the

[ASAP] Activation of C–C Bonds via s-Bond Metathesis: Hydroborenium-Catalyzed Hydrogenolysis of Cyclopropanes

Organometallics
DOI: 10.1021/acs.organomet.0c00099




the

[ASAP] Synthesis of Boryl-Substituted Disilane, Disilene, and Silyl Cation

Organometallics
DOI: 10.1021/acs.organomet.0c00148




the

[ASAP] Carboxylation of the Ni–Me Bond in an Electron-Rich Unsymmetrical PCN Pincer Nickel Complex

Organometallics
DOI: 10.1021/acs.organomet.9b00817




the

[ASAP] Electrochemical CO<sub>2</sub> Reduction — The Effect of Chalcogenide Exchange in Ni-Isocyclam Complexes

Organometallics
DOI: 10.1021/acs.organomet.0c00129




the

[ASAP] Neutral Ni(II) Catalysts Based on Maple-Lactone Derived [N,O] Ligands for the Polymerization of Ethylene

Organometallics
DOI: 10.1021/acs.organomet.0c00061




the

[ASAP] Dibromine Promoted Transmetalation of an Organomercurial by Fe(CO)<sub>5</sub>: Synthesis, Properties, and Cytotoxicity of Bis(2-C<sub>6</sub>H<sub>4</sub>-2'-py-<italic toggle="yes">?C,N</

Organometallics
DOI: 10.1021/acs.organomet.0c00107




the

[ASAP] Potentiostatically Controlled Olefin Metathesis

Organometallics
DOI: 10.1021/acs.organomet.0c00052




the

[ASAP] [2 + 2] Cycloaddition of <italic toggle="yes">o</italic>-Carboryne with Vinyl Ethers: Synthesis of Carborane-Fused Cyclobutanes

Organometallics
DOI: 10.1021/acs.organomet.0c00163




the

[ASAP] Synthesis, Characterization, and Catalytic Reactivity of {CoNO}<sup>8</sup> PCP Pincer Complexes

Organometallics
DOI: 10.1021/acs.organomet.0c00167




the

[ASAP] Revisiting the Palladium-Catalyzed Carbonylation of Allyl Alcohol: Mechanistic Insight and Improved Catalytic Efficiency

Organometallics
DOI: 10.1021/acs.organomet.0c00117




the

[ASAP] NHC-Palladium(II) Mononuclear and Binuclear Complexes Containing Phenylene-Bridged Bis(thione) Ligands: Synthesis, Characterization, and Catalytic Activities

Organometallics
DOI: 10.1021/acs.organomet.0c00091




the

[ASAP] Spatial Recognition Within Terpenes: Redox and H-bond Promoted Linkage Isomerizations and the Selective Binding of Complex Alkenes

Organometallics
DOI: 10.1021/acs.organomet.0c00151




the

[ASAP] Self-Assembled Redox-Active Tetraruthenium Macrocycles with Large Intracyclic Cavities

Organometallics
DOI: 10.1021/acs.organomet.0c00116




the

[ASAP] Effect of the Lead(II) Bond Angle on the Reactivity of Diaminoplumbylenes toward Ammonia: From Inertness to Immediate Ammonolysis

Organometallics
DOI: 10.1021/acs.organomet.0c00196




the

[ASAP] Electrosynthetic Route to Cyclopentadienyl Rhenium Hydride Complexes Enabled by Electrochemical Investigations of their Redox-Induced Formation

Organometallics
DOI: 10.1021/acs.organomet.0c00049




the

[ASAP] Synthesis and Characterization of an Oxo-Centered Homotrimetallic Uranium(IV)–Cyclobutadienyl Dianion Complex

Organometallics
DOI: 10.1021/acs.organomet.0c00104




the

[ASAP] Development of Quinoline-Derived Chiral Diaminocarbene Ligands and Their Transition Metal Complexes: Synthesis, Structural Characterization, and Catalytic Properties

Organometallics
DOI: 10.1021/acs.organomet.0c00141




the

[ASAP] Ga(N,P) Growth on Si and Decomposition Studies of the N–P Precursor Di-<italic toggle="yes">tert</italic>-butylaminophosphane (DTBAP)

Organometallics
DOI: 10.1021/acs.organomet.0c00078




the

[ASAP] Synthesis and Characterization of Tungsten Alkylidene and Alkylidyne Complexes Featuring a New Carbazole-Based Rigid Trianionic ONO<sup>3–</sup> Pincer-Type Ligand

Organometallics
DOI: 10.1021/acs.organomet.0c00150




the

[ASAP] Heteroleptic ß-Ketoiminate Magnesium Catalysts for the Ring-Opening Polymerization of Lactide

Organometallics
DOI: 10.1021/acs.organomet.0c00168




the

[ASAP] Use of Ligand Steric Properties to Control the Thermodynamics and Kinetics of Oxidative Addition and Reductive Elimination with Pincer-Ligated Rh Complexes

Organometallics
DOI: 10.1021/acs.organomet.0c00122




the

[ASAP] Sesquicarbene Complexes: Bonding at the Interface Between M–C Single Bonds and M-C Double Bonds

Organometallics
DOI: 10.1021/acs.organomet.0c00102




the

[ASAP] Synthesis, Structures, and Electronic Properties of O- and S-Heterocyclic Carbene Complexes of Iridium, Copper, Silver, and Gold

Organometallics
DOI: 10.1021/acs.organomet.0c00066




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The Difficult First Episode

In our very first episode we discuss the difficulty of writing your own online biography, the pros and cons of co-working, the move towards flat file site generation, the upcoming New Adventures in Web Design conference, the shiny new Rode iXY microphone and end with bespoke fixed gear bikes.




the

The Problem of Overfunding on KickStarter

As the web appears to have gone on holiday we present a mixed bag of goodness on Episode 010. We lament the loss of one of our zero’s, Kieran brings forth the news and the funny and we engage in a almost academic level of discourse on the issues associated with overfunding on crowdfunding platforms. Also included – a bit of Startup talk, a new Mac code editor, the new Royal baby and our first ever competition.

Lunchbox Competition

To enter the Back to Front Show lunchbox giveaway simply tweet the answer to the following question before Friday 2nd August 2013. All correct answers will be entered into the draw. If nobody guesses correctly the closest response will win.

Question: What is the height difference in inches between Kieran and Keir?





the

The One with Marc

In our first episode of 2014 I am joined by new guest co-host Marc Roberts of Neutron Creations. After a lengthy chat about his rather special coat we moved onto more web related links and finished up with a discussion on node.js. Big thanks for Marc for taking the time to come on the show.




the

Around The Web

In the first of our bi-weekly links shows we chat about the latest news on the Editorially team, have some friendly banter about startup culture and Kieran delves into the world of devices.

If you have a link for us feel free to get in touch on Twitter and Facebook.




the

Around The Web

After discussing Kieran’s classic 90’s Peugeot 306 Turbo Diesel we turn our focus back to six cuts from our web travels. This week featuring the finest in USB protection and 15 of the best productivity hacks money can’t buy.

If you like our show please feel free to leave us a review on iTunes.




the

Around The Web

This week it’s our links show in which we ask the question “does having a beard make you a better dev” as well as discuss a very meta podcast and a new team collaboration tool. You may notice a slight audio disparity towards the end. Unfortunately, Kieran’s Yeti cable fell out (professional to the end) a new mic is on order!

If you like our show please feel free to leave us a review on iTunes.





the

Back behind the Yeti&#8217;s

Back from our travels we retrun behind the Yeti’s to discuss everything from the hunt for the perfect email app to the sartorial elegance of modern tech CEO’s. This episode also features a rather spledid retreat venue only four hours from Spokane.




the

The 2014 BAFTAS

It’s that time of the year when we look back on the past 12 months and dish out our (cough, cough) highly prized awards! This year in the 2014 BAFTAS we have eight categories and round off the show with a little bit of crystal ball gazing in which we both make our predictions for 2015.

Without further ado here are the categories and winners:

  1. The award for not being a very good year in the industry: 2014
  2. Conference/event of the year: Web Teaching Day & Beyond Tellerrand Berlin
  3. Podcast of the year: Startup
  4. Most hyped app of the year: Slack
  5. Man of the year: Sean McCabe
  6. Woman of the year: Rachel Andrew
  7. Trend of the year: Privacy & Security
  8. Foo Bar of the year: #VATMOSS

Happy holidays to our all listeners. We really do appreciate including us in your weekly audio listening. See you in 2015.




the

Around the Web

Happy 2015! We are back for the new year with a look at four links that caught our attention over the holiday season. We also spill the beans on some of the topics we’ll be covering this year.

Featured in this weeks episode:

If you like our little show we’d very much appreciate a review on iTunes if you have time. Thanks!




the

The Joys &#038; Perils of Remote Working

In a change to the announced billing, an impromptu early morning phone call made us think a chat about remote working might be in order. As many of us fight the January blues, and inevitable bout of illness that the new year often brings, it felt a timely opportunity to discuss the good, and the bad, aspects of working from a distance.

Topics we discuss include:

  • How does working remotely affect us?
  • What we both like and dislike about it
  • How much real work you achieve per day
  • The importance of “banter”
  • Is the reality like the dream?
  • A typical day for remote working?
  • Do we put extra pressure on ourselves to output more as we are not in the office?
  • How to feel part of the company you work for

And finally for those Nabaztag doubters out there you can read the full history of the internet enabled rabbit on Wikipedia!

Five Simple Steps Giveaway

To be in with a chance of winning one of the two sets of Five Simple Step’s Pocket Guide Collection 3 all you have to do it answer one of the following two questions correctly. Kieran’s decision will be final (he’s a harsh judge):

  1. Q: What was Matthew Lillard’s handle in the cult-classic 1995 film Hackers?
  2. Q: In the same year Sandra Bullock played a Systems Analyst in the film The Net. During the course of the film her identity is changed by cyber criminals but what is the name they gave her?

To enter just send a tweet to @backtofrontshow with your answer. We’ll announce winners on the next episode.




the

Moving Away from the Code Face

Like a phoenix from the flames, we have risen. Our year long retreat for slightly overweight tech men from the South West of England is officially over. We’ve eaten the kale, cleansed ourselves, got the glow and are now itching to get back behind the mics. It’s out with the Yeti’s and in with a spanking new steed for Kieran and a less than great “Madonna” mic for Keir.

In this week’s episode, we discuss where on earth we’ve been for the last 13 months, chat about how we’ve moved away from the code face and share experiences of a life away from daily development.

Finally, we announce the winner of the longest competition in Back to Front Show history!

It’s good to be back.




the

The Big 40!

Three years ago we started this little adventure called The Back to Front Show. Since then we’ve somehow managed to record 39 shows. Not the best of averages but who’s counting?

In our milestone 40th show, we discuss the cake that never happened, Keir’s favourite new TV show, standing desks and end with a discussion that starts with Sarah Parmenter’s recent blog post and ends with thoughts on specialisation.

You may also be pleased to hear that our “and finally” section returns this week and features a great satire on our industry.




the

The Gavin Ballard Special

This episode is dedicated to our favourite Australian Gavin Ballard — all round good guy, world traveller, bon viveur and last but by no means least Shopify Expert. Gavin is a long time listener (we still aren’t sure why) and friend of the show. If we had a pin badge and sticker “care package” he’d be the first recipient!

Topics covered in this mega-length show include the weather in the South West, Skype video, our favourite NYC diners, the use of technology in the bathroom, career paths for developers, and more.

If you would like a show dedicated to you please let us know via the comment link below and we’ll undoubtedly make it happen.




the

The Super Lit, Fam, Dope, En Flique Episode

It feels like only last week that the two “K Units” got behind the Samson CO1UPRO‘s and recorded episode #43. So close in fact, that we even manage to think we are still actually recording episode #43!

In this short 53 minute episode, we catch up on recent life goings on, learn that Kieran has been “tamping hard” in his role as “Digital Guy” at the bespoke artisanal coffee roasting company, discuss language used by people under the age of 30, announce our new club, and round out with a chat about Kickstarter. There may even be a mention of earphones!




the

The Future of Medium?

Happy New Year to you all! Rather unsurprisingly we missed our end of year review but the outline was probably one of our best. Maybe we’ll do it next year!

This episode we catch up on Kieran’s move behind the camera, argue over what exactly constitutes a pair of Daps and delve into the future of Medium in light of Ev Williams recent announcement.

If you like the show don’t forget you can support our astronomical S3 costs by becoming an exclusive member of the Back to Front Show Club!




the

Muppetry &amp; other Stories

Happy 2018! Eschewing a long-standing tradition of not actually releasing shows we are kicking off the year as we mean to go on (for now) with a brand spanking new edition!

Join us for 50 glorious high fidelity minutes (true for one of us) and celebrate five years of the show. We don’t dwell too long on our golden non-award winning archive and go on to indulge in some chat, review a book, have a moan about Kickstarter projects, and for once don’t end on dog tech!




the

Ahmedabad lockdown: Today's news from the city




the

Rajkot achieves another techno feat

In what could be a major breakthrough for N95 masks production in India, two Rajkot-based engineering firms have developed the machine indigenously to make this medically crucial masks. Most companies making N95 masks have been procuring the manufacturing machines from China, Japan and South Korea.




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Resource Showcase: The New York Times

Did you know that you can access The New York Times via Durham University Library and Collections? As well as access to current articles, via TimesMachine you can access The New York Times archive as far back as 1851. Access The New York Times Access the archive via TimesMachine See what other newspapers and news services are available via Durham University Library and Collections




the

Synthesis of lignin-functionalized phenolic nanosphere supported Ag nanoparticles with excellent dispersion stability and catalytic performance

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04311J, Paper
Shilin Chen, Guanhua Wang, Wenjie Sui, Ashak Mahmud Parvez, Chuanling Si
This work presents a novel and green lignin-based nanocomposite and highlights the synergism of lignin's multiple functions (surfactant, sacrificial template, and reducing agent) in the material preparation process.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




the

Water Effects in the Heterogeneous Catalytic Valorization of Levulinic Acid into γ-Valerolactone and its Derivatives

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC01082K, Critical Review
Rengui Weng, Zhihao Yu, Jian Xiong, Xuebin Lu
Levulinic acid (LA), which has been hailed as a versatile biomass-derived platform molecular, typically occupy a core position in the cellulosic biorefinery system. The heterogeneous catalytic valorization of LA for...
The content of this RSS Feed (c) The Royal Society of Chemistry




the

Sustainable synthesis of cobalt and cobalt oxide nanoparticles and their catalytic and biomedical applications

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00885K, Critical Review
Siavash Iravani, Rajender S. Varma
Recent advances and essential challenges as well as catalytic and biomedical applications of cobalt oxide and cobalt nanoparticles are highlighted.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




the

Ni-Catalyzed hydrocyanation of alkenes with formamide as the cyano source

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04275J, Communication
Xiao Shu, Yuan-Yuan Jiang, Lei Kang, Luo Yang
A novel Ni-catayzed hydrocyanation of various alkenes to provide aliphatic nitriles is developed by generating hydrocyanic acid in situ from safe and readily available formamide.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




the

Ni-Based Heterogeneous Catalysts for the Transformation of Fatty Acids into Higher Yields of O-Free Hydrocarbons

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00853B, Paper
Diego Valencia, Citlalli Zenteno, Diana Gomora-Herrera, María Teresa Gómez-Pérez, Jorge Aburto
A series of novel catalytic materials were synthesized by changing the chemical compounds in the impregnation solutions. A rigid, aromatic and bidentate molecule 1,10-phenanthroline (PhN) was used as a ligand...
The content of this RSS Feed (c) The Royal Society of Chemistry




the

Aqueous miscible organic layered double hydroxides as catalyst precursors for biodiesel synthesis

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00571A, Paper
Chunping Chen, Maxwell Greenwood, Jean-Charles Buffet, Dermot O'Hare
Surface area and basicity density dependence of base-catalysed transesterification of sunflower oil by potassium salt prepared AMO-layered double hydroxides.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry