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Iron-catalyzed thiolation of C(sp3)–H with sulfonyl chlorides via photoinduced ligand-to-metal charge transfer

By pubs.rsc.org
Published On ::

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01488J, Research Article
Sheng-Ping Liu, Lan Yang, Yan-Hong He, Zhi Guan
A photoinduced FeCl3/HCl synergistic catalytic method enables C(sp3)–S bond formation via reductive cross-coupling of activated/inert C(sp3)–H and aryl/alkyl sulfonyl chlorides through ligand-to-metal charge transfer (LMCT).
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Cockroach infestation found at CCMB canteen; hygiene violations flagged at Nacharam restaurants

By www.thehindu.com
Published On :: Sat, 09 Nov 2024 18:01:58 +0530


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Australian pacer Boland looks to keep KL Rahul under pressure ahead of Border-Gavaskar Trophy

By www.thehindu.com
Published On :: Wed, 06 Nov 2024 04:53:00 +0530

Rahul made a hundred on his debut tour to Australia in 2015, a 110 at Sydney, but his overall performance Down Under remains scratchy, evidenced by an average of 20.77 across four Tests.


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Latest scholarship opportunities

By www.thehindu.com
Published On :: Sun, 25 Oct 2015 17:00:14 +0530


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Latest scholarship opportunities

By www.thehindu.com
Published On :: Sun, 22 Nov 2015 17:00:02 +0530


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Latest scholarship opportunities

By www.thehindu.com
Published On :: Sun, 20 Dec 2015 17:00:29 +0530


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Latest scholarship opportunities

By www.thehindu.com
Published On :: Sun, 27 Dec 2015 17:00:46 +0530


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Scholarship Alert

By www.thehindu.com
Published On :: Sun, 17 Jan 2016 17:00:01 +0530


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Tiruppugazh scholar’s new book

By www.thehindu.com
Published On :: Thu, 23 Jun 2016 17:30:19 +0530


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  • History & Culture
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Chola architecture in full splendour

By www.thehindu.com
Published On :: Thu, 20 Oct 2016 17:09:45 +0530

The Kailasanatha temple, near Mannarkoil, is associated with the Sun god.


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History lessons by Lake Pichola

By www.thehindu.com
Published On :: Thu, 03 Nov 2016 17:00:38 +0530

Get up close with Udaipur’s royal past, its art and architecture at the City Palace museum, writes Chitra Swaminathan


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Probing intrinsic defects of aluminium-doped CuO thin films for solar cell applications

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,35184-35197
DOI: 10.1039/D4RA06413E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Adithya Prakash, Vikash Mishra, Mahesha M. G.
Defect-engineered Al-doped CuO thin films deposited via chemical spray pyrolysis find application in solar cell absorbers.
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Phenylsulfonate as a photolabile group for intramolecular carbon–carbon cross-coupling reactions

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RSC Adv., 2024, 14,35227-35231
DOI: 10.1039/D4RA06592A, Paper
Open Access
Simon Plaize, Jean-François Morin
This study reports the use of phenylsulfonates as photolabile groups to generate aryl radicals, which undergo radical cyclization to yield triphenylene derivatives. The reaction is efficiently carried out under 365 nm with a triplet sensitizer.
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Advanced oxidative degradation of monoethanolamine in water using ultraviolet light and hydrogen peroxide

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RSC Adv., 2024, 14,33223-33232
DOI: 10.1039/D4RA05590J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Atif Khan, Saima Yasin, Hamayoun Mahmood, Shabana Afzal, Tanveer Iqbal
Development of an eco-friendly and commercially feasible method for monoethanolamine (MEA) degradation in aqueous phase using ultraviolet/hydrogen peroxide (UV/H2O2) advanced oxidation process (AOP).
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Self-immolative polydisulfides and their use as nanoparticles for drug delivery systems

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RSC Adv., 2024, 14,35568-35577
DOI: 10.1039/D4RA07228F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Katharina Völlmecke, Maurice Kramer, Corinna Horky, Oliver Dückmann, Dennis Mulac, Klaus Langer, Dirk Kuckling
Polydisulfide based nanoparticles can be degraded by glutathione (GSH) to deliver hydrophobic drugs.
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Zeolitic imidazolate framework-67 in chitosan-grafted hydrogel as an effective catalyst for peroxymonosulfate activation to degrade antibiotics and dyes

By pubs.rsc.org
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RSC Adv., 2024, 14,35628-35637
DOI: 10.1039/D4RA06537A, Paper
Open Access
Atipong Nachaichot, Kunlarat Phonlakan, Supinya Nijpanich, Soraya Pornsuwan, Surangkhana Budsombat
Zeolitic imidazolate framework-67 (ZIF-67) was synthesized in situ in the hydrogel of chitosan-grafted poly(acrylic acid) (chitosan-g-PAA) to activate peroxymonosulfate (PMS) and degrade tetracycline (TC).
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A dual-response fluorescence sensor for SO2 derivatives and polarity and its application in real water and food samples

By pubs.rsc.org
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RSC Adv., 2024, 14,35638-35643
DOI: 10.1039/D4RA04805A, Paper
Open Access
Jianfeng Wang, Ruiji Li, Tao Ou, Yamin Fu, Chang Gao, Yehao Yan
A dual-response fluorescent probe for SO2 derivatives and polarity and their application in real samples.
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Computational discovery of two-dimensional tetragonal group IV–V monolayers

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RSC Adv., 2024, 14,36173-36180
DOI: 10.1039/D4RA06623E, Paper
Open Access
Qiubao Lin, Jungang Huang, Yimei Fang, Feng Zheng, Kaixuan Chen, Shunqing Wu, Zi-Zhong Zhu
Structural prediction of a stable tetragonal Td4 phase of 2D group IV–V monolayers.
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Applications and interventions of polymers and nanomaterials in alveolar bone regeneration and tooth dentistry

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Published On ::

RSC Adv., 2024, 14,36226-36245
DOI: 10.1039/D4RA06092J, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Prashish Sharma, Sushmita Saurav, Zeba Tabassum, Bhawana Sood, Anil Kumar, Tabarak Malik, Anand Mohan, Madhuri Girdhar
Inflammatory diseases exert a significant influence on the periodontium, serving as a primary contributor to the development of periodontitis and alveolar bone loss.
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Survey finds violations at Patna’s ‘Khan Centre’

By www.thehindu.com
Published On :: Thu, 01 Aug 2024 00:33:29 +0530

Patna has over 3,000 coaching centres, mostly concentrated in Mushallapur, Mahendru, Bhikhana Pahadi, Khazanchi Road, and Kankerbagh


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"Sanctioned companies not in violation of Indian law," says MEA after US sanctions 19 Indian companies

By www.thehindubusinessline.com
Published On :: Sat, 02 Nov 2024 16:14:28 +0530

The sanctions announced by the U.S. State Department targets 19 Indian companies and two individuals accused of allegedly supplying materials and technology to Russia to support its military amid the ongoing war in Ukraine


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US will be more isolationist whoever wins election, Jaishankar says

By www.thehindubusinessline.com
Published On :: Wed, 06 Nov 2024 10:06:31 +0530

"President Trump may be more articulate and expressive in that regard," he said during a panel discussion with the foreign ministers of Australia and New Zealand


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No extra pressure on in-form Barcola, says PSG manager Enrique

By www.thehindu.com
Published On :: Sun, 03 Nov 2024 09:34:23 +0530

The Spaniard said he was relying on all his players when asked about French forward Randal Kolo Muani, who has been linked with a move away from the reigning Ligue 1 champions


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An octanuclear 3-phenyl-5-(2-pyridyl)pyrazolate/phenylsilsesquioxane complex: synthesis, unique structure, and catalytic activity

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02690J, Communication
Alexey Bilyachenko, Victor N Khrustalev, Zhibin Huang, Lidia S. Shul'pina, Pavel Dorovatovskii, Elena Shubina, Nikolay S. Ikonnikov, Nikolai N. Lobanov, Karim G. Rahimov, Di Sun
First metallasilsesquioxane bearing pyrazolylpyridine ligands, Cu8-based complex 1, adopts cage structure with two zigzag-like copper tetramers sandwiched by two cyclic Si5 silsesquioxane ligands. Four 3-phenyl-5-(2-pyridyl)pyrazolate ligands in 1 exhibit dual...
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Oxaphosphiranes: isolable phosphorus-containing epoxide rings

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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02915A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Niklas Volk, Antonio García Alcaraz, Selvakumar Balasubramaniam, Jannik Heumann, Gregor Schnakenburg, Arturo Espinosa Ferao, Rainer Streubel
A new efficient protocol for the synthesis of isolable oxaphosphiranes based on easy decomplexation is described. Theoretical studies unveil a singlet carbene-like FMO situation at phosphorus explaining the reactions with oxidants, acids and bases.
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Investigating the formation of metal nitride complexes employing a tetradentate bis-carbene bis-phenolate ligand

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Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT01765J, Paper
Romain Kunert, Diego Martelino, Samyadeb Mahato, Nicholas Hein, Jason Pulfer, Christian Philouze, Olivier Jarjayes, Fabrice Thomas, Tim Storr
The synthesis of MnV and CrV nitride complexes of a pro-radical tetradentate bis-phenol bis-N-heterocyclic carbene ligand H2LC2O2 were investigated. Employing either azide photolysis of the MnIII precursor complex MnLC2O2(N3) or...
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Excited-state intramolecular proton transfer (ESIPT) active interwoven polycatenated coordination polymer for selective detection of Al3+ and Ag+ ions along with water detection in less polar solvents

By pubs.rsc.org
Published On ::

Dalton Trans., 2024, 53,18003-18012
DOI: 10.1039/D4DT02285H, Paper
Anupam Maiti, Rakesh Kumar, Bidyadhar Mahato, Debajyoti Ghoshal
An ESIPT active coordination polymer is successfully synthesized, exhibiting ESIPT induced blue shift for Al3+ ions and ESIPT-off for Ag+ ions. The material can also detect polar water, dimethylformamide and methanol in less polar organic solvents.
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End of an era? Man City loses fourth straight game and Guardiola faces some tough questions

By www.thehindu.com
Published On :: Sun, 10 Nov 2024 08:01:38 +0530

Champions City face crisis with four straight losses, while Liverpool shines; Guardiola faces unprecedented challenge in management career.


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Solar cell manufacturing to outstrip global demand by 2024: report

By www.thehindu.com
Published On :: Wed, 06 Nov 2024 04:03:00 +0530

The sector experienced huge growth in 2023 with solar cell, wafers and modules capacity nearly doubling in comparison with the previous year, says World Solar Market Report 2024


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Remembering a Deepavali-season solar eclipse ‘chase’

By www.thehindu.com
Published On :: Fri, 01 Nov 2024 18:52:05 +0530

Dipankar Banerjee, the noted solar physicist who recently took over as Director, Indian Institute of Space Science and Technology (IIST), describes himself as one of the ‘global eclipse chasers.’ He is also part of a theatre group where he plays Ramakrishna Paramahansa on stage


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Consolation win for Mizoram

By www.thehindu.com
Published On :: Tue, 08 Mar 2016 23:04:27 +0530


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China summons U.S. envoy Nicholas Burns, warns America shall 'pay price' as Pelosi visits Taiwan

By www.thehindu.com
Published On :: Wed, 03 Aug 2022 15:04:01 +0530

Chinese Vice-Foreign Minister Xie Feng “urgently summoned” the U.S. Ambassador to China Nicholas Burns late on August 2 night and lodged stern representations and strong protests over Nancy Pelosi’s visit


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‘Rajaram – DCM Shriram Scholarship’ launched at DialogueNEXT conference

By www.thehindubusinessline.com
Published On :: Mon, 15 Jul 2024 17:45:28 +0530

It is aimed at fostering the next generation of agricultural scientists


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Canara Bank disburses ₹18 crore in scholarships to advance educational opportunities

By www.thehindubusinessline.com
Published On :: Thu, 15 Aug 2024 18:40:41 +0530

Canara Bank distributes scholarships worth ₹18 crore to 44,742 students, supporting education for SC/ST girl students nationwide


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  • Money & Banking
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Sathyabama Institute of Science and Technology holds 33rd convocation; 3,508 undergraduate students, 644 postgraduate students, and 122 Ph.D. scholars receive degrees

By www.thehindubusinessline.com
Published On :: Tue, 20 Aug 2024 20:40:30 +0530

45 students awarded gold medals for their academic performance


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Rhodes Trust announces sixth scholarship for India

By www.thehindubusinessline.com
Published On :: Fri, 27 Sep 2024 20:44:38 +0530

Our current goal is to increase the number to 10, and then to 25, says Elizabeth Kiss, CEO, Rhodes Trust


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Honour for University of Hyderabad post-doctoral scholar

By www.thehindubusinessline.com
Published On :: Wed, 02 Oct 2024 08:44:01 +0530

Sarma’s research results were published in high impact journals and also resulted in a patent


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Communalism and a tendency to polarise voters are in the BJP’s DNA: Venugopal

By www.thehindu.com
Published On :: Wed, 15 Nov 2023 19:51:02 +0530

“You cannot feed the people with communal sentiments indefinitely,” the Congress leader said in an interview to The Hindu, where he also dismissed concerns about factionalism within the party


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Even Kennedy took James Bond creator’s help: biographer Nicholas Shakespeare

By www.thehindu.com
Published On :: Fri, 24 May 2024 09:01:00 +0530

The author of Ian Fleming: The Complete Man on Fleming’s legacy and his most famous fictional creation


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Revealing degradation mechanisms in 3D/2D perovskite solar cells under photothermal accelerated ageing

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Energy Environ. Sci., 2024, 17,8313-8324
DOI: 10.1039/D4EE03869J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zijian Peng, Andrej Vincze, Fabian Streller, Vincent M. Le Corre, Kaicheng Zhang, Chaohui Li, Jingjing Tian, Chao Liu, Junsheng Luo, Yicheng Zhao, Andreas Späth, Rainer Fink, Thomas Heumüller, Andres Osvet, Ning Li, Martin Stolterfoht, Larry Lüer, Christoph J. Brabec
Three-dimensional/two-dimensional (3D/2D) heterojunctions in perovskite solar cells exhibit excellent optoelectronic properties and enhanced stability under mild ageing conditions.
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Heterojunction lithiation engineering and diffusion-induced defect passivation for highly efficient Sb2(S,Se)3 solar cells

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Energy Environ. Sci., 2024, 17,8402-8412
DOI: 10.1039/D4EE03135K, Paper
Cong Liu, Anweng Gong, Chen Zuo, Tao Liu, Xiaoyang Liang, Donglou Ren, Kai Shen, Jianzha Zheng, Qifan Xue, Zhiqiang Li, Ruud E. I. Schropp, Bingsuo Zou, Yaohua Mai
A heterojunction lithiation strategy has been developed to achieve a certified efficiency of 10.50%, which is the record efficiency for all of the Sb-based solar cells.
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Synergistic enhancement of charge extraction and heat dissipation in inverted perovskite solar cells via n-doped top interlayers

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Energy Environ. Sci., 2024, 17,8304-8312
DOI: 10.1039/D4EE02836H, Paper
Sangmi Park, Sang Young Jeong, Jaehoon Kim, Heunjeong Lee, Hye Seung Kim, Young Wook Noh, Ye In Kim, Shinuk Cho, Joon Sang Kang, Han Young Woo, Myoung Hoon Song
n-Doping the fullerene-based interlayer in perovskite solar cells enhances heat dissipation and charge extraction by improving thermal/electrical conductivity, and energy level alignment, which boosts photovoltaic performance and stability.
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Efficient 1.77 eV-bandgap perovskite and all-perovskite tandem solar cells enabled by long-alkyl phosphonic acid

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Published On ::

Energy Environ. Sci., 2024, 17,8219-8227
DOI: 10.1039/D4EE02483D, Paper
Hongling Guan, Shiqiang Fu, Guojun Zeng, Weiqing Chen, Chen Wang, Hongsen Cui, Dexin Pu, Peng Jia, Weiwei Meng, Guojia Fang, Weijun Ke
Incorporating dodecylphosphonic acid additives into 1.77 eV-bandgap perovskites enabled single-junction solar cells to achieve a PCE of 20.2%. Tandem cells further reached impressive PCEs of 27.41% (two-terminal) and 28.65% (four-terminal).
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Well-regulated structure-featuring giant-molecule acceptors enable long-term stability and high-performance binary organic solar cells

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Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03754E, Paper
Jingyu Shi, Pengfei Ding, Jintao Zhu, Zhenyu Chen, Shuangjiao Gao, Xueliang Yu, Xiaochun Liao, Quan Liu, Ziyi Ge
Through systematically selecting the numbers and positions of selenium atom of giant-molecule acceptors, the device based on PM6:GMA-SSeS yields the highest PCE of 19.37% with high VOC of 0.917 V and exhibits extended t80% lifetimes of 5600 h.
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From generation to collection – impact of deposition temperature on charge carrier dynamics of high-performance vacuum-processed organic solar cells

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Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03623A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Richard Adam Pacalaj, Yifan Dong, Ivan Ramirez, Roderick C. I. MacKenzie, Seyed Mehrdad Hosseini, Eva Bittrich, Julian Eliah Heger, Pascal Kaienburg, Subhrangsu Mukherjee, Jiaying Wu, Moritz Riede, Harald Ade, Peter Müller-Buschbaum, Martin Pfeiffer, James Robert Durrant
Substrate heating during co-evaporation of bulk heterojunction organic solar cells aids phase separation and improves performance. While recombination remains unaffected, hole transport improves due to more crystalline donor domains.
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Stabilizing doped Spiro-OMeTAD by organic molten salt for efficient and stable perovskite solar cells

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Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04310C, Paper
Tengfei Pan, Zhiwei Li, Biyun Ren, Wan Yang, Xueqin Ran, Yajing Li, Yutian Xu, Yue Wang, Deli Li, Yingdong Xia, Xingyu Gao, Lingfeng Chao, Yonghua Chen
Bis(trifluoromethane)sulfonimide (LiTFSI) and 4-tert-butylpyridine (TBP) have been currently suggested to be irreplaceable in classic doped 2,2',7,7'-tetrakis (N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (Spiro-OMeTAD) for high-performance perovskite solar cells (PSCs). However, the stability of Spiro-OMeTAD was...
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Stress regulation via surface micro-etching and reconstruction for enhancing triple-cation perovskite solar cells with an efficiency of 25.54%

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Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE04248D, Paper
Yang Ding, Erming Feng, Siyuan Lu, Jianhui Chang, Caoyu Long, Sichao Tong, Hengyue Li, Junliang Yang
A surface micro-etching and reconstruction strategy is developed to regulate the stresses in a perovskite film, achieving a benign transition from tensile stress to compressive stress.
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N-type Ag2S modified CZTSSe solar cell with lowest Voc,def

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Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03244F, Paper
Jin Yang, Junjie Fu, Weiwei Dong, Shu Ren, Xin Zhang, Jingyi Su, Chaoliang Zhao, Meng Wei, Dandan Zhao, Yange Zhang, Sixin Wu, Zhi Zheng
The Sn, Zn-doped Ag2S plays a triple role in CZTSSe devices: p–n conversion, front-interface bandgap grading, and defect passivation. This strategy achieved an efficiency of 14.25%, with the Voc of 0.584 V and the lowest Voc,def of 0.228 V.
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Flexible spacer-block multi-component copolymerized donors enable resilient organic solar cells with over 40% crack-onset strain

By pubs.rsc.org
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Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE04208E, Paper
Congqi Lin, Zhenyu Chen, Ruixiang Peng, Wei Song, Jiangwei Gao, Xueliang Yu, Tingting Feng, Yongqi Bai, Ziyi Ge
A series of novel block donors were synthesized, achieving excellent PCE of 19.57% in rigid OSCs and 18.03% in f-OSCs, along with an outstanding crack-onset strain value of 40.29%.
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Regulating the Crystallization of Mixed-Halide Perovskites by Cation Alloying for Perovskite-Organic Tandem Solar Cells

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Published On ::

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03045A, Paper
Mingqian Chen, Yanxun Li, Zixin Zeng, Ming Liu, Tao Du, Xiaofeng Huang, Leyu Bi, Jiarong Wang, Wenlin Jiang, Yidan An, Sai Wing Tsang, Jun Yin, Shengfan Wu, Alex K. Y. Jen
Halide segregation and energy loss pose significant challenges for wide-bandgap perovskite solar cells, impairing their photovoltage and device stability. These issues are often exacerbated by inferior film quality and inhomogeneous...
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