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Visible-light-induced photocatalyst-free C-3 functionalization of indoles with diethyl bromomalonate

Green Chem., 2020, 22,2543-2548
DOI: 10.1039/D0GC00292E, Paper
Guangmiao Gu, Mengmeng Huang, Jung Keun Kim, Jianye Zhang, Yabo Li, Yangjie Wu
A visible-light-induced and XB-promoted green approach to construct α-indolyl diethyl malonates was developed.
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Hierarchically porous covalent organic frameworks assembled in ionic liquids for highly effective catalysis of C–C coupling reactions

Green Chem., 2020, 22,2605-2612
DOI: 10.1039/D0GC00223B, Paper
Jikuan Qiu, Huiyong Wang, Yuling Zhao, Pengxin Guan, Zhiyong Li, Hucheng Zhang, Hongshuai Gao, Suojiang Zhang, Jianji Wang
A simple and environmentally benign strategy was reported for the synthesis of hierarchically porous COFs in ionic liquids, and the obtained materials show highly effective catalytic performance for C–C bond formation reactions.
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Solvent-free and montmorillonite K10-catalyzed domino reactions for the synthesis of pyrazoles with alkynylester as a dual synthon

Green Chem., 2020, 22,2388-2393
DOI: 10.1039/D0GC00162G, Communication
Sesuraj Babiola Annes, Rajendhiran Saritha, Saravanan Subramanian, Bhaskaran Shankar, Subburethinam Ramesh
A highly regioselective, solvent-free and montmorillonite K10 clay-catalyzed domino process with an unprecedented C–C bond formation reaction is described for the synthesis of new class of tri-substituted and di-substituted pyrazole derivatives.
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Reusable, homogeneous water soluble photoredox catalyzed oxidative dehydrogenation of N-heterocycles in a biphasic system: application to the synthesis of biologically active natural products

Green Chem., 2020, 22,2575-2587
DOI: 10.1039/D0GC00569J, Paper
S. Srinath, R. Abinaya, Arun Prasanth, M. Mariappan, R. Sridhar, B. Baskar
Herein, a simple and efficient method for the oxidative dehydrogenation (ODH) of tetrahydro-β-carbolines, indolines and (iso)quinolines is described using a reusable, homogeneous cobalt-phthalocyanine photoredox catalyst in a biphasic medium.
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One-pot synthesis of 1,3-butanediol by 1,4-anhydroerythritol hydrogenolysis over a tungsten-modified platinum on silica catalyst

Green Chem., 2020, 22,2375-2380
DOI: 10.1039/D0GC00244E, Communication
Lujie Liu, Takehiro Asano, Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige
Chemical production of 1,3-butanediol from biomass-derived compounds was first reported by 1,4-anhydroerythritol hydrogenolysis over a Pt–WOx/SiO2 catalyst.
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Iridium-catalyzed orthogonal and regioselective synthesis of triazole disulfides in aqueous media under mild conditions

Green Chem., 2020, 22,2394-2398
DOI: 10.1039/D0GC00555J, Communication
Ming Li, Nan Zheng, Junhao Li, Yubin Zheng, Wangze Song
Triazole disulfides were prepared in water or biological media under mild conditions by orthogonal and regioselective Ir-catalyzed reactions.
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Double-metal cyanide as an acid and hydrogenation catalyst for the highly selective ring-rearrangement of biomass-derived furfuryl alcohol to cyclopentenone compounds

Green Chem., 2020, 22,2549-2557
DOI: 10.1039/C9GC04432A, Paper
Xiang Li, Qiang Deng, Lian Yu, Rui Gao, Zhikun Tong, Chenxi Lu, Jun Wang, Zheling Zeng, Ji-Jun Zou, Shuguang Deng
Herein, novel green synthetic routes to 4-hydroxy-2-cyclopentenone (HCP) and 2-cyclopentenone (CPE) from biomass-derived furfuryl alcohol via double-metal cyanide catalysis are proposed.
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Improving process efficiency of gold-catalyzed hydration of alkynes: merging catalysis with membrane separation

Green Chem., 2020, 22,2598-2604
DOI: 10.1039/D0GC00498G, Paper
Tahani A. C. A. Bayrakdar, Fady Nahra, Oihane Zugazua, Lies Eykens, Dominic Ormerod, Steven P. Nolan
In this report, we investigate the integration of a membrane separation protocol in line with the gold-catalyzed hydration of alkynes.
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Visible Light-Induced Aerobic Oxidation of Diarylalkynes to -Diketones Catalyzed by Copper-superoxo at Room Temperature

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00975J, Communication
Vaibhav Pramod Charpe, Arunachalam Sagadevan, Kuo Chu Hwang
We have developed the visible light induced simple copper(II) chloride catalyzed the oxidation of diarylacetylenes to -diketones by molecular oxygen at room temperature. The in-situ generated copper(II)-superoxo complex is a...
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Photocatalytic transfer hydrogenolysis of aromatic ketones using alcohols

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00732C, Paper
Hongji Li, Zhuyan Gao, Lijun Lei, Huifang Liu, Jianyu Han, Feng Hong, Nengchao Luo, Feng Wang
A mild method of photocatalytic deoxygenation of aromatic ketones to alkyl arenes was developed, which utilized alcohols as the green hydrogen donor. No hydrogen evolution during this transformation suggested a...
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Chemoselective O-formyl and O-acyl protection of alkanolamines, phenoxyethanols and alcohols catalyzed by nickel(II) and copper(II)-catalysts

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00520G, Paper
Rahul B. Sonawane, Swapnali R. Sonawane, Nishant K. Rasal, Sangeeta V. Jagtap
A crucial chemoselective O-formyl and O-acyl protection of alkanolamines, phenoxyethanols, and alcohols in the presence of amines catalyzed by Ni(II) and Cu(II) complexes with 8-hydroxyquinoline in a homogeneous medium is achieved.
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Degradation of poly(ethylene terephthalate) catalyzed by metal-free choline-based ionic liquids

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00327A, Paper
Yachan Liu, Xiaoqian Yao, Haoyu Yao, Qing Zhou, Jiayu Xin, Xingmei Lu, Suojiang Zhang
Glycolysis of PET is a prospective way for degradation of PET to its monomer bis(hydroxyethyl)terephthalate (BHET) which can be polymerized again to form new qualified PET materials, and hence provides possibilities for a permanent loop recycling.
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One-step catalytic amination of naphthalene to naphthylamine with exceptional yield

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00633E, Communication
Fang Hao, Xin Wang, Linfang Huang, Wei Xiong, Pingle Liu, Hean Luo
This is the first time to synthesize naphthylamine from one-step naphthalene amination by vanadium catalysts with high yield under mild condition. It could obtain ∼70% yield of naphthylamine, with major product of valuable 1,5-diaminonaphthalene.
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Nickel-catalyzed and Li-mediated regiospecific C–H arylation of benzothiophenes

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00917B, Paper
Yorck Mohr, Gaëlle Hisler, Léonie Grousset, Yoann Roux, Elsje Alessandra Quadrelli, Florian M. Wisser, Jérôme Canivet
A sustainable nickel-catalyzed direct C–H arylation of benzothiophenes, benzofuran and selenophene is reported for the first time.
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Mechanochemical Cleavage of Lignin Models and lignin via Oxidation and Subsequent Base-Catalyzed Strategy

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00372G, Paper
Weike Su, Chen Sun, Lei Zheng, Wenhao Xu, Alexandr V. Dushkin
Mechanochemical cleavage of lignin dimer model compounds to phenolic monomers has been developed via a two-step strategy under milling conditions. In the first step of this process, the secondary benzylic...
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Achieving visible light-driven hydrogen evolution at positive bias with a hybrid copper–iron oxide|TiO2-cobaloxime photocathode

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00979B, Paper
C. Tapia, E. Bellet-Amalric, D. Aldakov, F. Boudoire, K. Sivula, L. Cagnon, V. Artero
H2 is an environmentally-friendly fuel that would allow for a circular economy but its sustainable production from solar energy and water using stable, efficient and scalable Earth-abundant materials, remains a challenge.
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Photocatalytic Hydrogen Atom Transfer: the Philosopher’s Stone for Late-Stage Functionalization?

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC01035A, Tutorial Review
Luca Capaldo, Lorenzo Lafayette Quadri, Davide Ravelli
An overview about the potentialities of photocatalytic Hydrogen Atom Transfer (HAT) for the Late-Stage Functionalization (LSF) of complex molecules is offered. The examined approach allows the smooth homolytic cleavage of...
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Transparent, flexible and recyclable nanopaper-based touch sensors fabricated via inkjet-printing

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00658K, Paper
Hao Ling, Ruwei Chen, Quanbo Huang, Feng Shen, Yuyuan Wang, Xiaohui Wang
Using an eco-friendly PEDOT:PSS ink formula, a transparent and flexible nanopaper-based touch sensor was fabricated via inkjet-printing.
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Tandem catalytic aromatization of volatile fatty acids

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00964D, Paper
Open Access
Egor V. Fufachev, Bert M. Weckhuysen, Pieter C. A. Bruijnincx
The transition towards a circular economy requires closing the carbon loop, e.g. by the development of new synthesis routes to valuable intermediates and products from organic-rich waste streams.
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Yb(OTf)3 and Visible Light Relay Catalyzed [3+2] Cycloaddition/[3,3]-Rearrangement/[4+2] Cycloaddition in One Pot to Prepare Oxazonine-Fused Endoperoxides

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00929F, Paper
Xiao-Pan Ma, Cai-Mei Nong, Yu-Feng Liang, Pei-Pei Xu, Xiu-Yun GUO, Cui Liang, Chengxue Pan, Gui-Fa SU, Dong-Liang Mo
We report a relay catalysis for the highly stereoselective synthesis of densely substituted oxazonine-fused endoperoxides in good yields. This domino reaction is based on a Yb(OTf)3 and visible light promoted...
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Microwave-assisted aqueous carbon–carbon cross-coupling reactions of aryl chlorides catalysed by reduced graphene oxide supported palladium nanoparticles

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00833H, Paper
Qingxiao Zhang, Zhan Mao, Kaixuan Wang, Nam Thanh Son Phan, Fang Zhang
Microwave-assisted reduced graphene oxide supported palladium nanoparticles can efficiently promote aqueous Ullmann and Suzuki coupling reactions of aryl chlorides.
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Functionalized magnetic nanosized materials for efficient biodiesel synthesis via acid–base/enzyme catalysis

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00924E, Critical Review
Anping Wang, Putla Sudarsanam, Yufei Xu, Heng Zhang, Hu Li, Song Yang
This critical review introduces the preparation methods, structural and performance control, protection, and functionalization of magnetic nanoparticles as easily recyclable and efficient heterogeneous catalysts for biodiesel synthesis.
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Metal-catalysed selective transfer hydrogenation of α,β-unsaturated carbonyl compounds to allylic alcohols

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00855A, Critical Review
Ronald Alvaro Alvaro Farrar Tobar, Andrea Dell'Acqua, Sergey Tin, Johannes G. de Vries
Allylic alcohols are highly important compounds which are used in a variety of processes. They can be obtained from α,β-unsaturated carbonyl compounds via stoichiometric or catalytic reductions. Catalytic transfer hydrogenation...
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Highly efficient oxidation of alcohols to carboxylic acids using a polyoxometalate-supported chromium(III) catalyst and CO2

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00388C, Paper
Ying Wang, ZhiKang Wu, Han Yu, Sheng Han, Yongge Wei
A green and highly efficient oxidation of alcohols to carboxylic acids using a polyoxometalate-supported chromium(III) catalyst and CO2.
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Catalytic C–C coupling of diazo compounds with arylboronic acids: using surface modified sewage sludge as catalyst

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00317D, Paper
Zhipeng Zhang, Yang Yu, Yuxing Xie, Timothy Hughes, Jun Xu, Fei Huang, He Huang
A green, mild and efficient synthesis of diarylmethines using sewage sludge-derived carbonaceous materials (SW) by perchloric acid catalyzed coupling reactions between diazo compounds and arylboronic acids was developed.
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Photoreforming of food waste into value-added products over visible-light-absorbing catalysts

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC01240H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Taylor Uekert, Florian Dorchies, Christian M. Pichler, Erwin Reisner
Food and mixed wastes are converted into H2 and organics over CdS and carbon nitride photocatalysts.
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Photochemical strategies for C–N bond formation via metal catalyst-free (hetero) aryl C(sp2)–H functionalization

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC01088J, Tutorial Review
Qing-Qing Kang, Wenfeng Wu, Qiang Li, Wen-Ting Wei
The development of efficient and mild methods to assemble C–N bonds represents an important and appealing goal in modern synthetic chemistry.
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Photochemical Synthesis of Acetals utilizing Schreiner’s Thiourea as the Catalyst

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC01135E, Paper
Open Access
Nikoleta Spiliopoulou, Nikolaos Nikitas, Christoforos G Kokotos
Acetalization of aldehydes is an area of great importance in Organic Chemistry for both synthetic and biological puproses. Herein, we report a mild, inexpensive and green photochemical protocol, where Schreiner’s...
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A direct conversion of blast furnace slag to a mesoporous silica–calcium oxide composite and its application in CO2 captures

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00722F, Paper
Yasutaka Kuwahara, Aiko Hanaki, Hiromi Yamashita
A facile and cost-effective approach is presented that converts blast furnace slag into a mesoporous silica-CaO composite possessing high CO2 adsorption performance.
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Catalyst-Free Photodecarbonylation of 2-Amine Benzaldehyde

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC01256D, Communication
Jingwei Zhou, Lamei Li, Songping Wang, Ming Yan, Wentao Wei
It is almost a consensus that decarbonylation of aldehyde group (-CHO) need to not only be mediated by transition metal catalysts, but also react under severe reaction conditions (high temperature...
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Aqueous Phase Fabrication and Conversion of Pb(OH)Br into CH3NH3PbBr3 Perovskite and its Application in Resistive Memory Switching Devices

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00878H, Paper
Sanam Attique, Nasir Ali, Khatoon Rabia, Shahid Ali, Akmal Abbas, Yangchun Yu, Jiahui Hou, Bingqiang Cao, Huizhen Wu, Shikuan Yang
Organo-metal halide perovskites (OMHPs) have demonstrated promising applications in solar cells, light-emitting diodes, and photodetectors. However, besides the toxic lead, the intensive usage of organic solvents during their fabrication could...
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Catalytic production of 1, 4-Pentanediol from furfural in a fix-bed system under mild conditions

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00233J, Paper
QiaoYun Liu, Botao Qiao, Fei Liu, Leilei Zhang, Yang Su, Ai-Qin Wang, Tao Zhang
Furfural is one of the most important biomass-derived chemicals. Its large-scale availability calls for the exploration of new transformation routes for further valorization. Here we report on the direct, one-step...
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Cross-Border Relocation Law

Cross-Border Relocation Law is an authoritative guide to employment relocation issues on both sides of the Canada-U.S. border. It provides comprehensive coverage of immigration, customs, tax and employment issues for Canadian employees relocating to the U.S. and U.S. employees relocating to Canada. Recent changes to Canadian immigration law brought about by Bill C-11 are included.

Written by seven Canadian and U.S. experts, it will be of keen interest to legal, human resources, payroll and tax professionals who need to be aware of the myriad compliance issues surrounding cross-border relocation.

Topics covered:

  • U.S. immigration law for business visitors, trade NAFTA professionals, intra-company transfers and treaty traders/investors
  • Applying for a Green Card (family and employment based)
  • Canada's new Immigration and Refugee Protection Act
  • Canadian immigration law for temporary residents, including work permits and HRDC confirmation
  • Applying for permanent residence in Canada (skilled worker, business immigration and family class)
  • U.S. income taxation of non-U.S. and U.S. persons
  • U.S. employment and transfer taxes
  • Canadian tax issues for employees transferring from the U.S. to Canada
  • Canadian tax issues for employees transferring to Canada from the U.S.
  • Cross-border tax implications of pension and retirement plans
  • U.S. customs law on personal importations, including restrictions and exemptions
  • Canadian customs law, including duty and sales tax relief and exemptions
  • Benefits of NAFTA for cross-border relocations

About the Authors
Lorraine Allard (McCarthy Tétrault, Toronto) is a partner in the McCarthy Tétrault Tax Law Section.

John Boscariol (McCarthy Tétrault, Toronto) is recognized in the 2000/2001 LEXPERT® Directory of leading lawyers in the area of international trade matters.

Alan S. Diner (Bennett Jones, Toronto) practices federal regulatory law in Toronto, with a focus on immigration, competition and trade law.

James T. Ritzel (Hodgson Russ, Albany, NY) practices federal tax law, with particular emphasis on U.S. cross-border tax planning and tax controversy matters.

Kenneth Weigel (Alston + Bird, Washington, DC) concentrates on international trade and customs laws affecting the importation and exportation of merchandise involving the United States and other countries.

Andrew Wilson (Serotte Reich & Wilson, Buffalo, NY) specializes in U.S. immigration law.

John Yuan (McCarthy T

If you would like more details about this product, or would like to order a copy online, please click here.




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Archived Webinar - Jump Start Your HR Strategy - <i>How to Evaluate, Improve and Communicate a Winning HR Strategy</i>

Webinar information current as of October 9, 2008

 

When is the last time you really took stock of your HR strategy? Have you linked that strategy to your overall business plan? Do you have metrics in place to monitor its effectiveness? If your answers are shaky to any of these questions, your organization would benefit from some solid professional advice.

Learn how to:

  • Audit your current HR strategy or plan
  • Successfully link your HR strategy to the overall business strategy
  • Analyze and prioritize areas for strategic improvement
  • Develop a step by step plan for improvement of your HR strategy
  • Present the case for strategic changes to your superiors
  • Communicate the strategic changes to your organization
  • Measure strategic improvement
  • Make the connection between HR Strategy and return on investment

Speaker 

Tim McConnell, B.A, M.P.A., SPHR is a Senior HR Strategist with McConnell HR Consulting Inc. in Ottawa. He has over 25 years experience in Human Resources management, both as a Director of HR and as a senior HR consultant. Tim provides strategic HR guidance to senior executives and clients in the public, private and not-for-profit sectors.

He is a winner of the Ross A. Hennigar Memorial Award from HRPAO. He is the published author of several articles on HR management, Compensation and Organization Design. Tim is a past-President of the Ottawa Human Resources Professionals Association (OHRPA) and a past-President of HRPAO.

McConnell HRC provides services to clients in three key areas: Human Resources Strategy, Compensation and Organization Design.

Format

The following is required to access the archived webinar:

  • Flash Player installed in your computer
  • an Internet connection
  • a sound card

This archived webinar will include:

  • PowerPoint presentation with slides
  • Speaker and facilitator voice-over presenting the slides and answering pre-recorded questions.

There is no time limitation in usage, you can play, pause and stop the presentation at your convenience.

If you would like more details about this product, or would like to order a copy online, please click here.




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Archive Webinar - Webcast - Improve Workplace Performance through Effective Coaching and Communication

This webcast was recorded on November 16, 2006

Want to transform your employee unit into a high-performance team? It's been proven time and time again that when you use effective coaching and communication strategies, you can easily motivate your employees to reach higher levels of productivity. Improve Workplace Performance Through Effective Coaching and Communication is loaded with tips on how to motivate your employees and improve the dynamics of your team.

Agenda

  • Discover key strategies to boost employee motivation
  • Pinpoint the major roadblocks to successful teamwork
  • Identify strategies to overcome these roadblocks
  • Understand the "hows" of effective communication
  • Avoid pitfalls of poor communication habits
  • Encourage your team members to maximize their work performance by utilizing five key coaching skills
  • Make the connection between dedicated coaching and return on investment

Format
Participate right from your desk or office. All you need is an Internet connection and a sound card.

This archived webinar will include:

  • PowerPoint presentation with slides
  • Speaker and facilitator voice-over presenting the slides and answering pre-recorded questions.

The Speaker
Tammy Dewar, PhD, has been a coach for organizational leaders since 1996, with over 20 years' experience designing and delivering leadership and learning solutions. She will provide you with practical knowledge and step-by-step guidance to help you successfully coach your team, boost employee morale, facilitate effective communication, and drive higher performance.

If you would like more details about this product, or would like to order a copy online, please click here.




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Quality caring in nursing and health systems : implications for clinicians, educators, and leaders / Joanne R. Duffy

Duffy, Joanne R., author




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New perspectives in forensic human skeletal identification / edited by Krista E. Latham, Eric J. Bartelink, Michael Finnegan




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Communication for health care practice / Amanda Henderson

Henderson, Amanda, author




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Linné & Ringsrud's clinical laboratory science : concepts, procedures, and clinical applications

Turgeon, Mary Louise, author




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Communication skills for the health care professional : context, concepts, practice, and evidence / Gwen van Servellen

Van Servellen, Gwen, 1942- author




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Report / The Senate Select Committee on Stillbirth Research and Education

Australia. Parliament. Senate. Select Committee on Stillbirth Research and Education




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Collateral damage : the impacts of my mother's mental illness on me / Cate Grace

Grace, Cate, author




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Measurement in physical education / Donald K. Mathews; illus. by Todd Wallis

Mathews, Donald K




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Molecular diagnostics : fundamentals, methods, and clinical applications / Lela Buckingham

Buckingham, Lela, author




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Creative arts and play therapy for attachment problems / edited by Cathy A. Malchiodi, David A. Crenshaw

Malchiodi, Cathy A




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Nursing student's maths & medications survival guide / Kerry Reid-Searl, Trudy Dwyer, Lorna Moxham, Jo Reid-Speirs

Reid-Searl, Kerry, author




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Food & nutrition throughout life : a comprehensive overview of food and nutrition in all stages of life / edited by Sharon Croxford, Catherine Itsiopoulos, Adrienne Forsyth, Regina Belski, Antonia Thodis, Sue Shepherd, Audrey Tierney




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Working with serious mental illness : a manual for clinical practice / edited by Catherine Gamble, Geoff Brennan




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Physical education studies : a textbook for students ATAR units 1 and 2 / Peter Whipp [and nine others]




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The people behind 000 : mental health of our first responders / The Senate, Education and Employment References Committee

Australia. Parliament. Senate. Education and Employment References Committee, author, issuing body