ca Maha election officials seize over Rs 500 crores cash, valuables in Assembly polls season By www.ibtimes.co.in Published On :: Wed, 13 Nov 2024 17:40:00 +0530 The Maharashtra Chief Electoral Officer (CEO) has said that its vigilance squads have made seizure of more than Rs 500 crores from across the poll-bound state in the past few days. Full Article
ca India hosts senior cancer physicians, policymakers from Bay of Bengal countries By www.ibtimes.co.in Published On :: Wed, 13 Nov 2024 18:58:41 +0530 India hosted senior cancer physicians and policymakers from BIMSTEC countries during the annual meeting of National Cancer Grid (NCG) held at Mumbai's Tata Memorial Hospital. Full Article
ca Laapataa Ladies renamed as Lost Ladies: Aamir Khan, Kiran Rao host special screening amid Oscars campaign in NY By www.ibtimes.co.in Published On :: Wed, 13 Nov 2024 15:55:07 +0530 On November 12, a new poster for the film was revealed, accompanied by a caption that read, "Official entry: India. Best International Feature Film - 97th Academy Awards." Full Article
ca Abhay Deol's surprising regret about Dev D: 'It became cool, but that wasn't the point' By www.ibtimes.co.in Published On :: Wed, 13 Nov 2024 19:06:26 +0530 Anurag Kashyap's Dev D featuring Abhay Deol and Kalki Koechlin is not only one of the director's best works but also brought fame to the actors. But Abhay Deol shares some shocking details. Full Article
ca 7 latest images of space objects captured by NASA James Webb Telescope - India.com By news.google.com Published On :: Thu, 14 Nov 2024 01:56:15 GMT 7 latest images of space objects captured by NASA James Webb Telescope India.comNASA James Webb Space Telescope captures 5 stunning images of space objects HT Tech8 beautiful space images shared by NASA James Webb telescope DNA IndiaProtogalaxies as seen by the James Webb Space Telescope (IMAGE) EurekAlertAmazing James Webb Space Telescope's View Of Carina Nebula MSN Full Article
ca Manoj Bajpayee recalls experiencing starvation, would gatecrash film sets during lunchtime to get a meal: ‘Was shooed away by production guys’ - The Indian Express By news.google.com Published On :: Wed, 13 Nov 2024 05:45:26 GMT Manoj Bajpayee recalls experiencing starvation, would gatecrash film sets during lunchtime to get a meal: ‘Was shooed away by production guys’ The Indian ExpressSuperstars of Bharat: Unveiling Incredible Icons on HT’s brand new web series MintThis actor lived on a rooftop, starved for days, gatecrashed film sets for food; became one of India's biggest DNA IndiaManoj Bajpayee recalls early struggles: 'Gatecrashed film sets for a meal, was shooed away’ TOI EtimesManoj Bajpayee on perseverance, family, and following his passion Hindustan Times Full Article
ca iPhone SE 4 Camera Production Set to Begin Ahead of March 2025 Launch, Report Reveals - Analytics Insight By news.google.com Published On :: Wed, 13 Nov 2024 13:00:00 GMT iPhone SE 4 Camera Production Set to Begin Ahead of March 2025 Launch, Report Reveals Analytics InsightiPhone SE 4 leaks: 7 big upgrades India TodayApple iPhone SE 4 to launch next year, likely to become the cheapest iPhone to support Apple Intelligence... MoneycontroliPhone SE 4 Camera Production to Begin Soon Ahead of Anticipated Debut in March 2025: Report Gadgets 360iPhone SE 4 may spell trouble for iPhone 16 and premium Android phones, here’s why Hindustan Times Full Article
ca She Became CEO of Her Whole Company By Raising Her Hand and Saying This By www.entrepreneur.com Published On :: Wed, 13 Nov 2024 14:30:00 GMT Nobody cares what you want unless you speak up to tell them. That's how Tracy Panase became CEO of Just Between Friends. Full Article false
ca Bad Hires Can Cost You Thousands to Replace — and AI May Be to Blame. Try These 3 Ways to Ensure You Don't Fall Into Its Trap. By www.entrepreneur.com Published On :: Wed, 13 Nov 2024 16:00:00 GMT Over-relying on AI-driven hiring tools means taking human intuition out of the hiring process. The result? You miss out on top talent and risk stifling long-term growth. Full Article false
ca This Strategy is the Key to Scaling Your Business — and Reducing Costs Along the Way By www.entrepreneur.com Published On :: Wed, 13 Nov 2024 17:00:00 GMT Scaling a business meaningfully and sustainably can be challenging and requires more than ambition. Offshore staffing enables the flexibility and efficiency needed to thrive in today's fast-paced market. Full Article false
ca How This Professional Poker Player Became an AI Pioneer By www.entrepreneur.com Published On :: Wed, 13 Nov 2024 19:10:00 GMT Sergio Suarez Jr., founder and CEO of Tackle AI, shares how he built a successful tech company from the ground up. Full Article false
ca Spotify teases a ‘super premium’ tier for superfans and upcoming video expansion in Q3 earnings call By techcrunch.com Published On :: Wed, 13 Nov 2024 18:12:39 +0000 Spotify CEO Daniel Ek has once again teased the company’s long-delayed HiFi or “super premium” tier, a higher-qualify subscription offering the streaming service first announced in 2021 and then failed to roll out. In the company’s third-quarter earnings call with investors on Wednesday, the exec suggested that such a product was still on the way, […] © 2024 TechCrunch. All rights reserved. For personal use only. Full Article Apps Media & Entertainment hifi Premium Spotify streaming service subscriptions super fan apps Video
ca Zydus Healthcare Limited & Ors. vs Alder Biochem Private Limited on 13 November, 2024 By indiankanoon.org Published On :: 13.11.2024 MINI PUSHKARNA, J: I.A. 14145/2023 (Application under Order XXXIX Rules 1 & 2 read with Section 151 CPC, 1908) 1. The present application has been filed on behalf of the plaintiffs under Order XXXIX Rules 1 and 2 of Code of Civil Procedure, 1908 ("CPC") seeking interim injunction for restraining the defendant from manufacturing, selling, offering for sale, advertising and/or promoting by using the mark/ trade name „ALDER BIOCHEM‟ and any other mark/ trade name/ label/ device that contains the trademark BIOCHEM. Full Article
ca Dejo Kappan vs Deccan Herald on 7 November, 2024 By indiankanoon.org Published On :: Dr. A.K.Jayasankaran Nambiar, J. These writ petitions raise an interesting question as regards the scope, content and extent of the right to freedom of speech and expression enuring to the media when they report facts about ongoing criminal investigations or the proceedings in cases pending adjudication before the various adjudicatory forums in the country. The writ petitions were initially considered by a Full Bench of this Court. However, by an order dated 24.05.2018, the Full Bench took the view that in the light of an earlier decision of another Full Bench of this Court in S. Sudin v. Union of India and Others - [2015 (2) KLT 296 (FB)], these matters needed to be referred to a Larger Bench of five Judges for consideration. It is thus, and pursuant to an order dated 02.09.2024 of the Hon'ble the Acting Chief Justice, that these matters are now before us. Full Article
ca M/S. Cadila Pharmaceuticals Ltd. ... vs The Dy.Commissioner Of Income Tax, ... on 12 November, 2024 By indiankanoon.org Published On :: These cross appeals are filed by the Revenue and Assessee against order dated 12.03.2020 passed by the CIT(A)-1, Ahmedabad for the Assessment Year 2012-13. 2. The Revenue has raised the following grounds of appeal :- ITA Nos.345 & 383/Ahd/2020 Assessment Years: 2012-13 "(1) The ld. CIT(A) has erred in facts and law in deleting the transfer pricing adjustment made in respect of Corporate guarantee fees of Rs.60,83,440/- (2) The id. CIT(A) has erred in facts and law in deleting the interest disallowance of Rs.1,64,86,560/- u/s.36(1)(iii) of the Act. Full Article
ca The Dy.Commissioner Of Income Tax, ... vs M/S. Cadila Pharmaceuticals Ltd. , ... on 12 November, 2024 By indiankanoon.org Published On :: These cross appeals are filed by the Revenue and Assessee against order dated 12.03.2020 passed by the CIT(A)-1, Ahmedabad for the Assessment Year 2012-13. 2. The Revenue has raised the following grounds of appeal :- ITA Nos.345 & 383/Ahd/2020 Assessment Years: 2012-13 "(1) The ld. CIT(A) has erred in facts and law in deleting the transfer pricing adjustment made in respect of Corporate guarantee fees of Rs.60,83,440/- (2) The id. CIT(A) has erred in facts and law in deleting the interest disallowance of Rs.1,64,86,560/- u/s.36(1)(iii) of the Act. Full Article
ca Rajiv Singh vs Department Of Telecommunications on 13 November, 2024 By indiankanoon.org Published On :: and background of the case: The Appellant filed an RTI application dated 21.09.2023 seeking information on following points:- "What kind of punishment is sanctioned by the law for any Pilot who gets the RTR permit or licence on the basis of false documents?" The CPIO, Sr. DWA (COP & regulations) vide letter dated 05.10.2023 replied as under:- "- Information sought does not fall under purview of RTI Act 2005, hence this RTI is closed" Dissatisfied with the response received from the CPIO, the Appellant filed a First Appeal dated 08.10.2023. The FAA vide order dated 08.11.2023 stated as under:- "Reply :- I have gone through the case and found that information sought was denied by the CPIO stating that the information did not fall under the purview of the RTI Act, 2005. The undersigned is convinced with the above reply in view of Section 8-1(j) of the RTI Act. 2005." Full Article
ca Rajiv Singh vs Department Of Telecommunications on 13 November, 2024 By indiankanoon.org Published On :: and background of the case: The Appellant filed an RTI application dated 21.09.2023 seeking information on following points:- "To, Shri Umang Srivastva Sr.DWA (COP) I had complained on 05/05/2023 against Rahul Sinha regarding his COP permit. What action or inquiry has been conducted in this regard?" The CPIO, Sr DWA (COP & Regulation) vide letter dated 05.10.2023 replied as under:- "Information sought does not fall under purview of RTI Act 2005, hence this RTI is closed" Dissatisfied with the response received from the CPIO, the Appellant filed a First Appeal dated 08.10.2023. The FAA, JWA vide order dated 08.11.2023 stated as under:- "Reply :- I have gone through the case and found that information sought was denied by the CPIO stating that the information did not fall under the purview of the RTI Act, 2005. The undersigned is convir.ced with the above reply in view of Section 8-1(j) of the RTI Act. 2005." Full Article
ca Lalit Kamal vs Geological Survey Of India on 13 November, 2024 By indiankanoon.org Published On :: and background of the case: The Appellant filed an RTI application dated 19.07.2023 seeking information on following points:- "1. Copy of complete report with all supporting documents submitted by FFC 2. List of the name of the officials/persons to whom the letters were issued by FFC 3. List of Officials who appeared before FFC along with their copy of all statements and supporting documents provided by them. 4. List of Officials who DID NOT appear before FFC 5. List officials/person from the statements/documents was taken on record by FFC The copy of statements along with supporting documents is requested to be provided. Full Article
ca Servicii AI pentru Bazilica Sf. Petru lansate de Vatican înainte de anul jubiliar By www.forbes.ro Published On :: Wed, 13 Nov 2024 13:11:29 +0000 Vatican a lansat o serie de servicii noi bazate pe inteligență artificială pentru Bazilica Sf. Petru, permițând acces virtual la comorile arhitecturale din perioada Renașterii și tururi îmbunătățite pentru vizitatori – zilnic aproximativ 40.000-50.000 de oameni. Noile experiențe au fost prezentate în pregătirea pentru Anul Sfânt sau Jubileul Bisericii Catolice din 2025, care are loc ... The post Servicii AI pentru Bazilica Sf. Petru lansate de Vatican înainte de anul jubiliar appeared first on Forbes Romania. Full Article Actualitate Afaceri Bani și Investiţii
ca Eurostat: România a fost al șaptelea producător agricol din UE în 2023 By www.forbes.ro Published On :: Wed, 13 Nov 2024 13:14:46 +0000 Valoarea producţiei agricole a blocului comunitar a scăzut cu 1,5% în 2023, comparativ cu 2022, până la 537,1 miliarde de euro, însă România se numără printre ţările UE a căror valoare a producţiei agricole a crescut de la un an la altul, arată datele publicate miercuri de Eurostat. Scăderea uşoară din 2023 vine după o ... The post Eurostat: România a fost al șaptelea producător agricol din UE în 2023 appeared first on Forbes Romania. Full Article Actualitate Eurostat producator agricol Romania UE
ca Pehart Grup promovează evenimentele cu tradiție de la noi din țară printr-o campanie națională By www.forbes.ro Published On :: Wed, 13 Nov 2024 15:06:09 +0000 Pehart Grup, una dintre cele mai mari companii producătoare de hârtie tissue din Sud-Estul Europei, celebrează tradițiile românești prin cea de-a doua ediție a campaniei naționale Pufina Tradiții Românești. După ce anul trecut, de 1 Decembrie, producătorul a dat startul campaniei naționale Pufina Tradiții Românești, anul acesta, la debutul lui noiembrie a lansat cea de-a ... The post Pehart Grup promovează evenimentele cu tradiție de la noi din țară printr-o campanie națională appeared first on Forbes Romania. Full Article Actualitate Pehart Grup producator de hartie Pufina traditii romanesti
ca Kodakara Hawala Money Case: കൊടകര കുഴൽപ്പണകേസ്; പുനര:ന്വേഷണത്തിന് സർക്കാർ, ചുമതല കൊച്ചി ഡിസിപി കെ. സുദർശന് By zeenews.india.com Published On :: Wed, 13 Nov 2024 17:28:46 +0530 Kodakara Hawala Money Case: ബിജെപി തൃശൂർ ജില്ലാ കമ്മിറ്റി മുൻ ഓഫീസ് സെക്രട്ടറി തിരൂർ സതീഷിന്റെ വെളിപ്പെടുത്തലിന് പിന്നാലെയാണ് തുടരന്വേഷണത്തിന് സർക്കാർ തയാറെടുക്കുന്നത്. Full Article
ca Real Estate Scam: ഭൂമി വാങ്ങിത്തരാമെന്ന് പറഞ്ഞ് കോടികൾ തട്ടിയ പ്രതി അറസ്റ്റിൽ By zeenews.india.com Published On :: Thu, 14 Nov 2024 07:06:18 +0530 Land Scam Case: അടുത്ത കാലങ്ങളില് സാമ്പത്തികമായി പെട്ടന്ന് അഭിവൃദ്ധി പ്രാപിച്ച ബ്രോക്കര്മാരും പോലീസ് നിരീക്ഷണത്തിലാണ്. Full Article
ca This actor lived on a rooftop, starved for days, gatecrashed film sets for food; became one of India's biggest OTT stars By www.dnaindia.com Published On :: Thu, 14 Nov 2024 01:50:00 GMT This actor, who once used to starve for days, gatecrash film sets for food, later became a superstar. Full Article Entertainment Bollywood
ca Meet Vivek Ramaswamy, Harvard-Yale graduate, son of immigrants, now part of Donald Trump's cabinet, his net worth is... By www.dnaindia.com Published On :: Thu, 14 Nov 2024 01:55:00 GMT Born in the US to Indian immigrant parents, Ramaswamy gained wealth through his biotech company Full Article World
ca Synthesis of multisubstituted carbazol-4-amines from tetrahydrocarbazol-4-one oximes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00386A, Research ArticleJiahua Wang, Dandan Gao, Aanuoluwapo O. Oyejobi, Na Ji, Xiang-Ying Tang, Long WangA sequential synthetic method toward 1,3-disubstituted carbazol-4-amines is reported and an interesting C–S metathesis process is disclosed.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca A Mn(III)-catalyzed arylboronic acid-based cascade reaction via a nonclassical organometallic-radical mechanism By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00244J, Research ArticleHui-Min Qian, Jian-Dong Zhang, Shun-Jun Ji, Xiao-Ping XuAn efficient Mn(III)-catalyzed cascade reaction of arylboronic acids, o-cyanoaryl isocyanides, and indoles was developed. The mechanism was fully investigated and elucidated.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Practical photocatalytic hydroalkylation of alkenes with chloroacetates mediated by the formate ion By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00228H, Research ArticleEkaterina V. Malakhova, Vladislav S. Kostromitin, Vitalij V. Levin, Alexander D. DilmanCommodity chemicals are used as alkylating and reducing agents for radical addition to alkenes. The method is based on activation of the strong C–Cl bond by the radical anion of carbon dioxide.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca A Pd(II)-catalyzed denitrative alkyne annulation reaction for the synthesis of cyclopenta[b]chromanes By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00344F, Research ArticlePratiksha Bhorali, Deep J. Kalita, Babulal Das, Sanjib GogoiThe first denitrative Pd(II)-catalyzed alkyne annulation reaction is reported for the synthesis of cyclopenta[b]chromanes.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Organocatalyzed double dearomatization reaction of non-functionalized phenols and propargylic alcohols: the important regulating effect of steric hindrance By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00103F, Research ArticleXihong Liu, Boyan Zhu, Panpan Zhou, Jingying Zhang, Anqi Chu, Rui WangSteric hindrance-regulated double dearomatization reaction of non-functionalized phenols and propargylic alcohols for the efficient synthesis of polycyclic diketones is reported.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca DBU-catalyzed substitution-controlled synthesis of oxa[3.3.1] bridged ring and naphthylamine derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00012A, Research ArticleShiyu Xu, Zhihui Sun, Pengyutian Liu, Yuanlin Wei, Fan Sun, Man Zhao, Ying Wang, Ming Zhang, Guofeng Li, Hong LiangA switchable cascade cyclization reaction of ortho-alkynyl arylketones with amines has been developed, where the different reaction pathways are controlled by the substituent on the α-carbon of in-situ-generated ortho-alkynyl arylaldimines.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Photoredox catalyzed hydroazolylation of alkenes via phosphoranyl radicals By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00233D, Research ArticleFan Zhu, Zhi Qiao, Na He, Chunxiao Nong, Qiping He, Meilan Xi, Xizhong Song, Jun Lin, Jingbo Chen, Yi JinA general protocol for the hydroazolylation of alkenes with N-hydroxyl azoles is reported. These reactions proceed via a phosphoranyl radical, followed by radical coupling of the resulting azole radical to the alkene radical.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Recent advances in the metal-catalyzed asymmetric alkene hydrogenation of cyclic conjugated carbonyl compounds By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00227J, Review ArticleMin Tan, Bram B. C. Peters, Pher G. Andersson, Taigang ZhouThis review summarizes the recent advances (2016–2023) in the stereoselective metal-catalyzed hydrogenation of cyclic α,β-unsaturated ketones, lactams and lactones since considerable developments were made. Where possible the application of these methodologies in synthesis is outlined.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Palladium-catalyzed [4 + 4] cycloaddition of 2-pyrones with 2-alkylidenetrimethylene carbonates: access to bridged eight-membered oxygen heterocycles By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00329B, Research ArticleHuawei Lin, Biming Mao, Bing Han, Jiayi Luo, Yanqing Ge, Xuerui Zhang, Chang Wang, Hongchao Guo, Chunhao YuanA novel palladium-catalyzed [4 + 4] cycloaddition of 2-pyrones with 2-alkylidenetrimethylene carbonates has been developed for the synthesis of bridged eight-membered oxygen heterocycles in good yields and with excellent stereoselectivities.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Computational insights into the synergistic interplay of ligand and fluorine effects in palladium-catalyzed regiodivergent decarboxylative allylic alkylation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00147H, Research ArticleShiyu Wang, Hongli Wu, Xiangyang Tang, Genping HuangDFT calculations were performed to investigate palladium-catalyzed decarboxylative allylic alkylation of allyl difluoro-β-ketoesters. The synergistic effects of ligand and fluorine substituents on regioselectivity were uncovered.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Chiral guanidine catalyzed cyclization reactions of 1,3-enynes for lactone synthesis: switchable H-bond catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00374H, Research ArticleYongyan Zhang, Lichao Ning, Tianxin Zhu, Zheng Xie, Shunxi Dong, Xiaoming Feng, Xiaohua LiuCyclization and 1,4-conjugate addition/cyclization between 2-activated 1,3-enynes and azlactones were achieved with chiral guanidine-amides for enol-type activation to yield a range of δ-lactone derivatives.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Sustainable synthesis of long-acting local anesthetics ropivacaine and levobupivacaine under batch and continuous flow via asymmetric hydrogenation By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00072B, Research ArticleZhi Yang, Hanlin Chen, Linxi Wan, Xinyi Feng, Lingshuang Ma, Pei Tang, Fen-Er ChenA sustainable synthesis method was developed for long-acting local anesthetics, ropivacaine and levobupivacaine, using both batch and continuous flow processes via asymmetric hydrogenation.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Synthesis of a helical boron-doped PAH by post-functionalization of 3,9-diboraperylene By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00421C, Research ArticleCarina Mützel, Kazutaka Shoyama, Ana-Maria Krause, Frank WürthnerA doubly helical boron-doped polycyclic aromatic hydrocarbon was synthesized, which showed a low LUMO level, a high absorption coefficient and fluorescence (ΦF = 0.73), combined with a one-dimensional π–π stacking interaction in the solid state.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Enantioselective synthesis of 8-membered lactone derivatives via organocatalytic cascade reactions By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00148F, Research ArticleDong-Sheng Ji, Rui Zhang, Xu-Yan Han, Hai-Long Chai, Yucheng Gu, Xiu-Qin Hu, Peng-Fei XuThe challenging 8-membered lactone derivatives bearing two vicinal chiral stereocenters were synthesized via a cascade reaction mediated by the chiral squaramide.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Review of application of the I2 and dimethyl sulfoxide combined reagent system to aryl methyl ketones for diverse transformations By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00396A, Review ArticleDong-Sheng Yang, Xiang-Long Chen, An-Xin WuThe synthesis of small molecules and complex scaffolds is one of the most important topics in organic synthesis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Asymmetric [3 + 2] cycloaddition of donor–acceptor cyclopropanes with azadienes enabled by Brønsted base catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00002A, Research ArticleShu Li, Zhi-Hong Dong, Si-Yu Dan, Mei-Jun Zheng, Teng Long, Jie Zhan, Qing Zhou, Wen-Dao Chu, Quan-Zhong LiuA chiral bifunctional Brønsted base-catalyzed enantioselective [3 + 2] cycloaddition of D–A cyclopropanes and azadienes is reported. The protocol features broad substrate scope, mild reaction conditions and high functional group tolerance.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Organocatalytic formal [4 + 2] cycloaddition of o-quinone-methyl derivatives and 2-isocyanatomalonate diesters for the construction of chroman derivatives with adjacent quaternary chiral centers By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00141A, Research ArticleTong Xiong, Yi-Zhao Xu, Yao Wang, You-Cai Xiao, Fen-Er ChenAn asymmetric organocatalytic formal [4 + 2] cycloaddition/annulation cascade of ortho-quinone methides with 2-isocyanatomalonate diesters has been reported.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Stereodivergent synthesis of chiral spiropyrazolones through Pd-catalyzed asymmetric sequential hydroalkylation of 1,3-enynes: unusual solvent effects on the enantioselectivity By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00358F, Research ArticleShan Wang, Long Li, Yifei Zheng, Luqing Li, Yingcheng Wang, Fangzhi Peng, Zhihui ShaoChiral spiropyrazolones were constructed through Pd-catalyzed asymmetric sequential hydroalkylation of 1,3-enynes. Four stereoisomers could be obtained through substrate control and chiral ligand control.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Vaska's complex–PMHS combination enabled mild and chemoselective reduction of sulfoxides to sulfides with low catalyst loading By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00312H, Research ArticleFang-Fang Xu, Zhong-Lei Ruan, Pei-Qiang HuangWe report a highly efficient, versatile, and chemoselective method for the catalytic reduction of sulfoxides to sulfides under mild conditions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Decarbonylative C(sp2)–C(sp2) reductive cross-coupling of aroyl fluorides with aryl bromides by palladium/cobalt co-catalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00305E, Research ArticleChen He, Zhiyong Song, Wei Yao, Rui Lin, Yuanhong MaHerein, we report a decarbonylative C(sp2)–C(sp2) reductive cross-coupling of aroyl fluorides with aryl bromides by palladium and cobalt co-catalysis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Electrochemically dehydrogenative C(sp2)–H/S–H cross-coupling: efficient synthesis of ortho-aminophenyl thioglycoside derivatives By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00171K, Research ArticleLi-Yan Hu, Li Zhu, Shen-Yuan Zhang, Yu-Xin Guo, Yuan Li, Jie Zhu, Lei WuA method has been reported for synthesizing aryl thioglycosides through direct electrocatalytic dehydrogenative C(sp2)–H/S–H cross-coupling.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Blue light-mediated carbene transfer reaction of thioesters with diazoesters: efficient synthesis of tetrasubstituted Z-enol esters By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00265B, Research ArticleShuncheng Wang, Hua Zhang, Jin Yang, Dongfang Zhang, Xin-Ping HuiAn efficient metal-free, blue light-mediated carbene transfer reaction of thioesters with diazoesters has been achieved. This protocol produced tetrasubstituted Z-enol esters containing arylsulfur groups in good yields under mild conditions.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Cyclization reactions of 1,6-dienes and 1,6-enynes by dual cobalt photocatalysis By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00311J, Research ArticlePei-Ting Li, Zi-Fa Shi, Wei YuTwo triphenylamine-derived organophotocatalysts were developed. Their photocatalytic capacity was exploited to enable the [CoIII]-H-mediated cycloisomerization of 1,6-dienes and reductive cyclization of 1,6-enynes under visible light irradiation.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article
ca Iodine-catalyzed intermolecular 1,2-thio (seleno)amination of alkenes with 1,2,3-triazoles and disulfides (diselenides) in air By pubs.rsc.org Published On :: Org. Chem. Front., 2024, Advance ArticleDOI: 10.1039/D4QO00246F, Research ArticleJian Ji, Xuwen Chen, Zongjing Hu, Cong Guan, Jinhua Liu, Yaqi Deng, Shunying LiuIodine-catalyzed 1,2-thio (seleno)amination of alkenes via direct N- and C-centered radical cross-coupling was established to elicit highly regioselective β-triazolized thioalkyl compounds.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry Full Article