Inorg. Chem. Front., 2024, 11,8130-8138
DOI: 10.1039/D4QI02088J, Research Article

Bei-Bei Zhang, Wen-Ye Gao, Wei Xu, Liang Ma, Wenlong Liu, Ru-Ling Tang, Sheng-Ping Guo
The acentric Ce(IV) fluoride NH₄Ce₃F₁₃ is systematically studied, exhibiting the strong SHG effect (1.2 × KDP) and high LIDTs (39 × AGS). It also possesses the largest band gap among NLO materials containing Ce(IV).
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Inorg. Chem. Front., 2024, 11,8078-8092
DOI: 10.1039/D4QI01704H, Research Article

Zhengzheng Xu, Yanjiao Li, Shiqi Li, Yingying Chen, Majid Farahmandjou, Guoxiu Wang, Hongxun Yang, Hao Tian
A facile and general strategy is developed for constructing graphene aerogels with in situ encapsulated bimetallic selenide heterostructure materials exhibiting high rate-capabilities and long cycling stabilities in sodium-ion batteries.
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Inorg. Chem. Front., 2024, 11,7898-7909
DOI: 10.1039/D4QI01765J, Research Article

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Huayun Shi, Guy J. Clarkson, Peter J. Sadler
The photochemotherapeutic activity of diazido Pt(IV) complexes towards bladder cancer, a common cancer with expensive treatment, has been tuned via modification of trans N-heterocyclic ligands, to give a candidate for preclinical development.
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Inorg. Chem. Front., 2024, 11,7921-7929
DOI: 10.1039/D4QI01818D, Research Article

Miriam Abán, J. Marco Cuenca, Irene Embid, Alba de Toro, Pilar Gómez-Sal, Ernesto de Jesús, Marta Valencia, Cristina G. Yebra
[CpIr(CO)H₂] efficiently catalyses formic acid dehydrogenation, forming in situ from pyridyl-triazole pre-catalysts [Cp*Ir(k²-NN)(Cl)][OTf]. Neat formic acid is dehydrogenated with a TON of up to 26876 and a TOF exceeding 10700 h⁻¹.
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Inorg. Chem. Front., 2024, 11,8110-8122
DOI: 10.1039/D4QI01934B, Research Article

Hongbo Zhou, Xuan Hao, Jiexin Guan, Yilin Deng, Zi Wei, Yashu Liu, Guoxing Zhu
The 2,2'-bpy coordination shells surrounding the Ni/Fe active sites of NiFe(2,2'-bpy)_n@CNT materials effectively boost OER catalysis.
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Inorg. Chem. Front., 2024, 11,8101-8109
DOI: 10.1039/D4QI01796J, Research Article

Yong-Zheng Zhang, Xin-Dan Zhang, Yan-Kai Zhang, Fu-Tian Wang, Longlong Geng, Hui Hu, Zhen Li, Da-Shuai Zhang, Hongliang Huang, Xiuling Zhang
A novel mixed-ligand metal–organic framework, featuring naphthalene rings in its secondary linker, exhibits exceptional benzene adsorption and separation capacities.
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Inorg. Chem. Front., 2024, 11,8146-8146
DOI: 10.1039/D4QI90072C, Correction

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Ru-Ling Tang, Gang-Xiang Liu, Wen-Dong Yao, Li-Nan Zhang, Wenlong Liu, Sheng-Ping Guo
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Inorg. Chem. Front., 2024, 11,8147-8147
DOI: 10.1039/D4QI90073A, Correction

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Maddalena Paolillo, Giarita Ferraro, Irene Cipollone, Eugenio Garribba, Maria Monti, Antonello Merlino
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02372B, Research Article

Guo-guo Zhang, Pengtao Qiu, Jiaxin Kang, Zhiwei Lu, An-qi Zhu, Xiaohu Yu, Xuenian Chen
Solid-state potassium metal batteries have increasingly gained attention as promising alternatives in large-scale energy storage due to their safety and low cost. However, these batteries usually suffer from a lack...
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02451F, Review Article

Chunwen Sun
The progress of nanoengineering of electrodes fabricated by various methods for SOFCs operating at low and intermediate temperatures is reviewed. Future research directions on nanoengineering of cathodes for next-generation SOFCs are also provided.
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI01916D, Research Article

Jinggao Wu, Canyu Zhong, Xiaofan Chen, Jing Huang
Li3V2(PO4)3 (LVP)-coated with N and S co-doped carbon (NSC) is investigated by DFT calculation, suggesting that NSC significantly enhances electronic conductivity and lowers Li+ migration energy barrier in comparison to...
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02228A, Review Article

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Zongsu Han, Joshua Rushlow, Yihao Yang, Jiatong Huo, Wei Shi, Hong-Cai Zhou
Lithium extraction attracts great attention due to the rising demand for batteries, but faces challenges related to low natural abundance and environmental concerns. MOFs show promise in lithium extraction, benefitting from customizable structures.
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02262A, Research Article

Tamara A. Bazhenova, Vyacheslav Kopotkov, Denis V. Korchagin, Elena Yureva, Michael V. Zhidkov, Alexey I Dmitriev, Ilya Yakushev, N. N. Efimov, Konstantin Andreevich Babeshkin, Vladimir Sergeevich Mironov, Eduard B. Yagubskii
A series of three new seven-coordinate pentagonal-bipyramidal (PBPY-7) Dy(III) complexes [Dy(L^CH3)(Cy₃PO)₂]ClO₄∙CH₃CN (1), [Dy(L^2(t-Bu))(Ph₃PO)₂]ClO₄∙0.63C₂H₅OH (2), [Dy(L^OCH3)(Ph₃PO)₂]ClO₄∙2H₂O (3) including various chelating pentadentate ligands with a [N₃O₂]²⁻ binding node in the equatorial plane,...
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02422B, Research Article

Gengxin Wu, Yong-Kang Zhu, Dongxia Li, Jia-Rui Wu, Yan Wang, Zhiquan Zhang, Ying-Wei Yang
Engineering ideal functional coordination polymers (CPs) via post-synthetic modification has emerged as a powerful synthetic strategy to achieve desirable functionalities and superior properties. In this work, we report a versatile...
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Lab Chip, 2024, 24,1965-1976
DOI: 10.1039/D3LC01007D, Paper

Wei-Jen Soong, Chih-Hung Wang, Chihchen Chen, Gwo-Bin Lee
We devised an innovative method for automated sorting of extracellular vesicles (EVs) employing optically-induced dielectrophoresis on an integrated microfluidic chip. EVs of three distinct size categories could be isolated in 1 h at a purity of 86%.
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Lab Chip, 2024, 24,2049-2057
DOI: 10.1039/D3LC00707C, Paper

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Fumiaki Yokoyama, André Kling, Petra S. Dittrich
A microdevice with narrow winding channels is introduced to trap and culture single bacterial cells. It is used to study growth patterns of the cells and to monitor secretion of extracellular vesicles under treatment with an antibiotic drug.
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Lab Chip, 2024, 24,1957-1964
DOI: 10.1039/D3LC01014G, Paper

Yu Zhang, Tao Peng, Yu Ge, Mengda Li, Chendi Li, Jiyu Xi, Zixi Li, Zewen Wei, Yuntao Hu
Stratified delivery into specific retinal layers was realized by a flexible electrode array that exhibited high compatibility with surgical procedures.
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Lab Chip, 2024, 24,1918-1929
DOI: 10.1039/D3LC00793F, Paper

Lauren M. Delong, Colby E. Witt, Madison Pennell, Ashley E. Ross
Here, we have developed a 3D printed microfluidic device capable of oxygen gradient formation within intestinal tissue slices ex vivo. The device is open-welled and compatible with external electrochemical recording during tissue analysis.
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Lab Chip, 2024, 24,2122-2134
DOI: 10.1039/D3LC00945A, Paper

Meiying Zhao, Ye Tao, Wenshang Guo, Zhenyou Ge, Hanqing Hu, Ying Yan, Chaoxia Zou, Guiyu Wang, Yukun Ren
A multifunctional flexible magnetic drive gripper is synthetically designed to achieve active steering and carry out operations on different targets in a constrained environment by changing the external magnetic field.
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Lab Chip, 2024, 24,2069-2079
DOI: 10.1039/D3LC00830D, Paper

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Chaeeun Lee, Sumit Kumar, Juhee Park, Yongjun Choi, Elizabeth Maria Clarissa, Yoon-Kyoung Cho
Tonicity-induced cargo loading into extracellular vesicles (EVs) is achieved through controlled membrane permeability, ensuring cargo incorporation without causing damage to the EV membrane.
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Lab Chip, 2024, 24,1867-1874
DOI: 10.1039/D3LC00796K, Perspective

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Umut A. Gurkan, David K. Wood, Dorn Carranza, Luke H. Herbertson, Scott L. Diamond, E. Du, Suvajyoti Guha, Jorge Di Paola, Patrick C. Hines, Ian Papautsky, Sergey S. Shevkoplyas, Nathan J. Sniadecki, Vamsee K. Pamula, Prithu Sundd, Asif Rizwan, Pankaj Qasba, Wilbur A. Lam
In this perspective article, we present the state of the microfluidic field regarding current limitations and propose future directions and new approaches for the field to advance lab-on-a-chip technologies closer to translation and clinical use.
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Lab Chip, 2024, 24,2176-2192
DOI: 10.1039/D3LC00912B, Paper

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Priscilla Delgado, C. Alessandra Luna, Anjana Dissanayaka, Oluwamayokun Oshinowo, Jesse J. Waggoner, Sara Schley, Todd Fernandez, David R. Myers
This activity enables students to construct geometrically complex microfluidics at their desk with no specialized equipment. It can be easily transported, and helped students significantly improve their understanding of miniaturization science.
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Lab Chip, 2024, 24,2262-2271
DOI: 10.1039/D4LC00055B, Paper

Kawin Khachornsakkul, Ruben Del-Rio-Ruiz, Lita Chheang, Wenxin Zeng, Sameer Sonkusale
A carbon dots and dopamine-imprinted polymer was immobilized onto a distance-based paper channel for simultaneous detection of three cytokine biomarkers without requiring expensive reagents and instruments.
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Lab Chip, 2024, 24,2146-2175
DOI: 10.1039/D3LC01086D, Critical Review

Uditha Roshan, Amith Mudugamuwa, Haotian Cha, Samith Hettiarachchi, Jun Zhang, Nam-Trung Nguyen
This review paper provides a comprehensive overview of the state-of-the-art actuation mechanisms for flexible and stretchable microdevices.
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Lab Chip, 2024, 24,2287-2297
DOI: 10.1039/D3LC00866E, Paper

Arata Tsuchida, Taikopaul Kaneko, Kaori Nishikawa, Mayu Kawasaki, Ryuji Yokokawa, Hirofumi Shintaku
We introduce a simple integrated analysis method that links cellular phenotypic behaviour with single-cell RNA sequencing by utilizing a combination of optical indices from cells and hydrogel beads.
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Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00012A, Paper

Anna L. Butterworth, Matin Golozar, Zachary Estlack, Jeremy McCauley, Richard A. Mathies, Jungkyu Kim
This work presents the design, fabrication, and automation of our space flight-format microfabricated sample processing and capillary electrophoresis analysis instrument.
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Lab Chip, 2024, Accepted Manuscript
DOI: 10.1039/D4LC00291A, Paper

Nana Jin, Fan Jiang, Fengzhen Yang, Ying Ding, Ming Liao, Yanbin Li, Jianhan Lin
A colorimetric biosensor was elaboratively designed for fast, sensitive and multiplex bacterial detection on a single microfluidic chip using immune magnetic nanobeads for specific bacterial separation, immune gold@platinum palladium nanoparticles...
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Lab Chip, 2024, Advance Article
DOI: 10.1039/D4LC00132J, Paper

Oriana G. Chavez-Pineda, Roberto Rodriguez-Moncayo, Alan M. Gonzalez-Suarez, Pablo E. Guevara-Pantoja, Jose L. Maravillas-Montero, Jose L. Garcia-Cordero
A microfluidic platform isolates leukocytes from blood efficiently, offering diagnostic and immunotherapeutic potential. Enhanced by a handheld pressure controller, it enables near-patient testing and integration with downstream assays.
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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00203B, Paper

Xi-Bao Zhang, Yin-Ning Zhou, Hao Chen, Zheng-Hong Luo, Liyang Zhou, Guojun Yu, Wenwu Liu, Shiping Zhu
A reactor's heat transfer efficiency can be significantly enhanced and the fluid temperature uniformity can be controlled through introducing cooling water in the agitator and regulating the flow ratio of cooling water in the agitator and jacket.
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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00307A, Paper

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J. M. Jimenez-Martin, M. El Tawil-Lucas, C. García-Jerez, J. Moreno, A. García, B. Hernández, J. Iglesias
Two operational regions in the transformation of hexoses have been revealed by experimental and kinetic analysis: glycosidation and retroaldol cleavage at low and high temperatures, respectively.
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React. Chem. Eng., 2024, 9,2892-2901
DOI: 10.1039/D4RE00269E, Paper

Yujue Du, Wende Hu, Yunlei Chen, Chuanming Wang, Weimin Yang
The Lewis acid sites in ZSM-5 zeolite involving Co, Ni, and Cu cations were computationally studied on the stability and the PDH catalytic activity.
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React. Chem. Eng., 2024, 9,2984-2993
DOI: 10.1039/D4RE00127C, Paper

Leon Hennecke, Lucas Schaare, Mirko Skiborowski, Andreas Liese
This study presents an automated reactor platform for the identification of enzyme kinetic models using model-based design of experiments on the example of the reduction of NAD⁺ by formate dehydrogenase from Candida boidinii.
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React. Chem. Eng., 2024, 9,2846-2862
DOI: 10.1039/D4RE00259H, Review Article

Fuyu Jiao, Saif Al Ghafri, Keelan T. O'Neill, Paul S. Stanwix, Guinevere M. Sellner, Einar O. Fridjonsson, Neil Robinson, Eric F. May, Michael L. Johns
This work reviews ortho–para hydrogen conversion data for various types of catalysts at cryogenic temperatures and evaluates different reaction kinetic expressions employed to describe these experimental data.
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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00432A, Paper

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Theodoros Papalas, Andy N. Antzaras, Angeliki A. Lemonidou
MgO promoted with molten alkali salts and CaCO₃ displayed efficient CO₂ capture activity in a fixed bed reactor, attaining 75% CO₂ removal at 275 °C and stable cyclic performance, with the promoters providing an alternative carbonation mechanism.
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React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00397G, Paper

Xin Liu, Yuxin Yan, Zhenyu Liu, Qingya Liu
A novel synthesis of xanthenes and ethylphenols by the reaction of phenol with CaC₂ without catalysts and solvents.
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Soft Matter, 2024, 20,2961-2968
DOI: 10.1039/D4SM00074A, Paper

Takumi Kito, Mikihiro Hayashi
Unusual relaxation and creep properties by the trapping bond exchange phenomenon is revealed for vitrimer-like materials with bond exchangeable domains of quaternized pyridines, in the special case of off- stoichiometric cross-linking condition.
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Soft Matter, 2024, Advance Article
DOI: 10.1039/D3SM01141K, Paper

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Lukas Woolley, Adam Burbidge, Jan Vermant, Fotis Christakopoulos
We provide an insight into the compliance of β-cells and explore structural changes in conditions relevant to type-2 diabetes, showing an altered transport behavior and hindering the effective control of insulin secretion.
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Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00188E, Paper

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A. N. Semenov, I. A. Nyrkova
The quantitative transfer matrix approach and scaling arguments in terms of trains, loops, tails and supertrains allowed us to characterize the main regimes of semiflexible chain adsorption on a bar and double-chain complex formation.
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Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00216D, Paper

Yuting Wan, Yuening Qiu, Jin Zhou, Jinbo Liu, Martien A. Cohen Stuart, Yangfeng Peng, Junyou Wang
Stable and permeable polyion complex vesicles designed as enzymatic nanoreactors.
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Soft Matter, 2024, Advance Article
DOI: 10.1039/D3SM01354E, Paper

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Carlos Villarroel, Gustavo Düring
We investigated the yielding phenomenon under different scenarios of deformation in the quasistatic limit using numerical simulations of soft particles.
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Soft Matter, 2024, Advance Article
DOI: 10.1039/D3SM01042B, Communication

Yu Zou, Jidan Yang, Xinxin Zhang, Mingjun Huang, Satoshi Aya
Emerging polar nematics exhibits nontrivial topologies in confinement, controlled by the magnitude of the polarization.
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Soft Matter, 2024, Accepted Manuscript
DOI: 10.1039/D4SM00156G, Paper

Chunbo Zhang, Meng Xu, Minqiao Ren, Hongwei Shi, Guoming Liu, Juan Li, Xuanbo Liu, Longgui Zhang, Dali Gao
An impact polypropylene copolymer (IPC), composed of polypropylene (PP) and ethylene-propylene copolymer (EPC), was synthesized through two-stage in-reactor polymerization. A systematic investigation of the crystalline structure, thermal behavior, morphology, and...
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Soft Matter, 2024, 20,3299-3312
DOI: 10.1039/D3SM01198D, Paper

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Parth U. Kelkar, Matthew Kaboolian, Ria D. Corder, Marco Caggioni, Seth Lindberg, Kendra A. Erk
Material relationships at low temperatures were determined for concentrated surfactant solutions using a combination of rheological experiments, cross-polarized microscopy, calorimetry, and small angle X-ray scattering.
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Soft Matter, 2024, Advance Article
DOI: 10.1039/D3SM01216F, Paper

Christopher W. Barney, Szabolcs Berezvai, Allison L. Chau, Younghoon Kwon, Angela A. Pitenis, Robert M. McMeeking, Megan T. Valentine, Matthew E. Helgeson
The measured force during a puncture test is found to increase when the needle tip is near to the vial walls. An experimental method for quantifying this increase in stiffness is developed.
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Soft Matter, 2024, Advance Article
DOI: 10.1039/D4SM00022F, Paper

A-Reum Kim, Surjyasish Mitra, Sudip Shyam, Boxin Zhao, Sushanta K. Mitra
Soft, flexible hydrogels enable researchers to connect two discrete regimes: liquid wetting to contact adhesion in solids.
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RSC Adv., 2024, 14,12171-12178
DOI: 10.1039/D4RA01264J, Paper

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Pallavi B. Jagdale, Sai Rashmi Manippady, Rohit Anand, Geunsik Lee, Akshaya Kumar Samal, Ziyauddin Khan, Manav Saxena
Herein, we have utilized agri-waste and amalgamating low Fe³⁺, to develop an economic iron oxide–carbon hybrid-based electrocatalyst for oxygen reduction reaction (ORR) with water as a main product following close to 4e⁻ transfer process.
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RSC Adv., 2024, 14,12313-12322
DOI: 10.1039/D4RA01304B, Paper

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Vijay B. Autade, Kaustav Bhattacharjee, Ranjit S. Kate, Sudhir S. Arbuj, Ramchandra S. Kalubarme, Sanjay K. Apte, Bharat B. Kale, Sandeep A. Arote
Herein, the study reported unique one-pot and scalable solid-state methodology to prepare bismuth sulphide (Bi₂S₃)-reduced graphene oxide (rGO) nanocomposites using bismuth oxide (Bi₂O₃), thiourea and graphene oxide (GO) for energy storage applications.
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RSC Adv., 2024, 14,11570-11583
DOI: 10.1039/D3RA08527A, Paper

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Md. Kawsar, Md. Sahadat Hossain, Sumaya Tabassum, Newaz Mohammed Bahadur, Samina Ahmed
Exploration of the crystallographic parameters of various nano-hydroxyapatites for enhanced photocatalytic degradation of Congo red dye.
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RSC Adv., 2024, 14,12372-12385
DOI: 10.1039/D4RA01408A, Review Article

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Wanqi Tang, Yuxi Liu, Xianghai Jing, Jinsong Hou, Qianfeng Zhang, Chongguang Jian
Bond strength of two-layer adhesive-free flexible copper-clad laminate is an important factor that directly affects the stability and reliability of electronic devices.
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RSC Adv., 2024, 14,12397-12406
DOI: 10.1039/D3RA08900B, Paper

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Nuno Marques, Santanu Jana, Manuel J. Mendes, Hugo Águas, Rodrigo Martins, Shrabani Panigrahi
The long-term performance of metal halide perovskite solar cells (PSCs) can be significantly improved by tuning the surface characteristics of the perovskite layers.
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