r

Biodegradable polymers: from synthesis methods to applications of lignin-graft-polyester

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,10774-10803
DOI: 10.1039/D4GC03558E, Tutorial Review
Open Access
Sundol Kim, Hoyong Chung
Biodegradable lignin-based grafted polyesters have wide range of applications.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Light-driven ultrafast dual C–C cleavage and coupling of dihydroxyacetone into high-purity carbon monoxide and ethylene glycol

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,10859-10866
DOI: 10.1039/D4GC04180A, Paper
Fanhao Kong, Hongru Zhou, Zhiwei Chen, Zhaolin Dou, Min Wang
Reforming of biomass-based dihydroxyacetone to produce high-purity CO and ethylene glycol is achieved via a distinctive photochemical process under ambient conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Evaluation on the recovery of lignin from basic [Ch][Lys] systems using low-cost alcohols as anti-solvents under acid-free conditions

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,10950-10959
DOI: 10.1039/D4GC03898C, Paper
Yichen Liu, Wanting Zhao, Qizhen Luo, Jipeng Yan, Jian Sun
An acid-free, high efficiency, and mild method of precipitating and separating lignin from basic ionic liquids (BIL) such as choline lysinate ([Ch][Lys]) by using alchohols (such as tert-butanol) as anti--solvents.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Green and controllable synthesis of symmetrical and unsymmetrical difluoromethylated diarylmethanes via a direct bisarylation strategy enabled by an HFIP–B(C6F5)3 adduct

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,10969-10974
DOI: 10.1039/D4GC03917C, Paper
Xindi Li, Yiping Zhu, Zhina Gong, Jinshan Li, Jialin Xie, Zhendong Zhao, Jianwei Li, Chunman Jia
An efficient and environmentally friendly for the synthesis of symmetrical and unsymmetrical difluoromethylated diarylmethanes via direct bisarylation of difluoroacetaldehyde hemiacetal with aniline enabled by HFIP–B(C6F5)3 adduct is described.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

A sequential flow process of CO2 capture and conversion using cost-effective porous organic polymers

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,10960-10968
DOI: 10.1039/D4GC03494E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Zhongqi Wu, Zhong Li, Lei Hu, Samson Afewerki, Maria Strømme, Qian-Feng Zhang, Chao Xu
A sequential flow process utilizing cost-effective porous organic materials to capture CO2 and directly convert it into fine chemicals has been achieved, which could improve the practical applicability of CO2 capture and utilization technologies.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Straightforward solid-phase modification of TiO2 with propylphosphonic acid via manual grinding and shaker mixing: enhancing modification degree by thermal control while improving atom economy

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,10907-10920
DOI: 10.1039/D4GC03330B, Paper
Open Access
Kaimin Zhang, Jinxin Wang, Nick Gys, Elien Derveaux, Nahal Ghanemnia, Wouter Marchal, Peter Adriaensens, Vera Meynen
The straightforward manual grinding method achieves controllable grafting of organophosphonic acid onto TiO2, demonstrating its atom economy and greenness.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Monoliths enabling biocatalysis in flow chemistry

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,10718-10738
DOI: 10.1039/D4GC03535F, Critical Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Aleksandra Lambarska, Katarzyna Szymańska, Ulf Hanefeld
Biocatalysis in flow improves space time yields and enables straightforward downstream processing. The underlying principles of monolithic flow reactors and their application in mono- and bi-phasic biocatalytic systems are discussed.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Research progress on photocatalytic, electrocatalytic and photoelectrocatalytic selective oxidation of 5-hydroxymethylfurfural

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,10739-10773
DOI: 10.1039/D4GC03597F, Critical Review
Yang An, Tao Lei, Weiyi Jiang, Huan Pang
This paper summarizes the latest research progress in selective photocatalytic, electrocatalytic, and photoelectrocatalytic oxidation of HMF, along with the reaction mechanisms, advantages, and challenges faced during selective HMF oxidation.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Synthesis of axially chiral thiourea by NHC-catalyzed desymmetrizative amidation

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,10940-10949
DOI: 10.1039/D4GC03113J, Paper
Yingtao Wu, Xin Guan, Kehan Jiao, Huaqiu Zhao, Mingrui Li, Jiaqiong Sun, Guangfan Zheng, Qian Zhang
NHC-catalyzed desymmetrization amidation of biaryl dialdehydes has been developed for NH-free axially chiral thiourea. Sequential kinetic resolution enhances the chirality induction of the desymmetrization strategy, expanding the applicable scope.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Lipase-entrapped colloidosomes with light-responsive wettability for efficient and recyclable Pickering interfacial biocatalysis

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,10824-10828
DOI: 10.1039/D4GC03982C, Communication
Dingyi Yang, Qi Zeng, Kaiwen Tan, Haoyue Hou, Xingyuan Fang, Chenlong Guo, Hao Yuan, Tao Meng
We prepared lipase-entrapped TiO2 colloidosomes with excellent recyclability for light-responsive Pickering interfacial biocatalysis, providing a green, recyclable and efficient Pickering interfacial biocatalysis platform.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Metal-free photoinduced-radical hydrocyclization of 2-isocyanides: a unified synthetic approach to facilely assemble diverse N-heteroarenes

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,10804-10810
DOI: 10.1039/D4GC03774J, Communication
Ziyi Wang, Haonan Wei, Jinrong Du, Zhijun Zuo
We present an efficient and sustainable protocol for the photoinduced-radical hydrocyclization of isocyanides, providing a united route to assemble diverse α-unsubstituted N-heteroarenes.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Electroreductive deoxygenative carboxylation of alkyl oxalates with CO2

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,10811-10817
DOI: 10.1039/D4GC03452J, Communication
Yong Yuan, Hangfei Jiang, Ya-Nan Zhang, Yuyan Tao, Xincong Liu, Congde Huo
An electroreductive deoxygenative carboxylation of alkyl oxalates with CO2 is demonstrated.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Electrochemistry-enabled Rh-catalyzed regioselective [4 + 1] and [4 + 2] cycloaddition of benzoic acid with alkynyl esters/amides

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,10996-11002
DOI: 10.1039/D4GC03753G, Paper
Wei-Jung Chiu, Chung-Ming Sun
The reaction of benzoic acids with alkynyl esters/amides in the presence of a Rh-catalyst and AcOH as an additive to give phthalides by [4 + 1] annulation. In contrast, the additive NaOAc exclusively affords isocoumarins through the [4 + 2] pathway.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Electroreductive deuteration of N-propynylamides to enamides

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,10975-10981
DOI: 10.1039/D4GC03790A, Paper
Qiansong Gao, Mingchun Wang, Lianyou Zheng, Lingling Shi, Cheng Wu, He Li, Jinbao Xiang
A migratory reductive deuteration of terminal alkynes to access enamides with more than 3 deuteriums incorporated per molecule was realized.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Light-induced isomerization of quinoline-N-oxide derivatives through Zn-catalysis: a photochemical approach for synthesizing 2-quinolinone derivatives

By pubs.rsc.org
Published On ::

Green Chem., 2024, 26,10818-10823
DOI: 10.1039/D4GC03226H, Communication
Xiaoqiang Yu, Sana Yang, Ning Yan, Yukang Fu, Yang Li, Wanhui Wang, Ming Bao
The light-induced Zn-catalyzed isomerization of quinoline-N-oxides proceeded smoothly to afford 2-quinolinone derivatives via intramolecular hydrogen and oxygen transfer.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Visible light-driven α-sulfonylation of ketone-derived silyl enol ethers via an electron donor–acceptor complex

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04554H, Paper
Barakha Saxena, Roshan I. Patel, Anuj Sharma
We herein describe a versatile electron donor–acceptor complex (EDA) mediated α-sulfonylation of ketone-derived silyl enol ethers using thiosulfonates (acceptor) with DABCO (donor) under visible light irradiation.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Postliminary treatment of food-waste digestate via combined hydrothermal carbonization and microbial fuel cell for bio-energy recovery: a comparative life cycle impact assessment

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04081C, Paper
Shraddha Yadav, Manikanta M. Doki, Makarand M. Ghangrekar, Brajesh K. Dubey
Multiple resource recovery from food-waste digestate by deploying hydrothermal carbonisation and microbial fuel cells. A green route for environmental sustainability and economic gains.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Controllable tertiary amine-promoted photoactivation metal-free carbonylation of aryl sulfonium salts to aryl carboxylic acid derivatives

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04502E, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jiajun Zhang, Le-Cheng Wang, Yuanrui Wang, Xiao-Feng Wu
This paper describes a new method for the activation of aryl radicals via EDA complexes without metals and photosensitizers for carbonylation with various nucleophilic reagents under visible light.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

A solvent-free, self-emulsified and heat-responsive polyester coating enables chemically-recyclable and fire-safe PET foam

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04531A, Paper
Bei-Bei Zhang, Li-Xia Fan, Lin Chen, Xiu-Li Wang, Yu-Zhong Wang
This work implements a state-of-the-art strategy to simultaneously achieve use performance and future recycling, which will greatly benefit the green sustainable circular economy for wind turbine blades.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Does enzymatic catalysis lead to more sustainable chemicals production? A life cycle sustainability assessment of isopropyl palmitate

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04514A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Pieter Nachtergaele, Ozan Kocak, Yblin Roman Escobar, Jordy Motte, Dries Gabriels, Leopold Mottet, Jo Dewulf
A methodology is presented for assessing the life cycle sustainability of enzymatic catalysis for chemicals production. For IPP, lower environmental impacts, but higher costs and social risks were found for switching to enzymatic catalysis.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Valorization of pomegranate waste through green solvent extraction and biochar production: a zero-waste biorefinery approach

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC03707C, Paper
Leonardo M. de Souza Mesquita, Letícia S. Contieri, Bárbara M. C. Vaz, Vitor Sencadas, Filipe H. B. Sosa, João A. P. Coutinho, Maurício A. Rostagno, Sónia P. M. Ventura
This study presents a zero-waste biorefinery for pomegranate waste, extracting anthocyanins and ellagic acid with green solvents and converting leftovers to biochar.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Flow electrosynthesis of phosphinamides and phosphoramidates through P–N coupling

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04450A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tribani Boruah, Ren Ishizeki, Alberto Roldan, Rebecca L. Melen, Thomas Wirth
A robust flow electrochemical method for P–N and P–O oxidative coupling under mild conditions has been developed. Cyclic voltammetry (CV) was employed to investigate the redox behaviour of reactants.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Modular access to multi-substituted allenones via environmentally friendly organocatalytic C–H allenylation of aldehydes

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04550E, Paper
Xinying Hu, Ayisenbati Jialingbieke, Yuzhi Ren, Yifan Yang, Donghui Wei, Jian Gao, Ding Du
Organocatalytic direct C–H allenylation of aldehydes with propargyl bromides has provided a straightforward and step-economical strategy for allenone modular synthesis.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Advancing green chemistry in environmental monitoring: the role of electropolymerized molecularly imprinted polymer-based electrochemical sensors

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC03250K, Tutorial Review
Christopher Mwanza, Wei-Zhi Zhang, Kalulu Mulenga, Shou-Nian Ding
Molecularly imprinted polymers (MIPs) are synthetic materials designed to mimic the natural “lock and key” mechanism observed in biomolecular systems, such as the interactions between antibodies and antigens.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

The Effects of Polyolefin Structure and Source on Pyrolysis-Derived Plastic Oil Composition

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04029E, Paper
Jiayang Wu, Zhen Jiang, Victor S Cecon, Greg W. Curtzwiler, George W. Huber, Keith L. Vorst, Manos Mavrikakis
Seven types of plastics were pyrolyzed in a fluidized bed reactor: post-consumer recycled (PCR) high-density polyethylene (HDPE), PCR polypropylene (PP), virgin resins of varying molecular weights of HDPE, virgin resins...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Continuous-flow Synthesis of Cyclic Carbonates with Polymer-supported Imidazolium-based Ionic Liquid (Im-PSIL) Catalysts

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04499A, Communication
Open Access
Zhibo Yu, Haruro Ishitani, Shu Kobayashi
Carbon dioxide (CO2), a major greenhouse gas emitted through human activities, represents a valuable carbon source for chemical production. However, maximizing its efficiency requires novel methods for CO2 conversion that...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Catalytic hydrodeoxygenation and C–C coupling of lignin and its derivatives into renewable jet-fuel-range cycloalkanes

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC02051K, Critical Review
Xinyong Diao, Ying Xiong, Yawen Shi, Longlong Ma, Chenglong Dong, Shengbo Zhang, Na Ji
This review provides an in-depth understanding of the synthesis pathways and corresponding catalytic systems for the production of jet-fuel-range cycloalkanes from lignin and its derivatives via catalytic hydrodeoxygenation and C–C coupling.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Advances in catalytic chemical recycling of synthetic textiles

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04768K, Tutorial Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Carmen Moreno-Marrodan, Francesco Brandi, Pierluigi Barbaro, FRANCESCA LIGUORI
Synthetic fibres cover most of textile market, but their value chain is almost entirely linear. Common raw materials are non-renewable and oil-derived, while requiring large amounts of (toxic) chemicals and...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

A Comparative Study of 5-(Chloromethyl)furfural and 5-(Hydroxymethyl)furfural

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04609A, Tutorial Review
Sabah Karimi, Saeideh Gharouni Fattah, Zheng Li, Miao Zuo, Mahmoud Nasrollahzadeh, Xianhai Zeng
There has been a growth in research focusing on versatile platform molecules from biomass, such as 5-(chloromethyl)furfural (CMF) and 5-(hydroxymethyl)furfural (HMF), since they can produce a wide range of beneficial...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Green synthesis of N-sulfonyl amidine using a CuI-incorporated CoFe2O4 nano-catalyst in aqueous medium

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04033C, Paper
Samrat Charaimuria, Prodeep Phukan
A magnetically separable nanocatalyst has been developed by the incorporation of CuI on the functionalized surface of cobalt ferrite nanoparticles for the synthesis of N-sulfonyl amidines in aqueous medium at ambient temperature.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Engineering high-valence nickel sites in Ni3S2/Ni3Se2 architectures enabling urea-assisted hydrogen evolution reactions

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04318A, Paper
Taotao Ai, Miaomiao Bai, Weiwei Bao, Jie Han, Xueling Wei, Xiangyu Zou, Jungang Hou, Lizhai Zhang, Zhifeng Deng, Yuxin Zhang
Bifunctional Ni3S2@Ni3Se2 electrocatalysts were constructed for urea-assisted hydrogen evolution. In the HER/UOR two-electrode system, the heterogeneous interface modulates the electronic structure and thus improves the catalytic performance.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Engineering in situ: N-doped porous carbon-confined FeF3 for efficient lithium storage

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04097J, Paper
Open Access
Jinlong Hu, Weijun Xu, Lingzhi Zhang
Achieving N-doped porous carbon-confined FeF3 with enhanced lithium storage performance via an innovative in situ engineering approach.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

In silico modeling enables greener analytical and preparative chromatographic methods

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04300F, Paper
Troy T. Handlovic, Daipayan Roy, Muhammad Qamar Farooq, Gabriel Mazzi Leme, Kevin Crossley, Imad A. Haidar Ahmad
Environmental impact of chromatographic separation at both analytical and preparative scale can be significantly reduced using In Silico Modeling.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Hypervalent iodine chemistry with a mechanochemical twist

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04903A, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sayad Doobary, Miguel M. de Vries Ibáñez, Berit Olofsson
An assessment of mechanochemistry's utility with hypervalent iodine reagents highlighted its effectiveness, which showed better selectivity, reaction times and differing reactivity.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

CO2 catalyzed recycling of polyester and polycarbonate plastics

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04782F, Paper
Open Access
Qiao Zhang, Nan Wang, Chenyang Hu, Peng-Yuan Li, Fu-Quan Bai, Xuan Pang, Xuesi Chen, Xianhong Wang
CO2 was found to be an efficient catalyst for depolymerizing common waste polyesters and polycarbonates via alcoholysis, yielding valuable organic molecules. CO2 was considered a Lewis acid–base pair, activating both polymers and alcohol.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Single-layer 2D supramolecular-organic-framework-supported polyoxometalates: efficient selective oxidation of toluene in seawater under sunlight

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04480K, Paper
Xin-Long Ni, Yan Fan, Yi Luo, Xu Luo
Performing organic reactions in water, in particular in seawater under sunlight, is a desirable objective in chemistry because both are the most abundant and cheapest resources on earth. Herein, we...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Photo-Induced FeCl3-catalysed direct denitrative chlorination of (hetero)nitroarenes at room temperature

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04210G, Communication
Mingjing Deng, Ke Liu, Zhaolun Ma, Guanzhong Luo, Longyang Dian
We present herein an iron-catalyzed denitrative chlorination of (hetero)nitroarenes at room temperature under visible light irradiation. In this study, FeCl3 catalyzed direct chlorination was achieved through denitrative chlorination under light...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Single cobalt atom catalysis for the construction of quinazolines and quinazolinones via the aerobic dehydrocyclization of ethanol

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04928D, Paper
Xueping Zhang, Kai Xu, Yi Zhuang, Shihao Yuan, Yamei Lin, Guo-Ping Lu
It is still a significant and challenging for the synthesis of N-heterocycles through the aerobic dehydrocyclization of ethanol since ethanol is the largest renewable small molecule feedstock but with high...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Biological production and simulated moving bed purification of streptothricin F from food waste digestate

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04026K, Paper
Xiaofang Zhou, Peiyi Li, Yuchen Sun, Zeyang Zhang, Chuanyi Yao, Qingbiao Li, Yuanpeng Wang
Globally, a significant amount of food waste is generated annually, representing a considerable potential resource.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Rational modulation of cellulose for zinc ion-based energy storage devices

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC03525A, Tutorial Review
Penggao Liu, Chunrong He, Xinyue Chen, Ting Wang, Wei Song, Weifang Liu, Kaiyu Liu
Aqueous zinc-ion energy storage technology is currently undergoing intensive exploration. The construction of high-efficiency batteries remains a significant obstacle to the further advancement of novel battery types and enhanced electrochemical...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Green dipolar aprotic solvents for the dynamic polycondensation of high-performance polyimide membranes

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04279D, Paper
Open Access
E. San José, M. R. de la Viuda, F. J. Carmona, C. Soto, L. Palacio, P. Prádanos, A. Hernández, A. Tena
Guidelines for the evaluation of green solvents were revisited and integrated into a decision diagram. GVL, Cyrene™, DMC, NOP, DEC, DMI, GBL, NBP, Rhodiasolv® PolarClean, and DMSO showed the potential to substitute hazardous polar aprotic solvents.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

(B,P,Co,Fe)-Ni Modified on Nanowood for Boosting Seawater Urea Electro-Oxidation

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC05156D, Paper
Hongjiao Chen, Kewei Zhang, Yanzhi Xia, Jian Li, Bin Hui
Coupling urea oxidation reaction (UOR) and hydrogen evolution reaction (HER) in seawater is desirable to produce sustainable and green hydrogen due to the reduced energy consumption. However, developing high-performance UOR/HER...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Crystalline/amorphous c-NiMo/a-NiMoOx nanoarrays for urea-assisted energy-saving H2 production in alkaline seawater

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC05042H, Paper
Dongxue Guo, Yi Ping, Chuanjiao Wang, Changan Hou, Danhong Wang
Electrocatalytic seawater splitting is regarded as the most effective method for producing green hydrogen (H2), but it faces issues of high energy consumption and harmful chlorine evolution side reactions. Replacing...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

N–N atropisomer synthesis via electrolyte- and base-free electrochemical cobalt-catalysed C–H annulation

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04390A, Communication
Jiating Cai, Linzai Li, Chuitian Wang, Shi Qin, Yuanyuan Li, Si-Yan Liao, Shengdong Wang, Hui Gao, Zhi Zhou, Yugang Huang, Wei Yi, Zhongyi Zeng
An exogenous electrolyte- and base-free electrochemical cobalt-catalysed atroposelective C–H annulation has been established to construct N–N axially chiral isoquinolinones in excellent enantioselectivities and good yields.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Photo-driven reduction/cyclization of nitroarenes via electron donor–acceptor complexes: a novel method for the acquisition of N-heterocycles

By pubs.rsc.org
Published On ::

Green Chem., 2024, Advance Article
DOI: 10.1039/D4GC04082A, Communication
Bin Sun, Chun Lv, Xiaohui Zhuang, Yan Xu, Haijing Song, Jiayin Wang, Zhaokang Zhang, Jiayang Wang, Can Jin
An EDA complex-based method for the reduction/cyclization of nitroarenes to obtain N-heterocycles with H2O as a clean by-product is presented.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Active Hydrogen Tuning by Copper-Cobalt Bimetal Catalysts for Boosting Ammonia Electrosynthesis from Simulated Waster Water

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04120H, Paper
Chunqi Yang, Chang Liu, Jingwen Zhuang, Ziyan Yang, Aiping Chen, Yuhang Li, Chunzhong Li
Electrochemical nitrate reduction reaction (NO3RR) represents a promising approach to balance the nitrogen cycle, converting environmental pollutant NO3− to valuable ammonia (NH3). However, the whole reaction involves complex protons-coupled electron...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

High Efficiency Leaching of Valuable Metals from Waste Lithium-ion ternary Batteries under Mild Conditions Using Green Deep Eutectic Solvents

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04373A, Paper
Bo Li, Zhengfu Zhang, Chengping Li, Jinsong Wang, Rundong Wan, Jiangzhao Chen, Ying Liu, Yuejing Bin, xiaoping yang, Chongjun Bao, Shaohua Ju
Recently, the production and demand for lithium-ion batteries (LIBs) has increased owing to increasing number of electric vehicles and products. This surge has considerably increased spent LIBs, leading to environmental...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Multi-task Rhodium-Catalyzed Remote C(sp3)–H Functionalization Reactions of Acyclic Dienes to Yield Benzene-fused Heterocycles

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04927F, Paper
Yuta Sato, Momoko Nagafuchi, Masaharu Takatsuki, Tsuyoshi Matsuzaki, Takeyuki Suzuki, Makoto Sako, Mitsuhiro Arisawa
Remote C(sp3)–H bond functionalization reactions are environmentally benign methods for not only acyclic molecules but also cyclic molecules. However, previous reports' products have been limited to aliphatic five-membered ring structures....
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

The Chemistry of Oleates and Related Compounds in 2020s

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC04862H, Tutorial Review
Pavel V. Ivchenko, Ilya E. Nifant'ev
The use of renewable resources as an alternative to fossil raw materials is one of the topical directions of modern science. Consistent efforts are being taken to find the most...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

r

Production of propyl 4-hydroxybenzoate via selective hydrogenolysis of lignin catalyzed by Ni/MFI-ns

By pubs.rsc.org
Published On ::

Green Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4GC05260A, Paper
Lixia Li, Yinan Rao, Menghao Jiang, Jinxing Long
Selective conversion of lignin macromolecules into aromatic monomers is of great significance but remains a great challenge. Here, we present a metallic Ni supported on hierarchical multilamellar MFI nanosheets (MFI-ns)...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article