derivatives

OTC derivatives statistics at end-December 2019

Notional amounts of OTC derivatives rose from $544 trillion at end-December 2018 to $559 trillion at end-December 2019. This, however, corresponds to a significant fall over the last six months, which could be at least partly attributed to seasonal factors. The seasonal pattern in the data, whereby end-June values tend typically to be larger than end-of-year values, appears strongest in positions vis-à-vis central counterparties. Such end-of-year contractions can occur if dealer banks and/or their clients shrink their outstanding notional derivative positions for regulatory and financial reporting purposes. Contracts denominated in non-G4 currencies (ie excluding USD, EUR, JPY and GBP) have grown in size for both interest rate and foreign exchange derivatives, even though those denominated in US dollars remain the largest segment.




derivatives

OTC derivatives outstanding

The semiannual OTC derivatives statistics provide data on notional amounts outstanding and gross market values for all types of over-the-counter derivatives contracts. They are reported by large dealers in 12 countries on a worldwide consolidated basis.




derivatives

Fin24.com | Derivatives




derivatives

Coronavirus - Deferral of initial margin requirements for derivatives announced – Global

On 3 April 2020, the Basel Committee on Banking Supervision (“BCBS”) and the International Organization of Securities Commissions (“IOSCO”) issued a statement recommending an extension to Phases 5 and 6 of the initial margin ...




derivatives

Justice Department Announces Charges Filed Against Two Derivatives Traders in Connection with Multi-Billion Dollar Trading Loss at JPMorgan Chase & Company

U.S. Attorney General Eric Holder, U.S. Attorney for the Southern District of New York Preet Bharara and Assistant Director-in-Charge of the FBI’s New York Field Office George Venizelos announced the unsealing of criminal complaints against Javier Martin-Artajo and Julien Grout for their alleged participation in a conspiracy to hide the true extent of losses in a credit derivatives trading portfolio maintained by the Chief Investment Office (CIO) of JPMorgan Chase & Company (JPMorgan). Martin-Artajo served as a Managing Director and Head of Credit and Equity Trading for the CIO, and Grout was a Vice President and derivatives trader in the CIO.



  • OPA Press Releases

derivatives

Acai Berry Derivatives Treat Malaria in Mice

Acai berry extracts can reduce parasites in the blood and prolong the survival of malarial mice, according to the study published in iACS Omega/i.




derivatives

FII derivatives statistics




derivatives

COMMODITY DERIVATIVES SETTLEMENT SCHEDULE FOR June 2020




derivatives

Mexico Imports - Sulfonated, Nitrated Or Nitrosated Derivatives

Imports - Sulfonated, Nitrated Or Nitrosated Derivatives in Mexico increased to 2507 USD THO in March from 1099 USD THO in February of 2020. Imports - Sulfonated, Nitrated Or Nitrosated Deriv in Mexico averaged 1384.79 USD THO from 2014 until 2020, reaching an all time high of 3014 USD THO in October of 2015 and a record low of 462 USD THO in September of 2017. This page includes a chart with historical data for Mexico Imports of Sulfonated, Nitrated Or Nitrosated Der.




derivatives

Global regulators delay derivatives rules due to market volatility

Watchdogs put 12-month extension on new margin requirements, citing coronavirus threat




derivatives

[ASAP] Thiosemicarbazone Derivatives as Inhibitors of Amyloid-ß Aggregation: Effect of Metal Coordination

Inorganic Chemistry
DOI: 10.1021/acs.inorgchem.0c00467




derivatives

Self-crosslinking smart hydrogels through direct complexation between benzoxaborole derivatives and diols from hyaluronic acid

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00308E, Paper
Tamiris Figueiredo, Yu Ogawa, Jing Jing, Vanina Cosenza, Isabelle Jeacomine, Johan D. M. Olsson, Thibaud Gerfaud, Jean-Guy Boiteau, Craig Harris, Rachel Auzély-Velty
By tailoring the structure of benzoxaborole (BOR), self-crosslinking hydrogels based on hyaluronic acid (HA) modified with BOR derivatives are obtained for the first time through the direct BOR-HA diol complexation at physiological pH.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




derivatives

Self-supported rhodium catalysts based on a microporous metal–organic framework for polymerization of phenylacetylene and its derivatives

Polym. Chem., 2020, 11,2904-2913
DOI: 10.1039/D0PY00170H, Paper
Li Zhang, Qingbin Cao, Fei Gao, Yuping Dong, Xiaofang Li
Highly efficient, cis-selective, stable, recyclable and reusable heterogeneous single-site MOF-supported rhodium catalysts polymerize PA and its derivatives, producing cis-transoidal PPAs and their functional derivatives having a helical configuration or AIE properties.
The content of this RSS Feed (c) The Royal Society of Chemistry




derivatives

Design of new phenothiazine derivatives as visible light photoinitiators

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00497A, Paper
Mahmoud Rahal, Mira Abdallah, Thanh-Tuân Bui, Fabrice Goubard, Bernadette Graff, Frédéric Dumur, Joumana Toufaily, Tayssir Hamieh, Jacques Lalevée
In this article, four new phenothiazine derivatives (denoted as PT1, PT2, PT3 and PT4) are specifically in silico designed by molecular modelling for good light absorption properties @405 nm.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




derivatives

Facile synthesis and exploration of excited state assisted two-photon absorption properties of D–A–D type thiophene–pyridine derivatives

Photochem. Photobiol. Sci., 2020, Advance Article
DOI: 10.1039/D0PP00047G, Paper
Viprabha Kakekochi, Sathish Chatnahalli Gangadharappa, Nikhil P. P., Chandrasekharan Keloth, Ezequiel Wolcan, Udaya Kumar D
Diagrammatic representation of excited state assisted two-photon absorption (2PA) behavior of a donor–acceptor type conjugated polymer (P2TPy) exhibiting an extremely low optical limiting threshold.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




derivatives

Macrocyclic polyamine [12]aneN3 modified triphenylamine-pyrazine derivatives as efficient non-viral gene vectors with AIE and two-photon imaging properties

J. Mater. Chem. B, 2020, 8,3869-3879
DOI: 10.1039/D0TB00321B, Paper
Le-Le Ma, Ming-Xuan Liu, Xu-Ying Liu, Wan Sun, Zhong-Lin Lu, Yong-Guang Gao, Lan He
[12]aneN3 modified triphenylamine-pyrazines as non-viral gene vectors with AIE and two-photon imaging properties.
The content of this RSS Feed (c) The Royal Society of Chemistry




derivatives

[ASAP] Synthesis of Tri(4-formylphenyl) Phosphonate Derivatives as Recyclable Triple-Equivalent Supports of Peptide Synthesis

The Journal of Organic Chemistry
DOI: 10.1021/acs.joc.9b03023




derivatives

[ASAP] One-Pot Multicomponent Reaction of Catechols, Ammonium Acetate, and Aldehydes for the Synthesis of Benzoxazole Derivatives Using the Fe(III)–Salen Complex

The Journal of Organic Chemistry
DOI: 10.1021/acs.joc.0c00560




derivatives

[ASAP] Acylphloroglucinol Derivatives with a Tricyclo-[4.4.1.1<sup>1,4</sup>] Dodecane Skeleton from <italic toggle="yes">Garcinia bracteata</italic> Fruits

The Journal of Organic Chemistry
DOI: 10.1021/acs.joc.0c00637




derivatives

[ASAP] Synthesis of Indolizine Derivatives Triggered by the Oxidative Addition of Aroyl Chloride to Pd(0) Complex

The Journal of Organic Chemistry
DOI: 10.1021/acs.joc.0c00161




derivatives

[ASAP] Imidazo[1,2-<italic toggle="yes">a</italic>]pyridine Derivatives as Aldehyde Dehydrogenase Inhibitors: Novel Chemotypes to Target Glioblastoma Stem Cells

Journal of Medicinal Chemistry
DOI: 10.1021/acs.jmedchem.9b01910




derivatives

[ASAP] Discovery of Orally Bioavailable Chromone Derivatives as Potent and Selective BRD4 Inhibitors: Scaffold Hopping, Optimization, and Pharmacological Evaluation

Journal of Medicinal Chemistry
DOI: 10.1021/acs.jmedchem.0c00035




derivatives

[ASAP] Design and Synthesis of Bitopic 2-Phenylcyclopropylmethylamine (PCPMA) Derivatives as Selective Dopamine D3 Receptor Ligands

Journal of Medicinal Chemistry
DOI: 10.1021/acs.jmedchem.9b01835




derivatives

[ASAP] Discovery of Peptide Boronate Derivatives as Histone Deacetylase and Proteasome Dual Inhibitors for Overcoming Bortezomib Resistance of Multiple Myeloma

Journal of Medicinal Chemistry
DOI: 10.1021/acs.jmedchem.9b02161




derivatives

[ASAP] Discovery and Structure–Activity Relationship Study of (<italic toggle="yes">Z</italic>)-5-Methylenethiazolidin-4-one Derivatives as Potent and Selective Pan-phosphatidylinositol 5-Phosphate 4-Kinase Inhibitors

Journal of Medicinal Chemistry
DOI: 10.1021/acs.jmedchem.0c00227




derivatives

[ASAP] Design, Synthesis, and Mechanism Study of Benzenesulfonamide-Containing Phenylalanine Derivatives as Novel HIV-1 Capsid Inhibitors with Improved Antiviral Activities

Journal of Medicinal Chemistry
DOI: 10.1021/acs.jmedchem.0c00015




derivatives

[ASAP] Artemisinin Derivatives with Antimelanoma Activity Show Inhibitory Effect against Human DNA Topoisomerase 1

ACS Medicinal Chemistry Letters
DOI: 10.1021/acsmedchemlett.0c00131




derivatives

Synthesis of chiral α-substituted α-amino acid and amine derivatives through Ni-catalyzed asymmetric hydrogenation

Chem. Commun., 2020, 56,4934-4937
DOI: 10.1039/D0CC01220C, Communication
Gongyi Liu, Xianghe Zhang, Heng Wang, Hengjiang Cong, Xumu Zhang, Xiu-Qin Dong
Efficient Ni-catalyzed asymmetric hydrogenation of cyclic N-sulfonyl ketimino esters and ketimines was successfully developed to prepare a series of chiral α-monosubstituted α-amino acid derivatives and amine derivatives with excellent results.
The content of this RSS Feed (c) The Royal Society of Chemistry




derivatives

Pyrenoimidazole fused phenanthridine derivatives with intense red excimer fluorescence in solid-state

New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01223H, Paper
Joseph Ajantha, Shanmugam Karthik, Thirumanavelan Gandhi, Easwaramoorthi Shanmugam
A new series of polycyclic aromatic hydrocarbon (PAH), pyrenoimidazole (PyFPs) having different substituents were developed as fluorescence emitters for optoelectronic applications. The compounds were synthesized by means of transition metal-free,...
The content of this RSS Feed (c) The Royal Society of Chemistry




derivatives

Discovery of [1,2,4]triazolo[4,3-a]pyrazine derivatives bearing 4-oxo-pyridazinone moiety as potential c-Met kinase inhibitors

New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ00575D, Paper
Binliang Zhang, Xiaobo Liu, Hehua Xiong, Qian Zhang, Xin Sun, Zunhua Yang, Shan Xu, Pengwu Zheng, Wufu Zhu
Two series of [1,2,4]triazolo[4,3-a]pyrazine derivatives bearing 4-oxo-pyridazinone moiety (compounds 21a-l and 22a-l) were designed and evaluated for the IC50 values against three cancer cell lines (A549, MCF-7 and Hela) and...
The content of this RSS Feed (c) The Royal Society of Chemistry




derivatives

Effect of number and different types of proton donors on excited-state intramolecular single and double proton transfer in bipyridine derivatives: theoretical insights

New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ01304H, Paper
Komsun Chaihan, Nawee Kungwan
Intra-HBs are strengthened upon photoexcitation, confirmed by red-shift in vibrational mode and topology analysis. Number and type of donors result in difference in photophysical properties. Occurrence of ESIPT depends on barrier and reaction energy.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




derivatives

Novel nitro substituted formazan derivatives: Selective ratiometric and colorimetric chemosensors for fluoride anion sensing detectable by the naked eye

New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01860K, Paper
Gulsen Turkoglu
Novel two formazan derivatives FNB and FDNB were synthesized from their corresponding phenylhydrazone and characterized by various spectroscopic methods. The sensing ability of these formazan sensors towards different anions was...
The content of this RSS Feed (c) The Royal Society of Chemistry




derivatives

Synthesis of a new Ni complex supported on CoFe2O4 and its application as an efficient and green catalyst for the synthesis of bis(pyrazolyl)methane and polyhydroquinoline derivatives

New J. Chem., 2020, Advance Article
DOI: 10.1039/D0NJ00223B, Paper
Taiebeh Tamoradi, Seyedeh Masoumeh Mousavi, Masoud Mohammadi
A novel and magnetic nanocatalyst was synthesized for the synthesis of multicomponent compounds.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




derivatives

Fast and easy conversion of ortho amidoaryldiselenides into the corresponding Ebselen-like derivatives driven by theoretical investigations.

New J. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0NJ01605E, Paper
Vanessa Nascimento, Pâmella da Silva Cordeiro, Massimiliano Arca, Francesca Marini, Luca Sancineto, Antonio Luiz Braga, Vito Lippolis, Michio Iwaoka, Claudio Santi
DFT calculations performed on amidoaryldiselenides as electrophilic derivatives evidenced the presence of a prevalent Se···O weak interaction when selenium is bonded to a Se atom (diselenides), a Br atom (selenenyl...
The content of this RSS Feed (c) The Royal Society of Chemistry




derivatives

N-H···O Hydrogen Bonding to the Alkoxy Oxygen of a Carboxylic Ester Group: Crystal Structures of Methyl 2,6-Diaminobenzoate and Its Derivatives.

CrystEngComm, 2020, Accepted Manuscript
DOI: 10.1039/D0CE00495B, Paper
John D. Wallis, Alun Christopher Garner, Songjie Yang
Methyl 2,6-diaminobenzoate and its bis-triphenylboron complex show hydrogen bonding from NH2 groups to both oxygen atoms of the carboxylic ester, and there is little difference in the lengths of these...
The content of this RSS Feed (c) The Royal Society of Chemistry




derivatives

Progress in recent development of stereoselective synthesis of β2-amino acid derivatives from β-nitroacrylate derivatives

Org. Biomol. Chem., 2020, 18,2991-3006
DOI: 10.1039/D0OB00448K, Review Article
Hao-Wei Zeng, Ping-Yu Wu, Hsyueh-Liang Wu
β2-Amino acids: recent advances in the synthesis of β2-amino acids and their derivatives from various stereoselective transformations of β-nitroacrylates are summarized.
The content of this RSS Feed (c) The Royal Society of Chemistry




derivatives

Synthesis, radiolabelling and initial biological characterisation of 18F-labelled xanthine derivatives for PET imaging of Eph receptors

Org. Biomol. Chem., 2020, 18,3104-3116
DOI: 10.1039/D0OB00391C, Paper
Marc Pretze, Christin Neuber, Elisa Kinski, Birgit Belter, Martin Köckerling, Amedeo Caflisch, Jörg Steinbach, Jens Pietzsch, Constantin Mamat
Two new fluorine-18-labelled xanthine derivatives with high binding affinity were synthesised as PET-radioligand candidates for Eph receptors.
The content of this RSS Feed (c) The Royal Society of Chemistry




derivatives

Synthesis of disaccharide modified berberine derivatives and their anti-diabetic investigation in zebrafish using a fluorescence-based technology

Org. Biomol. Chem., 2020, Advance Article
DOI: 10.1039/D0OB00327A, Paper
Lizhen Wang, Haotian Kong, Meng Jin, Xiaobin Li, Rostyslav Stoika, Houwen Lin, Kechun Liu
Diglucose modified berberine derivatives can dramatically promote the uptake of 2-NBDG in both zebrafish larvae and their eyes.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




derivatives

Electrochemical synthesis of selenyl-dihydrofurans via anodic selenofunctionalization of allyl-naphthol/phenol derivatives and their anti-Alzheimer activity

Org. Biomol. Chem., 2020, Advance Article
DOI: 10.1039/D0OB00629G, Communication
Marcos R. Scheide, Alex R. Schneider, Guilherme A. M. Jardim, Guilherme M. Martins, Daniele C. Durigon, Sumbal Saba, Jamal Rafique, Antonio L. Braga
Herein, we report an eco-friendly, electrosynthetic approach for the intramolecular oxyselenylation of allyl-naphthol/phenol derivatives.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




derivatives

Electrochemically enabled functionalization of indoles or anilines to synthesis of hexafluoroisopropoxy indole and anilinederivatives

Org. Biomol. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0OB00157K, Communication
Zu-yu Mo, Xin-Yu Wang, Yu-zhen Zhang, Li Yang, Hai-Tao Tang, Ying-Ming Pan
An environmentally benign electrochemically enabled site-selective functionalization of indole or aniline derivatives with hexafluoroisopropanol in the presence of tetrabutyl ammonium hexafluorophosphate as redox catalyst and electrolyte was demonstrated in this...
The content of this RSS Feed (c) The Royal Society of Chemistry




derivatives

Blue emissive dimethylmethylene-bridged triphenylamine derivatives appending cross-linkable groups

Org. Biomol. Chem., 2020, Advance Article
DOI: 10.1039/D0OB00622J, Paper
Kangyu Zhou, Hongfei Pan, Yongjie Zhang, Houchen Wang, Xiaofei Dong, Xiangkui Ren, Xianggao Li, Shirong Wang, Zhijian Chen
Blue-emissive and cross-linkable dimethylmethylene-bridged triphenylamine derivatives were synthesized and their optical and electrochemical properties were investigated.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




derivatives

Enantioselective Synthesis of Indanone Spiro-Isochromanone Derivatives via Dinuclear Zinc-Catalyzed Michael/Transesterification Tandem Reaction

Org. Biomol. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0OB00541J, Paper
Xiao-Chao Yang, Meng Xu, Jin-Bao Wang, Meng-Meng Liu, Francois Mathey, Yuan-Zhao Hua, Mincan Wang
An enantioselective Michael/transesterification tandem reaction of α-hydroxy indanones with ortho-ester chalcones was realized by dinuclear zinc catalysts. A series of enantiomerically pure spiro[indanone-2,3’-isochromane-1-one] derivatives were obtained in good yields with...
The content of this RSS Feed (c) The Royal Society of Chemistry




derivatives

Phenylboronic acid-catalyzed tandem construction of S–S and C–S bonds: a new method for the synthesis of benzyl disulfanylsulfone derivatives from S-benzyl thiosulfonates

Org. Biomol. Chem., 2020, 18,3243-3248
DOI: 10.1039/D0OB00442A, Communication
Raju Jannapu Reddy, Md. Waheed, Gamidi Rama Krishna
A novel and unique phenylboronic acid-catalyzed tandem construction of S–S and C–S bonds via dimerization–sulfonylation has been disclosed for the synthesis of benzyl disulfanylsulfone derivatives.
The content of this RSS Feed (c) The Royal Society of Chemistry




derivatives

Modular synthesis of oligoacetylacetones via site-selective silylation of acetylacetone derivatives

Org. Biomol. Chem., 2020, 18,3297-3302
DOI: 10.1039/D0OB00501K, Paper
Parantap Sarkar, Yuya Inaba, Hayato Shirakura, Tomoki Yoneda, Yasuhide Inokuma
Aliphatic oligoketones with tailored carbonyl and substituent sequences were modularly synthesized utilizing site-selective formation of enol silyl ethers. Their unique conformational preferences in solid-state were revealed by X-ray crystallography.
The content of this RSS Feed (c) The Royal Society of Chemistry




derivatives

Synthesis of α-CF3-substituted E-dehydroornithine derivatives via copper(I)-catalyzed hydroamination of allenes

Org. Biomol. Chem., 2020, 18,3274-3280
DOI: 10.1039/D0OB00580K, Paper
Anna N. Philippova, Daria V. Vorobyeva, Florian Monnier, Sergey N. Osipov
Novel α-CF3-substituted E-dehydroornithine derivatives have been synthesized via the Cu(I)-catalyzed hydroamination of α-CF3-α-allenyl-α-aminocarboxylates/phosphonates with different amines.
The content of this RSS Feed (c) The Royal Society of Chemistry




derivatives

Correction: Nickel-catalyzed cyanation of phenol derivatives activated by 2,4,6-trichloro-1,3,5-triazine

Org. Biomol. Chem., 2020, Advance Article
DOI: 10.1039/D0OB90052D, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Liang Wang, Yaoyao Wang, Jun Shen, Qun Chen, Ming-Yang He
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




derivatives

[ASAP] Therapeutic Potential of Carnosine and Its Derivatives in the Treatment of Human Diseases

Chemical Research in Toxicology
DOI: 10.1021/acs.chemrestox.0c00010




derivatives

Multi-stimuli responsive cyanostilbene derivatives: pH, amine vapor sensing and mechanoluminescence

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/D0QM00113A, Research Article
Guangxi Huang, Xiaoyong Chang, Yuqing Jiang, Bei Lin, Bing Shi Li, Ben Zhong Tang
Two carboxyl substituted cyanostilbene derivatives can serve as novel mechanoluminescence materials and fluorescent sensors towards pH change and also amine vapors.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




derivatives

[ASAP] Palladium-Catalyzed Regio- and Stereoselective Cross-Coupling of Vinylethylene Carbonates with Ketimine Esters to Generate (<italic toggle="yes">Z</italic>)-Tri- and Tetra-substituted Allylic Amino Acid Derivatives

Organic Letters
DOI: 10.1021/acs.orglett.0c01211




derivatives

Effects of alkyl chain length and anion on the optical and electrochemical properties of AIE-active α-cyanostilbene-containing triphenylamine derivatives

J. Mater. Chem. C, 2020, Advance Article
DOI: 10.1039/D0TC00683A, Paper
Sin-Yu Chen, Min-Hao Pai, Guey-Sheng Liou
A series of AIE-active and redox-active α-cyanostilbene-containing triphenylamine derivatives with different alkyl chain lengths and anions were successfully synthesized, and their optical, photoluminescent and electrochromic behaviors were investigated.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry