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Diversified synthesis of poly(sulfonyl isourea)s by multicomponent polymerizations of isocyanides, sulfonyl azides, and alcohols/phenols

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Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY00953C, Paper
Dongyang Fan, Fenggang Chen, Dong Wang, Ting Han, Ben Zhong Tang
A novel multicomponent polymerization strategy using diverse monomer combinations of isocyanides, sulfonyl azides, and alcohols/phenols was developed to synthesize thermally and morphologically stable and heteroatom-rich poly(sulfonyl isourea)s.
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Sequence-defined structural transitions by calcium-responsive proteins

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Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00907J, Paper
Marina Chang, Winnie Huang, Gatha Shambharkar, Kenny Hernandez, Danielle Jamie Mai
Biopolymer sequences dictate their functions, and protein-based polymers are a promising platform to establish sequence–function relationships for novel biopolymers. To efficiently explore vast sequence spaces of natural proteins, sequence repetition...
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Crystallization ripening and erosion of calcium oxalate under the effect of bacteria and a polymer materials surface

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J. Mater. Chem. B, 2024, 12,10893-10901
DOI: 10.1039/D4TB01780C, Paper
Xiran Shen, Wentao Chen, Li Guo, Huayu Li, Hong Chen, Fan Liu
New insights into the role of bacteria in pathological biomineralization inspire novel anti-encrustation polymer material design for biomedical use.
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Intrafibrillar Calcium Carbonate Mineralization of Electrospinning Polyvinyl Alcohol/Collagen Films with Improved Mechanical and Bioactive Properties

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J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01472C, Paper
Yin Liu, Xin Gao, Yuqi Li, Anqi Gao, Zhuozhi Zheng, Jingjiang Wei, Hongye Yang, Hang Ping, Hao Xie, Hao Wang, Weiming Wang, Zhengyi Fu
Collagen films play an essential role in guided bone regeneration (GBR) techniques, which creat space, promote cell adhesion, and induce osteogenic differentiation. It is therefore crucial to design appropriate GBR...
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Correction: Blood-clotting model and simulation analysis of polyvinyl alcohol–chitosan composite hemostatic materials

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J. Mater. Chem. B, 2024, 12,11265-11266
DOI: 10.1039/D4TB90174F, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yifan Zhao, Junhong Hao, Zexin Chen, Mengmeng Li, Jianxun Ren, Xiaobing Fu
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Munawar's Sea Of Fans Welcome Him Home

By www.rediff.com
Published On :: Tue, 30 Jan 2024 11:25:20 +0530

'My fans always supported me and whenever I was left behind, they pulled me by holding my hand, so I am very grateful.'


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‘Gold Diggers’ and the alchemy of truth

By www.thehindubusinessline.com
Published On :: Sun, 18 Jul 2021 11:28:46 +0530

Part immigrant novel, part coming-of-age tale, Sanjena Sathian’s debut marks a shift in the way the Indian American experience is distilled into fiction


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Storing liquid chromatographic separations on surface energy traps: decoupling the LC and the mass spectrometer

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Analyst, 2024, 149,5336-5343
DOI: 10.1039/D4AN00828F, Paper
Timothy T. Salomons, David Simon, Richard Oleschuk
A micro-fractionation device to archive liquid chromatographic separations on an array of surface energy traps.
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Electrochemical Sensing of Sodium ions present in Bovine Serum using 4-tert Butylcalix[4]arene as Receptor

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Analyst, 2024, Accepted Manuscript
DOI: 10.1039/D4AN01297F, Paper
Adrian Ebenazer Paul, Gaurav Gaur, Abdullah Alswieleh, Jerry J. Wu, Sambandam Anandan
The concentration of sodium ions can cause severe imbalances (high pressure on blood vessels, swelling of the muscular tissues, and misfunctioning of the whole nervous system) to the system in...
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Impact of blue light on cutaneous barrier structures and properties: NPLC/HR-MSn and Raman analyses

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Analyst, 2024, Advance Article
DOI: 10.1039/D4AN01244E, Paper
Léa Habib, Rime Michael-Jubeli, Marie Abboud, Roger Lteif, Ali Tfayli
Blue light alters lipids and proteins in the reconstructed human epidermis.
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Insights of the peroxychloroformyl radical ClC(O)OO via microwave spectrum

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Phys. Chem. Chem. Phys., 2024, 26,27669-27676
DOI: 10.1039/D4CP03506B, Paper
Ching-Hua Chang, Wen Chao, Cheng-Han Tsai, Mitchio Okumura, Frank A. F. Winiberg, Yasuki Endo
Pure rotational spectra of trans-ClC(O)O2 (left) and cis-ClC(O)O2 (right), and the potential energy curve connecting the two conformers. The energy diagram and the observed transitions for the trans-ClC(O)O2 are also shown.
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A theoretical investigation on the OER and ORR activity of graphene-based TM–N3 and TM–N2X (X = B, C, O, P) single atom catalysts by density functional theory calculations

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Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP03779K, Paper
Jiaxiang Wu, Erjun Kan, Cheng Zhan
Promising ORR/OER single atom catalysts have been designed in the form of TM–N2X via DFT simulation.
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Optimization of preparation conditions and design of device configurations for Cu3AsS4 solar cells: a combined study of first-principles calculations and SCAPS-1D device simulations

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Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03392B, Paper
Yi Huang, Changqing Lin, Yang Xue, Bingyuan Huang, Dan Huang
Former studies have investigated the band structure and optoelectronic properties of Cu3AsS4 and suggested that it is a promising photovoltaic (PV) absorber. However, its power conversion efficiency (PCE) from experiments...
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DFT rationalization of the mechanism and selectivity in a gold-catalyzed oxidative cyclization of diynones with alcohols

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Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP01700E, Paper
Guowei Yan, Ji Ma, Simeng Qi, Alexander M. Kirillov, Lizi Yang, Ran Fang
The mechanism, regioselectivity, and chemoselectivity in a gold-catalyzed oxidative cyclization of diynones with alcohols to give furan-3-carboxylate derivatives were explored by density functional theory (DFT).
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Investigating Ni nanoparticles on CeO2 for methane dissociation: a comparative study of theoretical calculations and experimental insights

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Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP01324G, Paper
Takaya Fujisaki, Yuta Tsuji, Phuc Hoan Tu, Tin Chanh Duc Doan, David S. Rivera Rocabado, Aleksandar Tsekov Staykov, Keiji Yashiro, Yusuke Shiratori
CeO2 supported with Ni nanoparticles has emerged as a promising catalyst for enhancing the efficiency of dry reforming of methane (DRM) reaction.
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Calculating maintenance charges

By www.thehindu.com
Published On :: Fri, 30 Jan 2015 14:42:18 +0530

Your property-related legal queries answered by S.C. RAGHURAM, Partner, RANK Associates, a Chennai-based law firm


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Warm welcome and felicitations mark the return of the Indian hockey team

By www.thehindu.com
Published On :: Sat, 10 Aug 2024 18:53:06 +0530

The tired players, led by Harmanpreet Singh, express satisfaction with the performance at the Paris Olympics


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SSLC exam: board invites applications

By www.thehindu.com
Published On :: Thu, 03 Sep 2015 00:00:00 +0530


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Biindigen! : Amik says welcome / Nancy Cooper ; illustrated by Joshua Mangeshig Pawis-Steckley

By darius.uleth.ca
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Cooper, Nancy, 1967- author


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Mae and Gerty and the matter with matter / by Elaine Vickers ; illustrated by Erica Salcedo

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Vickers, Elaine, author


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Volcanoes / written by Nell Cross Beckerman ; illustrated by Kalen Chock

By darius.uleth.ca
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Beckerman, Nell Cross, 1973- author


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Welcome, rain! / by Sheryl McFarlane ; illustrated by Christine Wei

By darius.uleth.ca
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McFarlane, Sheryl, 1954- author


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Taking care of where we live : restoring ecosystems / Merrie-Ellen Wilcox ; illustrated by Amanda Key

By darius.uleth.ca
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Wilcox, Merrie-Ellen, author


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Alcohol beverage start-ups pour a stiff competition

By www.thehindubusinessline.com
Published On :: Sun, 25 Feb 2024 20:15:00 +0530

Newly minted makers of alcoholic beverages put up spirited fight in a market ruled by legacy corporations


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CO insertion enabled γ-C(sp3)–H heteroarylative carbonylation of tertiary alcohols via heteroaryl migration

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05361C, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xin Qi, Yuanrui Wang, Xiao-Feng Wu
A carbonylative γ-C(sp3)–H functionalization of alcohols via migration of heteroaryl groups to produce 1,4-diketones has been developed.
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Revealing the structural influence mechanism of intrinsic potassium/calcium elements on bio-waste-derived hard carbon for sodium-ion batteries

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Chem. Commun., 2024, 60,13380-13383
DOI: 10.1039/D4CC03546A, Communication
Yinghao Zhang, Chun Wu, Qinghang Chen, Chuangchuang Li, Wenjie Huang, Qianxiong Wen, Xiang-Xi He, Xingqiao Wu, Shu-Lei Chou
The evolution mechanism of hard carbon structures in terms of graphitization and pore structure caused by K/Ca has been clarified.
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The call of kulchas

By www.thehindu.com
Published On :: Sat, 19 Nov 2016 15:42:55 +0530

Discover special Amritsari kulchas in Central Delhi


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Unveiling the influence of oxidation state and heavy atom effects in chalcogen group on boron centered D(X)BNA core: a computational study on RTP versus TADF

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Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00131A, Paper
Ramalingam Mahaan, Murugesan Panneerselvam, Luciano T. Costa, Aruljothy John Bosco
The effects of heavy atoms and oxidation states in chalcogen groups on D(X)BNA cores, combined with substitutions of weak and strong donors, led to the identification of potential TADF and RTP molecules among the 14 molecules.
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He welcomes us

By www.thehindu.com
Published On :: Mon, 08 Aug 2016 00:32:04 +0530


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Mother Teresa declared Saint Teresa of Calcutta

By www.thehindu.com
Published On :: Sun, 04 Sep 2016 14:37:43 +0530

In his homily after Mother Teresa’s canonisation, Pope Francis admitted even he would find it hard to call her “St. Teresa” since her tenderness was so maternal.


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Synergistic effects of vanadium incorporation in cobalt-based LDH on electron and proton transfer during electrocatalytic benzyl alcohol oxidation

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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00728J, Paper
Jingjing Bai, Liang Chen, Chenghang Lv, Hongyu Ruo, Yanlong Pan, Shoudong Xu, Jiaqi Chen, Bingchuan Yang, Ding Zhang, Huimin Yang
Electricity-driven water splitting is a promising approach for cost-effective and environment-friendly hydrogen production.
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Catalytic Ethynylation of Formaldehyde for Selective Propargyl Alcohol Production Using the Copper Metal Organic Framework HKUST-1

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New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D3NJ06001B, Paper
Wanxi Yang, Wencai Peng, Han Li, Jin Mao, Liqiang Qian, Qingyu Zhang
HKUST-1 with high crystallinity has been successfully synthesized by solvothermal method using Cu(NO3)2·3H2O as a copper source, 1,3,5-benzenetricarboxylic acid as organic ligand, and N,N-dimethylformamide as solvent. HKUST-1 exhibited a typical...
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Metal–organic frameworks constructed using acid–base mixed ligands, carboxylic acids and N-containing chalcone, and their catalytic performance for Knoevenagel condensation

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New J. Chem., 2024, Advance Article
DOI: 10.1039/D3NJ05164A, Paper
Limin Cheng, Junyong Zhang, Caihong Zhan, Hao Xu, Chunhua Gong, Jingli Xie
MOF materials constructed using acid–base mixed ligands serve as efficient and economical porous heterogeneous catalysts for Knoevenagel condensation.
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Isolation and characterization of novel degradation products in Fenoverine by LC-QTOF-MS/MS, LC-MSn and 2D-NMR

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New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D3NJ05623F, Paper
Krishnam Raju CH, Shanmukha Kumar Jagarlapudi, Yesudas Kada, Sanath Kumar Goud Palusa
This study investigates the degradation profile of Fenoverine (FEN), an antispasmodic drug, following the International Conference on Harmonization (ICH) Q1A (R2) guidelines. FEN is stable in the presence of light,...
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Synthesis of copper(II) complex-functionalized Fe3O4@ISNA (ISNA = isonicotinic acid) as a magnetically recoverable nanomaterial: catalytic studies in alcohol oxidation and nitrophenol reduction, and TD-DFT studies

By pubs.rsc.org
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New J. Chem., 2024, 48,7308-7322
DOI: 10.1039/D3NJ05440C, Paper
Rimpa Mondal, Aratrika Chakraborty, Ennio Zangrando, Madhulata Shukla, Tanmay Chattopadhyay
The synthesis of a magnetically separable nanocatalyst Fe3O4@ISNA@CuL1 used as a catalyst for oxidation of alcohols and reduction of nitrophenols.
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Effective synthesis of diethyl carbonate over Mg–Y composite oxides via alcoholysis of ethyl carbamate

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New J. Chem., 2024, 48,7489-7496
DOI: 10.1039/D3NJ05757G, Paper
Peixue Wang, Shimin Liu, Xinjiang Cui, Yang Wu, Feng Shi
Effective synthesis of diethyl carbonate from ethyl carbamate and ethanol using Mg–Y composite oxides.
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Carbon dots analysis of charge transfer intrinsic capacity based on the analytic calculation of chemical reactivity descriptors

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New J. Chem., 2024, 48,7244-7255
DOI: 10.1039/D4NJ01100G, Paper
Jesús A. Lara-Cerón, Roberto Flores-Moreno, José A. Flores-Ramos, Gururaj K. Jayaprakash
Carbon dots analysis of charge transfer intrinsic capacity based on the analytic calculation of chemical reactivity descriptors.
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Facile synthesis of spiro-pyrazolone-tetrahydrofurans/pyrans: ipso-cyclization of arylidene pyrazolones with haloalcohols

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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00447G, Paper
Kavyashree Kuppayya Gond, Mahagundappa Rachappa Maddani
Facile synthesis of spiro-pyrazolone-tetrahydrofurans & pyrans by base-mediated cascade ipso-cyclization of haloalcohols & arylidine pyrazolones is realised. Features include brief reaction time, practicality, good yields and mild reaction conditions.
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Calcium L-aspartate nanoparticles modify root ultrastructure and improve plant yield in Brassica napus L.

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Environ. Sci.: Nano, 2024, Accepted Manuscript
DOI: 10.1039/D3EN00989K, Paper
kesong lu, jiayu hou, Riaz Muhammad, Babar Saba, Abd-Elkader Ali M., El-Desouki Zeinab, Cun-cang Jiang
Calcium (Ca) is an indispensable nutrient in plant development. Nanoparticles (NPs) are widely used in agricultural production, among which calcium L-aspartate nanoparticles (Ca(L-asp)-NPs), as a new type of Ca fertilizer,...
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Local concentration controls the hydrate phase of calcium oxalate

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01286G, Paper
Zhaodong Wang, Lala Du, Qihang Wang, Jingjing Xie, Zhengyi Fu, Zhaoyong Zou
The calcium oxalate phase selection in supersaturated solution is determined by a combination of thermodynamic and kinetic factors.
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Fans Welcome GOAT With Firecrackers

By www.rediff.com
Published On :: Thu, 05 Sep 2024 14:29:22 +0530

Thalapathy Vijay-starrer GOAT released to much fanfare and celebration.


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Sunny Leone Welcomes Ganpati

By www.rediff.com
Published On :: Mon, 09 Sep 2024 18:56:22 +0530

Film folk celebrated Ganesh Chaturthi with gusto over the weekend, and posted pictures on social media.


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Qualcomm bullish on India’s automotive growth, eyes major expansion in auto tech

By www.thehindubusinessline.com
Published On :: Fri, 25 Oct 2024 08:53:35 +0530

At the recent Snapdragon Summit, Qualcomm launched the Snapdragon Cockpit Elite and Ride Elite platforms, designed to enhance in-car entertainment and automated driving experiences


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Telcos creating a false equivalence with satellite operators on spectrum pricing : Amazon, Starlink

By www.thehindubusinessline.com
Published On :: Sun, 03 Nov 2024 18:26:51 +0530

Reliance Jio, which is pushing for auctioning spectrum, said that arguments that satellite frequencies are always assigned in a shared mode and on a non-exclusive basis are both factually and technically incorrect and should be ignored


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Electrochemical selective divergent C–H chalcogenocyanation of N-heterocyclic scaffolds

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Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00448E, Communication
Kusum Ucheniya, Pooja Kumari Jat, Amreen Chouhan, Lalit Yadav, Satpal Singh Badsara
An electrochemical direct selective C–H chalcogenocyanation approach for indolizine derivatives under mild conditions has been described.
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