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Magnetically recyclable nanophotocatalysts in photocatalysis-involving processes for organic pollutant removal from wastewater: current status and perspectives

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D3EN00906H, Critical Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zexiao Zheng, Juhua He, Zuyao Zhang, Ashutosh Kumar, Musharib Khan, Cheuk Wai Lung, Irene M. C. Lo
The critical review covers the applications, associated mechanisms, challenges, and prospects of magnetically recyclable nanophotocatalysts in photocatalysis-related processes.
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Highly radiation-resistant Al-MOF selected based on the radiation stability rules of metal–organic frameworks with ultra-high thorium ion adsorption capacity

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00076E, Paper
Xiaofan Ding, Zhanjun Zhang, Xinyan Li, Ke Ma, Tiantian Jin, Zhaoning Feng, Tian Lan, Jing Zhao, Songtao Xiao
Al-MOF synthesized based on MOF irradiation stability rules exhibits high stability against β-irradiation and ultra-high thorium adsorption capacity, which proves its huge potential application value in the field of radionuclide adsorption.
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Regulating water decontamination and food safety by a reusable, nano-sized MOF@cotton@chitosan composite through nanomolar detection of the drug nitroxinil and organoarsenic feed additive p-arsanilic acid

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00066H, Paper
Subhrajyoti Ghosh, Debjit Mal, Shyam Biswas
MOF@cotton@chitosan composite for nanomolar fluorescence sensing of nitroxinil drug and p-arsanilic acid in real samples is presented.
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Regulating the type of nitrogen to improve the performance of Co–N/C with a confinement effect in peroxymonosulfate activation for the effective degradation of organic pollutants

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00145A, Paper
Yanqing Cong, Lingjie Ye, Qiuang Zheng, Yudi Wang, Yifan Shao, Xuhua Ren, Shi-Wen Lv
Three Co–N/C-based catalysts with different types of nitrogen are prepared and employed to activate peroxymonosulfate for tetracycline degradation.
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Mycogenic silver nanoparticles from Penicillium citrinum IB-CLP11 – their antimicrobial activity and potential toxicity effects on freshwater organisms

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00002A, Paper
Arthur Pérez Aguiar, Cristiane Angélica Ottoni, Claudia de Lima Ramos Aquaroli, Evelyn Caroline Vicente Mendes, Ana Lúzia de Souza Araújo, Marta Filipa Simões, Edison Barbieri
Silver nanoparticles (AgNPs) are some of the most attractive nanomaterials for commercial applications, but they can also be a very challenging issue from the point of view of cytotoxicity and phytotoxicity as agents that damage genetic information.
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High-performance TiO2 catalyst composited with In–1,1,2,2-tetra(4-carboxylbiphenyl)ethylene for the efficient degradation of organic pollutants

Environ. Sci.: Nano, 2024, 11,1533-1542
DOI: 10.1039/D3EN00820G, Paper
Xinyu Liu, Chenchen Li, Jian Nan, Ruike Liang, Huabin Wang, Rui Xu, Yong Zhang
A combination of metal–organic frameworks (MOFs) with TiO2 can improve the performance of TiO2 in the photocatalytic degradation of organic pollutants.
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Co-transport of ferrihydrite–organic matter colloids with Sb(V) in saturated porous media: implications for antimony mobility

Environ. Sci.: Nano, 2024, 11,1462-1476
DOI: 10.1039/D3EN00701D, Paper
Wenjian Mao, Dengjun Wang, Pan Wu, Jian Zhu, Peng Liao, Kaidi Lai, Zihan Ding, Yuqin Zhang, Zhongxu He, Ruyi Zheng, Yonglin Chen
Schematic diagram of the mechanism of Fe–NOM–Sb(V) colloids formation and transport in the natural environment.
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Crystallinity regulation induced organics degradation on Ultra-thin 2D Co3O4/SiO2 Nanosheets: the critical trigger of oxygen vacancy

Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D4EN00134F, Paper
Wenhui Bai, Hongze Lu, Yang Liu, Xue Yuan, Yuejie Ai, Lidong Wang, Zhe Chen
As an antibiotic drug, sulfamethoxazole (SMX) is a nitrogen-containing and sulfur-containing heterocyclic compound, which is an endocrine disruptor and difficult to be biodegraded. Not only can it exist stably in...
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Anatase TiO2 nanomaterials are much more effective in enhancing hydrolysis of organophosphorus compounds than their rutile counterparts

Environ. Sci.: Nano, 2024, Advance Article
DOI: 10.1039/D4EN00138A, Paper
Tong Li, Yiting Ju, Tingting Du, Chuanjia Jiang, Tong Zhang, Wei Chen
The crystalline phase significantly affects the efficiency of TiO2 nanomaterials in catalyzing hydrolysis reactions of organophosphates, primarily by modulating the surface Lewis acidity of TiO2.
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Two multifunctional Dy(III)-based metal–organic frameworks exhibiting proton conduction, magnetic properties and second-harmonic generation

CrystEngComm, 2024, 26,2033-2042
DOI: 10.1039/D4CE00065J, Paper
Ya-Qing Liao, Tian-Zheng Xiong, Kang-Le Xie, Huan Zhang, Jun-Jie Hu, He-Rui Wen
Two novelty Dy-MOFs were synthesized using H4DTTP-2OMe ligand. MOF 1 displays a more superior proton conductivity, field-induced single molecule magnets behavior and obvious second-order nonlinear optical properties.
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Synthesis, structure, and properties of helical bis-Zn(II) complexes of hexapyrrolic ligands

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00019F, Paper
Pinky Chauhan, Poornenth Pushpanandan, Mangalampalli Ravikanth
Bis(3-pyrrolyl BODIPY)s were used to prepare rare examples of hexapyrrolic ligands by demasking BF2 units. The hexapyrrolic ligands, without isolating, were used to prepare novel examples of double-stranded bis-Zn(II) helicate complexes.
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Pure organic TPB single crystal for direct X-ray detection

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00200H, Paper
Kai Jiang, Lingyan Xu, Rongjin Shang, Lu Liang, Yingming Wang, Zhentao Qin, Wanqi Jie
High-quality TPB single crystals were obtained without obvious step-like growth morphology. The TPB devices could present α-particle and γ-ray spectral responses with high energy resolution, showing potential for direct radiation detection.
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Synthesis and luminescent properties of three excellent yellow emissive Cu(I) complexes based on the diphosphine ligand and the diimine ligand

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00206G, Paper
Wen-Long Mou, Cheng-Jie Gao, Zi-Xi Li, Si-Jie Fan, Chuan-Bin Hou, Jing-Tong Zhao, Shuai Zhang, Zhong-Feng Li, Hong-Liang Han, Chun-Bo Duan, Guo Wang, Qiong-Hua Jin
High quantum yield (72–88%) yellow-emitting Cu(I) complexes obtained by tuning the nitrogen ligands and anions.
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Extended isomerism in heteronuclear metal-organic frameworks: synthetic strategies and crystal structures of lanthanide-cobalt-oxydiacetate systems

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00168K, Paper
Fernando Igoa, Agustín López Cabrera, Javier Gonzalez-Platas, Leopoldo Suescun, Carlos Kremer, Julia Torres
Here, we present the synthesis and crystal structure of a series of heteronuclear metal-organic frameworks, which consists of cobalt(II) and lanthanide(III) ions or yttrium(III), connected by oxydiacetato (oda2-) as ligand....
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Metal–organic polyhedron from a flexible tetrakis(thiobenzyl-carboxylate)-tetrathiafulvalene

CrystEngComm, 2024, 26,2072-2077
DOI: 10.1039/D3CE01251D, Paper
Yohan Cheret, Narcis Avarvari, Nicolas Zigon
Wiggle, wiggle… Stay! A redox-active tetrakis(thiobenzyl-carboxylate)-TTF with a high degree of flexibility stands still in a self-assembled cage upon complexation with Cu(II).
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Enantioselective enrichment of chiral 1-phenylethanol in the camphor-based chiral metal–organic framework CFA-22

CrystEngComm, 2024, 26,2051-2055
DOI: 10.1039/D4CE00181H, Communication
Richard Röβ-Ohlenroth, Katharina Knippen, Maryana Kraft, Dirk Volkmer
The novel enantioselective CFA-22 metal–organic frameworks were successfully developed and investigated for chiral adsorption separation of e.g. racemic 1-phenylethanol.
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Ionic liquid-functionalized metal organic frameworks and their composite membranes for enhanced proton transport

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00186A, Highlight
Jeong Hwa Song, Seyoung Koo, Dong Won Kang
Post-synthetic modification is gaining prominence as a highly effective strategy for enhancing the functionality of porous materials without significant structural changes. Recently, there is growing interest in research focusing on...
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Construction of a novel cuboid-shape Mn-Urea nanozyme with arsenic(V)-enhanced oxidase-like activity as a colorimetric probe for the selective detection of inorganic arsenic

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00148F, Paper
Jia-Li Wang, Ling-Xiao Chen, Guo-Ying Chen, Tong-Qing Chai, Jia-Xin Li, Hua Chen, Feng-Qing Yang
Development of a facile and reliable assay for arsenic (As) detection is crucial for its pollution control, which is a well-known heavy-metal pollutant in environment. In this work, an efficient...
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AlN interlayer-induced reduction of dislocation density in the AlGaN epilayer

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00191E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
David Maria Tobaldi, Luc Lajaunie, Arianna Cretì, Massimo Cuscunà, Iolena Tarantini, Marco Esposito, Gianluca Balestra, Mauro Lomascolo, Adriana Passaseo, Vittorianna Tasco
The emerging ultrawide-bandgap AlGaN alloy system holds promise for the development of advanced materials in the next generation of power semiconductor and UV optoelectronic devices. Within this context, heterostructures based...
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Structural diversity and tetrel bonding significance in lead(II) complexes with pyrazoylisonicotinoylhydrazone and varied anionic co-ligands

CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00325J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ghodrat Mahmoudi, Isabel Garcia-Santos, Roi Fernández-Vázquez, Rosa Maria Gomila, Alfonso Castineiras, Esmail Doustkhah, Ennio Zangrando, Antonio Frontera
Four lead(II) complexes featuring pyrazoylisonicotinoylhydrazone ligand paired with various anionic co-ligands (azido, thiocyanato, nitrito, and nitrato) were synthesized and thoroughly examined using structural, analytical, and spectroscopic techniques. These ligands, in...
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Facile syntheses, structures and photocatalytic properties of 3D iodoargentate frameworks derived from TM-flexible-amino-ligand templates

CrystEngComm, 2024, 26,2172-2179
DOI: 10.1039/D4CE00247D, Paper
Yan Gao, Xiao Yang, Taohong Ren, Dingxian Jia
3D iodoargentates [Co(en)3(Ag2I4)]n (1), [Fe(en)3(Ag2I4)]n (2) and [Co(dien)2(Ag2I4)]n·nH2O (3) were prepared by solvothermal methods. Compounds 1–3 were catalytic activity for photodegradation of crystal violet under visible light irradiation.
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Study on Raman scattering spectroscopy of Mn-doped GaN grown by the ammonothermal method

CrystEngComm, 2024, 26,2166-2171
DOI: 10.1039/D4CE00093E, Paper
Wenhao Lu, Tengkun Li, Guoqiang Ren, Zhenghui Xia, Kaihe Xie, Shaozhe Li, Liangkun Shen, Ke Xu
Mn-doped GaN crystals of a-plane and (11−22) plane were grown by the ammonothermal method.
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A highly stable hydrogen-bonded organic framework for hydrogen storage

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00245H, Communication
Jeong Hwa Song, Byeong Hak Jeon, Dong Won Kang
Multiple hydrogen bonds construct a porous crystalline network, known as a hydrogen-bonded organic framework (HOF), which can store a moderate amount of hydrogen gas.
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Centre extends deadline for Telangana millers for supply of rice to FCI

Asks State government to adhere to quality norms




gan

Telangana attracted ₹2.60 lakh crore investment during 2014-23

New Congress Govt to continue thrust on industrial growth with a focus on MSMEs




gan

By the banks of the Ganga

The writer recounts her visit to the International Yoga Festival earlier this year




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Songs of the River Ganga: Shantanu Moitra’s lyrical journey to self-discovery

The six-episode series traces the emotional and spiritual calling of the 55-year-old Bollywood music composer, explores his creative dimension and puts his physical mettle to the test



  • Life & Style

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Rahul Gandhi joins bypoll campaign in Wayanad, vows to make it global tourism hub

Campaigning for Priyanka Gandhi, Rahul Gandhi says people of Wayanad have taught him that the ‘word love has a great place in politics’




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Wayanad bypoll: Priyanka Gandhi leads roadshow with Rahul on last day of campaigning

Addressing the crowd after roadshow, Priyanka Gandhi expresses her appreciation for diverse communities within Wayanad constituency




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Wayanad bypoll: LDF accuses Priyanka Gandhi of ‘misusing’ religious places for election campaign, moves ECI

Complaint lodged by LDF Wayanad Parliamentary Committee says Congress violated electoral rules and regulations




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The Turing Transformation [electronic resource] : artificial intelligence, intelligence augmentation, and skill premiums / Ajay K. Agrawal, Joshua S. Gans, Avi Goldfarb

Cambridge, MA. : National Bureau of Economic Research, 2023




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Labor market impacts of reducing felony convictions [electronic resource] / Amanda Y. Agan, Andrew Garin, Dmitri K. Koustas, Alexandre Mas, Crystal Yang

Cambridge, MA. : National Bureau of Economic Research, 2023




gan

Gangster Chhota Rajan gets bail in 2001 hotelier murder case

Rajan filed an appeal in the HC against the conviction. He sought that the sentence be suspended and he be granted bail in the interim




gan

Allies squirm as BJP’s Batenge toh katenge slogan divides Mahayuti

Yogi Adityanath’s slogan speaks to the BJP’s support base, but the party’s allies fear consolidation of minority communities behind the Opposition




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Rakul-Jackky's First Ganpati

Film folk celebrate Ganesh Chaturthi by bringing Lord Ganesha home and making beautiful memories on social media.




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Tamannaah, Kiara Give Us Ganpati Fashion

Bollywood's divas have been giving us #FashionGoals for the Ganpati festival.




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Shilpa Shetty Bids Adieu To Ganpati

Like every year, Shilpa Shetty danced to dhol beats and welcomed Lord Ganesha home with gusto on Ganesh Chaturthi.




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Sunny Leone Welcomes Ganpati

Film folk celebrated Ganesh Chaturthi with gusto over the weekend, and posted pictures on social media.




gan

Taapsee-Kanika Return With Gandhari

Aditi-Siddharth at Apple event in California... Varun prays to Lalbaughcha Raja...What are Akshay and son looking at?




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WATCH: Ranbir Bids Farewell To Ganpati

Ranbir Kapoor and his mum Neetu Kapoor performed the annual Ganpati Visarjan on Wednesday.




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Salman Visits Eknath Shinde's Home For Ganpati Darshan

Film folk visited Maharashtra Chief Minister Eknath Shinde's residence for Ganpati darshan over the weekend.




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Bollywood Says Goodbye To Ganpati

As India bids adieu to Lord Ganesha on the occasion of Anant Chaturdashi, film folk rush to the pandals for one last visit.




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Cinema Loved Gandhi

Gandhi will now be seen in two upcoming OTT series -- Hansal Mehta's Gandhi, starring Pratik Gandhi in the title role, and Freedom at Midnight by Nikkhil Advani.




gan

Telangana bans egg-based Mayonnaise




gan

Telangana SPF takes over security of Secretariat from the TGSP




gan

Telangana: BR Naidu appointed TTD Board chairman




gan

Telangana government adopted Indiramma as role model: Revanth Reddy




gan

T'gana to constitute dedicated panel for survey on Backward Class quota




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Telangana to strictly enforce prohibition on caging of birds




gan

Trump temple in Telangana village back into focus