Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02023E, Research Article

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Roberto Paciotti, Davide Corinti, Cecilia Coletti, Nazzareno Re, Giel Berden, Jos Oomens, Simonetta Fornarini, Maria Elisa Crestoni
The [(Et₃P)AuCys]⁺ and [(Et₃P)AuSec]⁺ ions and their deamination products were characterized using IRMPD spectroscopy backed by DFT calculations finding differences in binding motifs and reactivity.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02072C, Research Article

Xin Zhao, Yajun Zhao, Yuan-Peng Li, Pengbo Lyu, Chunying Chen, Zong-Wen Mo, Chao Peng, Jiewei Liu, Li Zhang
A new approach was reported for regulating the charge transfer mechanism in a pyrene-based MOF composite, transitioning from a type-II to a Z-scheme configuration.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02012J, Research Article

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Shib Shankar Paul, Jan Novotný, Jakub Jakubec, Kateřina Petrláková, Pia Jurček, Klára Rašková, Michaela Kuchynka, Michal Masařík, Petr Kulhánek, Radek Marek
Host–guest complementarity is shown to influence the chemical activation by aquation and the biological activity of platinum(II) drugs.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01824A, Research Article

Qianyi Chen, Zhenjie Lun, Dongdan Chen, Yongsheng Sun, Puxian Xiong, Siyun Li, Shanhui Xu, Zhongmin Yang
A defect engineering strategy mediated by the structural cationic substitution is proposed and experimentally demonstrated for ultra-broadband emission in a garnet Y₃Sc₂Al₃O₁₂:B³⁺ phosphor.
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01996B, Research Article

Alexander V. Artem'ev, Maxim I. Rogovoy, Ilia M. Odud, Maria P. Davydova, Marianna I. Rakhmanova, Pavel A. Petrov, Valery K. Brel, Oleg I. Artushin, Konstantin A. Brylev, Denis G. Samsonenko, Alexey S. Berezin, Dmitry E. Gorbunov, Nina P. Gritsan
Tetraphosphine-carbene Cu(I), Ag(I) and Au(I) complexes, synthesized via a symmetry-based design strategy, exhibit cyan to yellow TADF with excellent quantum yields (58–89%) and reduced lifetimes.
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Inorg. Chem. Front., 2024, 11,7803-7811
DOI: 10.1039/D4QI01846J, Research Article

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Aarón Terán, Francesca Fasulo, Giarita Ferraro, Ana Edilia Sánchez-Peláez, Santiago Herrero, Michele Pavone, Ana Belén Muñoz-García, Antonello Merlino
The reactivity of [Ru₂Cl(D-p-CNPhF)(O₂CCH₃)₃]_n (D-p-CNPhF⁻ = N,N'-bis(4-cyanophenyl)formamidinate) with the model protein RNase A has been investigated by X-ray crystallography and Quantum Chemistry.
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Inorg. Chem. Front., 2024, 11,7886-7897
DOI: 10.1039/D4QI02020K, Research Article

Zhiyuan Liu, Qixuan Xiang, Hao Zhang, Xianglong Zhang, Huijun Tan, Yaping Zhao
Complete conversion of MgCo₂O₄ with excellent electrochemical performance has been successfully achieved.
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Inorg. Chem. Front., 2024, 11,7966-7978
DOI: 10.1039/D4QI02373K, Research Article

Pawel J. Bonarek, Mikolaj Zychowicz, Jan Rzepiela, Michal Liberka, Sebastian Baś, Jakub J. Zakrzewski, Szymon Chorazy
Dysprosium(III) single-molecule magnets are bridged within a coordination polymer by Pt(II)-cyanido metalloligands serving as their temperature sensors.
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Inorg. Chem. Front., 2024, 11,8130-8138
DOI: 10.1039/D4QI02088J, Research Article

Bei-Bei Zhang, Wen-Ye Gao, Wei Xu, Liang Ma, Wenlong Liu, Ru-Ling Tang, Sheng-Ping Guo
The acentric Ce(IV) fluoride NH₄Ce₃F₁₃ is systematically studied, exhibiting the strong SHG effect (1.2 × KDP) and high LIDTs (39 × AGS). It also possesses the largest band gap among NLO materials containing Ce(IV).
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Inorg. Chem. Front., 2024, 11,7898-7909
DOI: 10.1039/D4QI01765J, Research Article

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Huayun Shi, Guy J. Clarkson, Peter J. Sadler
The photochemotherapeutic activity of diazido Pt(IV) complexes towards bladder cancer, a common cancer with expensive treatment, has been tuned via modification of trans N-heterocyclic ligands, to give a candidate for preclinical development.
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Inorg. Chem. Front., 2024, 11,7921-7929
DOI: 10.1039/D4QI01818D, Research Article

Miriam Abán, J. Marco Cuenca, Irene Embid, Alba de Toro, Pilar Gómez-Sal, Ernesto de Jesús, Marta Valencia, Cristina G. Yebra
[CpIr(CO)H₂] efficiently catalyses formic acid dehydrogenation, forming in situ from pyridyl-triazole pre-catalysts [Cp*Ir(k²-NN)(Cl)][OTf]. Neat formic acid is dehydrogenated with a TON of up to 26876 and a TOF exceeding 10700 h⁻¹.
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Inorg. Chem. Front., 2024, 11,8025-8036
DOI: 10.1039/D4QI01804D, Research Article

Fangyuan Yu, Qifa Lin, Xiangfu Zeng, Ping Zhou, Xiao Wu, Cong Lin, Chunlin Zhao, Min Gao, Tengfei Lin, Xingan Jiang, Laihui Luo, Qiwei Zhang
Sr/Er was codoped in KNN ceramics to induce the coexistence of O and T phases, resulting in improving optical transparency, maintaining moderate ferroelectricity, inducing excellent PC behavior and fluorescence temperature sensing performance.
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Inorg. Chem. Front., 2024, 11,8110-8122
DOI: 10.1039/D4QI01934B, Research Article

Hongbo Zhou, Xuan Hao, Jiexin Guan, Yilin Deng, Zi Wei, Yashu Liu, Guoxing Zhu
The 2,2'-bpy coordination shells surrounding the Ni/Fe active sites of NiFe(2,2'-bpy)_n@CNT materials effectively boost OER catalysis.
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02372B, Research Article

Guo-guo Zhang, Pengtao Qiu, Jiaxin Kang, Zhiwei Lu, An-qi Zhu, Xiaohu Yu, Xuenian Chen
Solid-state potassium metal batteries have increasingly gained attention as promising alternatives in large-scale energy storage due to their safety and low cost. However, these batteries usually suffer from a lack...
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02383H, Review Article

Maiyong Zhu
Ionic liquids (ILs) as emerging solvents have demonstrated a significant prospective in green chemistry, which can be used as green solvent, high efficiency catalyst, electrolyte, and so on. Metal–organic frameworks...
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02016B, Research Article

Xiaoyu Jiang, Boran Tao, Hongda Li
A multistage construction of the Gd-doped g-C₃N₄/Mo₁₅S₁₉ catalyst, with Gd³⁺ as redox centers and Mo₁₅S₁₉ as N₂ activation sites, synergistically enhances its photocatalytic NRR performance.
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02280G, Research Article

Qixian Ren, Wangfei Che, Mengmeng Chen, Chen Cui, Yabo Wu, Zhi Su
Thioantimonates containing high oxidation state Sb5+ have proven to exhibit excellent performance in the design of new materials such as infrared optics crystals and lithium-ion batteries. However, as described by...
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02262A, Research Article

Tamara A. Bazhenova, Vyacheslav Kopotkov, Denis V. Korchagin, Elena Yureva, Michael V. Zhidkov, Alexey I Dmitriev, Ilya Yakushev, N. N. Efimov, Konstantin Andreevich Babeshkin, Vladimir Sergeevich Mironov, Eduard B. Yagubskii
A series of three new seven-coordinate pentagonal-bipyramidal (PBPY-7) Dy(III) complexes [Dy(L^CH3)(Cy₃PO)₂]ClO₄∙CH₃CN (1), [Dy(L^2(t-Bu))(Ph₃PO)₂]ClO₄∙0.63C₂H₅OH (2), [Dy(L^OCH3)(Ph₃PO)₂]ClO₄∙2H₂O (3) including various chelating pentadentate ligands with a [N₃O₂]²⁻ binding node in the equatorial plane,...
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Lab Chip, 2024, 24,1987-1995
DOI: 10.1039/D4LC00096J, Paper

Bin Guo, Chong Hu, Zeping Yang, Chu Tang, Chuanxian Zhang, Fu Wang
In this study, we employed Cas12a protein and enzyme-assisted cycle amplification technology with a test strip to establish a precise platform for the detection of UDG enzyme.
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Lab Chip, 2024, 24,2058-2068
DOI: 10.1039/D3LC00942D, Paper

Xiaoming Chen, Mo Shen, Shun Liu, Chungang Wu, Liangliang Sun, Zhipeng Song, Jishun Shi, Yulong Yuan, Yong Zhao
We develop a novel microfluidic impedance cytometer for analysis of marine microalgae by inserting ground flat-end cylindrical electrodes into microchannels.
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Lab Chip, 2024, 24,1977-1986
DOI: 10.1039/D3LC01017A, Paper

Liyu Dai, Xiaomin Wu, Huimin Hou, Zhifeng Hu, Yukai Lin, Zhiping Yuan
Cuboid pump systems driven by liquid metal multi-droplets using pillars to restrain the motion of droplets are designed, which achieve a significant increase in the flow rate of the pump.
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Lab Chip, 2024, 24,2122-2134
DOI: 10.1039/D3LC00945A, Paper

Meiying Zhao, Ye Tao, Wenshang Guo, Zhenyou Ge, Hanqing Hu, Ying Yan, Chaoxia Zou, Guiyu Wang, Yukun Ren
A multifunctional flexible magnetic drive gripper is synthetically designed to achieve active steering and carry out operations on different targets in a constrained environment by changing the external magnetic field.
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Lab Chip, 2024, 24,1887-1902
DOI: 10.1039/D3LC00507K, Paper

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Chu-Chun Liang, Po-Yen Chen, Nien-Che Liu, I-Chi Lee
A 3D neural spheroid-based system with an interstitial level of flow for simulating the brain microenvironment toward a dynamic amyloid-β induced neuronal toxic model was established. A real-time impedance recording was used to monitor the neural network formation and disconnection.
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Lab Chip, 2024, 24,2253-2261
DOI: 10.1039/D3LC01053H, Paper

Ziran Ye, Ping Lu, Yiben Chen, Zhixian Xu, Haixia Huang, Mingjia Zhi, Zi Ang Chen, Bo Yan
We present an efficient approach for the consecutive synthesis of Au–TiO₂ nanocomposites with controlled morphologies in a microfluidic chip.
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Lab Chip, 2024, 24,2262-2271
DOI: 10.1039/D4LC00055B, Paper

Kawin Khachornsakkul, Ruben Del-Rio-Ruiz, Lita Chheang, Wenxin Zeng, Sameer Sonkusale
A carbon dots and dopamine-imprinted polymer was immobilized onto a distance-based paper channel for simultaneous detection of three cytokine biomarkers without requiring expensive reagents and instruments.
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Lab Chip, 2024, 24,2202-2207
DOI: 10.1039/D4LC00014E, Paper

Matthew S. Viglione, Aubrianna Saxton, Dawson Downs, Adam T. Woolley, Kenneth A. Christensen, Pam M. Van Ry, Gregory P. Nordin
A new 3D printing method allows for fabrication of porous membranes with 7 μm pores. A device mimicking an organ-on-a-chip design is fabricated and seeded with living cells, demonstrating potential for diverse biological and mechanical applications.
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Lab Chip, 2024, 24,2306-2316
DOI: 10.1039/D3LC01045G, Paper

Sabah H. Al-Jaf, Sameera Sh. Mohammed Ameen, Khalid M. Omer
On-site monitoring of ions in drinking water is essential for safeguarding public health, ensuring high water quality, and preserving the ecological balance of aquatic ecosystems.
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Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00159A, Paper

Lixue Liang, Xueying Wang, Dong Chen, Palaniappan Sethu, Guruprasad A. Giridharan, Yanxia Wang, Yu Wang, Kai-Rong Qin
The best pulsation frequency mode of the RBP would be one that changes every 2–3 times of the cardiac cycle. The proposed in vitro microfluidic model could provide an effective platform to select the best working mode of the RBP for heart failure.
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Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00009A, Paper

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Bastián Carnero, Yago Radziunas-Salinas, Bruno K. Rodiño-Janeiro, Sylvana Varela Ballesta, M. Teresa Flores-Arias
The proposed hybrid technique for passive straight micromixer manufacturing by combining pulsed laser ablation and stereolithographic 3D printing.
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Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00193A, Paper

Marti Z. Hua, Shenmiao Li, M. S. Roopesh, Xiaonan Lu
A QD-MIP based microfluidic device to detect mycotoxin in food.
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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00354C, Perspective

Anne Gaffney, Debtanu Maiti, Debasish Kuila, Gennaro Mafia
With the ever-increasing demand for plastics, sustainable recycling methods is a key necessity.
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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00203B, Paper

Xi-Bao Zhang, Yin-Ning Zhou, Hao Chen, Zheng-Hong Luo, Liyang Zhou, Guojun Yu, Wenwu Liu, Shiping Zhu
A reactor's heat transfer efficiency can be significantly enhanced and the fluid temperature uniformity can be controlled through introducing cooling water in the agitator and regulating the flow ratio of cooling water in the agitator and jacket.
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React. Chem. Eng., 2024, 9,2915-2924
DOI: 10.1039/D3RE00417A, Paper

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Pinaki Ranadive, Faiz Khan, Jessica O. Winter, Nicholas Brunelli
Sequential jet mixing reactors enable core@shell nanomaterial synthesis.
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React. Chem. Eng., 2024, 9,3016-3028
DOI: 10.1039/D4RE00313F, Paper

Junnan Wang, Wei Zhan, Yating Li, Ting Wang, Chengxiang He, Chunying Zhu, Youguang Ma, Taotao Fu
The oxidation of glyoxal by nitric acid to glyoxylic acid is a complex process with parallel and consecutive side reactions.
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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00300D, Paper

Q. Shen, A. Pikalev, F. J. J. Peeters, J. Gans, M. C. M. van de Sanden
A two-temperature model with a vibrational temperature different from the gas temperature is presented for the decomposition of CO₂.
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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00406J, Paper

Judith Cabello-Romero, Román Torres-Lubián, Javier Francisco Enríquez-Medrano, Adrián Ochoa-Terán, Jesús Jara-Cortés, Iván Zapata-González
Transesterification of 2-(diethylamino)ethyl methacrylate (DEAEMA) with methanol leads to the formation of methyl methacrylate (MMA) and amino alcohol. This reaction significantly affects DEAEMA polymerization giving rise to poly(DEAEMA-co-MMA).
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React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4RE00509K, Paper

Minhazur Rahman Shawon, Chinwendu Umeojiakor, Anthony Griffin, Jeffrey S. Aguinaga, Jiachun Wu, Derek Patton, Zhe Qiang, Hossein Toghiani, Yizhi Xiang
Electrified catalytic processes for ammonia (NH3) decomposition have been considered as essential technologies for distributed COx-free hydrogen production. Here we show that efficient NH3 decomposition can be achieved over low-loading...
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Soft Matter, 2024, 20,2900-2914
DOI: 10.1039/D3SM01616A, Paper

Lucas Myers, Carter Swift, Jonas Rønning, Luiza Angheluta, Jorge Viñals
The structure of isolated disclinations and disclination dipoles in anisotropically elastic nematic liquid crystals is explored via a singular potential computational model.
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Soft Matter, 2024, 20,2937-2954
DOI: 10.1039/D3SM01749D, Paper

Xuankun Gong, Amatjan Sawut, Rena Simayi, Ziyue Wang, Yurou Feng
A novel composite hydrogel with exceptional adsorption and photocatalytic properties was synthesized using modified coal-based humic acid (HA-C), modified titanium dioxide (TiO₂) nanoparticles, acrylic acid (AA), and acrylamide (AM) as precursors.
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Soft Matter, 2024, 20,2926-2936
DOI: 10.1039/D3SM01417G, Paper

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Ryotaro Miki, Tsutomu Yamaki, Masaki Uchida, Hideshi Natsume
A self-healing hydrogel can be easily prepared at physiological pH by using phenylboronic acid-modified hyaluronic acid and salicylic acid-modified hyaluronic acid.
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Soft Matter, 2024, 20,3021-3021
DOI: 10.1039/D4SM90038C, Correction

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Yang Lin, Junqiang Mao, Qingrui Fan, Jianjun Wang
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Soft Matter, 2024, 20,3143-3153
DOI: 10.1039/D3SM01717F, Paper

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M. Gimperlein, Jasper N. Immink, M. Schmiedeberg
Dilute and dense systems differ in the way structural properties emerge. Two regimes of percolation might be responsible for differences. Global and local structural properties give insights into these differences.
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Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00288A, Paper

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Masaki Yoshikai, Muneyuki Matsuo, Nobuhiko J. Suematsu, Hiraku Nishimori, Satoshi Nakata
We studied circular papers impregnated with camphor (CPs) and CPs with magnets (MCPs) as self-propelled objects floating on water under the compression of the water surface as an inanimate system for evacuation in an emergency.
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Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00047A, Paper

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Ruixin Lu, Peng Yu, Yi Sui
The inertial effect increases the cell deformation and membrane damage in the channel cross-slot; however, the enhancement can be reversed by the cell membrane viscosity.
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Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00117F, Paper

Manas Kumar Pradhan, Nayanika Misra, Fathima Sahala, Nyaya Prakash Pradhan, Aasheesh Srivastava
Enantiomeric single phenylalanine derivatives demonstrate very different self-assembling propensity and thermodynamic parameters associated with self-assembly.
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Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00188E, Paper

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A. N. Semenov, I. A. Nyrkova
The quantitative transfer matrix approach and scaling arguments in terms of trains, loops, tails and supertrains allowed us to characterize the main regimes of semiflexible chain adsorption on a bar and double-chain complex formation.
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Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D4SM00144C, Paper

Ramanand Singh Yadav, Sanaa Sharma, Ralf Metzler, Rajarshi Chakrabarti
Using computer simulations in two dimensions (2D), we explore the structure and dynamics of a star polymer with three arms made of passive monomers immersed in a bath of active...
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Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00216D, Paper

Yuting Wan, Yuening Qiu, Jin Zhou, Jinbo Liu, Martien A. Cohen Stuart, Yangfeng Peng, Junyou Wang
Stable and permeable polyion complex vesicles designed as enzymatic nanoreactors.
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Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D4SM00048J, Tutorial Review

Chenxian Xu, Yiran Zhang, Vivek Sharma
Freshly formed soap films, soap bubbles, or foam films display iridescent colors due to thin film interference that changes as squeeze flow drives drainage and a steady decrease in film...
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Soft Matter, 2024, Advance Article
DOI: 10.1039/D3SM01116J, Paper

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Max Sonzogni, Jean-Mathieu Vanson, Katerina Ioannidou, Yvan Reynier, Sébastien Martinet, Farhang Radjai
The compaction of cohesive granular materials is a common operation in powder-based manufacture of many products.
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