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Electron donor–acceptor complex photoactivation for deaminative alkynylation, alkenylation and allenylation: a comprehensive study

Org. Chem. Front., 2024, 11,2231-2240
DOI: 10.1039/D4QO00177J, Research Article
Romain Lapierre, Lina Truong, Matthieu Hedouin, Hassan Oulyadi, Bruno Schiavi, Alexandre Jean, Philippe Jubault, Thomas Poisson
Herein, we disclose our study toward photoinduced deaminative alkynylation, alkenylation and allenylation.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Palladium-catalyzed asymmetric [4 + 3] cycloaddition of acyclic α,β-unsaturated imines with trimethylenemethane donors: access to chiral non-fused azepines

Org. Chem. Front., 2024, 11,2326-2331
DOI: 10.1039/D4QO00064A, Research Article
Ting-Peng Li, Shuixiu Su, Jia-Huan Shen, Meng Zang, Yang-Zi Liu, Quannan Wang, Wei-Ping Deng
An efficient approach for the construction of non-fused azepines in good yields with high enantioselectivity via Pd-catalyzed asymmetric [4 + 3] cycloaddition was developed.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Assembly of ionic supramolecular polymers using a decacationic pillar[5]arene to noncovalently crosslink hyaluronic acid for short DNA delivery

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00447G, Research Article
Qian Li, Danying Ma, Yue-Yang Liu, Hui Wang, Wei Zhou, Dan-Wei Zhang, Zhan-Ting Li
A multicationic pillar[5]arene noncovalently crosslinks hyaluronic acid to afford ionic supramolecular polymers for intramolecular delivery of short DNA.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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NBN/BNB-doped phenalenyl homo- and heterodyads: structural uniformity but optoelectronic diversity

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO00468J, Research Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Alexander S. Scholz, Thomas Froitzheim, Michael Bolte, Hans-Wolfram Lerner, Jan-M. Mewes, Matthias Wagner
Phenylene-bridged homo- and heterodyads of NBN- and BNB-phenalenyls were synthesized. The heterodyads show ambipolar redox character and aggregation-induced emission in the solid state.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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MRPL honoured for excellence in AI-driven process efficiency

The award was presented at the 27th Energy Technology Meet in Bengaluru.




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India, Russia discuss economic cooperation, facilitating mobility of talent and skills




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Correction: Super-adsorbent hydrogel for removal of methylene blue dye from aqueous solution

J. Mater. Chem. A, 2024, 12,9242-9246
DOI: 10.1039/D4TA90061H, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xiao-Sai Hu, Rui Liang, Guoxing Sun
The content of this RSS Feed (c) The Royal Society of Chemistry




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Superhydrophilic covalent organic frameworks accelerate photocatalytic production of hydrogen peroxide through proton channels

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01785D, Paper
Xiaojuan Bai, Linlong Guo, Tianqi Jia, Zhuofeng Hu
Superhydrophilic COFs with D–A structure accelerate photocatalytic synthesis of H2O2 using water as a proton supply reservoir.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Prolonging exciton diffusion length via manipulating molecular stacking enables pseudo-planar heterojunction organic solar cells over 19% efficiency

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00594E, Paper
Wang Ke, Fuwen Zhao, Yufan Zhu, Yi He, Zesheng Liu, Xiao Han, Qi Ai, Xingxing Shen, Bao Li, Jianqi Zhang, Yuze Lin, Chun-Ru Wang, Dan He
The limited exciton diffusion length (LD) of organic semiconductors constraints exciton dissociation in pseudo-planar heterojunction (PPHJ) organic solar cells (OSCs), which is deemed as the bottleneck issue hampering the further...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of a pyridine-based covalent organic framework as an anode material for lithium-ion batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00892H, Paper
Shixi Zhong, He Zhao, Yingming Ji, Xiuhua Li, Ting Shu, Zhiming Cui, Shijun Liao
Covalent organic framework (COF) materials with redox activity have emerged as promising electrode materials for lithium-ion batteries.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Regulating Pt-Covalent Triazine Frameworks Schottky Junction by Tailor-Made Nitrogen Sites towards Efficient Photocatalysis

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00618F, Paper
Chao Li, Lijiang Guan, Jin Zhang, Cheng Cheng, Zhaoqi Guo, Zhihong Tian, Li-Ming Yang, Shangbin Jin
Covalent triazine frameworks (CTFs) of designable nitrogen-rich structures, which can form Schottky Junction with Pt nanoparticles, have been extensively studied in photocatalysis. However, how to tune the interaction inside the...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Regulating the local microenvironment on porous Cu nanosheets for enhancing electrocatalytic CO2 reduction selectivity to ethylene

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01198H, Paper
Dan Wang, Qingqing Song, Kaibin Li, Yuwei Zhou, Junjun Mao, Chenchen Zhang, Yang Lou, Chengsi Pan, Jiawei Zhang, Yongfa Zhu, Ying Zhang
Local microenvironments of the ECO2RR play an important role in tuning the adsorption energy of crucial intermediates, which helps enhance ECO2RR selectivity.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Closed pore structure engineering from ultra-micropores with the assistance of polypropylene for boosted sodium ion storage

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01375A, Paper
Xue Li, Ning Sun, Shaohong Zhang, Razium Ali Soomro, Bin Xu
Closed pore architectures with exceptional Na-storage performance have been successfully fabricated from ultra-micropores with the assistance of polypropylene.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Green solvents in battery recycling: status and challenges

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07905H, Review Article
Wenyuan Qiao, Ren Zhang, Yikai Wen, Xinyi Wang, Zheng Wang, Guoqiang Tang, Minghao Liu, Hyokyeong Kang, Zafar Said, Jang-Yeon Hwang, Changhui Liu
A green solvent hybrid system will bring about sustainable development in the battery industry by efficiently and environmentally friendly recycling of valuable resources contained in waste batteries.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Pi-extended hypervalent iodine macrocycles and their supramolecular assembly with Buckminsterfullerene

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC04251D, Paper
Krishna Pandey, Samsul Arafin, Grayson Venus, Eli Jones, Yachu Du, Mina Dumre Pandey, Tahir Awais, Lichang Wang, Kyle N. Plunkett
Hypervalent iodine based macrocycles with enlarged aromatic cores can form extended supramolecular assemblies with Buckminsterfullerene.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Entrepreneurs in Salem undergo training in business and financial excellence




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BJP accuses Congress of releasing election manifesto during “silence” period in Jharkhand

Mr. Patra claimed that the Congress wanted to give 4% reservation to the Muslim organisations and contractors in public tenders




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Coal import for blending purposes in power generation declines by 8.5% during April-Sept 2024




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India could save 91,000 crore rupees on import bill through biofuel blending: Hardeep Singh Puri




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Vikarabad violence: KTR condemns former BRS MLA’s arrest, says farmers detained were ill-treated by police




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Minister discusses solutions to traffic bottleneck on Bengaluru’s airport road

One of the proposals involves widening the stretch near the military land




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Lanthanum-doped nickel-based composite metal oxide catalyst for hydrogenation of isophthalonitrile to produce meta-xylenediamine

Catal. Sci. Technol., 2024, Advance Article
DOI: 10.1039/D4CY00802B, Paper
Heng Shao, Jing Guo, Rulong Li, Dekun Ji, Long Huang, Haibin Chu
Lanthanum-doped nickel-based composite metal oxide catalysts exhibited excellent activity in IPN hydrogenation reactions with remarkable stability in fixed-bed reactors.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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IRFC looks beyond Railways for lending opportunities

To focus on other sectors for improved margins and growth, with zero NPAs




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Macquarie sees bright prospects for India’s power utilities and lenders: Buy calls for PFC, REC, NTPC, PGCIL

With strong balance sheets, PFC, REC, NTPC, and PGCIL are well-prepared to increase capital expenditure




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KL Rahul finally breaks silence on animated chat with Lucknow Super Giants owner Sanjiv Goenka during IPL 2024

Following a crushing 10-wicket defeat against Sunrisers Hyderabad, LSG owner Sanjiv Goenka expressed his displeasure and engaged in a heated discussion with the captain on the field.




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Anupamaa producer Rajan Shahi breaks silence over Rupali Ganguly's dispute with stepdaughter Esha Verma: 'You have...'

Anupamaa producer Rajan Shahi has supported Rupali Ganguly after the actress slapped her stepdaughter Esha Verma with a legal notice, seeking Rs 50 crore in damages.




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Silence

Fr. Barnabas welcomes his seminary professor and friend the Rev. Dr. Philip Zymaris to talk about a little understood topic - silence. What is its importance and how do we achieve it?




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Keeping A Good Great Lent

Fr. Barnabas helps us enter the season of Great Lent with the right attitude and with good strength for the journey.




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Tribute to Kevin Allen

Kevin Allen was the host of two popular podcasts on AFR - The Illumined Heart and Ancient Faith Today. The latter was the first live call-in show on AFR starting in April of 2012. Kevin reposed in the Lord on August 7, 2018 after a 27 month battle with ALS (Lou Gehrig's disease). Fr. Barnabas Powell welcomes special guests John Maddex, Steve Christoforou, Bruce Heying, and Abbot Tryphon as well as listeners to share comments and memories of Kevin and honor his legacy. May his memory be eternal. (Memory Eternal at the end of the program was sung by the St. Athanasius Orthodox Church Choir)




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Stolen King

Stolen King by Kadir Nelson is a(n) Limited Edition. The Edition is Limited to Limited Edition pcs




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Participants of OSCE-supported discussion in Bosnia and Herzegovina called to unite efforts in addressing online content that incites violence

Addressing online content that incites violence was in the focus of a two-day OSCE-supported roundtable discussion that concluded today in Sarajevo, Bosnia and Herzegovina (BiH).




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OSCE calls for multidisciplinary approach to preventing violent extremism in Bosnia and Herzegovina

Partnership between the security sector, civil society, local government and communities, and the private sector is of vital importance to effectively counter violent extremism in Bosnia and Herzegovi




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Developing counter narratives to combat online violent extremism content, in focus of OSCE-supported course in Bosnia and Herzegovina

The OSCE Mission to Bosnia and Herzegovina this week organized a series of short courses, which concluded today in Sarajevo, on the use of Internet and social media in developing counter narratives to online content promoting violent extremism




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OSCE Mission to Bosnia and Herzegovina’s youth summits challenge stereotypes and promote tolerance to counter violent extremism

Some 100 high school students, pedagogues and psychologists from across Bosnia and Herzegovina (BiH) took part in two youth summits in Teslić and Vogosća this week co-hosted by the OSCE Mission to BiH and the BiH Security Ministry ...




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40Ar/39Ar hornblende and biotite cooling ages for metaplutonic rocks of the central Thelon Tectonic Zone, Nunavut

Camacho, A; Berman, R G; Sanborn-Barrie, M. Geological Survey of Canada, Open File 8625, 2020, 77 pages, https://doi.org/10.4095/315135
<a href="https://geoscan.nrcan.gc.ca/images/geoscan/of8625.jpg"><img src="https://geoscan.nrcan.gc.ca/images/geoscan/of8625.jpg" title="Geological Survey of Canada, Open File 8625, 2020, 77 pages, https://doi.org/10.4095/315135" height="150" border="1" /></a>




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UPS: After a challenging 18-month period, our company returned to revenue and profit growth

UPS today announced third-quarter 2024 consolidated revenues of $22.2 billion, a 5.6% increase from the third quarter of 2023.




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InPost CEO on Q3 results: we are relentlessly focused on delivering

InPost Group has announced it’s Q3 24 results this morning, featuring significant gains in volumes, sales and profitability, as well as continued expansion of its locker network in all key markets.




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“Air freight users should be prepared for long-term challenges caused by economic uncertainties”

The Q2 2024 results for the DHL Hong Kong Air Trade Leading Index (DTI) have been published.




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Видео с текстом от SILENT WINTER

SILENT WINTER опубликовали официальное видео с текстом на композицию “We Burn The Future”. Этот трек взят из нового альбома "Utopia", релиз которого намечен на 22 ноября на No Remorse Records.
#Silent_Winter #SilentWinter
Видео: https://www.youtube.com/watch?v=YbFmmEt9ynY




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MITCH MALLOY опубликовал демо VAN HALEN

Вокалист Mitch Malloy (ex-GREAT WHITE) опубликовал демо песни "It's The Right Time". Эта композиция была написана им вместе с Эдди Ван Халеном в середине 90-ых, когда он стал первым кандидатом на вакантное место вокалиста группы после ухода с этого поста Sammy Hagar'a:

«Я должен быть в состоянии пожинать плоды своего искусства, над совершенствованием которого я работал всю свою жизнь Какой человек не получает повышения за свои достижения? В Америке так и должно быть. Вместо того, чтобы получить признание как первый выбор Van Halen на место Sam'а, мне остается только отстаивать себя. Это неправильно и несправедливо по отношению ко мне. И я в некотором роде зол. Любой другой не справился бы с этим так хорошо, как я. Эд сказал мне об этом, когда я видел его в последний раз. Я просто хотел бы, чтобы в конце концов он рассказал прессе правду, чтобы мне не пришлось это делать. Я бы хотел, чтобы никто не знал, если честно. Но раз уж они знают, то должны услышать результат. Вот он».
#Van_Halen #VanHalen #HardRock #Hard_Rock
Видео: https://www.youtube.com/watch?v=nMi9SdwbD3o






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Toptalent van Real zet op amper 19-jarige leeftijd punt achter carrière: "6 september 2022 veranderde mijn leven" - sporza.be

  1. Toptalent van Real zet op amper 19-jarige leeftijd punt achter carrière: "6 september 2022 veranderde mijn leven"  sporza.be
  2. Real Madrid-talent (19) moet nu al stoppen met voetballen: ‘Ik ben bevoorrecht geweest’  AD
  3. Zeer treurig nieuws uit Spanje: Real-talent (19) moet noodgedwongen stoppen  VoetbalPrimeur.be
  4. Real Madrid-talent (19) gedwongen te stoppen: 'Ik heb alles gegeven'  Voetbal International





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Samsung introduceert de Galaxy A16-serie, met twee nieuwe toestellen - Samsung Newsroom België

  1. Samsung introduceert de Galaxy A16-serie, met twee nieuwe toestellen  Samsung Newsroom België
  2. Samsung A16 4G kost 199 euro, 30 euro minder dan 5G-variant - Tablets en telefoons - Nieuws  Tweakers
  3. De nieuwe Samsung Galaxy A16 van €199 heeft wat de iPhone 16 niet heeft  Bright.nl
  4. Samsung lanceert nog goedkopere Galaxy A16 met zes jaar ondersteuning  TechPulse







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A Miming Mashup That Goes Through the Ages! (Also, Talented Ladies)




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Health anxiety: the silent, disabling epidemic