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Manchester United want to extend Odion Ighalo loan deal as Ole Gunnar Solskjaer weighs up £15m transfer

Manchester United want to extend Odion Ighalo's loan deal as they continue to weigh up a permanent move.




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Odion Ighalo to Manchester United: No immediate transfer plans with loan extension the priority

Manchester United are only pursuing an extension to Odion Ighalo's loan deal and have no immediate plans to negotiate a permanent move.




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Halogen bulbs banned in EU as of September 1

The LED revolution will not be stopped.




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Negative rates tarnish bankers’ halos

The failures of loose monetary policy could prompt a fall from grace




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Transfer news: Palace 'make £14m bid for CSKA Moscow striker Fedor Chalov'

The Eagles are low on fire-power with Christian Benteke, Connor Wickham and Alexander Sorloth all having problems - be it form or injury - and Roy Hodgson is desperate to add some attacking threat.




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MasterChef judge George Calombaris shares hack for cooking haloumi

He has been giving advice to aspiring chefs as a judge on MasterChef since 2009.




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Will Odion Ighalo have a successful late season cameo at Man Utd like these players?

Odion Ighalo is likely to make his Manchester United debut when they play Chelsea on Monday and Ole Gunnar Solskjaer will be hoping the striker makes as much impact as these loan stars.




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University women's team 'kicked Odion Ighalo off their training pitch'

Odion Ighalo angered a student football team while he was participating in a solo training session over the winter break, according to The Sun. 




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Ex-Chelsea goalkeeper Marcin Bulka reveals how Diego Costa confronted Nathaniel Chalobah

Former Chelsea goalkeeper Marcin Bulka has recalled a bizarre incident involving a Diego Costa and Nathaniel Chalobah. Bulka rose through the Chelsea ranks before moving to PSG.




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Nigeria 3-2 Cameroon: Odion Ighalo scores a brace to knock out holders

Nigeria produced a second-half comeback to beat Cameroon 3-2 and book their place in the quarter-finals of the Africa Cup of Nations. The Super Eagles had taken an early lead.




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Manchester United fans get excited about Odion Ighalo's trademark 'scoop' trick after sealing move

The Nigeria striker, 30, sealed a dramatic deadline day loan move to United from Shanghai Shenhua as boss Ole Gunnar Solskjaer's search for a striker went down to the wire.




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Odion Ighalo grew up idolising Andy Cole and Dwight Yorke in a house crammed with 50 people

Manchester United's decision to sign Odion Ighalo on loan in the final few hours of deadline day last week certainly raised a few eyebrows. But can he deliver for the club he has supported for years?




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New arrival Odion Ighalo in the clear for Manchester United's trip to face Club Brugge

Odion Ighalo will be able to travel with Manchester United for their Europa League tie in Bruges next week despite having to miss the club's training camp in Marbella over the coronavirus alert.




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Andy Cole backs Odion Ighalo to succeed during Man United loan spell

Manchester United fan Odion Ighalo will be desperate to prove himself at Old Trafford and earn a permanent move, according to former striker Andy Cole.




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Ole Gunnar Solskjaer declares Odion Ighalo ready for Manchester United debut at Chelsea

Odion Ighalo will be ready to make his Manchester United debut at Chelsea on Monday if needed despite not having trained with his new teammates yet, claims manager Ole Gunnar Solskjaer.




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Top 10 Nigerian players in Premier League as Odion Ighalo prepares for Man United debut

There will be plenty of excitement in Nigeria when Odion Ighalo makes his debut for Manchester United. But the striker is far from the first player from the country to grace the Premier League.




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Odion Ighalo could make permanent Manchester United switch if he impresses - Solskjaer

Ole Gunnar Solskjaer has denied that Manchester United's deadline day signing of Odion Ighalo was an act of desperation - and left the door open for the striker to make his loan move permanent.




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Odion Ighalo has last laugh after first Manchester United goal - his time to shine is now

Nobody is laughing at Odion Ighalo now. The "joke" whose deadline day signing for Man United from China created more social media traffic than Brexit Day celebrated his first start with a goal.




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Odion Ighalo earning big bonuses at Manchester United after taking pay cut

Odion Ighalo is being rewarded for his fine start to life at Manchester United with some huge bonuses, according to The Sun. The Nigeria striker has scored four goals since arriving in January.




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Odion Ighalo excited at prospect of a Bruno Fernandes and Paul Pogba partnership at United

Ighalo is one of many United stars to have benefited from the arrival of Fernandes. The Portuguese has taken to life at United and has triggered a sense of optimism among fans.




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Odion Ighalo 'may not be wanted' at Man United and should sign for Chelsea, Real Madrid or Barcelona

Despite being written off by many following his surprise loan switch to United in January, Ighalo has impressed with four goals in eight outings for Ole Gunnar Solskjaer's side.




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JAMIE REDKNAPP: Eric Dier showed footballer's halos can slip

JAMIE REDKNAPP: I remember times my brother, Mark, got angry or upset if someone was having a go at me in the stands. He'd want to say something. Now we have seen this with Eric Dier.




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Halo Trust boss who arranged Prince Harry's trip to minefield in Angola where Diana went 'emotional'

Halo Trust chief executive James Cowan last month accompanied Harry in Huambo, Angola, to the area where Diana, Princess of Wales took the same 50-metre stroll 22 years earlier.




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Man United hold fire on opening talks over extending Odion Ighalo's loan

United want to keep him for longer after he scored four goals in eight games, but the issue has been complicated by the global football shutdown as Ighalo's loan enters its final three weeks.




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Big Brother 2017's Ellie Young kisses Sam Chaloner AGAIN

Ellie Young and Sam Chaloner may have finally overcome their obstacles to reality show romance as they end up in a passionate embrace on tonight's episode of the show.




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Big Brother's Sam Chaloner incurs wrath of housemates

Sam Chaloner falls out of favour with his housemates in tonight's episode of the show, after Isabelle Warburton saves him, sacrificing herself to face the public vote, and he stays silent.




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Big Brother's Ellie Young and Sam Chaloner get frisky

They recently admitted to feeling 'sexually frustrated' and Big Brother stars Ellie Young and Sam Chaloner almost succumbed to their urges as the frisky pair took things up a notch during Sunday's episode.




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Ellie Young & Sam Chaloner evicted from Big Brother house

On Friday night, Big Brother bosses served up a surprise for the housemates, when two additional contestants were evicted after Sam Chaloner's expected departure.




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Big Brother: Ellie Young & Sam Chaloner still not had sex

One would have expected Ellie Young and Sam Chaloner to 'seal the deal' as soon as they were booted out of the Borehamwood house but she said he was too drunk to get aroused.




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It's all hail the halo now... it's hard to argue against its efficacy

JONATHAN MCEVOY: In the name of balance we should record the traditionalist’s argument that the ugly device, though not as repulsive as feared, gnaws at soul of open-cockpit motor racing.




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Derby County 0-3 Manchester United - FA Cup: Ighalo hits brace to ruin Rooney's night

Wayne Rooney is the star attraction as the Derby County player-coach comes up against his former side Manchester United in the FA Cup. Follow all the updates here with Sportsmail.




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Derby County 0-3 Manchester United: Odion Ighalo notches a brace as Red Devils cruise into quarters

CHRIS WHEELER AT PRIDE PARK: Ole Gunnar Solskjaer was right about Wayne Rooney. There is still fight in the old dog. The problem for Rooney is that Man Utd have a bit of bite themselves.




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Odion Ighalo 'desperate to stay at Manchester United' with striker due for return to China on May 31

Odion Ighalo was settling in nicely to his dream Manchester United loan before it was cruelly cut off by coronavirus, leaving the striker desperate to extend his stay with the Premier League club.




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Nigeria 1-0 Burundi: Ex-Watford striker Odion Ighalo grabs late winner

Nigeria needed a late goal from substitute Odion Ighalo to claim a 1-0 win over a brave Burundi side playing their first-ever match at the Africa Cup of Nations on Saturday.




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Man United hold fire on opening talks over extending Odion Ighalo's loan

United want to keep him for longer after he scored four goals in eight games, but the issue has been complicated by the global football shutdown as Ighalo's loan enters its final three weeks.




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Odion Ighalo 'desperate to stay at Manchester United' with striker due for return to China on May 31

Odion Ighalo was settling in nicely to his dream Manchester United loan before it was cruelly cut off by coronavirus, leaving the striker desperate to extend his stay with the Premier League club.




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Skiing photographer captures stunning 'ice halo' around the sun over the Swiss Alps

Using just an iPhone 11, Michael Schneider snapped a stunning image the moment the moment ice crystals froze midair, creating a perfect 'halo' around the sun while skiing in the Swiss Alps.




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From the GoPro to the SmartHalo: The best bicycle accessories for London cyclists

Cycling in London can be one of the most incredible experiences a person can have. However, to get the most out of cycling in the capital, you need the right kit. Here are some of the best accessories for it




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Derby County 0-3 Manchester United - FA Cup: Ighalo hits brace to ruin Rooney's night

Wayne Rooney is the star attraction as the Derby County player-coach comes up against his former side Manchester United in the FA Cup. Follow all the updates here with Sportsmail.




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Derby County 0-3 Manchester United: Odion Ighalo notches a brace as Red Devils cruise into quarters

CHRIS WHEELER AT PRIDE PARK: Ole Gunnar Solskjaer was right about Wayne Rooney. There is still fight in the old dog. The problem for Rooney is that Man Utd have a bit of bite themselves.




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Pillar[5]arene-based self-assembled linear supramolecular polymer driven by guest halogen–halogen interactions in solid and solution states

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00327A, Paper
Talal F. Al-Azemi, Mickey Vinodh
A pillar[5]arene-based linear supramolecular polymer mediated by guest halogen–halogen interactions (C–Br⋯Br–C) was studied in both the solution and solid states.
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Effects of non-halogenated solvent on the main properties of a solution-processed polymeric thin film for photovoltaic applications: a computational study

Phys. Chem. Chem. Phys., 2020, 22,9693-9702
DOI: 10.1039/D0CP01303J, Paper
Karlisson Rodrigo de Almeida Sousa, Leandro Benatto, Luana Wouk, Lucimara Stolz Roman, Marlus Koehler
Our nano-scale simulations of polymeric films processed with different solvents reveal important details of morphological and electrical changes important for OPV applications.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Imaging Lipophilic Regions in Rodent Brain Tissue with Halogenated BODIPY Probes

Analyst, 2020, Accepted Manuscript
DOI: 10.1039/D0AN00099J, Communication
David Hartnell, Bradley Schwehr, Kate Gillespie-Jones, Dasuni Alwis, Ramesh Rajan, Huishu Hou, nicole j sylvain, M. Jake Jake Pushie, Michael E Kelly, Massimiliano Massi, Mark Hackett
The effect of halogen substitution in fluorescent BODIPY species was evaluated in the context of staining lipids in situ within brain tissue sections. Herein we demonstrate that the halogenated species...
The content of this RSS Feed (c) The Royal Society of Chemistry




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A homogeneous photoelectrochemical hydrogen sulfide sensor based on the electronic transfer mediated by tetrasulfophthalocyanine

Analyst, 2020, Advance Article
DOI: 10.1039/D0AN00302F, Paper
Xinyang Wang, Huanan Zhao, Zhonghui Chen, Fang Luo, Longhua Guo, Bin Qiu, Zhenyu Lin, Jian Wang
A homogeneous photoelectrochemical sensor for H2S detection based on the electronic transfer mediated by [Fe(III)PcS4]+ was developed with an un-modified photoelectrode.
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Graphene-modulated assembly of zinc phthalocyanine on BiVO4 nanosheets for efficient visible-light catalytic conversion of CO2

Chem. Commun., 2020, 56,4926-4929
DOI: 10.1039/D0CC01518K, Communication
Ji Bian, Jiannan Feng, Ziqing Zhang, Jiawen Sun, Mingna Chu, Ling Sun, Xin Li, Dongyan Tang, Liqiang Jing
Graphene-modulated ZnPc/BiVO4 Z-scheme heterojunctions for efficient visible-light catalytic CO2 conversion are achieved by increasing the optimized amount of highly dispersed ZnPc.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Halogen bonding for molecular recognition: new developments in materials and biological sciences

Chem. Commun., 2020, 56,4970-4981
DOI: 10.1039/D0CC00841A, Highlight
Gilles Berger, Pierre Frangville, Franck Meyer
This review highlights recent developments of halogen bonding in materials and biological sciences with a short discussion on the nature of the interaction.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Novel 2-naphthyl substituted zinc naphthalocyanine: synthesis, optical, electrochemical and spectroelectrochemical properties

New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00987C, Paper
T. V. Dubinina, E. O. Moiseeva, D. A. Astvatsaturov, N. E. Borisova, P. A. Tarakanov, S. A. Trashin, K. De Wael, L. G. Tomilova
New zinc naphthalocyanine with bulky 2-naphthyl groups was obtained. Aggregation drastically influences its optical and electrochemical behavior. Spectroelectrochemistry helps to establish the oxidation potential and reveals unusual color change.
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Synthesis of 3-halochromones with simple KX halogen sources enabled by in situ halide oxidation

New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00825G, Paper
Yan Lin, Jie-Ping Wan, Yunyun Liu
An in situ oxidation strategy for generating molecular halogen has been developed for the synthesis of 3-halochromones by employing simple potassium halides as halogen sources.
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The effect of vicinal di-halo substituents on the organogelling properties of aromatic supramolecular gelators and their application as soft templates

New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ01440K, Paper
Andrea S. Mac Cormack, Verónica M. Busch, M. Laura Japas, Lisandro Giovanetti, Florencia Di Salvo, Pablo H. Di Chenna
Vicinal di-halo substituents have a determinant effect on the supramolecular self-assembly and properties of aromatic physical gelators with application as soft templates.
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Novel phthalocyanine-based micelles/PNIPAM composite hydrogels: spatial/temporal-controlled drug release triggered by NIR laser irradiation

New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01882A, Letter
Tao Jia, Lu Li, Enna Ha, Zheng Qu, Lei Shi, Tiedong Sun, Shengnan Tan, Wancheng Zhao
Near-infrared (NIR) light-responsive hydrogels hold significant potential for biomedical application, especially in remote-controlled release of anticancer drugs. Herein we report a novel NIR light responsive composite hydrogel system that undergoes...
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