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Insights into N-heterocyclic carbene and Lewis acid cooperatively catalyzed oxidative [3 + 3] annulation reactions of α,β-unsaturated aldehyde with 1,3-dicarbonyl compounds

Org. Chem. Front., 2020, 7,1113-1121
DOI: 10.1039/D0QO00091D, Research Article
Xinghua Wang, Yang Wang, Jinshuai Song, Donghui Wei
N-Heterocyclic carbene and Lewis acid cooperatively catalyzed oxidative [3 + 3] annulation reactions of 1,3-dicarbonyl compounds have been systematically studied in theory.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Anthranils: versatile building blocks in the construction of C–N bonds and N-heterocycles

Org. Chem. Front., 2020, 7,1177-1196
DOI: 10.1039/D0QO00163E, Review Article
Yang Gao, Jianhong Nie, Yanping Huo, Xiao-Qiang Hu
This review article provides an overview of the recent progress in the transformations of anthranils, which have emerged as versatile building blocks in the assembly of various C–N bonds and medicinally active heterocyclic systems.
The content of this RSS Feed (c) The Royal Society of Chemistry




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A guide to scientific writing : manual for students and research workers / David Lindsay

Lindsay, David




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A guide to scientific writing / David Lindsay

Lindsay, D. R




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Nanotechnology : global strategies, industry trends and applications / edited by Jurgen Schulte




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Introduction to nanoscience / S.M.Lindsay

Lindsay, S. M. (Stuart Martin)




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[ASAP] Net-Clipping: An Approach to Deduce the Topology of Metal–Organic Frameworks Built with Zigzag Ligands

Journal of the American Chemical Society
DOI: 10.1021/jacs.0c03404




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Thousands from Bengal stranded in Telangana

The wait to return home might finally come to an end for the thousands of migrant workers from West Bengal, stranded across Telangana. On Friday, the Mamata Banerjee-government announced that special trains will be arranged to ferry home migrant labourers, patients, students and stranded tourists.




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Polypropylene Handbook: Morphology, Blends and Composites / József Karger-Kocsis, Tamás Bárány, editors

Online Resource




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New trends in coal conversion: combustion, gasification, emissions, and coking / editors, Isabel Suárez-Ruiz, Maria Antonia Diez, Fernando Rubiera

Hayden Library - TP352.N49 2019




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Human Factors in the Chemical and Process Industries: Making it Work in Practice / edited by Janette Edmonds

Online Resource




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Essential Oil Research: Trends in Biosynthesis, Analytics, Industrial Applications and Biotechnological Production / Sonia Malik, editor

Online Resource




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Plasticizers derived from post-consumer PET: research trends and potential applications / Ewa Langer, Krzysztof Bortel, Marta Lenartowicz-Klik, Sylwia Waskiewicz

Online Resource




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Unsaturated Polyester Resins: blends, interpenetrating polymer networks, composites, and nano composites / edited by Sabu Thomas, Mahesh Hosur and Cintil Jose Chirayil

Online Resource




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New trends in natural dyes for textiles / Padma Shree Vankar, Dhara Shukla

Online Resource




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Bourbon's backroads: a journey through Kentucky's distilling landscape / Karl Raitz

Dewey Library - TP605.R35 2019




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Tomorrows trends in fire retardant regulations, testing, and applications / by FRCA

Online Resource




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Jesus of Nazareth : Jew from Galilee, savior of the world / Jens Schröter ; translated by Wayne Coppins and S. Brian Pounds

Schröter, Jens, 1961- author




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The resurrection of Mary Magdalene : legends, apocrypha, and the Christian testament / Jane Schaberg

Schaberg, Jane, author




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Come and read : interpretive approaches to the Gospel of John / edited by Alicia D. Myers and Lindsey S. Jodrey




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A concise and sequential synthesis of the nitroimidazooxazole based drug, Delamanid and related compounds

RSC Adv., 2020, 10,17085-17093
DOI: 10.1039/D0RA01662D, Paper
Open Access
Sumit Sharma, Radhika Anand, Pankaj Singh Cham, Sushil Raina, Ram. A. Vishwakarma, Parvinder Pal Singh
A concise, protection-group free and sequential route has been developed for the synthesis of the nitroimidazole based FDA-approved multi-drug resistant anti-tuberculosis drug, Delamanid and anti-leishmanial lead candidate VL-2098.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Multiple Backgrounds and Borders with CSS 2.1

Using CSS 2.1 pseudo-elements to provide up to 3 background canvases, 2 fixed-size presentational images, and multiple complex borders for a single HTML element. This method of progressive enhancement works for all browsers that support CSS 2.1 pseudo-elements and their positioning. No CSS3 support required.

Support: Firefox 3.5+, Safari 4+, Chrome 4+, Opera 10+, IE8+.

How does it work?

Essentially, you create pseudo-elements using CSS (:before and :after) and treat them similarly to how you would treat HTML elements nested within your target element. But they have distinct benefits – beyond semantics – over the use of nested HTML elements.

To provide multiple backgrounds and/or borders, the pseudo-elements are pushed behind the content layer and pinned to the desired points of the HTML element using absolute positioning.

The pseudo-elements contain no true content and are absolutely positioned. This means that they can be stretched to sit over any area of the “parent” element without affecting its content. This can be done using any combination of values for the top, right, bottom, left, width, and height properties and is the key to their flexibility.

What effects can be achieved?

Using just one element you can create parallax effects, multiple background colours, multiple background images, clipped background images, image replacement, expandable boxes using images for borders, fluid faux columns, images existing outside the box, the appearance of multiple borders, and other popular effects that usually require images and/or the use of presentational HTML. It is also possible to include 2 extra presentational images as generated content.

The Multiple Backgrounds with CSS 2.1 and Multiple Borders with CSS 2.1 demo pages show how several popular examples of these effects can be achieved with this technique.

Most structural elements will contain child elements. Therefore, more often than not, you will be able to gain a further 2 pseudo-elements to use in the presentation by generating them from the first child (and even last-child) element of the parent element. In addition, you can use style changes on :hover to produce complex interaction effects.

Example code: multiple background images

Using this technique it is possible to reproduce multiple-background parallax effects like those found on the Silverback site using just one HTML element.

The element gets its own background image and any desired padding. By relatively positioning the element it acts as the reference point when absolutely positioning the pseudo-elements. The positive z-index will allow for the correct z-axis positioning of the pseudo-elements.

#silverback {
  position: relative;
  z-index: 1;
  min-width: 200px;
  min-height: 200px;
  padding: 120px 200px 50px;
  background: #d3ff99 url(vines-back.png) -10% 0 repeat-x;
}

Both pseudo-elements are absolutely positioned and pinned to each side of the element. The z-index value of -1 moves the pseudo-elements behind the content layer. This way the pseudo-elements sit on top of the element’s background and border but all the content is still selectable or clickable.

#silverback:before,
#silverback:after {
  position: absolute;
  z-index: -1;
  top: 0;
  left: 0;
  right: 0;
  bottom: 0;
  padding-top: 100px;
}

Each pseudo-element then has a repeated background-image set. This is all that is needed to reproduce the parallax effect.

The content property lets you add an image as generated content. With two pseudo-elements you can add 2 further images to an element. They can be crudely positioned within the pseudo-element box by varying other properties such as text-align and padding.

#silverback:before {
  content: url(gorilla-1.png);
  padding-left: 3%;
  text-align: left;
  background: transparent url(vines-mid.png) 300% 0 repeat-x;
}

#silverback:after {
  content: url(gorilla-2.png);
  padding-right: 3%;
  text-align: right;
  background: transparent url(vines-front.png) 70% 0 repeat-x;
}

The finished product is part of the Multiple Backgrounds with CSS 2.1 demo.

Example code: fluid faux columns

Another application is creating equal height fluid columns without images or extra nested containers.

The HTML base is very simple. I’ve used specific classes on each child div rather than relying on CSS 2.1 selectors that IE6 does not support. If you don’t require IE6 support you don’t actually need the classes.

<div id="faux">
  <div class="main">[content]</div>
  <div class="supp1">[content]</div>
  <div class="supp2">[content]</div>
</div>

The percentage-width container is once again relatively positioned and a positive z-index is set. Applying overflow:hidden gets the element to wrap its floated children and will hide the overflowing pseudo-elements. The background colour will provide the colour for one of the columns.

#faux {
  position: relative;
  z-index: 1;
  width: 80%;
  margin: 0 auto;
  overflow: hidden;
  background: #ffaf00;
}

By using relative positioning on the child div‘s you can also control the order of the columns independently of their source order.

#faux div {
  position: relative;
  float: left;
  width: 30%;
}

#faux .main { left: 35%; }
#faux .supp1 { left: -28.5%; }
#faux .supp2 { left: 8.5%; }

The other two full-height columns are produced by creating, sizing, and positioning pseudo-elements with backgrounds. These backgrounds can be (repeating) images if the design requires.

#faux:before,
#faux:after {
   content: "";
   position: absolute;
   z-index: -1;
   top: 0;
   right: 0;
   bottom: 0;
   left: 33.333%;
   background: #f9b6ff;
}

#faux:after {
   left: 66.667%;
   background: #79daff;
}

The finished product is part of the Multiple Backgrounds with CSS 2.1 demo.

Example code: multiple borders

Multiple borders are produced in much the same way. Using them can avoid the need for images to produce simple effects.

An element must be relatively positioned and have sufficient padding to contain the width of the extra border you will be creating with pseudo-elements.

#borders {
   position: relative;
   z-index: 1;
   padding: 30px;
   border: 5px solid #f00;
   background: #ff9600;
}

The pseudo-elements are positioned at specific distances away from the edge of the element’s box, moved behind the content layer with the negative z-index, and given the border and background values you want.

#borders:before {
   content: "";
   position: absolute;
   z-index: -1;
   top: 5px;
   left: 5px;
   right: 5px;
   bottom: 5px;
   border: 5px solid #ffea00;
   background: #4aa929;
}

#borders:after {
   content: "";
   position: absolute;
   z-index: -1;
   top: 15px;
   left: 15px;
   right: 15px;
   bottom: 15px;
   border: 5px solid #00b4ff;
   background: #fff;
}

That’s all there is to it. The finished product is part of the Multiple Borders with CSS 2.1 demo.

Progressive enhancement and legacy browsers

IE6 and IE7 have no support for CSS 2.1 pseudo-elements and will ignore all :before and :after declarations. They get none of the enhancements but are left with the basic usable experience.

A warning about Firefox 3.0

Firefox 3.0 supports CSS 2.1 pseudo-elements but does not support their positioning. Due to this partial support, you should avoid declaring display:block for absolutely positioned pseudo-elements that explicitly declare a width or height values. However, when using borders there is no graceful fallback for Firefox 3.0. Although, sometimes an improved appearance in Firefox 3.0 can be achieved by adding display:block to pseudo-element hacks that use borders.

Enhancing with CSS3

All the applications included in this article could be further enhanced to take advantage of present-day CSS3 implementations.

Using border-radius, rgba, and transforms, and CSS3 multiple background images in tandem with pseudo-elements can produce even more complex presentations that I hope to include in a future article. Currently there is no browser support for the use of CSS3 transitions or animations on pseudo-elements.

In the future: CSS3 pseudo-elements

The proposed extensions to pseudo-elements in the CSS3 Generated and Replaced Content Module include the addition of nested pseudo-elements (::before::before), multiple pseudo-elements (::after(2)), wrapping pseudo-elements (::outside), and the ability to insert pseudo-elements into later parts of the document (::alternate).

These changes would provide a near limitless number, and arrangement, of pseudo-elements for all sorts of complex effects and presentations using just one element.

Let me know what you’ve done

I’ve focused on just a few applications and popular effects. If you find other applications, limitations, or want to share how you’ve applied this technique please leave a comment below or let me know on Twitter (@necolas.

Translations




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Coronavirus | Maharashtra adds 1,089 new cases; Mumbai’s death toll stands at 462

Of the 1,089 new cases, Mumbai accounted for 748, with a cumulative tally of 12,142. With 75 new cases, Pune district’s tally has risen to 2,537.




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Party stands by jailed AIUDF MLA




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Thriving under stress [electronic resource] : harnessing demands in the workplace / Thomas W. Britt, Ph.D., Professor of Psychology, Clemson University, Steve M. Jex, Ph.D., Professor of Psychology, Bowling Green State University

Britt, Thomas W., 1966-




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Truth, growth, repeat [electronic resource] : (a business manual for generation why) / by Mike Edmonds with Ronnie Duncan

Edmonds, Mike, author




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Workarounds that work [electronic resource] : how to conquer anything that stands in your way at work / Russell Bishop

Bishop, Russell, 1950-











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Inflows in equity mutual funds plunge 25% to Rs 83,781 cr in FY20

This was the sixth successive year of net inflows in equity mutual funds




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Asian Paints extends loss into 8th day on report RIL mulls stake sale

The company controlled by Mukesh Ambani, is in discussions with banks for a potential sale of its 4.9 per cent stake in Asian Paints through a series of block trades, reports suggest.




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Risk-averse investors re-deploy funds in arbitrage MF schemes in April

Aversion to debt products has contributed to renewed interest in the category




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Thousands mourn death of Indian-origin Israeli soldier



  • DO NOT USE Indians Abroad
  • World

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UN Chief commends outgoing Indian force commander



  • DO NOT USE Indians Abroad
  • World

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Indian-origin ex-lawmaker in Germany stands trial for child pornography



  • DO NOT USE Indians Abroad
  • World

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Prabha Shetty stabbing: Seconds before death, Indian techie called husband to say she was being followed



  • DO NOT USE Indians Abroad
  • World

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US-Indians raise hundreds of thousands of dollars for Nepal



  • DO NOT USE Indians Abroad
  • World

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Chromium lands Flexbox gap

I mentioned this the other day via Michelle Barker’s coverage, but here I’ll link to the official announcement. The main thing is that we’ll be getting gap with flexbox, which means:

.flex-parent {
  display: flex;
  gap: 1rem;
}
.flex-child {
  flex: 1;
}

That’s excellent, as putting space in between flex items has been tough in the past. We have justify-content: space-between, which is nice sometimes, but that doesn’t allow you to explicitly tell the flex container how Read article “Chromium lands Flexbox gap”

The post Chromium lands Flexbox gap appeared first on CSS-Tricks.




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Goa: Congress demands probe into ex-MLA’s death

Congress on Friday demanded an independent inquiry, headed by a retired high court judge, into the death of two-time MLA Jitendra Deshprabhu. State Congress president Girish Chodankar alleged that Deshprabhu died due to the negligence of Goa Medical College authorities.




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Bird bonds : sex, mate-choice and cognition in Australian native birds / Gisela Kaplan

Kaplan, Gisela T., author




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Diamidophosphites from β-hydroxyamides: readily assembled ligands for Pd-catalyzed asymmetric allylic substitution

Dalton Trans., 2020, 49,5625-5635
DOI: 10.1039/D0DT00741B, Paper
Ilya V. Chuchelkin, Konstantin N. Gavrilov, Nataliya E. Borisova, Alexander M. Perepukhov, Alexander V. Maximychev, Sergey V. Zheglov, Vladislav K. Gavrilov, Ilya D. Firsin, Vladislav S. Zimarev, Igor S. Mikhel, Victor A. Tafeenko, Elena V. Murashova, Vladimir V. Chernyshev, Nataliya S. Goulioukina
Novel diamidophosphites based on β-hydroxyamides were prepared, and their individual and in situ formed complexes were tested in Pd-mediated allylations.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Design and synthesis of photoluminescent active interpenetrating metal–organic frameworks using N-2-aryl-1,2,3-triazole ligands

Dalton Trans., 2020, 49,5429-5433
DOI: 10.1039/D0DT00933D, Communication
Jingyang Li, Ying He, Li Wang, Qinhe Pan, Zhiguang Song, Xiaodong Shi
N-2-aryl-1,2,3-triazole derivatives were synthesized as new ligand systems for the construction of photoluminescent active metal–organic frameworks (MOFs).
The content of this RSS Feed (c) The Royal Society of Chemistry




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Chemoselective oxidative addition of vinyl sulfones mediated by palladium complexes bearing picolyl-N-heterocyclic carbene ligands.

Dalton Trans., 2020, 49,5684-5694
DOI: 10.1039/D0DT01144D, Paper
Thomas Scattolin, Claudio Santo, Nicola Demitri, Luciano Canovese, Fabiano Visentin
We have examined in depth the features of oxidative addition of (E)-1,2 ditosylethene on palladium(0) complexes bearing picolyl-N-heterocyclic carbenes.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Comment on “Investigation on the structure and thermoelectric properties of CuxTe binary compounds” by Shriparna Mukherjee et al., Dalton Trans., 2019, 48, 1040

Dalton Trans., 2020, 49,5736-5737
DOI: 10.1039/C9DT03607E, Comment
Aarón H. Barajas-Aguilar, A. M. Garay-Tapia, Sergio J. Jiménez-Sandoval
Copper telluride sensitivity to laser power: effect on the Raman spectra.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Reply to the ‘Comment on “Investigation on the structure and thermoelectric properties of CuxTe binary compounds”’ by A. H. Barajas-Aguilar, A. M. Garay-Tapia, and S. J. Jiménez-Sandoval, Dalton Trans., 2020, 49, DOI: 10.1039/C9DT03607E

Dalton Trans., 2020, 49,5738-5740
DOI: 10.1039/D0DT00412J, Comment
Shriparna Mukherjee, Raju Chetty, P. V. Prakash Madduri, Ajaya K. Nayak, Krzysztof Wojciechowski, Tanmoy Ghosh, Kamanio Chattopadhyay, Satyam Suwas, Ramesh Chandra Mallik
In a communication to Dalton Transaction and in a paper in Journal of Physics: Condensed Matter, Aarón H. Barajas-Aguilar et al. have raised comments on our paper published earlier in Dalton Transactions.
The content of this RSS Feed (c) The Royal Society of Chemistry