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Phosphacycloalkyldiones: synthesis and coordinative behaviour of 6- and 7-member cyclic diketophosphanyls

Dalton Trans., 2020, 49,5482-5492
DOI: 10.1039/D0DT00864H, Paper
Kyle G. Pearce, Vladimir Simenok, Ian R. Crossley
Condensation of glutaryl and adipoyl chlorides with bis(silyl)phosphanes RP(SiMe3)2 (R = Me, nBu, tBu, Ph, Mes) affords the conformationally fluxional phosphacycloalkyldiones (CH2)n(CO)2PR (n = 3, 4); their coordination behaviour is explored.
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Efficient CO2 electroreduction to CO at low overpotentials using a surface-reconstructed and N-coordinated Zn electrocatalyst

Dalton Trans., 2020, 49,5434-5439
DOI: 10.1039/D0DT00800A, Communication
Wanan Deng, Shixiong Min, Fang Wang, Zhengguo Zhang, Chao Kong
A surface-reconstructed and N-coordinated Zn electrocatalyst exhibits enhanced activity and selectivity for CO2 electroreduction to CO at reduced overpotentials.
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Time-resolved infra-red spectroscopy reveals competitive water and dinitrogen coordination to a manganese(I) carbonyl complex

Dalton Trans., 2020, 49,5463-5470
DOI: 10.1039/C9DT04878B, Paper
Jonathan B. Eastwood, L. Anders Hammarback, Matthew T. McRobie, Ian P. Clark, Michael Towrie, Ian. J. S. Fairlamb, Jason M. Lynam
Photolysis of [Mn(C^N)(CO)4] (C^N = bis-(4-methoxyphenyl)methanimine) in heptane solution results in ultra-fast CO dissociation and ultimate formation of a rare Mn-containing dinitrogen complex fac-[Mn(C^N)(CO)3(N2)].
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Design and synthesis of photoluminescent active interpenetrating metal–organic frameworks using N-2-aryl-1,2,3-triazole ligands

Dalton Trans., 2020, 49,5429-5433
DOI: 10.1039/D0DT00933D, Communication
Jingyang Li, Ying He, Li Wang, Qinhe Pan, Zhiguang Song, Xiaodong Shi
N-2-aryl-1,2,3-triazole derivatives were synthesized as new ligand systems for the construction of photoluminescent active metal–organic frameworks (MOFs).
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Two amino acid-templated metal phosphates: surfactant-thermal synthesis, water stability, and proton conduction

Dalton Trans., 2020, 49,5440-5444
DOI: 10.1039/D0DT00966K, Communication
Lijuan Huang, Lei Wang, Yan Zhao, Ling Huang, Jian Bi, Guohong Zou, Zhien Lin, Daojiang Gao
An amino acid-templated gallium phosphate with a zeolitic topology has been prepared under surfactant-thermal conditions and it shows exceptional water stability and interesting proton-conducting properties.
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Oxaliplatin and [Pt(R,R-DACH)(panobinostat-2H)] show nanomolar cytotoxicity towards diffuse intrinsic pontine glioma (DIPG)

Dalton Trans., 2020, 49,5703-5710
DOI: 10.1039/C9DT04862F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Marie H. C. Boulet, Laura K. Marsh, Alison Howarth, Alice Woolman, Nicola J. Farrer
Oxaliplatin and the platinum(II) panobinostat complex (2) demonstrate nanomolar cytotoxicity towards diffuse intrinsic pontine glioma cells (DIPG); with 2 exhibiting improved solubility in comparison to panobinostat.
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Photo-reduction enables catalyst regeneration in Fenton reaction on an Fe2O3-decorated TiO2 nanotube-based photocatalyst

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00670J, Paper
Quanming Peng, Guiming Peng, Liangpeng Wu, Yaqian Chen, Bin Han, Qiucheng Su, Shijun Liu, Xinjun Li
Active Fe2+ sites of TNT(Pd)/Fe2O3 with a unique electronic structure for the Fenton reaction can be self-generated.
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A novel self-assembled-derived 1D MnO2@Co3O4 composite as a high-performance Li-ion storage anode material

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00980F, Paper
Zongtang Li, Xiao Lian, Mingzai Wu, Fangcai Zheng, Yuanhao Gao, Helin Niu
Manganese dioxide (MnO2) is a high-performance anodic material and applied widely in lithium-ion batteries (LIBs).
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Comment on “Investigation on the structure and thermoelectric properties of CuxTe binary compounds” by Shriparna Mukherjee et al., Dalton Trans., 2019, 48, 1040

Dalton Trans., 2020, 49,5736-5737
DOI: 10.1039/C9DT03607E, Comment
Aarón H. Barajas-Aguilar, A. M. Garay-Tapia, Sergio J. Jiménez-Sandoval
Copper telluride sensitivity to laser power: effect on the Raman spectra.
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Reply to the ‘Comment on “Investigation on the structure and thermoelectric properties of CuxTe binary compounds”’ by A. H. Barajas-Aguilar, A. M. Garay-Tapia, and S. J. Jiménez-Sandoval, Dalton Trans., 2020, 49, DOI: 10.1039/C9DT03607E

Dalton Trans., 2020, 49,5738-5740
DOI: 10.1039/D0DT00412J, Comment
Shriparna Mukherjee, Raju Chetty, P. V. Prakash Madduri, Ajaya K. Nayak, Krzysztof Wojciechowski, Tanmoy Ghosh, Kamanio Chattopadhyay, Satyam Suwas, Ramesh Chandra Mallik
In a communication to Dalton Transaction and in a paper in Journal of Physics: Condensed Matter, Aarón H. Barajas-Aguilar et al. have raised comments on our paper published earlier in Dalton Transactions.
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Structural design of cubic Sr,V:CeFeO3 thin films with a strong magneto-optical effect and high compatibility with a Si substrate

Dalton Trans., 2020, Advance Article
DOI: 10.1039/C9DT04837E, Paper
Nanxi Lin, Shengnan Zhang, Haixin Chen, Yunjin Chen, Xin Chen, Yongfan Zhang, Xiaolin Hu, Naifeng Zhuang
Orthorhombic CeFeO3 is optimized to be cubic perovskite with high compatibility with Si substrate by introducing Sr, V ions into lattice. Cubic Sr,V:CeFeO3 film exhibit strong magneto-optical effect due to spin-coupling hybrid of Ce 4f with Fe/V 3d.
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Facile synthesis of Mn-doped NiCo2O4 nanoparticles with enhanced electrochemical performance for a battery-type supercapacitor electrode

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT01177K, Paper
To Van Nguyen, Le The Son, Vu Van Thuy, Vu Dinh Thao, Masahito Hatsukano, Koichi Higashimine, Shinya Maenosono, Sang-Eun Chun, Tran Viet Thu
We report the synthesis of manganese-doped nickel cobalt oxide (Mn-doped NiCo2O4) nanoparticles (NPs) by an efficient hydrothermal and subsequent calcination route.
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Copolymerization of CHO/CO2 catalyzed by a series of aluminum amino-phenolate complexes and insights into structure–activity relationships

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00726A, Paper
Hart Plommer, Laura Stein, Jennifer N. Murphy, Nduka Ikpo, Nelaine Mora-Diez, Francesca M. Kerton
Five aluminum catalysts demonstrated different selectivity and activity during reactions of carbon dioxide and epoxides.
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Self-assembly of mixed-valent and heterometallic metallocycles: efficient catalyst for oxidation of alcohols to aldehydes with ambient air

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01340D, Communication
Ya-Liang Lai, Xue-Zhi Wang, Rui-Rong Dai, Yong-Liang Huang, Xian-Chao Zhou, Xiao-Ping Zhou, Dan Li
Two mixed-valent CuII/CuI and two heterometallic CuII/AgI metallocycles have been synthesized by the assembly of designed metalloligands and CuI/AgI ions, respectively. The CuII/CuI metallocycle can catalyze oxidation of alcohols to...
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1,2-Insertion Reactions of Alkynes into Ge–C Bonds of Arylbromogermylene

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01223H, Paper
Tomohiro Sugahara, Arturo Espinosa Ferao, Alicia Rey, Jing-Dong Guo, Shin Aoyama, Kazunobu Igawa, Katsuhiko Tomooka, Takahiro Sasamori, Daisuke Hashizume, Shigeru Nagase, Norihiro Tokitoh
1,2-insertion reactions of alkynes into the Ge–C bonds in dibromodigermenes afford stable crystalline bromovinylgermylenes. In contrast to previously reported Lewis-base-supported vinylgermylenes, the bromovinylgermylene obtained from reaction of the bromogermylene with...
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Amorphous Co-doped MoSex Effectively Enhances Photocatalysis in Visible Light

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01295E, Paper
Rui Feng, Rong Wu, Yuncheng Cao, Xiaolin Guo, Xu Ma
Molybdenum selenide has great potential for degradation of water pollutants,but its performance is limited by the active sites and recombination of photogenerated electron-hole pairs. In this study, amorphous Co-doped MoSex...
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Tin based organic-inorganic hybrid semiconductors with reversible phase transition and dielectric anomaly

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01401J, Paper
Zhenhong Wei, Xiuli You, Jiaojiao Yao
Organic−inorganic hybrid materials with perovskite structure have recently attracted tremendous interest due to their structural tunability and rich functional properties, such as phase transition and photoelectric properties. Within this context,...
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Double addition of phenylacetylene onto the mixed bridge phosphinito–phosphanido Pt(I) complex [(PHCy2)Pt(μ-PCy2){κ2P,O-μ-P(O)Cy2}Pt(PHCy2)](Pt–Pt)

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00923G, Paper
Stefano Todisco, Mario Latronico, Vito Gallo, Nazzareno Re, Alessandro Marrone, Iogann Tolbatov, Piero Mastrorilli
Double addition of phenylacetylene onto the Pt(I)–Pt(I) complex [(PHCy2)Pt(μ-PCy2){κ2P,O-μ-P(O)Cy2}Pt(PHCy2)] (Pt–Pt) affords the η1-alkenyl-μ,η12-alkynyl complex [(η1-trans-(Ph)HCCH)(PHCy2)Pt(μ-PCy2)(μ,η12-PhCC)Pt{κP-P(O)Cy2}(PHCy2)].
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Amide and ester derivatives of chlorido[4-carboxy-1,2-disalicylideneaminobenzene]iron(III) as necroptosis and ferroptosis inducers

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00168F, Paper
Daniel Baecker, Benjamin N. Ma, Jessica Sagasser, Lukas Schultz, Carina Hörschläger, Maria Weinreich, Lucy Steiner, Brigitte Kircher, Ronald Gust
Amide and ester derivatives of chlorido[4-carboxy-1,2-disalicylideneaminobenzene]iron(III) were synthesized and characterized as necroptosis and ferroptosis inducers using the acute myeloid leukemia cell line HL-60.
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Reactive metallocene cations as sensitive indicators of gas-phase oxygen and water

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00798F, Paper
Anuj Joshi, Sofia Donnecke, Ori Granot, Dongju Shin, Scott Collins, Irina Paci, J. Scott McIndoe
Gas-phase oxidation of air-sensitive organometallic compounds does not proceed to a significant extent in mass spectrometric analysis unless a vacant coordination site is generated, making nitrogen generators a suitable source of desolvation gas.
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Photophysical, photodynamical, redox properties and BSA-interactions of novel isomeric tetra-cationic peripheral palladium(II)-bipyridyl porphyrins

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01063D, Paper
Fabiano S Santos, Carolina H. da Silveira, Fabio Souza Nunes, Daniele Ferreira, Henrique Victória, Klaus Krambrock, Otávio Augusto Chaves, Fabiano Severo Rodembusch, Bernardo Almeida Iglesias
New isomeric tetra-cationic porphyrins containing peripheral [Pd(bpy)Cl]+ units attached at pyridyl substituents were synthetized and fully characterized. The porphyrins present an intense Soret band located in the blue spectral region...
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The differential magnetic relaxation behaviours of slightly distorted triangular dodecahedral dysprosium analogues in a type of cyano-bridged 3d–4f zig-zag chain compounds

Dalton Trans., 2020, Advance Article
DOI: 10.1039/D0DT00990C, Paper
An-Qi Xue, Yang-Yu Liu, Jia-Xin Li, Yan Zhang, Yin-Shan Meng, Wen-Hua Zhu, Yi-Quan Zhang, Hao-Ling Sun, Fei Wang, Guan-Xia Qiu, Lu-Yu Liang, Xiang Wang, Song Gao
Differential magnetic properties were observed for triangular dodecahedral dysprosium analogues in a type of cyano-bridged 3d–4f zig-zag chain compound.
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A Review: Recent Advances in Preparations and Applications of Heteroatom-Doped Carbon Quantum Dots

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01004A, Perspective
Xiaoli Kou, Shicui Jiang, Soo-Jin Park, Long-Yue Meng
Carbon quantum dots (CQDs) are widely used in optoelectronic catalysis, biological imaging, and ion probes owing to their low toxicity, stable photoluminescence, and ease of chemical modification. However, the low...
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Highly cytotoxic gold(I)-phosphane dithiocarbamate complexes trigger an ER stress-dependent immune response in ovarian cancer cells

Dalton Trans., 2020, Accepted Manuscript
DOI: 10.1039/D0DT01411G, Paper
Hai Van Le, Maria Babak, Muhammad Ali Ehsan, Mohammad Altaf , Lisa Reichert, Artem Gushchin, Wee Han Ang, Anvarhusein Isab
Ovarian cancer is a highly aggressive disease which is treated by surgery and platinum chemotherapy. However, a significant proportion of treated patients develop resistance to platinum treatment resulting in tumor...
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Big History Ebooks Now Available For WH & BHP Classes

Cynthia Stokes Brown wrote BIG HISTORY, SMALL WORLD to help Big History Project students and their teachers, many of whom she knew and befriended in the earliest days of big history education. David Christian's THIS FLEETING WORLD is widely used in AP World History as well as big history courses. BIG HISTORY: A BERKSHIRE ESSENTIAL is a collection of essays by

The post Big History Ebooks Now Available For WH & BHP Classes appeared first on Berkshire Publishing.




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Tom’s 2nd letter from Beijing

This Princess and Prince Party is sure to be canceled. I'm delighted to report that the Train Campaign projects were included in the governor's bond bill last week, and the bills I filed by petition (a unique Massachusetts citizen right) have been favorably reported on. Read about A Great Week for Train Advocates

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COVID-19 is here (& where has all the toilet paper gone?)

We lived through the ‘80s. We lived through the ‘90s. We lived through the ‘00s. We lived through the ‘10s. And we’ve lived through March. Most of us, that is, have lived. I’m still coming to terms with what is happening. It’s like grief. I go about my day, getting absorbed in work, or a

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Berkshire Joins COVID-19 Support Efforts With JStor, EBSCO, ProQuest

We want to make sure you know about some of the ways in which publishers - including Berkshire - are making our books and reference publications available online at reduced cost, or even free, during the COVID-19 crisis. We're well aware that taking classes and doing research papers online is a huge challenge for many

The post Berkshire Joins COVID-19 Support Efforts With JStor, EBSCO, ProQuest appeared first on Berkshire Publishing.




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Do exclusionary rules ensure a fair trial?: a comparative perspective on evidentiary rules / Sabine Gless, Thomas Richter, editors

Online Resource




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Our selfish tax laws: toward tax reform that mirrors our better selves / Anthony C. Infanti

Dewey Library - KF6289.I49 2018




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The World Bank policy for projects on international waterways: an historical and legal analysis / Salman M.A. Salman

Online Resource




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Many nations under many gods: public land management and American Indian sacred sites / Todd Allin Morman

Rotch Library - KF5605.M67 2018




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Decarcerating America: from mass punishment to public health / edited by Ernest Drucker

Dewey Library - KF9730.D43 2018




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Contempt: a memoir of the Clinton investigation / Ken Starr

Dewey Library - KF5076.C57 S72 2018




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Practitioner's guide to project-based vouchers: a successor to the Beginner's guide / Sarah Molseed and Julie S. McGovern

Rotch Library - KF5735.M654 2018




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Networked press freedom: creating infrastructures for a public right to hear / Mike Ananny

Dewey Library - K3255.A958 2018




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Separate: the story of Plessy v. Ferguson, and America's journey from slavery to segregation / Steve Luxenberg

Hayden Library - KF223.P56 L88 2019




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The essential guide to intellectual property / Aram Sinnreich

Dewey Library - K1401.S56 2019




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Winning together: the natural resource negotiation playbook / Bruno Verdini Trejo

Dewey Library - KZ6047.V47 2017




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Punishing atrocities through a fair trial: international criminal law from Nuremberg to the age of global terrorism / Jonathan Hafetz

Dewey Library - KZ7050.H34 2018




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From slaves to prisoners of war: the Ottoman Empire, Russia, and international law / Will Smiley

Dewey Library - KZ6495.S63 2018




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Practical Guide to LTE-A, VoLTE and IoT: Paving the way towards 5G / by Ayman Elnashar, Mohamed El-Saidny

Online Resource




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Regulatory counter-terrorism: a critical appraisal of proactive global governance / Nathanael Tilahun Ali

Dewey Library - KZ7220.A9565 2018




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Good kids, bad city: a story of race and wrongful conviction in America / Kyle Swenson

Dewey Library - KF224.A38 S94 2019




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Transactional intellectual property: from startups to public companies / Richard S. Gruner, professor of law, John Marshall Law School), Shubha Ghosh (Crandall Melvin Professor of Law, director, Technology Commercialization Law Program & Syracuse Inte

Dewey Library - KF2980.G78 2018




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Military professionalism and humanitarian law: the struggle to reduce the hazards of war / Yishai Beer

Dewey Library - KZ6396.B44 2018




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History and Power in the Study of Law: New Directions in Legal Anthropology.

Online Resource




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Xénotransplantation: le brevet sur l'animal / Alexandra Obadia ; préface de Jean-Christophe Galloux

Online Resource




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Derecho, conflicto social y emancipación: entre la depresión y la esperanza / Mauro Benente, Marco Navas Alvear (compiladores)

Online Resource




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Reconsidering Constitutional Formation II Decisive Constitutional Normativity: From Old Liberties to New Precedence / edited by Ulrike Müßig

Online Resource