the [ASAP] Activation of C–C Bonds via s-Bond Metathesis: Hydroborenium-Catalyzed Hydrogenolysis of Cyclopropanes By feedproxy.google.com Published On :: Thu, 02 Apr 2020 04:00:00 GMT OrganometallicsDOI: 10.1021/acs.organomet.0c00099 Full Article
the [ASAP] Synthesis of Boryl-Substituted Disilane, Disilene, and Silyl Cation By feedproxy.google.com Published On :: Wed, 08 Apr 2020 04:00:00 GMT OrganometallicsDOI: 10.1021/acs.organomet.0c00148 Full Article
the [ASAP] Carboxylation of the Ni–Me Bond in an Electron-Rich Unsymmetrical PCN Pincer Nickel Complex By feedproxy.google.com Published On :: Mon, 13 Apr 2020 04:00:00 GMT OrganometallicsDOI: 10.1021/acs.organomet.9b00817 Full Article
the [ASAP] Electrochemical CO<sub>2</sub> Reduction — The Effect of Chalcogenide Exchange in Ni-Isocyclam Complexes By feedproxy.google.com Published On :: Wed, 15 Apr 2020 04:00:00 GMT OrganometallicsDOI: 10.1021/acs.organomet.0c00129 Full Article
the [ASAP] Neutral Ni(II) Catalysts Based on Maple-Lactone Derived [N,O] Ligands for the Polymerization of Ethylene By feedproxy.google.com Published On :: Fri, 17 Apr 2020 04:00:00 GMT OrganometallicsDOI: 10.1021/acs.organomet.0c00061 Full Article
the [ASAP] Dibromine Promoted Transmetalation of an Organomercurial by Fe(CO)<sub>5</sub>: Synthesis, Properties, and Cytotoxicity of Bis(2-C<sub>6</sub>H<sub>4</sub>-2'-py-<italic toggle="yes">?C,N</ By feedproxy.google.com Published On :: Mon, 20 Apr 2020 04:00:00 GMT OrganometallicsDOI: 10.1021/acs.organomet.0c00107 Full Article
the [ASAP] Potentiostatically Controlled Olefin Metathesis By feedproxy.google.com Published On :: Wed, 22 Apr 2020 04:00:00 GMT OrganometallicsDOI: 10.1021/acs.organomet.0c00052 Full Article
the [ASAP] [2 + 2] Cycloaddition of <italic toggle="yes">o</italic>-Carboryne with Vinyl Ethers: Synthesis of Carborane-Fused Cyclobutanes By feedproxy.google.com Published On :: Wed, 22 Apr 2020 04:00:00 GMT OrganometallicsDOI: 10.1021/acs.organomet.0c00163 Full Article
the [ASAP] Synthesis, Characterization, and Catalytic Reactivity of {CoNO}<sup>8</sup> PCP Pincer Complexes By feedproxy.google.com Published On :: Fri, 24 Apr 2020 04:00:00 GMT OrganometallicsDOI: 10.1021/acs.organomet.0c00167 Full Article
the [ASAP] Revisiting the Palladium-Catalyzed Carbonylation of Allyl Alcohol: Mechanistic Insight and Improved Catalytic Efficiency By feedproxy.google.com Published On :: Fri, 24 Apr 2020 04:00:00 GMT OrganometallicsDOI: 10.1021/acs.organomet.0c00117 Full Article
the [ASAP] NHC-Palladium(II) Mononuclear and Binuclear Complexes Containing Phenylene-Bridged Bis(thione) Ligands: Synthesis, Characterization, and Catalytic Activities By feedproxy.google.com Published On :: Sun, 26 Apr 2020 04:00:00 GMT OrganometallicsDOI: 10.1021/acs.organomet.0c00091 Full Article
the [ASAP] Spatial Recognition Within Terpenes: Redox and H-bond Promoted Linkage Isomerizations and the Selective Binding of Complex Alkenes By feedproxy.google.com Published On :: Mon, 27 Apr 2020 04:00:00 GMT OrganometallicsDOI: 10.1021/acs.organomet.0c00151 Full Article
the [ASAP] Self-Assembled Redox-Active Tetraruthenium Macrocycles with Large Intracyclic Cavities By feedproxy.google.com Published On :: Tue, 28 Apr 2020 04:00:00 GMT OrganometallicsDOI: 10.1021/acs.organomet.0c00116 Full Article
the [ASAP] Effect of the Lead(II) Bond Angle on the Reactivity of Diaminoplumbylenes toward Ammonia: From Inertness to Immediate Ammonolysis By feedproxy.google.com Published On :: Tue, 28 Apr 2020 04:00:00 GMT OrganometallicsDOI: 10.1021/acs.organomet.0c00196 Full Article
the [ASAP] Electrosynthetic Route to Cyclopentadienyl Rhenium Hydride Complexes Enabled by Electrochemical Investigations of their Redox-Induced Formation By feedproxy.google.com Published On :: Wed, 29 Apr 2020 04:00:00 GMT OrganometallicsDOI: 10.1021/acs.organomet.0c00049 Full Article
the [ASAP] Synthesis and Characterization of an Oxo-Centered Homotrimetallic Uranium(IV)–Cyclobutadienyl Dianion Complex By feedproxy.google.com Published On :: Wed, 29 Apr 2020 04:00:00 GMT OrganometallicsDOI: 10.1021/acs.organomet.0c00104 Full Article
the [ASAP] Development of Quinoline-Derived Chiral Diaminocarbene Ligands and Their Transition Metal Complexes: Synthesis, Structural Characterization, and Catalytic Properties By feedproxy.google.com Published On :: Wed, 29 Apr 2020 04:00:00 GMT OrganometallicsDOI: 10.1021/acs.organomet.0c00141 Full Article
the [ASAP] Ga(N,P) Growth on Si and Decomposition Studies of the N–P Precursor Di-<italic toggle="yes">tert</italic>-butylaminophosphane (DTBAP) By feedproxy.google.com Published On :: Thu, 30 Apr 2020 04:00:00 GMT OrganometallicsDOI: 10.1021/acs.organomet.0c00078 Full Article
the [ASAP] Synthesis and Characterization of Tungsten Alkylidene and Alkylidyne Complexes Featuring a New Carbazole-Based Rigid Trianionic ONO<sup>3–</sup> Pincer-Type Ligand By feedproxy.google.com Published On :: Fri, 01 May 2020 04:00:00 GMT OrganometallicsDOI: 10.1021/acs.organomet.0c00150 Full Article
the [ASAP] Heteroleptic ß-Ketoiminate Magnesium Catalysts for the Ring-Opening Polymerization of Lactide By feedproxy.google.com Published On :: Mon, 04 May 2020 04:00:00 GMT OrganometallicsDOI: 10.1021/acs.organomet.0c00168 Full Article
the [ASAP] Use of Ligand Steric Properties to Control the Thermodynamics and Kinetics of Oxidative Addition and Reductive Elimination with Pincer-Ligated Rh Complexes By feedproxy.google.com Published On :: Mon, 04 May 2020 04:00:00 GMT OrganometallicsDOI: 10.1021/acs.organomet.0c00122 Full Article
the [ASAP] Sesquicarbene Complexes: Bonding at the Interface Between M–C Single Bonds and M-C Double Bonds By feedproxy.google.com Published On :: Thu, 07 May 2020 04:00:00 GMT OrganometallicsDOI: 10.1021/acs.organomet.0c00102 Full Article
the [ASAP] Synthesis, Structures, and Electronic Properties of O- and S-Heterocyclic Carbene Complexes of Iridium, Copper, Silver, and Gold By feedproxy.google.com Published On :: Fri, 08 May 2020 04:00:00 GMT OrganometallicsDOI: 10.1021/acs.organomet.0c00066 Full Article
the The Difficult First Episode By backtofrontshow.com Published On :: Sat, 19 Jan 2013 03:00:00 +0000 In our very first episode we discuss the difficulty of writing your own online biography, the pros and cons of co-working, the move towards flat file site generation, the upcoming New Adventures in Web Design conference, the shiny new Rode iXY microphone and end with bespoke fixed gear bikes. The Back to Front Show on Twitter Site44 Jekyll Kirby Perch WP Super Cache Codekit for Mac Mixture Mixture multiple device demo Fast Company article on co-working The Rode iXY Mic New Adventures in Web Design BÖIKZMÖIND Mango Bikes The Zombie Stomper Full Article
the The Problem of Overfunding on KickStarter By backtofrontshow.com Published On :: Thu, 25 Jul 2013 05:00:00 +0000 As the web appears to have gone on holiday we present a mixed bag of goodness on Episode 010. We lament the loss of one of our zero’s, Kieran brings forth the news and the funny and we engage in a almost academic level of discourse on the issues associated with overfunding on crowdfunding platforms. Also included – a bit of Startup talk, a new Mac code editor, the new Royal baby and our first ever competition. Our new about page An Event Apart lunchboxes Keir on his Tom Cruise box Insites: ConfShop Macaw Pixeli.st Startupland Crowdfunding sites should ban over-funding Man Vs Raccoon Royally Desperate Lunchbox Competition To enter the Back to Front Show lunchbox giveaway simply tweet the answer to the following question before Friday 2nd August 2013. All correct answers will be entered into the draw. If nobody guesses correctly the closest response will win. Question: What is the height difference in inches between Kieran and Keir? Full Article
the Back to the Code Face By backtofrontshow.com Published On :: Thu, 22 Aug 2013 05:00:00 +0000 Episode #012 goes back to the code face with a good chat about some new online services, the hard topic of what to call yourself and an in-depth discussion about the often contentious idea of charging for software and online services. One Last Scare Digest Webby Podcasts Coffitivity Clipping Magic Kraken We are Makers Web industry job titles Twitter Uni Petzila Full Article
the The One with Marc By backtofrontshow.com Published On :: Thu, 19 Dec 2013 09:00:01 +0000 In our first episode of 2014 I am joined by new guest co-host Marc Roberts of Neutron Creations. After a lengthy chat about his rather special coat we moved onto more web related links and finished up with a discussion on node.js. Big thanks for Marc for taking the time to come on the show. MKGN All Dayer EJS on being less social I can smell your CMS Bitcoins explained in terms a 5 year old can understand Letterboxd 2013 review Cameron Moll’s “typo” node.js Express web application framework for node The Particle Lab showterm Full Article
the Around The Web By backtofrontshow.com Published On :: Thu, 11 Sep 2014 12:00:00 +0000 In the first of our bi-weekly links shows we chat about the latest news on the Editorially team, have some friendly banter about startup culture and Kieran delves into the world of devices. Editorially team goes to Vox Media The 10 Things You Should Do When You Have Your Next Web Idea How Startup Funding Really Works (Infographic) Disney Engineers Invented an Algorithm That Automatically Edits Multi-Cam Footage By-pass App Store QA with Rollout Connect SDK If you have a link for us feel free to get in touch on Twitter and Facebook. Full Article
the Around The Web By backtofrontshow.com Published On :: Thu, 25 Sep 2014 12:00:00 +0000 After discussing Kieran’s classic 90’s Peugeot 306 Turbo Diesel we turn our focus back to six cuts from our web travels. This week featuring the finest in USB protection and 15 of the best productivity hacks money can’t buy. USB Condom 1 Year as a Digital Nomad – How to Build a Business by the Beach iPhone ATM PIN code hack Improving Smashing Magazines Performance: A Case Study Can I use? 15 Instant Productivity Hacks Every Professional Needs to Know If you like our show please feel free to leave us a review on iTunes. Full Article
the Around The Web By backtofrontshow.com Published On :: Fri, 10 Oct 2014 12:00:00 +0000 This week it’s our links show in which we ask the question “does having a beard make you a better dev” as well as discuss a very meta podcast and a new team collaboration tool. You may notice a slight audio disparity towards the end. Unfortunately, Kieran’s Yeti cable fell out (professional to the end) a new mic is on order! Mendip Hills Somerset Levels How to Beard Talko Hear Startup Tesco to sell Blinkbox Inside the company that rebuilt Digg Archive Today If you like our show please feel free to leave us a review on iTunes. Full Article
the The Club Sandwich Special By backtofrontshow.com Published On :: Fri, 31 Oct 2014 12:00:00 +0000 Due to logistical issues Kieran was unable to join the party today. Thankfully Marc and Ben from Neutron Creations kindly joined Keir for a chat over lunch (literally). This week we discuss the recent web.is conference in Cardiff put together by our good friend Mr. Craig Lockwood. The Web Is Christopher Murphy Benjamin Hollway David Hieatt Managing Oneself Full Article
the Back behind the Yeti’s By backtofrontshow.com Published On :: Sat, 08 Nov 2014 12:00:00 +0000 Back from our travels we retrun behind the Yeti’s to discuss everything from the hunt for the perfect email app to the sartorial elegance of modern tech CEO’s. This episode also features a rather spledid retreat venue only four hours from Spokane. The Web Is Beyond Tellerrand Berlin Punctuation Tips Google Inbox Define the CTO Business casual has become a little too casual Dog Bark Park Inn Full Article
the The 2014 BAFTAS By backtofrontshow.com Published On :: Fri, 19 Dec 2014 15:10:48 +0000 It’s that time of the year when we look back on the past 12 months and dish out our (cough, cough) highly prized awards! This year in the 2014 BAFTAS we have eight categories and round off the show with a little bit of crystal ball gazing in which we both make our predictions for 2015. Without further ado here are the categories and winners: The award for not being a very good year in the industry: 2014 Conference/event of the year: Web Teaching Day & Beyond Tellerrand Berlin Podcast of the year: Startup Most hyped app of the year: Slack Man of the year: Sean McCabe Woman of the year: Rachel Andrew Trend of the year: Privacy & Security Foo Bar of the year: #VATMOSS Happy holidays to our all listeners. We really do appreciate including us in your weekly audio listening. See you in 2015. Full Article
the Around the Web By backtofrontshow.com Published On :: Fri, 09 Jan 2015 12:10:22 +0000 Happy 2015! We are back for the new year with a look at four links that caught our attention over the holiday season. We also spill the beans on some of the topics we’ll be covering this year. Featured in this weeks episode: TechCrunch Cribs 12 Startups in 12 Months Just Try and do a Good Job Moonpig Vulnerability If you like our little show we’d very much appreciate a review on iTunes if you have time. Thanks! Full Article
the The Joys & Perils of Remote Working By backtofrontshow.com Published On :: Sat, 17 Jan 2015 09:17:03 +0000 In a change to the announced billing, an impromptu early morning phone call made us think a chat about remote working might be in order. As many of us fight the January blues, and inevitable bout of illness that the new year often brings, it felt a timely opportunity to discuss the good, and the bad, aspects of working from a distance. Topics we discuss include: How does working remotely affect us? What we both like and dislike about it How much real work you achieve per day The importance of “banter” Is the reality like the dream? A typical day for remote working? Do we put extra pressure on ourselves to output more as we are not in the office? How to feel part of the company you work for And finally for those Nabaztag doubters out there you can read the full history of the internet enabled rabbit on Wikipedia! Five Simple Steps Giveaway To be in with a chance of winning one of the two sets of Five Simple Step’s Pocket Guide Collection 3 all you have to do it answer one of the following two questions correctly. Kieran’s decision will be final (he’s a harsh judge): Q: What was Matthew Lillard’s handle in the cult-classic 1995 film Hackers? Q: In the same year Sandra Bullock played a Systems Analyst in the film The Net. During the course of the film her identity is changed by cyber criminals but what is the name they gave her? To enter just send a tweet to @backtofrontshow with your answer. We’ll announce winners on the next episode. Full Article
the Moving Away from the Code Face By backtofrontshow.com Published On :: Wed, 24 Feb 2016 10:05:26 +0000 Like a phoenix from the flames, we have risen. Our year long retreat for slightly overweight tech men from the South West of England is officially over. We’ve eaten the kale, cleansed ourselves, got the glow and are now itching to get back behind the mics. It’s out with the Yeti’s and in with a spanking new steed for Kieran and a less than great “Madonna” mic for Keir. In this week’s episode, we discuss where on earth we’ve been for the last 13 months, chat about how we’ve moved away from the code face and share experiences of a life away from daily development. Finally, we announce the winner of the longest competition in Back to Front Show history! It’s good to be back. Full Article
the The Big 40! By backtofrontshow.com Published On :: Wed, 02 Mar 2016 11:55:37 +0000 Three years ago we started this little adventure called The Back to Front Show. Since then we’ve somehow managed to record 39 shows. Not the best of averages but who’s counting? In our milestone 40th show, we discuss the cake that never happened, Keir’s favourite new TV show, standing desks and end with a discussion that starts with Sarah Parmenter’s recent blog post and ends with thoughts on specialisation. You may also be pleased to hear that our “and finally” section returns this week and features a great satire on our industry. Waitrose Caterpillar Cake Tattoo Fixers The $25 Oristand Standing Desk The Elephant in the Room Vitaly from Smashing Magazine’s response The Passable Designer Full Article
the The Gavin Ballard Special By backtofrontshow.com Published On :: Sat, 30 Apr 2016 12:11:48 +0000 This episode is dedicated to our favourite Australian Gavin Ballard — all round good guy, world traveller, bon viveur and last but by no means least Shopify Expert. Gavin is a long time listener (we still aren’t sure why) and friend of the show. If we had a pin badge and sticker “care package” he’d be the first recipient! Topics covered in this mega-length show include the weather in the South West, Skype video, our favourite NYC diners, the use of technology in the bathroom, career paths for developers, and more. Gavin Ballard Skype Etiquette RIP The Market Diner Modern stock photography The Vazoo Video Keir Forgot Being A Developer After 40</ul> If you would like a show dedicated to you please let us know via the comment link below and we’ll undoubtedly make it happen. Full Article
the The Super Lit, Fam, Dope, En Flique Episode By backtofrontshow.com Published On :: Fri, 23 Sep 2016 12:24:26 +0000 It feels like only last week that the two “K Units” got behind the Samson CO1UPRO‘s and recorded episode #43. So close in fact, that we even manage to think we are still actually recording episode #43! In this short 53 minute episode, we catch up on recent life goings on, learn that Kieran has been “tamping hard” in his role as “Digital Guy” at the bespoke artisanal coffee roasting company, discuss language used by people under the age of 30, announce our new club, and round out with a chat about Kickstarter. There may even be a mention of earphones! Colonna Coffee Sir Gavin Ballard (see also Episode #42) Yorkshire Fat Rascal The Get Along Gang Sport Billy Super Lit Cat En Flique 8 Faces Collected Origin – The Ultimate Coffee Brew Stand Woodbuds Full Article
the The Future of Medium? By backtofrontshow.com Published On :: Fri, 20 Jan 2017 10:20:26 +0000 Happy New Year to you all! Rather unsurprisingly we missed our end of year review but the outline was probably one of our best. Maybe we’ll do it next year! This episode we catch up on Kieran’s move behind the camera, argue over what exactly constitutes a pair of Daps and delve into the future of Medium in light of Ev Williams recent announcement. Colonna Brewing Guide Video What are Daps? Renewing Medium’s Focus Joe Polastre at Canvas Conference 2015 Venture Capital is going to Murder Medium Dear Medium … Why Didn’t You Ask Us? Long Medium Drew Wilson’s Cave Week If you like the show don’t forget you can support our astronomical S3 costs by becoming an exclusive member of the Back to Front Show Club! Full Article
the Muppetry & other Stories By backtofrontshow.com Published On :: Sat, 13 Jan 2018 00:00:00 +0000 Happy 2018! Eschewing a long-standing tradition of not actually releasing shows we are kicking off the year as we mean to go on (for now) with a brand spanking new edition! Join us for 50 glorious high fidelity minutes (true for one of us) and celebrate five years of the show. We don’t dwell too long on our golden non-award winning archive and go on to indulge in some chat, review a book, have a moan about Kickstarter projects, and for once don’t end on dog tech! Beyond Tellerrand Munich 2018 Quiet: The Power of Introverts in a World That Can’t Stop Talking Space Gray Apple iMac Pro Stuff sold for Thousands The Cozydesk The Rise, Fall and Rise Again of the Creative Technologist: Full Article
the Ahmedabad lockdown: Today's news from the city By timesofindia.indiatimes.com Published On :: Fri, 08 May 2020 07:52:13 IST Full Article
the Rajkot achieves another techno feat By timesofindia.indiatimes.com Published On :: Sat, 09 May 2020 04:44:00 IST In what could be a major breakthrough for N95 masks production in India, two Rajkot-based engineering firms have developed the machine indigenously to make this medically crucial masks. Most companies making N95 masks have been procuring the manufacturing machines from China, Japan and South Korea. Full Article
the Resource Showcase: The New York Times By www.dur.ac.uk Published On :: Mon, 04 May 2020 11:11:56 +0100 Did you know that you can access The New York Times via Durham University Library and Collections? As well as access to current articles, via TimesMachine you can access The New York Times archive as far back as 1851. Access The New York Times Access the archive via TimesMachine See what other newspapers and news services are available via Durham University Library and Collections Full Article
the Synthesis of lignin-functionalized phenolic nanosphere supported Ag nanoparticles with excellent dispersion stability and catalytic performance By feeds.rsc.org Published On :: Green Chem., 2020, Advance ArticleDOI: 10.1039/C9GC04311J, PaperShilin Chen, Guanhua Wang, Wenjie Sui, Ashak Mahmud Parvez, Chuanling SiThis work presents a novel and green lignin-based nanocomposite and highlights the synergism of lignin's multiple functions (surfactant, sacrificial template, and reducing agent) in the material preparation process.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Water Effects in the Heterogeneous Catalytic Valorization of Levulinic Acid into γ-Valerolactone and its Derivatives By feeds.rsc.org Published On :: Green Chem., 2020, Accepted ManuscriptDOI: 10.1039/D0GC01082K, Critical ReviewRengui Weng, Zhihao Yu, Jian Xiong, Xuebin LuLevulinic acid (LA), which has been hailed as a versatile biomass-derived platform molecular, typically occupy a core position in the cellulosic biorefinery system. The heterogeneous catalytic valorization of LA for...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Sustainable synthesis of cobalt and cobalt oxide nanoparticles and their catalytic and biomedical applications By feeds.rsc.org Published On :: Green Chem., 2020, Advance ArticleDOI: 10.1039/D0GC00885K, Critical ReviewSiavash Iravani, Rajender S. VarmaRecent advances and essential challenges as well as catalytic and biomedical applications of cobalt oxide and cobalt nanoparticles are highlighted.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Ni-Catalyzed hydrocyanation of alkenes with formamide as the cyano source By feeds.rsc.org Published On :: Green Chem., 2020, Advance ArticleDOI: 10.1039/C9GC04275J, CommunicationXiao Shu, Yuan-Yuan Jiang, Lei Kang, Luo YangA novel Ni-catayzed hydrocyanation of various alkenes to provide aliphatic nitriles is developed by generating hydrocyanic acid in situ from safe and readily available formamide.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Ni-Based Heterogeneous Catalysts for the Transformation of Fatty Acids into Higher Yields of O-Free Hydrocarbons By feeds.rsc.org Published On :: Green Chem., 2020, Accepted ManuscriptDOI: 10.1039/D0GC00853B, PaperDiego Valencia, Citlalli Zenteno, Diana Gomora-Herrera, María Teresa Gómez-Pérez, Jorge AburtoA series of novel catalytic materials were synthesized by changing the chemical compounds in the impregnation solutions. A rigid, aromatic and bidentate molecule 1,10-phenanthroline (PhN) was used as a ligand...The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
the Aqueous miscible organic layered double hydroxides as catalyst precursors for biodiesel synthesis By feeds.rsc.org Published On :: Green Chem., 2020, Advance ArticleDOI: 10.1039/D0GC00571A, PaperChunping Chen, Maxwell Greenwood, Jean-Charles Buffet, Dermot O'HareSurface area and basicity density dependence of base-catalysed transesterification of sunflower oil by potassium salt prepared AMO-layered double hydroxides.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article