfeng Zou
Hypericin undergoing electron transfer can be used for type I PDT and PTT.
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Enhanced selectivity, cellular uptake, and in vitro activity of an intrinsically fluorescent copper–tirapazamine nanocomplex for hypoxia targeted therapy in prostate cancer

Biomater. Sci., 2020, 8,2420-2433
DOI: 10.1039/C9BM01905G, Paper
Vera L. Silva, Abdessamad Kaassis, Ashkan Dehsorkhi, Cédrik-Roland Koffi, Maja Severic, Moustafa Abdelhamid, Duuamene Nyimanu, Christopher J. Morris, Wafa’ T. Al-Jamal
Cu(TPZ)2 complex as a promising hypoxia selective cytotoxin in prostate cancer.
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The electrospinning of a thermo-responsive polymer with peptide conjugates for phenotype support and extracellular matrix production of therapeutically relevant mammalian cells

Biomater. Sci., 2020, 8,2611-2626
DOI: 10.1039/C9BM01965K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
F. A. A. Ruiter, L. E. Sidney, K. L. Kiick, J. I. Segal, C. Alexander, F. R. A. J. Rose
The fabrication and application of a biocompatible peptide conjugated thermo-responsive fibrous scaffolds for cellular phenotype support and enzymatic-free passaging of mammalian cells.
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A super-stretchable, self-healing and injectable supramolecular hydrogel constructed by a host–guest crosslinker

Biomater. Sci., 2020, Advance Article
DOI: 10.1039/D0BM00290A, Paper
Yang Zhou, Yuanhao Zhang, Zhaobo Dai, Fang Jiang, Jia Tian, Weian Zhang
Supramolecular hydrogels based on host–guest interactions have drawn considerable attention due to their unique properties and promising applications.
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Ministry of Defence inks Rs 1,200 cr contract to boost electronics sector

The deal, Modernisation of Air Field Infrastructure Phase 2 (MAFI-2), follows from an earlier contract, called MAFI-1, which TPSED won in 2011 to upgrade 30 IAF airfields.




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Tamil Nadu CM asks PM to keep Electricity Amendment Bill on hold till talks

Proposed Bill takes away certain powers of the State government, and seeks to bring in changes in the existing Electricity Act that would make power utilities in the public sector totally unviable




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Probing permanent dipoles in CdSe nanoplatelets with transient electric birefringence

Nanoscale, 2020, Advance Article
DOI: 10.1039/D0NR00884B, Paper
Ivan Dozov, Claire Goldmann, Patrick Davidson, Benjamin Abécassis
Transient electric birefringence experiments with colloidal suspensions of zinc-blende CdSe semiconducting nanoplatelets prove that these particles bear a large ground-state electric dipole despite the cubic structure of bulk zinc-blende CdSe.
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RGD functionalized chitosan nanoparticle mediated targeted delivery of raloxifene selectively suppresses angiogenesis and tumor growth in breast cancer

Nanoscale, 2020, Advance Article
DOI: 10.1039/C9NR10673A, Paper
Amit S. Yadav, N. Naga Venkata Radharani, Mahadeo Gorain, Anuradha Bulbule, Dattatrya Shetti, Gaurab Roy, Thejus Baby, Gopal C. Kundu
Peptide functionalized pH sensitive raloxifene-chitosan nanoparticles with high biocompatibility synergistically inhibit tumor growth and angiogenesis in breast cancer.
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Dy2@C79N: A New Member of Dimetalloazafullerenes with Strong Single Molecular Magnetism

Nanoscale, 2020, Accepted Manuscript
DOI: 10.1039/D0NR02519D, Paper
Yuanyuan Wang, Jin Xiong, Jie Su, Zi-Qi Hu, Fang Ma, Rong Sun, Xue-You Tan, Hao-Ling Sun, Bingwu Wang, Zujin Shi, Song Gao
Enhancing the exchange interaction between magnetic ions is a long-term target in molecular magnetism. Endohedral metallofullerenes (EMFs) provide a possibility for achieving such a goal by imprisoning multiple magnetic centers...
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A super stable assembled P nanowire with variant structural and magnetic/electronic properties via transition metal adsorption

Nanoscale, 2020, Accepted Manuscript
DOI: 10.1039/D0NR02176H, Paper
Sukai Wang, Jinxing Gu, Yinan Dong, Linwei Sai, Fengyu Li
By means of first-principles calculations, we systematically investigated the structure, stability, magnetic and electronic properties of one-dimensional P nanowire (1D-P10 NW) assembled by Pn subunits (n = 2, 8) and...
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Facile fabrication of sponge-like porous micropillar arrays via an electrochemical process

Nanoscale, 2020, Advance Article
DOI: 10.1039/D0NR01518K, Paper
Deyin Zheng, Chang-Hwan Choi, Xin Zhao, Guangyi Sun
Highly ordered and aligned pore structures perpendicular to the exposed surfaces are achieved on the surfaces of 3D Si microstructures.
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Plasma-assisted filling electron beam lithography for high throughput patterning of large area closed polygon nanostructures

Nanoscale, 2020, Advance Article
DOI: 10.1039/D0NR01032D, Paper
You Sin Tan, Hailong Liu, Qifeng Ruan, Hao Wang, Joel K. W. Yang
The PFEBL process allows enhancement of electron beam writing efficiency for patterning of closed polygon structures using a post-exposure plasma treatment.
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Mechanistic Insight in Site-selective and Anisotropic Etching of Prussian Blue Analogues toward Designable Complex Architectures for Efficient Energy Storage

Nanoscale, 2020, Accepted Manuscript
DOI: 10.1039/D0NR02241A, Paper
Hai Xu, Xi Zhao, Chenyang Yu, Yue Sun, Zengyu Hui, Ruicong Zhou, Jialu Xue, Henghan Dai, Yue Zhao, Lumin Wang, Yujiao Gong, Jin Yuan Zhou, Jianing An, Qiang Chen, Gengzhi Sun, Wei Huang
Engineering coordination compounds, e.g., prussian blue (PB) and its analogues (PBAs), with designable complex nanostructures via chemical etching holds great opportunities for improving energy storage performances by adjusting topological geometry,...
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A three-dimensional Cu nanobelt cathode for highly efficient electrocatalytic nitrate reduction

Nanoscale, 2020, 12,9385-9391
DOI: 10.1039/C9NR10743F, Paper
Xiaodan Wang, Mengqi Zhu, Guoshen Zeng, Xun Liu, Chihhsiang Fang, Chuanhao Li
A three-dimensional Cu nanobelt cathode was developed to efficiently catalyze the electrocatalytic nitrate reduction process.
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Analysis of sparse molecular distributions in fibrous arrangements based on the distance to the first neighbor in single molecule localization microscopy

Nanoscale, 2020, 12,9495-9506
DOI: 10.1039/C9NR10805J, Paper
Alan M. Szalai, Lucía F. Lopez, Miguel Ángel Morales-Vásquez, Fernando D. Stefani, Pedro F. Aramendía
We introduce a robust and sensitive metric to characterize the underlying structure responsible for the molecular distribution, even at a very low labeling density.
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The CpG molecular structure controls the mineralization of calcium phosphate nanoparticles and their immunostimulation efficacy as vaccine adjuvants

Nanoscale, 2020, 12,9603-9615
DOI: 10.1039/C9NR09782A, Paper
Razieh Khalifehzadeh, Hamed Arami
Effects of the CpG molecular structure on the mineralization and immunostimulation efficacy of calcium phosphate nanoparticles are explored for vaccine delivery applications.
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Oxygen vacancy-rich amorphous porous NiFe(OH)x derived from Ni(OH)x/Prussian blue as highly efficient oxygen evolution electrocatalysts

Nanoscale, 2020, 12,9557-9568
DOI: 10.1039/D0NR00607F, Paper
Shuang Wang, Xingbo Ge, Chao Lv, Cun Hu, Hongtai Guan, Jing Wu, Zhengnan Wang, Xianhui Yang, Yan Shi, Jiangfeng Song, Zhi Zhang, Akira Watanabe, Jinguang Cai
Oxygen vacancy-rich amorphous porous NiFe(OH)x on carbon paper is prepared through a two-step electrochemical depostion of Prussian blue nanocrystal layer and Ni(OH)x layer followed by an alkaline etching process for efficient OER catalysis.
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N- & S-co-doped carbon nanofiber network embedded with ultrafine NiCo nanoalloy for efficient oxygen electrocatalysis and Zn–air batteries

Nanoscale, 2020, 12,9581-9589
DOI: 10.1039/D0NR01516D, Paper
Chaojun Liu, Zhuang Wang, Xin Zong, Yingmin Jin, Dong Li, Yueping Xiong, Gang Wu
A 3D carbon nanofiber network embedded with ultrafine nanoparticles is prepared by electrospinning. Thioacetamide is used to prevent the aggregation of active sites.
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Enhanced type I photoreaction of indocyanine green via electrostatic-force-driven aggregation

Nanoscale, 2020, 12,9517-9523
DOI: 10.1039/D0NR01208D, Paper
Huizhen Fan, Yu Fan, Wenna Du, Rui Cai, Xinshuang Gao, Xinfeng Liu, Hao Wang, Lei Wang, Xiaochun Wu
ICG forms aggregates in positively charged mesoporous silica, which show an enhanced type I photoreaction pathway.
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Tuning ferroelectricity and ferromagnetism in BiFeO3/BiMnO3 superlattices

Nanoscale, 2020, 12,9810-9816
DOI: 10.1039/C9NR09670A, Paper
Cai Jin, Wanrong Geng, Linjing Wang, Wenqiao Han, Dongfeng Zheng, Songbai Hu, Mao Ye, Zedong Xu, Yanjiang Ji, Jiali Zhao, Zuhuang Chen, Gan Wang, Yunlong Tang, Yinlian Zhu, Xiuliang Ma, Lang Chen
Superlattice structure provides an effective path for integrating multifunctional properties. The interfacial coupling in the ferromagnetic/ferroelectric superlattices is a possible route to achieve multiferroicity.
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Ternary PtFeCo alloys on graphene with high electrocatalytic activities for methanol oxidation

Nanoscale, 2020, 12,9824-9832
DOI: 10.1039/D0NR00757A, Paper
Hongfei Wang, Kefu Zhang, Jun Qiu, Juan Wu, Jingwen Shao, Huijuan Wang, Yujuan Zhang, Jie Han, Yong Zhang, Lifeng Yan
Ternary PtFeCo alloys as alternatives to conventional Pt electrocatalysts are highly important in the field of the methanol oxidation reaction.
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Characteristics of crystalline sputtered LaFeO3 thin films as photoelectrochemical water splitting photocathodes

Nanoscale, 2020, 12,9653-9660
DOI: 10.1039/D0NR01762K, Paper
Min-Kyu Son, Hyunwoong Seo, Motonori Watanabe, Masaharu Shiratani, Tatsumi Ishihara
A transparent crystalline sputtered LaFeO3 photocathode with an early onset potential for stable photoelectrochemical water splitting.
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Designing transition-metal-boride-based electrocatalysts for applications in electrochemical water splitting

Nanoscale, 2020, 12,9327-9351
DOI: 10.1039/D0NR01279C, Review Article
Yuanyuan Jiang, Yizhong Lu
Recent progresses made in transition metal boride (TMB)-based electrocatalysts for electrochemical water splitting are summarized.
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NiSe2-anchored N, S-doped graphene/Ni foam as a free-standing bifunctional electrocatalyst for efficient water splitting

Nanoscale, 2020, 12,9866-9872
DOI: 10.1039/D0NR00879F, Paper
Jinhao Zhou, Zegao Wang, Dongxu Yang, Fei Qi, Xin Hao, Wanli Zhang, Yuanfu Chen
A strategy to synthesize free-standing electrocatalysts coupling active nanostructured NiSe2 with conductive S, N-doped 3D graphene foam (3DSNG) is presented and the hybrid delivers superior performances for the HER, OER and overall water splitting.
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An ultra-broadband terahertz metamaterial coherent absorber using multilayer electric ring resonator structures based on anti-reflection coating

Nanoscale, 2020, 12,9769-9775
DOI: 10.1039/C9NR10668E, Paper
Chao Du, Di Zhou, Huan-Huan Guo, Yong-Qiang Pang, Hong-Yu Shi, Wen-Feng Liu, Jin-Zhan Su, Charanjeet Singh, Sergei Trukhanov, Alex Trukhanov, Larissa Panina, Zhuo Xu
We propose a method for achieving THz ultra-broadband coherent absorption using the anti-reflection theory of metamaterials.
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Efficient polyalcohol oxidation electrocatalysts enabled by PtM (M = Fe, Co, and Ni) nanocubes surrounded by (200) crystal facets

Nanoscale, 2020, 12,9842-9848
DOI: 10.1039/D0NR00163E, Paper
Tongxin Song, Fei Gao, Yangping Zhang, Chunyan Chen, Cheng Wang, Shujin Li, Hongyuan Shang, Yukou Du
The (200)-enclosed Pt4M nanocubes (NCs) exhibit ascendant catalytic property towards GOR and EGOR due to the introduction of transition metals.
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Trace metals dramatically boost oxygen electrocatalysis of N-doped coal-derived carbon for zinc–air batteries

Nanoscale, 2020, 12,9628-9639
DOI: 10.1039/C9NR10800A, Paper
Huimin Liu, Xinning Huang, Zhenjie Lu, Tao Wang, Yaming Zhu, Junxia Cheng, Yue Wang, Dongling Wu, Zhenyu Sun, Alex W. Robertson, Xingxing Chen
The commercialization of metal–air batteries requires efficient, low-cost, and stable bifunctional electrocatalysts for reversible electrocatalysis of the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER).
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Point defect induced intervalley scattering for the enhancement of interlayer electron transport in bilayer MoS2 homojunctions

Nanoscale, 2020, 12,9859-9865
DOI: 10.1039/D0NR01339K, Paper
Yang Ou, Zhuo Kang, Qingliang Liao, Shihan Gao, Zheng Zhang, Yue Zhang
The interlayer transport of MoS2 homojunctions can be enhanced by point defect induced K–Q intervalley scattering.
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Supramolecular chemistry of carbon nano-onions

Nanoscale, 2020, 12,9352-9358
DOI: 10.1039/D0NR01713B, Minireview
Michał Bartkowski, Silvia Giordani
An exhaustive and succinct minireview of the various reported approaches to the non-covalent surface modification of carbon nano-onions (CNOs).
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2D molybdenum disulphide nanosheets incorporated with single heteroatoms for the electrochemical hydrogen evolution reaction

Nanoscale, 2020, Advance Article
DOI: 10.1039/D0NR01295E, Minireview
Thomas H. M. Lau, John S. Foord, S. C. Edman Tsang
2D nanosheets give enhanced surface area to volume ratios in particle morphology and they can also provide defined surface sites to disperse foreign atoms.
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Cyclodextrin-based superparamagnetic host vesicles as ultrasensitive nanobiocarriers for electrosensing

Nanoscale, 2020, 12,9884-9889
DOI: 10.1039/D0NR01702G, Paper
Jose Muñoz, Núria Crivillers, Bart Jan Ravoo, Marta Mas-Torrent
Magnetic cyclodextrin vesicles (mCDVs) have been used as novel electrochemical biorecognition probes for the picomolar determination of thyroxine (T4), using a magneto nanocomposite carbon-paste electrode (mNC-CPE) as a transducer platform.
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Emerging pnictogen-based 2D semiconductors: sensing and electronic devices

Nanoscale, 2020, Advance Article
DOI: 10.1039/D0NR02932G, Review Article
Pradip Kumar Roy, Jan Luxa, Zdeněk Sofer
Pnictogens have drawn tremendous attention due to their electronic structure and semiconducting character. Their fascinating features provide a novel platform for new devices in 2D materials which will pave the way for new nanodevices.
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