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Murray-Darling basin plan : five-year assessment / Australian Government, Productivity Commission

Australia. Productivity Commission, author, issuing body




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Marine protected areas : science, policy and management / edited By John Humphreys, Robert W.E. Clark




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World heritage sites of Australia / Peter Valentine ; foreword by Peter Garrett

Valentine, Peter Sinclair, author




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Practical evaluation for conservation education and outreach : assessing impacts & enhancing effectiveness / Katherine Clavijo and Kathayoon A. Khalil ; foreword by Judy Diamond

Clavijo, Katherine, author




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The dysfunctional library: challenges and solutions to workplace relationships / Jo Henry, Joe Eshleman, Richard Moniz

Barker Library - Z682.H495 2018




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Association Between Genetically Proxied Inhibition of HMG-CoA Reductase and Epithelial Ovarian Cancer

This study uses mendelian randomization to estimate the associations between genetic variants related to reduced HMG-CoA reductase activity and epithelial ovarian cancer in the general population and in BRCA1/2 mutation carriers.




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SCR orders probe into railway accident

Goods train runs over people sleeping on the tracks killing 16 and injuring one




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HC suspends decision to surrender medical PG diploma courses

This is not the way to treat govt. doctors, observes bench




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Palladium-catalyzed synthesis of [60]fullerene-fused furochromenones and further electrochemical functionalization

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00264J, Research Article
Majid Hussain, Chuang Niu, Guan-Wu Wang
The palladium-catalyzed heteroannulation of [60]fullerene with 4-hydroxycoumarins affords [60]fullerene-fused furochromenones, which can be further derivatized via an electrochemical method to synthesize 1,2,3,4-adducts.
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Rhodium-catalyzed asymmetric transfer hydrogenation of 4-quinolone derivatives

Org. Chem. Front., 2020, 7,975-979
DOI: 10.1039/C9QO01514K, Research Article
Bin He, Phannarath Phansavath, Virginie Ratovelomanana-Vidal
4-Quinolone derivatives were conveniently reduced to 1,2,3,4-tetrahydroquinoline-4-ols with excellent enantioselectivities through asymmetric transfer hydrogenation using a tethered rhodium complex and formic acid/triethylamine as the hydride source.
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Expeditious access of chromone analogues via a Michael addition-driven multicomponent reaction

Org. Chem. Front., 2020, 7,987-992
DOI: 10.1039/D0QO00145G, Research Article
Jie Lei, Yong Li, Liu-Jun He, Ya-Fei Luo, Dian-Yong Tang, Wei Yan, Hui-Kuan Lin, Hong-yu Li, Zhong-Zhu Chen, Zhi-Gang Xu
A Michael addition-driven four-component reaction (4-CR) with four Ugi inputs was developed and utilized for the synthesis of chromone derivatives and tetrazole substituted chromones under mild reaction conditions.
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HKOCl-4: a rhodol-based yellow fluorescent probe for the detection of hypochlorous acid in living cells and tissues

Org. Chem. Front., 2020, 7,993-996
DOI: 10.1039/D0QO00081G, Research Article
Xiaoyu Bai, Bowei Yang, Hansen Chen, Jiangang Shen, Dan Yang
Highly sensitive and selective yellow probes, HKOCl-4 and its derivatives, have been developed for detecting endogenous HOCl in cytosol and mitochondria of living cells. In addition, visualization of HOCl production in ischemic stroke model has been achieved with HKOCl-4r.
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Copper-catalyzed tandem phosphorylative allenylation/cyclization of 1-(o-aminophenyl)prop-2-ynols with the P(O)–H species: access to C2-phosphorylmethylindoles

Org. Chem. Front., 2020, 7,980-986
DOI: 10.1039/D0QO00159G, Research Article
Xiao-Yan Liu, Yun-Xiang Zou, Hai-Liang Ni, Jing Zhang, Hong-Bo Dong, Long Chen
A novel method to synthesize C2-phosphorylmethylindoles via the carbocation formation initiated tandem phosphorylative allenylation/cyclization of 1-(o-aminophenyl)prop-2-ynols with the P(O)–H species has been developed.
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Chelation-assisted transition metal-catalysed C–H chalcogenylations

Org. Chem. Front., 2020, 7,1022-1060
DOI: 10.1039/C9QO01497G, Review Article
Wenbo Ma, Nikolaos Kaplaneris, Xinyue Fang, Linghui Gu, Ruhuai Mei, Lutz Ackermann
This review summarizes recent advances in C–S and C–Se formations via transition metal-catalyzed C–H functionalization utilizing directing groups to control the site-selectivity.
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Oxidative N-heterocyclic carbene-catalyzed [3 + 3] annulation reaction of enals with benzofuran-3-ones: efficient access to benzofuran-fused δ-lactones

Org. Chem. Front., 2020, 7,1011-1015
DOI: 10.1039/D0QO00161A, Research Article
Zhan-Yong Wang, Ting Yang, Kai-Kai Wang, Rongxiang Chen, Menghan Liu, Hongxin Liu
A facile route to benzofuran-fused δ-lactones was developed via an N-heterocyclic carbene-catalyzed [3 + 3] annulation reaction, giving the expected products in high yields (up to 99%) with excellent enantioselectivities (up to 98% ee).
The content of this RSS Feed (c) The Royal Society of Chemistry




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Construction of spirooxindole-fused spiropyrazolones containing contiguous three stereogenic centres via [3 + 2] annulation utilizing a ferrocene derived bifunctional phosphine catalyst

Org. Chem. Front., 2020, 7,1016-1021
DOI: 10.1039/D0QO00140F, Research Article
Wenjun Luo, Bingxuan Shao, Jingyi Li, Xiao Xiao, Dingguo Song, Fei Ling, Weihui Zhong
Regional and stereoselective construction of spirooxindole-fused spiropyrazolones containing contiguous three stereogenic centres via [3 + 2] annulation catalyzed by ferrocene derived bifunctional phosphine.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Total synthesis of tumor-associated KH-1 antigen core nonasaccharide via photo-induced glycosylation

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00314J, Research Article
Bo-Han Li, Wenlong Yao, Hong Yang, Congying Wu, De-Cai Xiong, Yuxin Yin, Xin-Shan Ye
KH-1 antigen core nonasaccharide was efficiently assembled by photo-induced glycosylation.
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Cooperative photoredox and chiral hydrogen-bonding catalysis

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00276C, Review Article
Yanli Yin, Xiaowei Zhao, Baokun Qiao, Zhiyong Jiang
Chiral hydrogen-bonding catalysis is a classic strategy in asymmetric organocatalysis. Recently, it has been used to cooperate with photoredox catalysis, becoming a powerful tool to access optical pure compounds via radical-based transformations.
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Double allylic defluorinative alkylation of 1,1-bisnucleophiles with (trifluoromethyl)alkenes: construction of all-carbon quaternary centers

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00121J, Research Article
Yingying Cai, Hao Zeng, Chuanle Zhu, Chi Liu, Guangying Liu, Huanfeng Jiang
Synthesis of symmetric gem-difluoroalkene substituted products bearing all-carbon quaternary centers via double allylic defluorinative alkylation of 1,1-bisnucleophiles with (trifluoromethyl)alkenes.
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Pd/light-induced alkyl–alkenyl coupling reaction between unactivated alkyl iodides and alkenylboronic acids

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00318B, Research Article
Hsin-Ju Huang, Yi-Ting Wang, Yen-Ku Wu, Ilhyong Ryu
Alkyl–alkenyl coupling reaction between unactivated alkyl iodides and 2-arylalkenylboronic acids utilizing a Pd/light combined system was studied.
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Folding of fluorinated oligoarylenes into non-alternant PAHs with various topological shapes

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00370K, Research Article
Vladimir Akhmetov, Andreas Förtsch, Mikhail Feofanov, Sergey Troyanov, Konstantin Amsharov
An unprecedented [6]helicene's cavity closure indicating the possibility of introducing seven-membered rings via alumina-mediated C–F activation is shown.
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Rh-Catalyzed nitrene alkyne metathesis/formal C–N bond insertion cascade: synthesis of 3-iminoindolines

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00294A, Research Article
Kemiao Hong, Su Zhou, Wenhao Hu, Xinfang Xu
A Rh-catalyzed nitrene/alkyne metathesis (NAM) cascade reaction terminated by a formal C–N bond insertion has been developed, which provides facile access to the tricyclic 3-iminoindolines in good yields with broad substrate scope.
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Pyridine tetrafluoro-λ6-sulfanyl chlorides: spontaneous addition to alkynes and alkenes in the presence or absence of photo-irradiation

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00339E, Research Article
Kiyoteru Niina, Kazuhiro Tanagawa, Yuji Sumii, Norimichi Saito, Norio Shibata
A radical addition reaction of Py-SF4Cl to alkynes and alkenes provide pyridine-SF4-alkenes and pyridine-SF4-alkanes under blue LED light irradiation or absence of light irradiation in CPME or without solvent.
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Discovery of new polycyclic polyprenylated acylphloroglucinols with diverse architectures as potent cyclooxygenase-2 inhibitors

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00259C, Research Article
Shuangshuang Xie, Changxing Qi, Yulin Duan, Qianqian Xu, Yaping Liu, Yingying Huang, Xu Yin, Weiguang Sun, Yuan Zhou, Yonghui Zhang
Cyclooxygenase-2 (COX-2) is a significant therapeutic target of chronic inflammatory diseases.
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Visible-light mediated oxidative ring expansion of anellated cyclopropanes to fused endoperoxides with antimalarial activity

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00168F, Research Article
Simon Budde, Felix Goerdeler, Johannes Floß, Peter Kreitmeier, Elliot F. Hicks, Oren Moscovitz, Peter H. Seeberger, Huw M. L. Davies, Oliver Reiser
Hetero- and carbocyclic anellated cyclopropanes were converted in one step by a visible light induced photooxidation to their corresponding polycyclic endoperoxides, which show promising antimalarial activity.
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Roquefornine A, a sesterterpenoid with a 5/6/5/5/6-fused ring system from the fungus Penicillium roqueforti YJ-14

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00301H, Research Article
Jia-Peng Wang, Yan Shu, Jun-Tao Hu, Rui Liu, Xue-Yun Cai, Cheng-Tong Sun, Dong Gan, Di-Jiao Zhou, Rui-Feng Mei, Hao Ding, Xiao-Ran Zhang, Le Cai, Zhong-Tao Ding
Roquefornine A, a sesterterpenoid with an unprecedented 5/6/5/5/6-membered pentacyclic system, was characterized from Penicillium roqueforti YJ-14. Its structure was determined by extensive spectroscopic analyses, [Rh2(OCOCF3)4]-induced CD data and DP4+ calculations....
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Transition metal-catalyzed coupling of heterocyclic alkenes via C-H activation: Recent trends and applications

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00279H, Review Article
Sundaravel Vivek Kumar, Sonbidya Banerjee, Tharmalingam Punniyamurthy
Heterocyclic alkenes represent an important class of reactive feedstock and valuable synthons for the synthesis of biologically important heterocyclic scaffolds. Although functionalized heterocyclic alkenes and their derivatives can be accessed...
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Turn-on fluorescence sensors based on dynamic intramolecular N→B-coordination

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00267D, Research Article
Raphael Koch, Yu Sun, Andreas Orthaber, Antonio J. Pierik, Frank Pammer
A series of ten aryl-triazole-functionalized boranes bearing BMes2-groups and capable of forming intramolecular five-membered N→B-coordinated heterocycles, has been prepared by 1,3-dipolar cycloaddition.
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Ag2O-catalysed nucleophilic isocyanation: selective formation of less-stable benzylic isonitriles

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00336K, Research Article
Taiga Yurino, Yuji Tange, Ryutaro Tani, Takeshi Ohkuma
Both primary and secondary benzylic isonitriles were exclusively produced by the Ag2O-catalysed reaction of benzylic phosphates and trimethylsilyl cyanide without formation of the thermodynamically favoured regioisomers, benzylic nitriles.
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Hyperforones A–C, benzoyl-migrated [5.3.1]-type polycyclic polyprenylated acylphloroglucinols from Hypericum forrestii

Org. Chem. Front., 2020, 7,1070-1076
DOI: 10.1039/D0QO00152J, Research Article
Wei-Jia Lu, Wen-Jun Xu, Yan-Qiu Zhang, Yi-Ran Li, Xin Zhou, Qi-Ji Li, Hao Zhang, Jun Luo, Ling-Yi Kong
Unprecedented benzoyl-migrated polycyclic polyprenylated acylphloroglucinols with a unique C-1 H-substituted bicyclo[5.3.1]hendecane framework, hyperforones A–C (1–3), were isolated from Hypericum forrestii.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Discrete boronate ester ladders from the dynamic covalent self-assembly of oligo(phenylene ethynylene) derivatives and phenylenebis(boronic acid)

Org. Chem. Front., 2020, 7,1082-1094
DOI: 10.1039/D0QO00083C, Research Article
Vasileios Drogkaris, Brian H. Northrop
Reversible boronate ester chemistry enables the controlled, dynamic self-assembly of olig(phenylene ethynylene)s into highly conjugated ladder frameworks.
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Differential formation of nitrogen-centered radicals leading to unprecedented, regioselective bromination of N,N'-(1,2-phenylene)bisamides and 2-amidophenols

Org. Chem. Front., 2020, 7,1095-1106
DOI: 10.1039/C9QO01508F, Research Article
Damoder Reddy Motati, Dilipkumar Uredi, Amarender Goud Burra, J. Phillip Bowen, Frank R. Fronczek, Clint R. Smith, E. Blake Watkins
A highly efficient, site-selective, visible light-accelerated, remote C–H halogenation of unsymmetrical aromatic bisamides/amidoesters has been developed.
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Insights into N-heterocyclic carbene and Lewis acid cooperatively catalyzed oxidative [3 + 3] annulation reactions of α,β-unsaturated aldehyde with 1,3-dicarbonyl compounds

Org. Chem. Front., 2020, 7,1113-1121
DOI: 10.1039/D0QO00091D, Research Article
Xinghua Wang, Yang Wang, Jinshuai Song, Donghui Wei
N-Heterocyclic carbene and Lewis acid cooperatively catalyzed oxidative [3 + 3] annulation reactions of 1,3-dicarbonyl compounds have been systematically studied in theory.
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Access to branched allylsilanes by nickel-catalyzed regioselective hydrosilylation of allenes

Org. Chem. Front., 2020, 7,1132-1136
DOI: 10.1039/D0QO00156B, Research Article
Jia-Hao Zeng, Jun-Jia Chen, Li Chen, Zhuang-Ping Zhan
A Ni(acac)2/Xantphos-catalyzed hydrosilylation of allenes has been developed.
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Toward C2-nitrogenated chromones by copper-catalyzed β-C(sp2)–H N-heteroarylation of enaminones

Org. Chem. Front., 2020, 7,1107-1112
DOI: 10.1039/D0QO00065E, Research Article
Tian Luo, Jie-Ping Wan, Yunyun Liu
The synthesis of C2-nitrogenated chromones has been performed via reactions of enaminones and nitrogen nucleophiles based on an unconventional β-C–H bond functionalization and a featured chromone annulation of enaminones.
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Recent developments in palladium-catalyzed C–S bond formation

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00377H, Research Article
Jianxiao Li, Shaorong Yang, Wanqing Wu, Huanfeng Jiang
This review summarized the recent developments in palladium-catalyzed C–S bond formation involving sulfenylation and sulfonylation reactions.
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en

Tricarabrols A–C, three anti-inflammatory sesquiterpene lactone trimers featuring a methylene-tethered linkage from Carpesium faberi

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00093K, Research Article
Jie Yuan, Xuelan Wen, Chang-Qiang Ke, Tian Zhang, Ligen Lin, Sheng Yao, Jason D. Goodpaster, Chunping Tang, Yang Ye
Three anti-inflammatory trimeric compounds constructed from carabrol-type sesquiterpenoids through a methylene-tethered linkage were characterized from Carpesium faberi.
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en

Chiral strong Brønsted acid-catalyzed enantioselective addition reaction of simple olefins with ethyl glyoxylate

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00448K, Research Article
Jun Kikuchi, Yuki Aizawa, Masahiro Terada
An enantioselective intermolecular addition reaction of 1,1,2-trisubstituted and 1,2- disubstituted simple olefins with ethyl glyoxylate was developed using F10BINOL-derived N-sulfonyl phosphoramide as a chiral strong Brønsted acid catalyst.
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An exocyclic π-system extension of the phenanthriporphyrin framework: towards azaaceneporphyrinoids

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00436G, Research Article
Bartosz Szyszko, Damian Dróżdż, Aleksandra Sarwa, Sebastian G. Mucha, Agata Białońska, Michał J. Białek, Katarzyna Matczyszyn, Lechosław Latos-Grażyński
An exocyclic π-extension of phenanthriporphyrin reduces the macrocyclic antiaromaticity of the formed expanded carbaporphyrinoids.
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Phosphine/Palladium Cooperative Catalysis: Enantioselective [5+4] Annulations of ortho-Quinone Methides and Vinylethylene Carbonates

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00128G, Research Article
Chao Xia, Dong-Chao Wang, Gui-Rong Qu, Hai-Ming Guo
Highly enantioselective [5+4] annulations of ortho-quinone methides with vinylethylene carbonates were enabled by phosphine/palladium asymmetric cooperative catalysis for the first time. Efficient synthesis of various nine-membered benzo-heterocycles was achieved in...
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Mechanism and Origins of Stereo- and Enantioselectivities of Palladium-Catalyzed Hydroamination of Racemic Internal Allenes via Dynamic Kinetic Resolution: A Computational Study

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00174K, Research Article
Zhenzhen Wu, Mei Zhang, Yu Shi, Genping Huang
Density functional theory calculations have been performed to investigate the Pd-catalyzed hydroamination of racemic internal allenes with pyrazoles. The computations show that the originally proposed reaction mechanisms initiated by the...
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Catalyst-Controlled Formal [4+1] Annulation of N-Vinyl Fluorenone Nitrones and Allenoates to Prepare Spirofluorenylpyrrolines

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00224K, Research Article
Cui Wei, Jin-Qi Zhang, Jia-Jie Zhang, Cui Liang, Dong-Liang Mo
We report a readily commercial Gimeracil-catalyzed formal [4+1] annulation approach for the synthesis of spirofluorenylpyrrolines in good yields with high diastereoselectivity from easily available N-vinyl fluorenone nitrones and allenoates. The...
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A Vinylogous Michael Reaction of 2-Furanones Dimers to α, β-Unsaturated Nitroolefins for Constructing Chiral γ, γ-Disubstituted Butenolides

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00376J, Research Article
Zhushuang Bai, Cairong Zhang, Yongyi Chen, Aiqin Liu, Xinyu Wang, Chuna Yan, Xuechao Liu, Xiaoru Zhang, Ying Li, Ye Yuan, Zemei Ge, Jingxiang Pang, Yongshuai Chai, Xin Wang, Runtao Li
An efficient bifunctional thiourea catalyzed asymmetric vinylogous Michael addition of 2-furanones dimers to α, β-unsaturated nitroolefins has been developed to give the functional chiral γ,γ-disubstituted butenolides in good yields (up...
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Rhodium(III)-catalyzed synthesis of 3-trifluoromethylindanones from N-Methoxybenzamides via C-H activation and Claisen/Retro-Claisen reaction

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00330A, Research Article
Satyasheel Sharma, Bharatkumar Chaudhary, Neeraj Kulkarni
The Rhodium(III)-catalyzed reaction of N-methoxybenzamides as a directing group with β-trifluoromethyl-α,β-unsaturated ketones is reported. The reaction involved sp2 C−H activation, followed by Claisen condensation involving C-N bond cleavage to form...
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Targeted Isolation of Two Disesquiterpenoids Macrocephadiolides A and B from Ainsliaea macrocephala using Molecular Networking-based Dereplication Strategy

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00030B, Research Article
Yong-Mei Ren, Shuaizhen Zhou, Tian Zhang, Meijia Qian, Rui Zhang, Sheng Yao, Hong Zhu, Chunping Tang, Ligen Lin, Yang Ye
A molecular networking-based dereplication strategy was applied to the phytochemical investigation of Ainsliaea macrocephala, leading to the isolation of two novel disesquiterpenoids macrocephadiolides A (1) and B (2). Their structures,...
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en

How to write and publish a scientific paper / Robert A. Day

Day, Robert A., 1924-




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Scientists must write : a guide to better writing for scientists, engineers and students / Robert Barrass

Barrass, Robert




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Writing scientific papers in English : an ELSE-Ciba Foundation guide for authors / Maeve O'Connor and F.Peter Woodford

O'Connor, Maeve




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The art of scientific writing : from student reports to professional publications in chemistry and related fields / Hans F. Ebel, Claus Bliefert, William E. Russey

Ebel, Hans Friedrich




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Communicating in science : writing and speaking / Vernon Booth

Booth, Vernon