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The critical effect of water content in the electrolyte on the reversible electrochemical performance of Zn–VPO4F cells

J. Mater. Chem. A, 2020, 8,8262-8267
DOI: 10.1039/D0TA01622E, Communication
Hooman Yaghoobnejad Asl, Shyam Sharma, Arumugam Manthiram
The critical role of water as a source of H+ working ions and reactive species in the Zn–VPO4F electrochemical system with an ionic liquid electrolyte.
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Insight into the correlation of Pt–support interactions with electrocatalytic activity and durability in fuel cells

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA01530J, Review Article
Subramaniam Jayabal, Govindarajan Saranya, Dongsheng Geng, Lu-Yin Lin, Xiangbo Meng
This review aims at providing an overview of the interactions between Pt and supports from experimental and theoretical results, in the hope of correlating the metal–support interactions with the activity and durability of the catalysts in fuel cells.
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Understanding the mechanism of byproduct formation with in operando synchrotron techniques and its effects on the electrochemical performance of VO2(B) nanoflakes in aqueous rechargeable zinc batteries

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA00858C, Paper
Qiang Pang, Hainan Zhao, Ruqian Lian, Qiang Fu, Yingjin Wei, Angelina Sarapulova, Junqi Sun, Chunzhong Wang, Gang Chen, Helmut Ehrenberg
The byproduct protects the vanadium-based positive electrode of ARZBs and facilitates Zn2+ insertion into the electrode.
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A universal cross-linking binding polymer composite for ultrahigh-loading Li-ion battery electrodes

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA00714E, Paper
Dong Wang, Qian Zhang, Jie Liu, Erying Zhao, Zhenwei Li, Yu Yang, Ziyang Guo, Lei Wang, Shanqing Zhang
A general, facile-operability, and sustainable strategy to achieve ultrahigh-loading electrodes has been proposed that is simply replacing the traditional PVDF binder with an eco-friendly and robust c-PAA-XG binder with a high-efficiency damper.
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UV-cured eutectic gel polymer electrolytes for safe and robust Li-ion batteries

J. Mater. Chem. A, 2020, 8,8485-8495
DOI: 10.1039/D0TA01901A, Paper
Matthew W. Logan, Spencer Langevin, Bing Tan, Adam W. Freeman, Christopher Hoffman, Douglas B. Trigg, Konstantinos Gerasopoulos
We report UV-cured eutectic gel polymer electrolytes that improve cell performance, non-flammability, and water tolerance compared to the liquid solvent.
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A disorder-free conformation boosts phonon and charge transfer in an electron-deficient-core-based non-fullerene acceptor

J. Mater. Chem. A, 2020, 8,8566-8574
DOI: 10.1039/D0TA01260B, Paper
Chujun Zhang, Jun Yuan, Ka Lok Chiu, Hang Yin, Weifang Liu, Guanhaojie Zheng, Johnny Ka Wai Ho, Suzhen Huang, Gaoxing Yu, Feng Gao, Yingping Zou, Shu Kong So
A disorder-free molecular conformation caused by alkyl side chains facilitates electron transport, heat transfer and reduces electronic disorder.
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The highly efficient collection of underwater oil droplets on an anisotropic porous cone surface via an electric field

J. Mater. Chem. A, 2020, 8,8605-8611
DOI: 10.1039/D0TA02055A, Paper
Yufeng Yan, Qiuya Zhang, Yan Li, Zhenyan Guo, Dongliang Tian, Xiaofang Zhang, Lei Jiang
The highly efficient collection of underwater oil droplets on an anisotropic porous cone surface via an electric field was demonstrated.
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Achieving a 2.7 V aqueous hybrid supercapacitor by the pH-regulation of electrolyte

J. Mater. Chem. A, 2020, 8,8648-8660
DOI: 10.1039/D0TA02926B, Paper
Lijun Su, Qingnuan Zhang, Yue Wang, Jianing Meng, Yongtai Xu, Lingyang Liu, Xingbin Yan
We present an effective electrolyte pH-regulation strategy for cation-intercalated manganese oxides to extend the voltage window of aqueous supercapacitors.
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Decoupled electrolytes towards enhanced energy and high temperature performance of thermally regenerative ammonia batteries

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03236K, Paper
Weiguang Wang, Gequn Shu, Xiuping Zhu, Hua Tian
An electrolyte decoupling strategy is proposed for ammonia batteries to restrain the self-discharge and enhance energy density as well as power generation at high temperatures.
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Hexagonal boron nitride induces anion trapping in a polyethylene oxide based solid polymer electrolyte for lithium dendrite inhibition

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03677C, Paper
Yuhan Li, Libo Zhang, Zongjie Sun, Guoxin Gao, Shiyao Lu, Min Zhu, Yanfeng Zhang, Zhiyu Jia, Chunhui Xiao, Huaitian Bu, Kai Xi, Shujiang Ding
Lithium ion conductivity and mechanical strength of a PEO based composite solid polymer electrolyte are improved by adding h-BN.
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A highly efficient artificial light-harvesting system with two-step sequential energy transfer based on supramolecular self-assembly

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03169K, Paper
Guangping Sun, Weirui Qian, Jianmin Jiao, Tingting Han, Yukun Shi, Xiao-Yu Hu, Leyong Wang
An efficient artificial light-harvesting system with two-step sequential energy transfer has been successfully constructed based on supramolecular self-assembly.
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Optical in-situ monitoring during the synthesis of halide perovskite solar cells reveals formation kinetics and evolution of optoelectronic properties

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA01237H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Klara Suchan, Justus Just, Pascal Becker, Eva Lisa Unger, Thomas Unold
The formation mechanism and the evolution of optoelectronic properties during annealing of chlorine-derived methylammonium lead iodide (MAPbI3-xClx) is investigated in detail combining in-situ und ex-situ optical and structural characterization. Using...
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Reversible changes in the electronic structure of carbon nanotube-hybrids upon NO2 exposure under ambient conditions

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA02749A, Paper
Open Access
Filippo Fedi, Oleg Domanov, Hidetsugu Shiozawa, Kazuhiro Yanagi, Paolo Lacovig, Silvano Lizzit, Andrea Goldoni, Thomas Pichler, Paola Ayala
Single-walled carbon nanotubes have enormous potential for gas sensing. This study shows that cluster filling is a key to high sensitivity and it opens the possibility for a very high desorption at ambient temperature.
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A smart lithiophilic polymer filler in gel polymer electrolyte enables stable and dendrite-free Li metal anode

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA02499F, Paper
Fei Ye, Xiu Zhang, Kaiming Liao, Qian Lu, Xiaohong Zou, Ran Ran, Wei Zhou, Yijun Zhong, Zongping Shao
A new conceptional lithiophilic polymer-filler-reinforced gel polymer electrolyte was proposed and prepared to guide uniform Li-ion flux during the Li plating/stripping process.
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Fe/Fe3C nanoparticle-decorated N-doped carbon nanofibers for improving the nitrogen selectivity of electrocatalytic nitrate reduction

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA02317E, Paper
Yue Lan, Junliang Chen, Hui Zhang, Wei-xian Zhang, Jianping Yang
N-doped carbon nanofibers embedded with Fe/Fe3C nanodomains demonstrate superior electrocatalytic nitrate reduction ability and nitrogen selectivity.
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Highly efficient and durable aqueous electrocatalytic reduction of CO2 to HCOOH with a novel bismuth–MOF: experimental and DFT studies

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA00384K, Paper
Xurui Zhang, Yanxing Zhang, Qingqing Li, Xiaodong Zhou, Qingyu Li, Jin Yi, Yuyu Liu, Jiujun Zhang
Electrochemical reduction of carbon dioxide (ERCO2) to low-carbon fuel and useful chemicals, which can simultaneously store renewable energy and recover CO2 in a green manner, has proven to be a viable energy storage and conversion strategy.
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A Cu2B2 monolayer with planar hypercoordinate motifs: an efficient catalyst for CO electroreduction to ethanol

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA02471F, Paper
Jingjing Jia, Haijun Zhang, Zhongxu Wang, Jingxiang Zhao, Zhen Zhou
By means of first-principles computations, we identified that metallic Cu2B2 monolayer with planar heptacoordinate motifs could effectively reduce CO to ethanol through the “carbene” mechanism with a low limiting potential and a small barrier for C–C coupling.
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Semiconducting polymer contributes favorably to the Seebeck coefficient in multi-component, high-performance n-type thermoelectric nanocomposites

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA02388D, Paper
Junhui Tang, Ruisi Chen, Lidong Chen, Guillermo C. Bazan, Ziqi Liang
n-Type Co NWs/N2200 TENCs yield a high S, mainly from the semiconducting polymer, yet σ is limited by poor connectivity between inorganic and organic domains. By adding flexible n-doped SWCNTs to yield more conductive paths, σ and mechanical bendability are greatly enhanced.
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Perovskite-Sensitized β-Ga2O3 Nanorod Arrays for Highly Selective and Sensitive NO2 Detection at High Temperature

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA02691C, Paper
Bo Zhang, Hui-Jan Lin, Haiyong Gao, Xingxu Lu, Chang-Yong Nam, Pu-Xian Gao
Amongst various gaseous pollutants, NO2 is one of the major exhausts originating from fossil fuel and gas combustions in vehicle engines and power plants at high temperature. Under such scenario,...
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Recent progress in carbonyl-based organic polymers as promising electrode materials for lithium-ion batteries (LIBs)

J. Mater. Chem. A, 2020, Advance Article
DOI: 10.1039/D0TA03321A, Review Article
Hao Wang, Chang-Jiang Yao, Hai-Jing Nie, Ke-Zhi Wang, Yu-Wu Zhong, Pengwan Chen, Shilin Mei, Qichun Zhang
Lithium-ion batteries (LIBs) have been demonstrated as one of the most promising energy storage devices for applications in electric vehicles, smart grids, large-scale energy storage systems, and portable electronics.
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Al-Sc Dual Doped LiGe2(PO4)3 - a NASICON-Type Solid Electrolyte with Improved Ionic Conductivity

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA00517G, Paper
Yosef Nikodimos, Meng-Che Tsai, Ljalem Hadush Abrha, Haile Hisho Weldeyohannis, Shuo-Feng Chiu, Hailemariam Kassa Bezabh, Kassie Nigus Shitaw, Fekadu Wubatu Fenta, She-Huang Wu, Wei-Nien Su, Yang Chun-Chen, Bing Joe Hwang
LiGe2(PO4)3 (LGP), a NASICON type solid electrolyte has many advantages like superior electrochemical and thermal stability to use in all solid state lithium batteries. However, its low ionic conductivity is...
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Surface-Functionalized Palladium Catalysts for Electrochemical CO2 Reduction

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA03427D, Paper
Rong Xia, Sheng Zhang, Xinbin Ma, Feng Jiao
Rational design and synthesis of efficient catalysts for electrochemical CO2 reduction is a critical step towards practical CO2 electrolyzer systems. In this work, we report a strategy to tune the...
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Plasmon-Enhanced Electrocatalytic Oxygen Reduction in Alkaline Media on Gold Nanohole Electrodes

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/C9TA14174J, Paper
Nait Saada Tamazouzt, Anderson da Silva, Palaniappan Subramanian, Liuqing Pang, Noual Adnane, Bahram Djafari-Rouhani, Vladyslav Mishyn, Dalila Meziane, Sorin Melinte, Georgiana Sandu, Franck Dumeignil, Sebastien Paul, Robert Wojcieszak, Rabah Boukherroub, Sabine Szunerits
Plasmon-driven chemical transformation has become a promising approach for enhancing sluggish electrocatalytic reactions. Herein, an alternative enhancement strategy employing plasmon-induced hot electrons is developed to be competitive with oxygen reduction...
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Catalyst design strategies for stable electrochemical CO2 reduction reaction

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA02633F, Review Article
Woong Choi, Da Hye Won, Yun Jeong Hwang
The gradual increase in the atmospheric CO2 concentration due to the combustion of fossil fuels is an urgent issue that poses a threat to human beings. Recently, the electrochemical CO2...
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Nitrogen-doped phosphorene for electrocatalytic ammonia synthesis

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA03237A, Paper
Guang-Rui Xu, Hao Li, Abdulaziz Bati, Munkhjargal Bat-Erdene, Md Julker Nine, Dusan Losic, Yu Chen, Joseph G Shapter, Munkhbayar Batmunkh, Tianyi Ma
The rapid surface oxidation of phosphorene under ambient conditions is considered to be serious issue for many applications, but here is used as a strategy to achieve efficient heteroatom doping....
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Organic Solar Cells Based on Small Molecule Donor and Polymer Acceptor Operating at 150 °C

J. Mater. Chem. A, 2020, Accepted Manuscript
DOI: 10.1039/D0TA02865G, Paper
Junhui Miao, Bin Meng, Zicheng Ding, Jun Liu, Lixiang Wang
Inorganic or organic solar cells always operate at temperature lower than 100 °C and are not suitable for operating at high temperature. In this work, using blends of small molecular...
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NEWS: Cherry Blossom Book Features Library Collections

Vibrant springtime traditions of cherry blossom viewing in Japan and Washington, D.C., are explored in the new book “Cherry Blossoms: Sakura Collections from the Library of Congress,” published today by Smithsonian Books, in association with the Library of Congress. Events at the Library in April will feature the book and celebrate the annual return of the cherry blossoms to the nation's capital.

Click here for more information.




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Betty and the sensory world: experimental electronic music / Doug Bielmeier

MEDIA PhonCD B4763 bet




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The bad-tempered electronic keyboard: 24 preludes and fugues / Anthony Burgess ; Stephane Ginsburgh, keyboard

MEDIA PhonCD B912 bad




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An anthology of Greek experimental electronic music, 1966-2016.

MEDIA PhonCD F G6810.A584




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[ASAP] Electrochemical Oxidative Phosphorylation of Aldehyde Hydrazones

Organic Letters
DOI: 10.1021/acs.orglett.0c01343




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[ASAP] Thiol Activation toward Selective Thiolation of Aromatic C–H Bond

Organic Letters
DOI: 10.1021/acs.orglett.0c01050




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[ASAP] Synthesis of Stable, High-SOMO Zwitterionic Radicals: Enabling Intermolecular Electron Transfer between Naphthalenediimides

Organic Letters
DOI: 10.1021/acs.orglett.0c01263




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[ASAP] Visible-Light-Induced Palladium-Catalyzed Intermolecular Narasaka–Heck Reaction at Room Temperature

Organic Letters
DOI: 10.1021/acs.orglett.0c01267




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[ASAP] Chiral Binaphthyl Box-Copper-Catalyzed Enantioselective Tandem Michael–Ketalization Annulations for Optically Active Aryl and Heteroaryl Fused Bicyclicnonanes

Organic Letters
DOI: 10.1021/acs.orglett.0c01221




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[ASAP] Carbocation versus Carbene Controlled Chemoselectivity: DFT Study on Gold- and Silver-Catalyzed Alkylation/Cyclopropanation of Indoles with Vinyl Diazoesters

Organic Letters
DOI: 10.1021/acs.orglett.0c01476




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[ASAP] DNA Compatible Intermolecular Wittig Olefination for the Construction of a, ß-Unsaturated Carbonyl Compounds

Organic Letters
DOI: 10.1021/acs.orglett.0c01215




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[ASAP] Selective Synthesis of Secondary Alkylboronates: Markovnikov-Selective Hydroboration of Vinylarenes with Bis(pinacolato)diboron Catalyzed by a Nickel Pincer Complex

Organic Letters
DOI: 10.1021/acs.orglett.0c01416




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[ASAP] Organocatalytic Regiodivergent Ring Expansion of Cyclobutanones for the Enantioselective Synthesis of Azepino[1,2-<italic toggle="yes">a</italic>]indoles and Cyclohepta[<italic toggle="yes">b</italic>]ind

Organic Letters
DOI: 10.1021/acs.orglett.0c01406




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[ASAP] Catalytic, Enantioselective C2-Functionalization of 3-Aminobenzofurans Using N-Heterocyclic Carbenes

Organic Letters
DOI: 10.1021/acs.orglett.0c01112




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[ASAP] Stereoselective Asymmetric Synthesis of Pyrrolidines with Vicinal Stereocenters Using a Memory of Chirality-Assisted Intramolecular S<sub>N</sub>2' Reaction

Organic Letters
DOI: 10.1021/acs.orglett.0c01307




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[ASAP] Enantioselective Copper-Catalyzed Remote C(sp<sup>3</sup>)–H Alkynylation of Linear Primary Sulfonamides

Organic Letters
DOI: 10.1021/acs.orglett.0c01325




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[ASAP] Sequential Visible-Light and <italic toggle="yes">N</italic>-Heterocyclic Carbene Catalysis: Stereoselective Synthesis of Tetrahydropyrano[2,3-<italic toggle="yes">b</italic>]indoles

Organic Letters
DOI: 10.1021/acs.orglett.0c01447




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[ASAP] Palladium-Catalyzed Regio- and Stereoselective Cross-Coupling of Vinylethylene Carbonates with Ketimine Esters to Generate (<italic toggle="yes">Z</italic>)-Tri- and Tetra-substituted Allylic Amino Acid Derivatives

Organic Letters
DOI: 10.1021/acs.orglett.0c01211




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[ASAP] Addition to “Selective Methylation of Amides, <italic toggle="yes">N</italic>-Heterocycles, Thiols, and Alcohols with Tetramethylammonium Fluoride”

Organic Letters
DOI: 10.1021/acs.orglett.0c01524




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[ASAP] Rh(I)-Catalyzed C6-Selective Decarbonylative Alkylation of 2-Pyridones with Alkyl Carboxylic Acids and Anhydrides

Organic Letters
DOI: 10.1021/acs.orglett.0c01277




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Unnatural selection / Katrina van Grouw

Browsery SF105.V24 2018




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Micron and microscopica acta [electronic resource].

Publisher Oxford : Pergamon Press, c1983-c1992.
Location World Wide Web
Call No. QH212.E4




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Micron [electronic resource].

Publisher Oxford : Pergamon Press, 1969-1983.
Location World Wide Web
Call No. QH212.E4




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Progress in crystal growth and characterization [electronicresource].

Publisher Oxford ; New York : Pergamon Press, 1977-
Location World Wide Web
Call No. QD921