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New treatment option for young women with hormone-sensitive breast cancer

A drug used for treating breast cancer, known as exemestane, is more effective than a common breast cancer prevention drug, tamoxifen, in preventing breast cancer recurrence in young women who also receive post-surgical treatment to suppress ovarian function. The combined results of the Tamoxifen and Exemestane Trial and Suppression of Ovarian Function Trial were presented at the 2014 ASCO Annual Meeting in Chicago.




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IIT Kharagpur-led study says tropical rainforests could survive global warming

The study, published online in the Elsevier journal, was conducted on records of rainforests in sediments from Gujarat’s Vastan coal mines deposited in coastal lagoons around 56 million years ago




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Centre releases ₹266.8 crore under 15th Finance Commission grants for rural local bodies in Kerala

Allocation represents second instalment of untied grants for 2024-25, and is meant for all eligible district panchayats, block panchayats and gram panchayats in Kerala




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Waqf Board can initiate criminal proceedings in post-2013 Waqf land encroachment cases

A Single Judge of the Kerala High Court quashed the proceedings against two people in an alleged pre-2013 land encroachment case on Tuesday by noting that such acts were made punishable only through an amendment to the Waqf Act in 2013, the accused were in possession of the property even before the introduction of the amendment, and no penal acts could be given retrospective operation




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Cambodia to deploy over 16,000 security forces for water festival this week




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Africa's elephant population declines by 70 per cent over past 50 years: study




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Africa's policymakers, educators seek ways to end learning poverty on continent




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Coast Guard Chief S Paramesh calls on India's High Commissioner to Sri Lanka, discusses maritime security




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Canada: Peel Police requests temple body to postpone event amid 'threats'




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Indian Embassy in Kathmandu calls on diaspora to sign-up for Pravasi Bharatiya Divas Convention of January




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South Africa expects G20 summit to strengthen multilateralism




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Four-day Africa Tech Festival 2024 kicks off in Cape Town




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Carpet fibres used by Australian researchers to make stronger concrete




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Modi honoured Marathi by giving it classical language status, Amit Shah




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Gujarat: Consumers can lodge electricity-related complaints online at any time




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‘Unfortunate that Congress failed to rein in its rebel candidates…effect could be felt in 7-8 seats’: NCP leader Jayant Patil




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[LINK] Mark Boulton on “A Richer Canvas”

I won’t lie to you: I might’ve pounded the table emphatically a few times while reading Mark Boulton’s latest entry:

We can now design effective adaptive layouts that respond to their environment. If these layouts are based on a system that defines its ratios from the content, then there is connectedness on two levels: connectedness to the device, and connectedness to the content.

Mark’s thinking about flexible, content-driven grids has me damned excited about his upcoming talk at AEA Boston, and you know I’ll be flinging fistfuls of lucre at my laptop screen whenever his new book’s available to preorder.

The web really feels fun again.




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Non-classical electrostriction in calcium-doped cerium oxide ceramics

J. Mater. Chem. A, 2024, 12,9173-9183
DOI: 10.1039/D3TA07512E, Paper
Ahsanul Kabir, Victor Buratto Tinti, Simone Santucci, Maxim Varenik, Samuel Griffiths, Sebastian Molin, Igor Lubomirsky, Vincenzo Esposito
Oxygen-defective metal oxides, e.g., acceptor-doped CeO2, demonstrate exceptionally large electrostrictive responses compared to state-of-the-art electromechanically active ceramic materials.
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Electrochemical nitrate reduction for ammonia production: amorphous or crystalline oxidized copper catalyst?

J. Mater. Chem. A, 2024, 12,8689-8693
DOI: 10.1039/D3TA07506K, Communication
Quanxiao Peng, Dandan Xing, Liuqi Dong, Yuhan Fu, Jixue Lu, Xiaoyu Wang, Changhong Wang, Chunxian Guo
An amorphous oxidized copper (a-O–Cu) is designed to investigate for electrochemical nitrate reduction to ammonia. It is found that a-O–Cu has high capability for water dissociation and amorphous structure-enabled high catalytic activity.
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Crystal reconstruction and defect healing enabled high-quality Sb2Se3 films for solar cell applications

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00734D, Paper
Qi Zhao, Bo Che, Haolin Wang, Xiaoqi Peng, Junjie Yang, Rongfeng Tang, Changfei Zhu, Tao Chen
A post-sulfurization technique has been developed to refine Sb2Se3 crystallization. This process enables high-quality Sb2Se3 with a smooth surface, large compact crystal grains and benign [hkl] growth orientation. It also mitigates the device VOC deficit, owing to the healed deep level defects.
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Porous carbon nitride rods as an efficient photoanode for water splitting and benzylamine oxidation

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00237G, Paper
Sanjit Mondal, Gabriel Mark, Ayelet Tashakory, Michael Volokh, Menny Shalom
A polymeric carbon nitride layer with controlled directionality, morphology, and nitrogen defects serves as a photoanode to allow photoelectrochemical (PEC) water-splitting and benzylamine oxidation.
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Correction: Superhydrophobic and mechanical properties enhanced the electrospinning film with a multiscale micro-nano structure for high-efficiency radiation cooling

J. Mater. Chem. A, 2024, 12,9241-9241
DOI: 10.1039/D4TA90062F, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lijing Kong, Puqing Sun, Jincheng Liu, Yongxing Lin, Chao Xiao, Chao Bao, Kang Zheng, Meng Xue, Xian Zhang, Xianglan Liu, Xingyou Tian
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Retraction: Nickel nanoparticles immobilized on three-dimensional nitrogen-doped graphene as a superb catalyst for the generation of hydrogen from the hydrolysis of ammonia borane

J. Mater. Chem. A, 2024, 12,9247-9247
DOI: 10.1039/D4TA90071E, Retraction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Mojtaba Mahyari, Ahmad Shaabani
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Superhydrophilic covalent organic frameworks accelerate photocatalytic production of hydrogen peroxide through proton channels

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01785D, Paper
Xiaojuan Bai, Linlong Guo, Tianqi Jia, Zhuofeng Hu
Superhydrophilic COFs with D–A structure accelerate photocatalytic synthesis of H2O2 using water as a proton supply reservoir.
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A review of noble metal-free high entropy alloys for water splitting applications

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00690A, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Hamzah Kamaruddin, Zhang Jianghong, Liang Yu, Wei Yuefan, Huang Yizhong
Nano-sized high entropy alloy (HEA) catalysts have attracted much attention as extraordinary electrocatalysts in water-splitting applications, i.e., the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER).
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Photothermal conversion enabled temperature modulation for the growth of complex polymorphic architectures of calcium carbonate

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00802B, Paper
Boning Shi, Lifu Zhang, Zeda Yang, Jiangnan Deng, Shun An, Benwei Fu, Chengyi Song, Peng Tao, Tao Deng, Wen Shang
As a highly efficient and eco-friendly heat generation approach, photothermal conversion process has been applied to many important areas such as desalination and medical treatments. We explored in this work...
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Aggregation between oligomeric Ir photosensitizers promote efficient and long-lifetime photocatalytic hydrogen evolution

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D3TA07365C, Paper
Yifan Huang, Shihan Liu, Bo Wang, Ying Wang, Yifan Zhang, Pengyang Deng
In this paper, the aggregation effect between oligomeric Ir photosensitizers on photocatalytic hydrogen evolution was first discovered and investigated. Four oligomeric Ir photosensitizers were synthesized by copolymerization of [Ir(ppy)2(dabpy)](PF6) (H1)...
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Design of Interfacial Dual Schottky Junctions to Modulate Charge Transfer for Enhanced Piezo-assisted Photocatalytic Degradation RhB Performances

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00619D, Paper
Xiaoqi Jiang, Shengdong Sun, Yuqiao Wang, Lebing Zhao, Fangzhi Huang, Shikuo Li
Regulating charge transfer is a great challenge to improving the efficiency of piezoelectric photocatalytic reactions. Herein, sandwich-like Bi2WO6@Ag/MXene nanoflower spheres (BWO@Ag/MXene) with piezoelectric/plasma dual characteristics were synthesized by a facile...
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Probing the potential of Al2CO/SiC heterostructures for visible light driven photocatalytic water splitting using first-principles strategies

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00885E, Paper
Amina Shehbaz, Abdul Majid, Hira Batool, Mohammad Alkhedher, Sajjad Haider, Kamran Alam
Photocatalytic water splitting is a sustainable and eco-friendly method for renewable energy production. The fabrication of an efficient photocatalyst based on two-dimensional (2D) interfaces with suitable band offsets is at...
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Structure/interface synergistic stabilizes high-nickel cathodes for lithium-ion batteries

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01230E, Paper
Guihong Mao, Liming Zeng, Jieyu Yang, Tengyu Yao, Fanming Xiao, Renheng Tang, Xin Shu, Ying Wang, Laifa Shen
Due to with high specific capacity, high nickel layered oxides have been at the forefront of the development of high-energy density lithium-ion batteries. However, high nickel cathodes invariably suffer from...
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Oxygen vacancy-induced efficient hydrogen spillover in Ni17W3/WO3−x/MoO3−x for a superior pH-universal hydrogen evolution reaction

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00729H, Paper
Open Access
Yiqing Sun, Yiwei Bao, Di Yin, Xiuming Bu, Yuxuan Zhang, Kaihang Yue, Xiaoshuang Qi, Ziyan Cai, Yongqiang Li, Xiulan Hu, Johnny C. Ho, Xianying Wang
By regulating the oxygen vacancy in the WO3−x/MoO3−x support synergistically, the active phase transition can be accomplished at low voltage, resulting in fast intermediate hydrogen uptake/transfer/desorption kinetics on the prepared catalyst surface and interface.
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Engineering electronic band structure of ternary thermoelectric nanocatalysts for highly efficient detection of hydrogen sulfide

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00438H, Paper
Hongyuan Shang, Xiaofei Zhang, Aiping Zhang, Jinwen Du, Ruiping Zhang
This study rationally designs a ternary thermoelectric nanocatalyst PtTeCu nanorod for the accurate detection of hydrogen sulfide in biomedical applications.
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A sacrificial separator facilitating in situ creation of a durable CEI layer and tailoring lithium dendrites for practical lithium metal batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01234H, Paper
Sung Joon Park, Yun Jeong Choi, Jaemun Cheon, Hyungjun Kim, Jong-Won Lee, Taeeun Yim, Ki Jae Kim
The TBB–PE separator can form a robust and uniform boron-rich CEI (cathode electrolyte interphase) layer on the cathode surface via electrochemical oxidation as well as inhibit the growth of lithium dendrites by anion anchoring.
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Enhanced catalytic activity and stability of SOFC electrodes through plasma-driven surface modification

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA06111F, Paper
Open Access
Hyunduck Shin, Jongsu Seo, SungHyun Jeon, Seung Jin Jeong, Jinwook Kim, Siwon Lee, Jeong Jin Lee, WooChul Jung
Plasma-induced surface amorphization prevents Sr phase separation, boosting the catalytic activity and stability of SOFC cathode. This finding expands the application of amorphous features to practical electrodes, previously limited to model studies.
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Atomically Dispersed Ru Sites on MOF-derived NC-ZnO for Efficient Oxygen Evolution Reaction in Acid Media

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00586D, Paper
Sagar Varangane, Ragunath Madhu, Saad Mehmood, Bhavya Jaksani, Vidha Bhasin, Moses Abraham Abraham Bokinala, Ammavasi Nagaraj, Chandra Shobha Vennapoosa, Venkata Subba Reddy Basireddy, Subrata Kundu, Ujjwal Pal
Developing acid-stable oxygen evolution/reduction reaction (OER/ORR) electrocatalysts is essential for high-performance water splitting. Still, the slow kinetics of the ORR and OER during the discharge and charge processes seriously impede...
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Scalable preparation of flexible heterogeneous graphene oxide structures for high performance wet power generation

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01819B, Paper
Yu Gao, Xiaoming Cai, Yuzhou Zhao, Wentian Huang, Jian Lv, Jie Wang, Zhenliang Hao, Huiming Liang, Honglin Tan, Jinming Cai
Moisture-driven energy generation (MEG) has attracted great attention in recent years, and the interaction of functionalized nanomaterials with water offers the possibility of MEG. However, current MEG devices require specific...
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Bi-intercalated vanadium pentoxide synthesized via hydrogen peroxide-induced phase transition for highly stable cathode in aqueous zinc ion batteries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07984H, Paper
Jian-an Chen, Xuejun Hou, Xueli Wang, Chunxia Wang, Jiawei Wen, Yongjie Bu, Guoyong Huang, Tiantian Cao, Shengming Xu
Operating principle of aqueous zinc-ion batteries (ZIBs).
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Structure–property–performance relationship of vanadium- and manganese-based metal–organic frameworks and their derivatives for energy storage and conversion applications

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00736K, Review Article
Reza Abazari, Soheila Sanati, Ashok Kumar Nanjundan, Qiyou Wang, Deepak P. Dubal, Min Liu
The current review discusses on vanadium- and manganese-based metal–organic frameworks and their derivatives for energy storage and conversion applications along with the potential future advancements in these fields.
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A bioinspired sulfur-surrounded iron catalyst for ammonia synthesis

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00710G, Paper
Na Zhang, Yubing Si, Qiang Fu, Xing Chen
A nitrogenase-inspired inorganic compound consisting of iron (Fe) and molybdenum disulfide (MoS2) is designed with a promising capability of N2 fixation using first principles.
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Metal–support interaction triggered d–p orbital hybridization for efficient electrocatalytic semi-hydrogenation of alkynes

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01240B, Paper
Qiong Wan, Jiaxun Zhang, Xuan Liu, Huizhi Li, Abdullah, Taotao Ren, Qiyuan Liu, Yongheng Xu, Jia Liu, Jicheng Liu, Bingqing Yao, Yiyun Fang, Xinzhe Li, Chi He
Atomic restructuring in Pd/Fe2O3 catalysts weakens Pd binding to chemisorbed 4-aminophenylacetylene and hydrogen intermediates, boosting conversion and selectivity in 4-aminophenylacetylene semi-hydrogenation, surpassing Pd/C and other catalysts.
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Enhanced photocatalytic activity in Mn-doped multiferroic BiFeO3

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00886C, Paper
Jafar Hussain Shah, Zhi Huaqian, Rashid Mehmood, Ali Imran Channa, Jamal Kazmi, Liang Zhang, Federico Rosei, Zhiming Wang
Mn doping in ferroelectric BiFeO3 enhanced photocatalytic activity through the synergistic effect of the enhanced band bending on the surface as a result of internal screening of polarization bound charges and formation of inter-band energy levels while shifting the energy bands closer together.
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Co–Co2C catalysts supported on carbon-coated ordered mesoporous silica with promoted CO insertion and C–C coupling for higher alcohol synthesis from syngas

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01179A, Paper
Zhuoshi Li, Siqi Fan, Zhuang Zeng, Shaoxia Guo, Xiaofeng Pei, Shouying Huang, Yong Wang, Yue Wang, Xinbin Ma
Co–Co2C catalysts supported on carbon-coated ordered mesoporous silica showed superior performance for HAS than catalysts with uncoated and amorphous supports.
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Development of diverse aluminium concentration gradient profiles in Ni-rich layered cathodes for enhanced electrochemical and thermal performances

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00433G, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xinwei Jiao, Junwei Yap, Junbin Choi, Mengyuan Chen, Devendrasinh Darbar, Gongshin Qi, Xiaosong Huang, Jung-Hyun Kim
Nickel (Ni)-rich cathodes with elemental concentration gradients within particles have attracted great interest due to their considerably enhanced interfacial stability and electrochemical performance for advanced Li-ion batteries.
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Size and orientation of polar nanoregions characterized by PDF analysis and using a statistical model in a Bi(Mg1/2Ti1/2)O3–PbTiO3 ferroelectric re-entrant relaxor

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00240G, Paper
Laijun Liu, Kaiyuan Chen, Dawei Wang, Manuel Hinterstein, Anna-Lena Hansen, Michael Knapp, Biaolin Peng, Xianran Xing, Yuanpeng Zhang, Jing Kong, Abhijit Pramanick, Mads Ry Vogel Jørgensen, Frederick Marlton
Local structure information of relaxor ferroelectrics is key to a clear understanding of their structure–property relationships. The size of polar nanoregions is determined based on the local atomic displacement and dielectric response.
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A heterostructured WO3–SnO2 nanocomposite for the efficient photocatalytic production of H2O2 under visible light

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01223B, Paper
Diya Xie, Chen Chen, Yaru Wang, Cheng Sun, Yiming Xu, Jianguo Huang
A WO3–SnO2 (WSN) nanocomposite was synthesized with unique heterostructures formed in-between the two phases, resulting in the efficient production of H2O2 under visible light due to the synergistic effect.
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Regulating Pt-Covalent Triazine Frameworks Schottky Junction by Tailor-Made Nitrogen Sites towards Efficient Photocatalysis

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00618F, Paper
Chao Li, Lijiang Guan, Jin Zhang, Cheng Cheng, Zhaoqi Guo, Zhihong Tian, Li-Ming Yang, Shangbin Jin
Covalent triazine frameworks (CTFs) of designable nitrogen-rich structures, which can form Schottky Junction with Pt nanoparticles, have been extensively studied in photocatalysis. However, how to tune the interaction inside the...
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Cationic Radical Metal–Organic Framework Enabling Low Water Evaporation Enthalpy and High Photothermal Conversion Efficiency for Solar-Driven Water Purification

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01126K, Paper
Zi-Yu Wang, Rui Wang, Hannah M Johnson, Lei Cai, An-An Zhang, Qiang Zhang, Tianfu Liu
Solar vapor generation is a promising and sustainable strategy to purify seawater and contaminated water sources. Yet, efficient integration between solar capture and desalination remains a critical challenge. In this...
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Renewable Aromatic Hydrocarbons from Waste Cooking Oil over Hierarchical Imidazole Supported Zeolite

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00416G, Paper
Bipul Sarkar, Bhanu Joshi, Omvir Singh, Ankit Agrawal, Neha Dhiman, Bhanu Prasad Vempatapu, Navin Gopinathan , Anjan Ray
Unlike coal, oil, or natural gas, waste cooking oil (WCO) acts as a renewable source of carbon. It can be converted into energy, fuels, and fine chemicals, instead of being...
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Modulation of active metal species in MOF-derived catalysts for Efficient NO reduction by CO

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA01075B, Paper
Ning-Rui Zhou, Zhen Yang, Ying Tang, Ming-Qi Zhang, Yun-Peng Zha, Min-Min Liu, Feng Yu, Jiang Liu
Transition metal oxides are usually used as one of the most excellent catalysts for NO selective catalytic reduction by CO (CO-SCR), but their catalytic activity is limited by the content...
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High-performance planar Zn-ion micro-capacitors

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00300D, Paper
Open Access
Yujia Fan, Xiaopeng Liu, Nibagani Naresh, Yijia Zhu, Iman Pinnock, Tianlei Wang, Mingqing Wang, Ivan P. Parkin, Buddha Deka Boruah
Proposing a planar zinc-ion micro-capacitor, featuring battery type anode and supercapacitor type cathode to offer intermediate energy storage performance, boasting greater energy density than typical supercapacitors, superior power density compared to batteries, and minimal self-discharge rates.
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