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[ASAP] Size-Tunable Nanoneedle Arrays for Influencing Stem Cell Morphology, Gene Expression, and Nuclear Membrane Curvature

ACS Nano
DOI: 10.1021/acsnano.9b08689




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Singular thought and mental files [Electronic book] / Rachel Goodman, James Genone, and Nick Kroll.

Oxford : Oxford University Press, 2020.




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Highly-Excited State Properties of Cumulenone Chlorides in the Vacuum-Ultraviolet

Phys. Chem. Chem. Phys., 2020, Accepted Manuscript
DOI: 10.1039/D0CP01835J, Paper
Quynh L. Nguyen, William K Peters, Ryan C. Fortenberry
Recent observations of chloromethane in interstellar environments suggest that other organohalogens, which are known to be critically important in Earth's atmosphere, may also be of significance beyond our own terrestrial...
The content of this RSS Feed (c) The Royal Society of Chemistry




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[ASAP] Discovery of an Isothiazolinone-Containing Antitubercular Natural Product Levesquamide

The Journal of Organic Chemistry
DOI: 10.1021/acs.joc.0c00339




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[ASAP] Palladium-Catalyzed Cascade Cyclization/Dearomatization/Arylation of Alkyne-Containing Phenol-Based Biaryls with Aryl Halides: An Entry to Diversely Functionalized Spirocyclohexadienones

The Journal of Organic Chemistry
DOI: 10.1021/acs.joc.0c00710




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[ASAP] Introduction of the Menaquinone Biosynthetic Pathway into <italic toggle="yes">Rhodobacter sphaeroides</italic> and <italic toggle="yes">de Novo</italic> Synthesis of Menaquinone for Incorporation into He

ACS Synthetic Biology
DOI: 10.1021/acssynbio.0c00066




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[ASAP] Exploration of the Structural Space in 4(3<italic toggle="yes">H</italic>)-Quinazolinone Antibacterials

Journal of Medicinal Chemistry
DOI: 10.1021/acs.jmedchem.0c00153




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Dorothy Iannone: a cookbook / Dorothy Iannone ; [edited by Clément Dirié]

Rotch Library - N6537.I26 A4 2018




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1,6-Conjugate addition initiated formal [4+2] annulation of p-quinone methides with sulfonyl allenols: a unique access to spiro[5.5]undeca-1,4-dien-3-one scaffolds

Chem. Commun., 2020, 56,5022-5025
DOI: 10.1039/D0CC01005G, Communication
Ganesh S. Ghotekar, Sachin R. Shirsath, Aslam C. Shaikh, M. Muthukrishnan
An expedient one-pot synthesis of carbocyclic spiro[5.5]undeca-1,4-dien-3-ones via 1,6-conjugate addition initiated formal [4+2] annulation sequences by employing p-quinone methides and sulfonyl allenols.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Rh(III)-catalyzed sequential ortho- C–H oxidative arylation/cyclization of sulfoxonium ylides with quinones toward 2-hydroxy-dibenzo[b,d]pyran-6-ones

Chem. Commun., 2020, Accepted Manuscript
DOI: 10.1039/D0CC00176G, Communication
Yaqun Dong, Jin-Tao Yu, Song Sun, Jiang Cheng
A rhodium(III)-catalyzed ortho- C−H functionalization of sulfoxonium ylides followed by intramolecular annulation reactions with quinones is described, where the carbonyl in sulfoxonium ylides served as a chelation group. This protocol...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Smart society: a sociological perspective on smart living / Roberta Iannone and Romina Gurashi, with Ilaria Iannuzzi, Giovanni de Ghantuz Cubbe and Melissa Sessa

Dewey Library - HM846.S56 2020




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Singular thought and mental files / edited by Rachel Goodman, James Genone, and Nick Kroll

Online Resource




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Iodine-Catalyzed α,β-Dehydrogenation of Ketones and Aldehydes Generating Conjugated Enones and Enals

New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01244K, Letter
Yuanjie Cao, Long Liu, Tianzeng Huang, Tieqiao Chen
A transition metal-free α,β-dehydrogenation of ketones and aldehydes was developed. This reaction was conducted in a facile I2/KI/DMSO system to produce the corresponding unsaturated compounds in good to high yields....
The content of this RSS Feed (c) The Royal Society of Chemistry




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An expedient synthesis of new imino-thiazolidinone grafted dispiro-pyrrolidine-oxindole/indeno hybrids via a multicomponent [3+2] cycloaddition reaction in a deep eutectic solvent

New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00801J, Paper
Ruby Singh, Munna Ram Saini, Diksha Bhardwaj, Aakash Singh
A facile and selective synthesis of novel factionalized dispiro-pyrrolidines via a three component [3+2] cycloaddition reaction using a deep eutectic solvent.
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Discovery of [1,2,4]triazolo[4,3-a]pyrazine derivatives bearing 4-oxo-pyridazinone moiety as potential c-Met kinase inhibitors

New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ00575D, Paper
Binliang Zhang, Xiaobo Liu, Hehua Xiong, Qian Zhang, Xin Sun, Zunhua Yang, Shan Xu, Pengwu Zheng, Wufu Zhu
Two series of [1,2,4]triazolo[4,3-a]pyrazine derivatives bearing 4-oxo-pyridazinone moiety (compounds 21a-l and 22a-l) were designed and evaluated for the IC50 values against three cancer cell lines (A549, MCF-7 and Hela) and...
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Construction and application of nonenzymatic ascorbic acid sensor based on NiO1.0/polyaniline3.0 hybrid

New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ00696C, Paper
shichao Zhu, Aijuan Xie, Bingyan Wei, Xiang Tao, Jianghui Zhang, Wenhao Peng, Chenyang Liu, Linyang Gu, Chenfei Xu, Shiping Luo
NiO1.0/PANI3.0 was prepared by in-situ polymerization method in one-pot and applied in detection of ascorbic acid (AA). Cyclic voltammetry (CV) and Differential pulse voltammetry (DPV) were used to optimize the...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Electric power system basics: for the nonelectrical professional / Steven W. Blume

Online Resource




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Co-Inclusion of cyclic ethers and chloroform by a macrocycle with benzophenone-3,3',4,4'-tetracarboxylic diimide units

CrystEngComm, 2020, 22,2964-2969
DOI: 10.1039/D0CE00221F, Paper
Masahide Tominaga, Kosuke Mizuno, Haruka Yamamoto, Tadashi Hyodo, Kentaro Yamaguchi
Crystallization of a diimide-based macrocycle having adamantane parts and several cyclic ethers in chloroform provided inclusion crystals, where both guests were cooperatively accommodated within inner spaces between the macrocycles.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Selenium-promoted electrophilic cyclization of arylpropiolamides: synthesis of 3-organoselenyl spiro[4,5]trienones

Org. Biomol. Chem., 2020, Advance Article
DOI: 10.1039/D0OB00609B, Paper
Ana Maria S. Recchi, Pedro H. P. Rosa, Davi F. Back, Gilson Zeni
A synthetic approach to regioselective synthesis of 3-organochalcogenyl spiro[4,5]trienones and 3-organochalcogenyl[4,5]triene-2,6-diones is described through the reaction of arylpropiolamides with an electrophilic chalcogen source.
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The silver catalyzed direct C–H functionalization of quinones with dialkyl amides

Org. Biomol. Chem., 2020, 18,3027-3031
DOI: 10.1039/D0OB00323A, Communication
Sakthivel Pandaram, Adarsh Krishna T. P., Andivelu Ilangovan
A novel and efficient strategy for the direct C–H amidoalkylation of quinones via a radical pathway has been achieved using readily available alkyl amides and an AgNO3-TBHP catalyst system. This is the first ever example of the synthesis of novel amidoquinone derivatives.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Experimental results and computational insight into sequential reactions of β-(2-aminophenyl)-α,β-ynones with aryl isocyanates/benzoyl isothiocyanate

Org. Biomol. Chem., 2020, 18,3177-3189
DOI: 10.1039/D0OB00087F, Paper
Antonio Arcadi, Massimiliano Aschi, Marco Chiarini, Fabio Marinelli, Vincenzo Marsicano, Gustavo Portalone
The selective formation of quinazoline vs. benzoxazine  and benzothiazine derivatives from β-(2-aminophenyl)-α,β-ynones and aryl isocyanates/benzoyl isothiocyanate was explored. DFT calculations provide a plausible rationale.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Rhodium-Catalyzed ortho-Acrylation of Aryl Ketone O-Methyl Oximes with Cyclopropenones

Org. Biomol. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0OB00064G, Communication
Yafeng Liu, Yuan Tian, Kexin Su, Xin Guo, Baohua Chen
An efficient Rh-catalyzed ortho-acrylation reaction for the synthesis of chalcones from O-methyl ketoximes and cyclopropenones via C–H bond activation has been described. This cross-coupling reaction exhibits high functional group tolerance...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of unsymmetrical benzils via palladium-catalysed α-arylation–oxidation of 2-hydroxyacetophenones with aryl bromides

Org. Biomol. Chem., 2020, Advance Article
DOI: 10.1039/D0OB00575D, Paper
Open Access
Takanori Matsuda, Souta Oyama
Unsymmetrical benzils are synthesised by a one-pot tandem palladium-catalysed α-arylation and oxidation of 2-hydroxyacetophenones with aryl bromides.
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Copper(I)/Ganphos catalysis: enantioselective synthesis of diverse spirooxindoles using iminoesters and alkyl substituted methyleneindolinones

Org. Biomol. Chem., 2020, Advance Article
DOI: 10.1039/D0OB00546K, Paper
Hao Cui, Ke Li, Yue Wang, Manman Song, Congcong Wang, Donghui Wei, Er-Qing Li, Zheng Duan, François Mathey
A copper/Ganphos-catalyzed asymmetric 1,3-dipolar cycloaddition of glycine iminoesters with alkyl substituted 3-methylene-2-oxindoles is described, producing the spiro[pyrrolidin-3,3'-oxindole]s in good yields with high ee.
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Enantioselective Synthesis of Indanone Spiro-Isochromanone Derivatives via Dinuclear Zinc-Catalyzed Michael/Transesterification Tandem Reaction

Org. Biomol. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0OB00541J, Paper
Xiao-Chao Yang, Meng Xu, Jin-Bao Wang, Meng-Meng Liu, Francois Mathey, Yuan-Zhao Hua, Mincan Wang
An enantioselective Michael/transesterification tandem reaction of α-hydroxy indanones with ortho-ester chalcones was realized by dinuclear zinc catalysts. A series of enantiomerically pure spiro[indanone-2,3’-isochromane-1-one] derivatives were obtained in good yields with...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Base-promoted 1,6-conjugate addition of alkylazaarenes to para-quinone methides

Org. Biomol. Chem., 2020, 18,3354-3359
DOI: 10.1039/D0OB00419G, Paper
Amritha Rayaroth, Rajat Kumar Singh, Kalyanakrishnan A. V., Krishna Hari, Alagiri Kaliyamoorthy
1,1,2-Triarylethanes embedded with an azaarene unit were prepared in a single step at ambient temperature via the sodium hexamethyldisilazide mediated 1,6-conjugate addition of unactivated alkylazaarenes on para-quinone methides (p-QMs).
The content of this RSS Feed (c) The Royal Society of Chemistry




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Gold(III)-catalyzed azide-yne cyclization/O–H insertion cascade reaction for the expeditious construction of 3-alkoxy-4-quinolinone frameworks

Org. Biomol. Chem., 2020, Advance Article
DOI: 10.1039/D0OB00745E, Paper
Jingjing Huang, Han Su, Ming Bao, Lihua Qiu, Yuanqing Zhang, Xinfang Xu
A gold-catalyzed cascade reaction has been developed, and it provides an expeditious access to 3-alkoxy-4-quinolines and applications in alkaloid synthesis.
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Arylation of Indoles Using Cyclohexanones Dually-Catalyzed by Niobic Acid and Palladium-on-Carbons

Org. Biomol. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0OB00702A, Paper
Kazuho Ban, Yuta Yamamoto, Hironao Sajiki, Yoshinari Sawama
3-Arylindoles were easily constructed from indoles and cyclohexanone derivatives using a combination of catalytic niobic acid-on-carbon (Nb2O5/C) and palladium-on-carbon (Pd/C) under heating conditions without any oxidants. The Lewis acidic Nb2O5/C...
The content of this RSS Feed (c) The Royal Society of Chemistry




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[ASAP] The ONIOM/PMM Model for Effective Yet Accurate Simulation of Optical and Chiroptical Spectra in Solution: Camphorquinone in Methanol as a Case Study

Journal of Chemical Theory and Computation
DOI: 10.1021/acs.jctc.0c00124




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[ASAP] Bottom-Up Nonempirical Approach To Reducing Search Space in Enzyme Design Guided by Catalytic Fields

Journal of Chemical Theory and Computation
DOI: 10.1021/acs.jctc.0c00139




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[ASAP] Efficient Synthesis of 1,4-Thiazepanones and 1,4-Thiazepanes as 3D Fragments for Screening Libraries

Organic Letters
DOI: 10.1021/acs.orglett.0c01230




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[ASAP] Catalytic C–C Cleavage/Alkyne–Carbonyl Metathesis Sequence of Cyclobutanones

Organic Letters
DOI: 10.1021/acs.orglett.0c01317




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[ASAP] Organocatalytic Regiodivergent Ring Expansion of Cyclobutanones for the Enantioselective Synthesis of Azepino[1,2-<italic toggle="yes">a</italic>]indoles and Cyclohepta[<italic toggle="yes">b</italic>]ind

Organic Letters
DOI: 10.1021/acs.orglett.0c01406




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Neutral pH aqueous redox flow batteries using an anthraquinone-ferrocyanide redox couple

J. Mater. Chem. C, 2020, 8,5727-5731
DOI: 10.1039/D0TC00640H, Paper
Wonmi Lee, Agnesia Permatasari, Yongchai Kwon
Anthraquinone-2,7-disulfonic acid (2,7-AQDS) and ferrocyanide including potassium and sodium salts are used as a redox couple for neutral aqueous redox flow batteries (ARFBs).
The content of this RSS Feed (c) The Royal Society of Chemistry




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[ASAP] Obtusaquinone: A Cysteine-Modifying Compound That Targets Keap1 for Degradation

ACS Chemical Biology
DOI: 10.1021/acschembio.0c00104




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None of your damn business: privacy in the United States from the gilded age to the digital age / Lawrence Cappello

Hayden Library - BF637.P74 C36 2019




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[ASAP] Directing Quinone Methide-Dependent Alkylation and Cross-Linking of Nucleic Acids with Quaternary Amines

Bioconjugate Chemistry
DOI: 10.1021/acs.bioconjchem.0c00166




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[ASAP] Flow-Induced Micellar Morphological Transformation in Microfluidic Chips under Nonequilibrium State: From Aggregates to Spherical Micelles

Langmuir
DOI: 10.1021/acs.langmuir.0c00836




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Quinone Methide Dimers Lacking Labile Hydrogen Atoms Are Surprisingly Excellent Radical-Trapping Antioxidants

Chem. Sci., 2020, Accepted Manuscript
DOI: 10.1039/D0SC02020F, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Derek A. Pratt, Mark A R Raycroft, Jean-Philippe R Chauvin, Matthew Galliher, Kevin Romero, Corey Stephenson
Hydrogen atom transfer (HAT) is the mechanism by which the vast majority of radical-trapping antioxidants (RTAs), such as hindered phenols, inhibit autoxidation. As such, at least one weak O–H bond...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Nonequilibrium gas dynamics and molecular simulation / Iain D. Boyd (University of Michigan), Thomas E. Schwartzentruber (University of Minnesota)

Online Resource




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'None more unbeatable than Djokovic'

There is no one more unbeatable in men's tennis than Novak Djokovic when the Serb is at his best, former world number four American Todd Martin said. Reigning world number one Djokovic has already established himself as one of the best ever to play the game and the Serb's Grand Slam haul of 17 is just three behind the 20 that Roger Federer has amassed. The Swiss player will be 39 in August.




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[ASAP] Photochemical Generation of Benzoazetinone by UV Excitation of Matrix-Isolated Precursors: Isatin or Isatoic Anhydride

The Journal of Physical Chemistry A
DOI: 10.1021/acs.jpca.0c02562




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Palladium-catalyzed synthesis of [60]fullerene-fused furochromenones and further electrochemical functionalization

Org. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QO00264J, Research Article
Majid Hussain, Chuang Niu, Guan-Wu Wang
The palladium-catalyzed heteroannulation of [60]fullerene with 4-hydroxycoumarins affords [60]fullerene-fused furochromenones, which can be further derivatized via an electrochemical method to synthesize 1,2,3,4-adducts.
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Toward C2-nitrogenated chromones by copper-catalyzed β-C(sp2)–H N-heteroarylation of enaminones

Org. Chem. Front., 2020, 7,1107-1112
DOI: 10.1039/D0QO00065E, Research Article
Tian Luo, Jie-Ping Wan, Yunyun Liu
The synthesis of C2-nitrogenated chromones has been performed via reactions of enaminones and nitrogen nucleophiles based on an unconventional β-C–H bond functionalization and a featured chromone annulation of enaminones.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Phosphine/Palladium Cooperative Catalysis: Enantioselective [5+4] Annulations of ortho-Quinone Methides and Vinylethylene Carbonates

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00128G, Research Article
Chao Xia, Dong-Chao Wang, Gui-Rong Qu, Hai-Ming Guo
Highly enantioselective [5+4] annulations of ortho-quinone methides with vinylethylene carbonates were enabled by phosphine/palladium asymmetric cooperative catalysis for the first time. Efficient synthesis of various nine-membered benzo-heterocycles was achieved in...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Catalyst-Controlled Formal [4+1] Annulation of N-Vinyl Fluorenone Nitrones and Allenoates to Prepare Spirofluorenylpyrrolines

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00224K, Research Article
Cui Wei, Jin-Qi Zhang, Jia-Jie Zhang, Cui Liang, Dong-Liang Mo
We report a readily commercial Gimeracil-catalyzed formal [4+1] annulation approach for the synthesis of spirofluorenylpyrrolines in good yields with high diastereoselectivity from easily available N-vinyl fluorenone nitrones and allenoates. The...
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A Vinylogous Michael Reaction of 2-Furanones Dimers to α, β-Unsaturated Nitroolefins for Constructing Chiral γ, γ-Disubstituted Butenolides

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00376J, Research Article
Zhushuang Bai, Cairong Zhang, Yongyi Chen, Aiqin Liu, Xinyu Wang, Chuna Yan, Xuechao Liu, Xiaoru Zhang, Ying Li, Ye Yuan, Zemei Ge, Jingxiang Pang, Yongshuai Chai, Xin Wang, Runtao Li
An efficient bifunctional thiourea catalyzed asymmetric vinylogous Michael addition of 2-furanones dimers to α, β-unsaturated nitroolefins has been developed to give the functional chiral γ,γ-disubstituted butenolides in good yields (up...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Rhodium(III)-catalyzed synthesis of 3-trifluoromethylindanones from N-Methoxybenzamides via C-H activation and Claisen/Retro-Claisen reaction

Org. Chem. Front., 2020, Accepted Manuscript
DOI: 10.1039/D0QO00330A, Research Article
Satyasheel Sharma, Bharatkumar Chaudhary, Neeraj Kulkarni
The Rhodium(III)-catalyzed reaction of N-methoxybenzamides as a directing group with β-trifluoromethyl-α,β-unsaturated ketones is reported. The reaction involved sp2 C−H activation, followed by Claisen condensation involving C-N bond cleavage to form...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Simple organocatalyst component system for asymmetric hetero Diels–Alder reaction of isatins with enones

RSC Adv., 2020, 10,17486-17491
DOI: 10.1039/D0RA03006F, Paper
Open Access
Perumalsamy Parasuraman, Zubeda Begum, Madhu Chennapuram, Chigusa Seki, Yuko Okuyama, Eunsang Kwon, Koji Uwai, Michio Tokiwa, Suguru Tokiwa, Mitsuhiro Takeshita, Hiroto Nakano
A simple two catalysts component system of β-amino alcohols (catalyst) and amino acids (co-catalyst) works as an efficient organocatalysts in hetero Diels–Alder reaction of isatins with enones to afford chiral spirooxindole-tetrahydropyranones.
The content of this RSS Feed (c) The Royal Society of Chemistry




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[ASAP] Discovery of Potent and Novel Quinazolinone Sulfide Inhibitors with Anti-ToCV Activity

Journal of Agricultural and Food Chemistry
DOI: 10.1021/acs.jafc.0c00686