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Versatile poly(N-vinylcaprolactam)-grafted-hydroxypropyl cellulose polymers with tailored thermo- and pH-responsive properties via sustainable organocatalyzed atom transfer radical polymerization

By pubs.rsc.org
Published On ::

Polym. Chem., 2024, 15,4244-4254
DOI: 10.1039/D4PY00931B, Paper
Muhammad Asif Iqbal, Asif Mahmood, Waheed Al-Masry, Chan Ho Park, Sadaf Ul Hassan, Toheed Akhter
This study explores the synthesis of dual pH- and thermo-responsive poly(N-vinylcaprolactam)-grafted-hydroxypropyl cellulose (PNVCL-g-HPC) polymers via visible-light-driven, metal-free organocatalyzed atom transfer radical polymerization (O-ATRP).
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Heterogenous catalysis for oxygen tolerant photoredox atom transfer radical polymerization and small-molecule dehalogenation

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Published On ::

Polym. Chem., 2024, 15,4264-4280
DOI: 10.1039/D4PY00899E, Paper
Open Access
Kriti Kapil, Mingkang Sun, Ting-Chih Lin, Hironobu Murata, Grzegorz Szczepaniak, Khidong Kim, Stephen DiLuzio, Jaepil Jeong, Mitchell Baumer, Stefan Bernhard, Tomasz Kowalewski, Krzysztof Matyjaszewski
Heterogeneous photocatalysts (PCs) have garnered attention for their sustainability and cost-effectiveness.
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Tetrazine-based inverse-electron-demand Diels–Alder reaction: a powerful tool for fabrication and functionalization of polymeric materials

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Published On ::

Polym. Chem., 2024, 15,4173-4195
DOI: 10.1039/D4PY00912F, Review Article
Open Access
Mehmet Arslan, Aysun Degirmenci, Rana Sanyal, Amitav Sanyal
The IEDDA click reaction plays an important role in the fabrication and functionalization of polymeric materials.
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Emerging trends in the chemistry of polymeric resists for extreme ultraviolet lithography

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Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00957F, Review Article
Jie Cen, Zhengyu Deng, Shiyong Liu
Patterning materials have advanced significantly to achieve high-resolution fabrication of integrated circuits for extreme ultraviolet (EUV) lithography. Emerging trends in the chemistry of polymeric resists for EUV lithography are summarized.
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Green perspective drives the renaissance of anionic diene polymerization

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Published On ::

Polym. Chem., 2024, 15,4297-4311
DOI: 10.1039/D4PY00805G, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Moritz Rauschenbach, Moritz Meier-Merziger, Holger Frey
Polymers based on 1,3-diene monomers play a pivotal role in many commercial elastomers and thermoplastic elastomers. This review summarizes the state of the art and recent developments in the living anionic polymerization of dienes.
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Comment on “Limonene as a renewable unsaturated hydrocarbon solvent for living anionic polymerization of β-myrcene” by A. Dev, A. Rösler and H. Schlaad, Polym. Chem., 2021, 12, 3084

By pubs.rsc.org
Published On ::

Polym. Chem., 2024, 15,4364-4365
DOI: 10.1039/D4PY00913D, Comment
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Akhil Dev, Alexander Rösler, Helmut Schlaad
Polymyrcenyllithium chains in DL-limonene solution are present as dimeric associates and not as single chains.
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Functionalization of nano-objects in living anionic polymerization-induced self-assembly and their use for improving thermal properties of epoxy resins

By pubs.rsc.org
Published On ::

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY01008F, Paper
Guicun Guo, Jiali Wu, Jingwei Zhang, Peng Zhou, Ding Shen, Penghan Li, Guowei Wang
Using LAPISA or LAPICA, stabilized PDVB@(PI-b-PS) and PDVB@(PI-b-PS/PS) nano-objects were prepared, functionalized and used as additives for epoxy resin, providing improved Tgs, integrated interfaces, uniform distributions, and scalable applications.
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Expanding the poly(2-oxazoline) block copolymer possibilities through nitroxide mediated polymerisation

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Published On ::

Polym. Chem., 2024, 15,4416-4424
DOI: 10.1039/D4PY00887A, Paper
Open Access
James Lefley, C. Remzi Becer
In recent years, poly(2-oxazoline)s (POx) have become a sought-after biomaterial to replace PEG. Endcapping POx with BlocBuilder MA enables copolymerization with a variety of vinylic monomers, producing unique POx-vinyl block copolymer combinations.
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Bio-photo-Fenton-like RAFT polymerization under blue light

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Published On ::

Polym. Chem., 2024, 15,4447-4453
DOI: 10.1039/D4PY00593G, Paper
James L. Grace, Greg G. Qiao
An oxygen-tolerant bio-photo-Fenton RAFT polymerization method that possesses good livingness and temporal control.
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Acid-labile and non-degradable cross-linked star polymer model networks by aqueous polymerization for in situ encapsulation and release

By pubs.rsc.org
Published On ::

Polym. Chem., 2024, 15,4454-4464
DOI: 10.1039/D3PY00677H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Gavin Irvine, Stuart Herron, Daniel W. Lester, Efrosyni Themistou
Aqueous RAFT polymerization for the preparation of degradable and non-degradable cross-linked star polymer model networks, in situ dye encapsulation and release.
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Increase of spatiotemporal resolution and reproducible layer thicknesses in cationic vat photopolymerization

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Published On ::

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY01046A, Paper
Emile Goldbach, Xavier Allonas, Christian Ley, Lucile Halbardier, Céline Croutxé-Barghorn
Pyridines allow a good control of the cationic photopolymerization of epoxies.
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Bisbenzothieno[b]-fused BODIPYs in panchromatic photoinitiating for the free radical and cationic photopolymerization and application in 3D printing

By pubs.rsc.org
Published On ::

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00926F, Paper
Yangyang Xu, Wenlong Tang, Hui Deng, Jianjun Zhang, Zhongquan Zhu, Changjiang Yu, Haiguang Zhu, Ke Sun, Jiazhu Li, Jacques Lalevée
Abstract: Polymerization reactions induced by lights occupy an increasing share in the area of polymer synthesis; however, the effective photopolymerization under visible light emitting diodes (LEDs) rather than UV still...
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Reversible aminolysis: a new concept for postpolymerization modification

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Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00827H, Communication
Koki Kasai, Hideki Amii, Ryohei Kakuchi
Efficient yet reversible aminolysis postpolymerization modification reactions.
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Alternating Radical Copolymerization of α-Styrylboronic Acid Pinacol Ester with Electron-Deficient Olefins

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Published On ::

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00976B, Paper
Yiyang Xiao, Zepeng Zhang, Yan Xu, Jianbo Wang
Here, α-styryl boronic acid pinacol ester (StBpin) has been found to undergo alternating radical copolymerization with electron-deficient olefin comonomers, including n-butyl acrylate, N,N-dimethylacrylamide, acrylonitrile, and N-ethylmaleimide. Compared with styrene, which...
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Diversified synthesis of poly(sulfonyl isourea)s by multicomponent polymerizations of isocyanides, sulfonyl azides, and alcohols/phenols

By pubs.rsc.org
Published On ::

Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00953C, Paper
Dongyang Fan, Fenggang Chen, Dong Wang, Ting Han, Ben Zhong Tang
A novel multicomponent polymerization strategy using diverse monomer combinations of isocyanides, sulfonyl azides, and alcohols/phenols was developed to synthesize thermally and morphologically stable and heteroatom-rich poly(sulfonyl isourea)s.
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Axial-phenyl Constrained Bis(imino)acenaphthene-Nickel Precatalysts Enhancing Ethylene Polymerization

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Published On ::

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01110D, Paper
Quanchao Wang, Qiuyue Zhang, Yizhou Wang, Song Zou, Yanping Ma, Tongling Liang, Wen Hua Sun
To enhance the performance of the bis(imino)acenaphthene-nickel precatalyst, the axial phenyl group is introduced on the acenaphthenyl backbone forming five analogues, bis(aryl)imino-5-phenylacenaphthene nickel bromides (aryl: 2,6-dimethylphenyl, Ni1; 2,6-diethylphenyl, Ni2; 2,6-diisopropylphenyl,...
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Catalytic copolymerization of carbon dioxide and cyclohexene oxide by a trinuclear cyclohexane-bridged tetradentate Schiff base chromium complex

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Polym. Chem., 2024, 15,4519-4528
DOI: 10.1039/D4PY00956H, Paper
Jie Huang, Boxiong Shen
The development of catalytic systems is a central area of research in carbon dioxide (CO2) and epoxy copolymerization.
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Acrylate–methacrylate radical copolymerization kinetics of sparingly water-soluble monomers in polar and nonpolar solvents

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Polym. Chem., 2024, 15,4542-4553
DOI: 10.1039/D4PY01015A, Paper
Noushin Rajabalinia, Fatemeh Salarhosseini, Robin A. Hutchinson
The influence of solvent on radical copolymerization kinetics is studied to provide insight to emulsion polymerization systems.
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Synthesis of degradable polyester with high molecular weight and excellent mechanical properties through copolymerization modification of poly(butylene succinate)

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Polym. Chem., 2024, 15,4570-4579
DOI: 10.1039/D4PY01050G, Paper
Hongji Wang, Xiaojun Ma, Hanyu Yao, Haohao Chang, Yin Lv, Zhong Wei
The degradable copolymer of polybutylene succinate (PBS) modified with tricyclodecane dimethanol (TCD) presented significantly enhanced tensile strength and elongation at break.
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Interpretable machining learning assisted insights into bifunctional squaramide catalyzed ring-opening polymerization of lactide

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Polym. Chem., 2024, 15,4562-4569
DOI: 10.1039/D4PY00866A, Paper
Shaoju Cao, Mengting Hong, Junyuan Hu, Zhenjiang Li, Jin Huang, Kai Guo
A bifunctional squaramide catalyst with tunable activity enables the controlled ring-opening polymerization of lactide. Combining bench experiments and interpretable machine learning offer insights into catalyst structures, promoting catalyst design.
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Polymer chemistry informed neural networks (PCINNs) for data-driven modelling of polymerization processes

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Polym. Chem., 2024, 15,4580-4590
DOI: 10.1039/D4PY00995A, Paper
Nicholas Ballard, Jon Larrañaga, Kiarash Farajzadehahary, José M. Asua
A method for training neural networks to predict the outcome of polymerization processes is described that incorporates fundamental chemical knowledge. This permits generation of data-driven predictive models with limited datasets.
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A highly active zinc-based catalyst system for lactide homo- and copolymerization under industrially relevant conditions

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Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY01034E, Paper
Zisheng Zhang, Yi Zhou, Shuang Liu, Baixue Li, Rui Qu, Yanan Gu, Hongyi Suo, Yusheng Qin
A guanidine-based zinc catalyst with a rigid backbone exhibited excellent activity in the ring-opening polymerization and copolymerization of lactide.
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Long-term leaching kinetics and solution chemistry of aqueous BaTiO3 powder suspensions: a numerical model supported experiment

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J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01708K, Paper
Marcus Bentzen, Vojtěch Lindauer, Pavel Mokrý, Ragnhild Elizabeth Aune, Julia Glaum
The advent of lead-free perovskite materials with favorable toxicity profiles has made them candidates for in vivo and environmental applications.
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Structural isomerism engineering regulates molecular AIE behavior and application in visualizing endogenous hydrogen sulfide

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J. Mater. Chem. B, 2024, 12,11134-11141
DOI: 10.1039/D4TB01617C, Paper
Yaxi Li, Yong-Xiang Wang, Dujuan Liu, Chen-Chieh Ni, Jianming Ni, Jen-Shyang Ni
The isomerization effect on coumarin-based AIEgens was systematically analyzed and further applied to H2S detection.
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Drug-delivery and biological activity in colorectal cancer of a supramolecular porous material assembled from heptameric chromium-copper-adenine entities

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J. Mater. Chem. B, 2024, 12,11156-11164
DOI: 10.1039/D4TB01521E, Paper
Sandra Mena-Gutiérrez, Ekain Maiza-Razkin, Jon Pascual-Colino, Marcos J. Araúzo-Bravo, Garikoitz Beobide, Oscar Castillo, Ainara Castellanos-Rubio, Daniela Gerovska, Antonio Luque, Sonia Pérez-Yáñez
Supramolecular metal-organic porous materials as drug delivery systems, modulation of the release kinetics using cholesterol as pore blocking agent and its impact on colorectal cancer cell cultures: cytotoxicity and RNA-seq transcriptomics studies.
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Captain America Chris Evans Weds

By www.rediff.com
Published On :: Mon, 11 Sep 2023 10:48:17 +0530

The wedding was attended by several of the couple's friends including Chris Hemsworth (who plays Thor in the Marvel Cinematic Universe) and his wife Elsa Pataky, Robert Downey Jr (Iron Man in the MCU) and Susan Downey, Jeremy Renner (Hawkeye in the MCU), John Krasinski and his wife Emily Blunt.


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Organoboron-mediated polymerizations

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Chem. Soc. Rev., 2024, 53,3384-3456
DOI: 10.1039/D3CS00115F, Review Article
Yao-Yao Zhang, Guan-Wen Yang, Chenjie Lu, Xiao-Feng Zhu, Yuhui Wang, Guang-Peng Wu
This review provides a comprehensive summary of organoboron-mediated free radical polymerization, Lewis pair polymerization, ionic polymerization, and polyhomologation, laying the groundwork for further establishment of polymerization methods.
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Emerging polymeric materials for treatment of oral diseases: design strategy towards a unique oral environment

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Chem. Soc. Rev., 2024, 53,3273-3301
DOI: 10.1039/D3CS01039B, Review Article
Open Access
Bo Jia, Beibei Zhang, Jianhua Li, Jinlong Qin, Yisheng Huang, Mingshu Huang, Yue Ming, Jingjing Jiang, Ran Chen, Yufen Xiao, Jianzhong Du
We highlight the recent progress and design strategies of polymeric materials with tailored functions to overcome the highly movable and wet, microbial and inflammatory environment in the oral cavity for treatment of oral diseases.
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How to spacewalk : step-by-step with shuttle astronauts / created by Kathryn D. Sullivan, the first American woman to walk in space, and Michael J. Rosen ; illustrated with images from NASA and drawings by Michael J. Rosen

By darius.uleth.ca
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Sullivan, Kathy, 1951- author


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Lipidic biomass as a renewable chemical building block for polymeric materials

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04993D, Feature Article
Rafael Turra Alarcon, Gabriel Iago Iago, Caroline Gaglieri, Aniele De Moura, Éder Tadeu Gomes Cavalheiro, Gilbert Bannach
Polymers are intrinsically connected to our modern society and are found and used in different technologies. Although polymers are worthwhile, concerns about synthetic polymers from non-renewable sources have arisen. Therefore,...
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Polymeric antibubbles with strong ultrasound imaging capabilities

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Chem. Commun., 2024, 60,13340-13343
DOI: 10.1039/D4CC03572K, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Roman A. Barmin, Jens Köhler, Michael Pohl, Bea Becker, Fabian Kiessling, Twan Lammers, Albert T. Poortinga, Roger M. Pallares
Antibubbles are liquid droplets encapsulated by a gas film and are proposed for ultrasound-triggered drug release. Here, we develop polymeric microbubbles with greater ultrasound imaging response than conventional Pickering-stabilized antibubbles.
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Polymeric membrane ion-selective electrode based on potential-modulated ion transfer: ultrasensitive measurement of oceanic pH

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Chem. Commun., 2024, 60,13404-13407
DOI: 10.1039/D4CC04807E, Communication
Lu Liu, Yuanxin Liu, Tianjia Jiang, Rongning Liang, Wei Qin
A simple approach to improve the precision of potentiometric sensors is proposed based on potential-modulated ion transfer without memory effects.
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Bioinspired hydrogels: polymeric designs towards artificial photosynthesis

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Chem. Commun., 2024, 60,13314-13324
DOI: 10.1039/D4CC04033C, Feature Article
Open Access
Reina Hagiwara, Ryo Yoshida, Kosuke Okeyoshi
This Feature Article outlines the design of polymer networks for water splitting induced by visible light to develop artificial chloroplasts. The network serves as a mediator for photoinduced electron transfer among precisely organised molecules.
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Metal-free photocatalysts with charge-transfer excited states enable visible light-driven atom transfer radical polymerization

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Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04470C, Communication
Yuchen Huang, Yangxin Liu, Yingde Yan, Yanjun Gong, Yifan Zhang, Yanke Che, Jincai Zhao
Photoredox-catalyzed atom transfer radical polymerization (O-ATRP) offers powerful tools for the precise control of polymer synthesis. Metal-free photocatalysts are particularly desirable due to their high level of control in O-ATRP...
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Merits of generosity

By www.thehindu.com
Published On :: Tue, 18 Oct 2016 00:01:52 +0530


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18 kDa TSPO specific ligand based polymeric nanoformulation: Synthesis, computational and biological studies

By pubs.rsc.org
Published On ::

New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ00463A, Paper
Priya Singh, Vijay K. Singh, Dipti Kakkar, Anjani Kumar Tiwari
The 18 kDa Translocator protein (TSPO) serves as a promising target for drug delivery and imaging applications. In this investigation, we have encapsulated MCBP, a TSPO compound based on acetamidobenzoxazolone,...
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Depolymerization mechanism of MgO on a silicate microstructure under different CaO contents: a theoretical and experimental study

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Published On ::

New J. Chem., 2024, 48,7480-7488
DOI: 10.1039/D4NJ00454J, Paper
Maierhaba Abudoureheman, Lanzhen He, Fangru Ma, Bo Wei, Jianjiang Wang, Quan Zhu, Hong Yao
The mechanism of the effect of MgO on the microstructure depolymerization of Zhundong coal ash under the condition of different CaO contents was studied using molecular dynamics simulation and experimental methods.
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Mentalist Suhani Shah is all set to mesmerise Bangaloreans

By www.thehindu.com
Published On :: Thu, 06 Oct 2022 13:50:13 +0530

Suhani Shah, said to be India’s first female mentalist, will be performing in Bengaluru this weekend as part of her silver jubilee celebrations in the field of magic


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Polymeric polyiodo-chlorotellurates(IV): new supramolecular hybrids in halometalate chemistry

By pubs.rsc.org
Published On ::

CrystEngComm, 2024, 26,2018-2024
DOI: 10.1039/D4CE00088A, Paper
Nikita A. Korobeynikov, Andrey N. Usoltsev, Maxim N. Sokolov, Alexander S. Novikov, Sergey A. Adonin
Reaction between TeO2 and I2 in HCl afforded a series of supramolecular hybrids Cat2{[TeCl6](I2)} (1–5) where diiodine fragments are linked to [TeCl6]2− octahedra via halogen bonds (XB).
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Extended isomerism in heteronuclear metal-organic frameworks: synthetic strategies and crystal structures of lanthanide-cobalt-oxydiacetate systems

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CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00168K, Paper
Fernando Igoa, Agustín López Cabrera, Javier Gonzalez-Platas, Leopoldo Suescun, Carlos Kremer, Julia Torres
Here, we present the synthesis and crystal structure of a series of heteronuclear metal-organic frameworks, which consists of cobalt(II) and lanthanide(III) ions or yttrium(III), connected by oxydiacetato (oda2-) as ligand....
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PM Modi virtually inaugurates new manufacturing plant of medical devices at Meril Company in Vapi

By www.newkerala.com
Published On :: Wed, 30 Oct 2024 21:26:02 +0530


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Photochromism of phenazine-2,3-diol derivatives through excited state intermolecular proton transfer based on keto–enol tautomerization

By pubs.rsc.org
Published On ::

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00387J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Kazuki Ohira, Kumpei Kozuka, Naoki Kaneda, Masahiro Yamamoto, Keiichi Imato, Yousuke Ooyama
It was found that phenazine-2,3-diol derivatives exhibit photochromism through excited state intermolecular proton transfer (ESInterPT) processes based on keto–enol tautomerization.
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Cu(OTf)2/HFIP catalyzed regioselective cycloisomerization of indole-C3-functionalized alkynols to carbazoles

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Published On ::

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00421C, Communication
Srinivasarao Yaragorla, Tabassum Khan, Sayonika Chakroborty
We report here a simple and atom economic cycloisomerization reaction of indole-tethered alkynols for constructing diverse carbazoles via 1,2-alkly migration using Cu(OTf)2/HFIP as the excellent promoter system.
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Photoproperties of Favipiravir and their 6-Substituted Analogues: Fluorescence Controlled through Halogen Substitution and Tautomerism

By pubs.rsc.org
Published On ::

Org. Biomol. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4OB00397G, Paper
Angel H Romero, Marcos Couto, Ivan E Romero, German Fuentes, Matías N. Möller
Herein, we showed the photophysical properties of the favipiravir and their 6-substituted analogues. Also, we interpreted the origin of the fluorescence of the favipiravir and their 6-substituted analogues as function...
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What's This American Doing In Bollywood?

By www.rediff.com
Published On :: Thu, 18 Apr 2024 13:45:18 +0530

'In India, I'm able to work with the biggest stars on creating a scene, creating that emotion, without being too hung up on their persona.'


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Ahead of Telangana election, Turmeric Board constituted

By www.thehindu.com
Published On :: Wed, 04 Oct 2023 21:28:10 +0530

The Board is expected to help develop and grow the spice’s market in India, which controls over 62% share of the turmeric world trade


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Sceptical Nizamabad farmers ask why PM has not laid foundation stone for Turmeric Board

By www.thehindu.com
Published On :: Sat, 25 Nov 2023 22:25:36 +0530

After dominating the region’s electoral stage for almost a decade, turmeric has lost its sheen; the PM’s announcement of a National Turmeric Board has not satisfied farmers, who also ask for MSP


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The great American outdoors

By www.thehindubusinessline.com
Published On :: Mon, 01 Jan 2018 14:58:18 +0530

A trek through one of the more memorable national parks of the US


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Journal of Southeast Asian American education & advancement [electronic resource] : JSAAEA

By darius.uleth.ca
Published On ::

Dorchester, Mass. : National Association for the Education and Advancement of Cambodian, Laotian, and Vietnamese Americans


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Watch | Directors’ Take: How director Sashi Kiran Tikka approached ‘Goodachari’ and ‘Major’ like an American indie

By www.thehindu.com
Published On :: Thu, 01 Jun 2023 12:06:08 +0530

Sashi Kiran Tikka, director of ‘Goodachari’ and ‘Major’, looks back at the indie approach to filmmaking, collaborative work atmosphere and his days at the New York Film Academy


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