and

[ASAP] Synthesis of Boryl-Substituted Disilane, Disilene, and Silyl Cation

By feedproxy.google.com
Published On :: Wed, 08 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00148


Full Article

and

[ASAP] Neutral Ni(II) Catalysts Based on Maple-Lactone Derived [N,O] Ligands for the Polymerization of Ethylene

By feedproxy.google.com
Published On :: Fri, 17 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00061


Full Article

and

[ASAP] Dibromine Promoted Transmetalation of an Organomercurial by Fe(CO)<sub>5</sub>: Synthesis, Properties, and Cytotoxicity of Bis(2-C<sub>6</sub>H<sub>4</sub>-2'-py-<italic toggle="yes">?C,N</

By feedproxy.google.com
Published On :: Mon, 20 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00107


Full Article

and

[ASAP] (Isonitrile)platinum(II) Complexes of an Amido Bis(N-heterocyclic carbene) Pincer Ligand

By feedproxy.google.com
Published On :: Mon, 20 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00065


Full Article

and

[ASAP] Effect of Ancillary Ligands as a Part of Counteranion in Neodymium-Catalyzed Isoprene Polymerization

By feedproxy.google.com
Published On :: Tue, 21 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00112


Full Article

and

[ASAP] Development of P- and N-Chirogenic Ligands Based on Chiral Induction from a Phosphorus Donor to a Nitrogen Donor in Palladium Complexes

By feedproxy.google.com
Published On :: Wed, 22 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00154


Full Article

and

[ASAP] Update to Our Reader, Reviewer, and Author Communities—April 2020

By feedproxy.google.com
Published On :: Thu, 23 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00266


Full Article

and

[ASAP] S<sub>N</sub>2 and E2 Branching of Main-Group-Metal Alkyl Intermediates in Alkane CH Oxidation: Mechanistic Investigation Using Isotopically Labeled Main-Group-Metal Alkyls

By feedproxy.google.com
Published On :: Fri, 24 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00120


Full Article

and

[ASAP] Synthesis, Characterization, and Catalytic Reactivity of {CoNO}<sup>8</sup> PCP Pincer Complexes

By feedproxy.google.com
Published On :: Fri, 24 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00167


Full Article

and

[ASAP] Revisiting the Palladium-Catalyzed Carbonylation of Allyl Alcohol: Mechanistic Insight and Improved Catalytic Efficiency

By feedproxy.google.com
Published On :: Fri, 24 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00117


Full Article

and

[ASAP] Transformation of a Norbornadiene Unit to Ethylenylcyclopentene Requiring Cooperation between Boron and Rhodium Centers

By feedproxy.google.com
Published On :: Fri, 24 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00155


Full Article

and

[ASAP] NHC-Palladium(II) Mononuclear and Binuclear Complexes Containing Phenylene-Bridged Bis(thione) Ligands: Synthesis, Characterization, and Catalytic Activities

By feedproxy.google.com
Published On :: Sun, 26 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00091


Full Article

and

[ASAP] C–F Bond Activation of a Perfluorinated Ligand Leading to Nucleophilic Fluorination of an Organic Electrophile

By feedproxy.google.com
Published On :: Mon, 27 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00176


Full Article

and

[ASAP] Spatial Recognition Within Terpenes: Redox and H-bond Promoted Linkage Isomerizations and the Selective Binding of Complex Alkenes

By feedproxy.google.com
Published On :: Mon, 27 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00151


Full Article

and

[ASAP] Linkage Isomerism in Dinuclear Al and Ga Organometallic Complexes: Structural and Reactivity Consequences

By feedproxy.google.com
Published On :: Tue, 28 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00096


Full Article

and

[ASAP] Improving Redox Reversibility and Intermetallic Coupling of Co(III) Alkynyls through Tuning of Frontier Orbitals

By feedproxy.google.com
Published On :: Tue, 28 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00183


Full Article

and

[ASAP] Synthesis and Characterization of an Oxo-Centered Homotrimetallic Uranium(IV)–Cyclobutadienyl Dianion Complex

By feedproxy.google.com
Published On :: Wed, 29 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00104


Full Article

and

[ASAP] Development of Quinoline-Derived Chiral Diaminocarbene Ligands and Their Transition Metal Complexes: Synthesis, Structural Characterization, and Catalytic Properties

By feedproxy.google.com
Published On :: Wed, 29 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00141


Full Article

and

[ASAP] Ga(N,P) Growth on Si and Decomposition Studies of the N–P Precursor Di-<italic toggle="yes">tert</italic>-butylaminophosphane (DTBAP)

By feedproxy.google.com
Published On :: Thu, 30 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00078


Full Article

and

[ASAP] Radical Capture at Nickel(II) Complexes: C–C, C–N, and C–O Bond Formation

By feedproxy.google.com
Published On :: Thu, 30 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00021


Full Article

and

[ASAP] Reactivity of Amidinatosilylenes and Amidinatogermylenes with [PtMe<sub>2</sub>(?<sup>4</sup>-cod)]: <italic toggle="yes">cis</italic>- versus <italic toggle="yes">trans</italic>-[

By feedproxy.google.com
Published On :: Thu, 30 Apr 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00188


Full Article

and

[ASAP] Synthesis and Characterization of Tungsten Alkylidene and Alkylidyne Complexes Featuring a New Carbazole-Based Rigid Trianionic ONO<sup>3–</sup> Pincer-Type Ligand

By feedproxy.google.com
Published On :: Fri, 01 May 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00150


Full Article

and

[ASAP] Use of Ligand Steric Properties to Control the Thermodynamics and Kinetics of Oxidative Addition and Reductive Elimination with Pincer-Ligated Rh Complexes

By feedproxy.google.com
Published On :: Mon, 04 May 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00122


Full Article

and

[ASAP] Sesquicarbene Complexes: Bonding at the Interface Between M–C Single Bonds and M-C Double Bonds

By feedproxy.google.com
Published On :: Thu, 07 May 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00102


Full Article

and

[ASAP] Synthesis, Structures, and Electronic Properties of O- and S-Heterocyclic Carbene Complexes of Iridium, Copper, Silver, and Gold

By feedproxy.google.com
Published On :: Fri, 08 May 2020 04:00:00 GMT

Organometallics
DOI: 10.1021/acs.organomet.0c00066


Full Article

and

Gujarat HC restores land to civic body from royals

By timesofindia.indiatimes.com
Published On :: Sat, 09 May 2020 06:42:55 IST

The Gujarat high court rebuked the erstwhile royal family of the princely state of Bhavnagar for its "dishonest intention" to claim a land parcel in an unauthorized manner from the Bhavnagar Municipal Corporation.


Full Article

and

Synthesis of lignin-functionalized phenolic nanosphere supported Ag nanoparticles with excellent dispersion stability and catalytic performance

By feeds.rsc.org
Published On ::

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC04311J, Paper
Shilin Chen, Guanhua Wang, Wenjie Sui, Ashak Mahmud Parvez, Chuanling Si
This work presents a novel and green lignin-based nanocomposite and highlights the synergism of lignin's multiple functions (surfactant, sacrificial template, and reducing agent) in the material preparation process.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

and

Water Effects in the Heterogeneous Catalytic Valorization of Levulinic Acid into γ-Valerolactone and its Derivatives

By feeds.rsc.org
Published On ::

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC01082K, Critical Review
Rengui Weng, Zhihao Yu, Jian Xiong, Xuebin Lu
Levulinic acid (LA), which has been hailed as a versatile biomass-derived platform molecular, typically occupy a core position in the cellulosic biorefinery system. The heterogeneous catalytic valorization of LA for...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

and

Humin based resin for wood modification and property improvement

By feeds.rsc.org
Published On ::

Green Chem., 2020, Advance Article
DOI: 10.1039/C9GC03620B, Paper
Open Access
Anna Sangregorio, Anitha Muralidhara, Nathanael Guigo, Lisbeth G. Thygesen, Guy Marlair, Carlo Angelici, Ed de Jong, Nicolas Sbirrazzuoli
Focus on humins, a co-product from sugar conversion, to highlight their capacity to impregnate wood cell walls for making durable wood products.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

and

Methylation-triggered fractionation of lignocellulosic biomass to afford cellulose-, hemicellulose-, and lignin-based functional polymers via click chemistry

By feeds.rsc.org
Published On ::

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00451K, Paper
Kentaro Miki, Hiroshi Kamitakahara, Arata Yoshinaga, Yuki Tobimatsu, Toshiyuki Takano
This paper reports a new concept for the biorefinery of lignocellulosic biomass where the derivatisation and fractionation of lignocellulose are accomplished at the same time.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

and

Sustainable synthesis of cobalt and cobalt oxide nanoparticles and their catalytic and biomedical applications

By feeds.rsc.org
Published On ::

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00885K, Critical Review
Siavash Iravani, Rajender S. Varma
Recent advances and essential challenges as well as catalytic and biomedical applications of cobalt oxide and cobalt nanoparticles are highlighted.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

and

Eco-friendly and sustainable synthesis of biocompatible nanomaterials for diagnostic imaging: current challenges and future perspectives

By feeds.rsc.org
Published On ::

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC00734J, Critical Review
Ghazaleh Jamalipour Soufi, Siavash Iravani
Current advancements, important challenges and future perspectives of biocompatible nanomaterials for diagnostic imaging are discussed as well as their greener synthesis.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

and

New biobased-zwitterionic ionic liquids: efficiency and biocompatibility for the development of sustainable biorefinery processes

By feeds.rsc.org
Published On ::

Green Chem., 2020, Advance Article
DOI: 10.1039/D0GC01002B, Paper
Gaël Huet, Monica Araya-Farias, Ranim Alayoubi, Sylvain Laclef, Benjamin Bouvier, Isabelle Gosselin, Christine Cézard, Romain Roulard, Matthieu Courty, Caroline Hadad, Eric Husson, Catherine Sarazin, Albert Nguyen Van Nhien
A combination of experiments and modeling reveals the influence of alkyl chain lengths in biobased ZILs on the biocompatibility towards various microorganisms.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

and

A Strategy for The Assembly of Glypromate® and Structure-Related Analogues by Tandem Sequential Peptide Coupling

By feeds.rsc.org
Published On ::

Green Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0GC00143K, Paper
Ivo E Sampaio-Dias, Luís Pinto da Silva, Sandra G Silva, Xerardo Garcia-Mera, José Enrique Rodriguez-Borges
This work describes an improved and greener methodology in solution-phase synthesis for the preparation of Glypromate® (glycyl-L-prolyl-L-glutamic acid, GPE), a potent neuropeptide with applications in neurodegenerative conditions such as Huntington's,...
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

and

Solvent-free hydrogenation of levulinic acid to γ-valerolactone using a Shvo catalyst precursor: optimization, thermodynamic insights, and life cycle assessment

By feeds.rsc.org
Published On ::

Green Chem., 2020, 22,2443-2458
DOI: 10.1039/C9GC02088H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Christian A. M. R. van Slagmaat, Marie A. F. Delgove, Jules Stouten, Lukas Morick, Yvonne van der Meer, Katrien V. Bernaerts, Stefaan M. A. De Wildeman
We studied the solvent-free hydrogenation of levulinic acid to γ-valerolactone with the Shvo catalyst involving comparative catalysis, DFT, and LCA.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

and

Ga/ZSM-5 catalyst improves hydrocarbon yields and increases alkene selectivity during catalytic fast pyrolysis of biomass with co-fed hydrogen

By feeds.rsc.org
Published On ::

Green Chem., 2020, 22,2403-2418
DOI: 10.1039/C9GC03408K, Paper
Kristiina Iisa, Yeonjoon Kim, Kellene A. Orton, David J. Robichaud, Rui Katahira, Michael J. Watson, Evan C. Wegener, Mark R. Nimlos, Joshua A. Schaidle, Calvin Mukarakate, Seonah Kim
An integrated experimental and computational study to understand the catalytic upgrading of biomass vapors into high yield of alkenes.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

and

Dioxomolybdenum complex as an efficient and cheap catalyst for the reductive depolymerization of plastic waste into value-added compounds and fuels

By feeds.rsc.org
Published On ::

Green Chem., 2020, 22,2419-2425
DOI: 10.1039/C9GC04206G, Paper
Beatriz F. S. Nunes, M. Conceição Oliveira, Ana C. Fernandes
Several types of PCL, PLA, PDO, PET and PBT plastic waste were efficiently converted into value-added compounds and fuels catalyzed by MoO2Cl2(H2O)2.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

and

Synthesis of renewable C–C cyclic compounds and high-density biofuels using 5-hydromethylfurfural as a reactant

By feeds.rsc.org
Published On ::

Green Chem., 2020, 22,2468-2473
DOI: 10.1039/D0GC00195C, Paper
Taimei Cai, Qiang Deng, Hailong Peng, Jin Zhong, Rui Gao, Jun Wang, Zheling Zeng, Ji-Jun Zou, Shuguang Deng
Renewable C–C six-membered ring compound and high-density biofuel are synthesized using 5-hydromethylfurfural as a reactant.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

and

Novel insights into biomass delignification with acidic deep eutectic solvents: a mechanistic study of β-O-4 ether bond cleavage and the role of the halide counterion in the catalytic performance

By feeds.rsc.org
Published On ::

Green Chem., 2020, 22,2474-2487
DOI: 10.1039/C9GC02569C, Paper
André M. da Costa Lopes, José R. B. Gomes, João A. P. Coutinho, Armando J. D. Silvestre
The potentiality of acidic deep eutectic solvents for β-O-4 ether bond cleavage is herein demonstrated from a mechanistic point of view.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

and

Fabrication of highly proton-conductive chitosan whole-bio-membrane materials functionalized with adenine and adenosine monophosphate

By feeds.rsc.org
Published On ::

Green Chem., 2020, 22,2426-2433
DOI: 10.1039/C9GC04104D, Paper
Guanglei Zhao, Yuanyuan Chen, Xiao-Feng Li, Sihan Zhang, Yuanqiu Situ
A successful strategy to prepare novel proton-conductive chitosan membrane biomaterials functionalized with adenine and adenosine monophosphate via a one-pot grafting procedure.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

and

A facile solution-phase synthetic approach for constructing phenol-based porous organic cages and covalent organic frameworks

By feeds.rsc.org
Published On ::

Green Chem., 2020, 22,2498-2504
DOI: 10.1039/C9GC04033A, Paper
Lei Zhang, Rongran Liang, Cheng Hang, Haiying Wang, Lin Sun, Lei Xu, Dairong Liu, Zhenyi Zhang, Xingmin Zhang, Feifan Chang, Shengyu Zhao, Wei Huang
A general solution-phase synthetic strategy is developed to construct both porous organic cages (POCs) and covalent organic frameworks (COFs) by simply stirring and heating organic solvent/water solutions of aldehydes and amines in the presence of MOH (M = Na, K, and Cs).
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

and

Upgrading 1-butanol to unsaturated, carbonyl and aromatic compounds: a new synthesis approach to produce important organic building blocks

By feeds.rsc.org
Published On ::

Green Chem., 2020, 22,2365-2369
DOI: 10.1039/D0GC00254B, Communication
Jorge Mora Vargas, Luiz Henrique Tofaneli Morelato, Julieth Orduna Ortega, Mauricio Boscolo, Gustavo Metzker
Conversion of 1-butanol into added-value organic building blocks was achieved using fixed-bed flow reactor and Cu-based catalyst at 550 and 600 °C with and without methanol as addictive.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

and

A non-phosgene process for bioderived polycarbonate with high molecular weight and advanced property profile synthesized using amino acid ionic liquids as catalysts

By feeds.rsc.org
Published On ::

Green Chem., 2020, 22,2534-2542
DOI: 10.1039/D0GC00265H, Paper
Zhencai Zhang, Fei Xu, Yaqin Zhang, Chenhao Li, Hongyan He, Zifeng Yang, Zengxi Li
Bio-based polycarbonate with high molecular weight and advanced property profile was synthesized using amino acid ionic liquids as catalysts.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

and

Solvent-free and montmorillonite K10-catalyzed domino reactions for the synthesis of pyrazoles with alkynylester as a dual synthon

By feeds.rsc.org
Published On ::

Green Chem., 2020, 22,2388-2393
DOI: 10.1039/D0GC00162G, Communication
Sesuraj Babiola Annes, Rajendhiran Saritha, Saravanan Subramanian, Bhaskaran Shankar, Subburethinam Ramesh
A highly regioselective, solvent-free and montmorillonite K10 clay-catalyzed domino process with an unprecedented C–C bond formation reaction is described for the synthesis of new class of tri-substituted and di-substituted pyrazole derivatives.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

and

Base-mediated benzannulation of α-cyanocrotonates with ynones: facile synthesis of benzonitriles and fluorenes

By feeds.rsc.org
Published On ::

Green Chem., 2020, 22,2370-2374
DOI: 10.1039/D0GC00608D, Communication
Maneesh Kumar Reddy Singam, Attunuri Nagireddy, Sridhar Reddy Maddi
Benzonitriles and cyanofluorenes have been rapidly obtained via the [3 + 3] benzannulation of readily available alkynones and α-cyanocrotonates using KOtBu as the only reagent and EtOH (and CO2) is the only by-product.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

and

Iridium-catalyzed orthogonal and regioselective synthesis of triazole disulfides in aqueous media under mild conditions

By feeds.rsc.org
Published On ::

Green Chem., 2020, 22,2394-2398
DOI: 10.1039/D0GC00555J, Communication
Ming Li, Nan Zheng, Junhao Li, Yubin Zheng, Wangze Song
Triazole disulfides were prepared in water or biological media under mild conditions by orthogonal and regioselective Ir-catalyzed reactions.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

and

Double-metal cyanide as an acid and hydrogenation catalyst for the highly selective ring-rearrangement of biomass-derived furfuryl alcohol to cyclopentenone compounds

By feeds.rsc.org
Published On ::

Green Chem., 2020, 22,2549-2557
DOI: 10.1039/C9GC04432A, Paper
Xiang Li, Qiang Deng, Lian Yu, Rui Gao, Zhikun Tong, Chenxi Lu, Jun Wang, Zheling Zeng, Ji-Jun Zou, Shuguang Deng
Herein, novel green synthetic routes to 4-hydroxy-2-cyclopentenone (HCP) and 2-cyclopentenone (CPE) from biomass-derived furfuryl alcohol via double-metal cyanide catalysis are proposed.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

and

Properties and activity of Zn–Ta-TUD-1 in the Lebedev process

By feeds.rsc.org
Published On ::

Green Chem., 2020, 22,2558-2574
DOI: 10.1039/D0GC00103A, Paper
Open Access
Guillaume Pomalaza, Pardis Simon, Ahmed Addad, Mickaël Capron, Franck Dumeignil
A zinc and tantalum-containing mesoporous silica catalyst highly active and selective in the Lebedev process has been prepared using the one-pot TUD-1 methodology. Characterization established a correlation between acidity and butadiene formation.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article

and

Evaluating lignin valorization via pyrolysis and vapor-phase hydrodeoxygenation for production of aromatics and alkenes

By feeds.rsc.org
Published On ::

Green Chem., 2020, 22,2513-2525
DOI: 10.1039/C9GC04245H, Paper
Open Access
Alireza Saraeian, Alvina Aui, Yu Gao, Mark M. Wright, Marcus Foston, Brent H. Shanks
Lignin valorization to chemicals is an important component of creating economically viable biofuels production from lignocellulosic biomass.
The content of this RSS Feed (c) The Royal Society of Chemistry


Full Article