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Theoretical calculations-driven rational screening of d-block single-atom electrocatalysts based on d-p orbital hybridization for durable aqueous zinc-iodine batteries

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04119D, Paper
Jin Yang, Yuanhong Kang, Fanxiang Meng, weiwei meng, guanhong Chen, Minghao Zhang, Zeheng Lv, Zhipeng Wen, Chengchao Li, Jinbao Zhao, Yang Yang
Aqueous Zn−iodine (Zn-I2) batteries, featuring intrinsically high-safety aqueous electrolytes and eco-friendly cathode/anode materials, however are restricted by the shuttling of polyiodide and sluggish redox kinetics of iodine redox. Although various...
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Flexible spacer-block multi-component copolymerized donors enable resilient organic solar cells with over 40% crack-onset strain

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE04208E, Paper
Congqi Lin, Zhenyu Chen, Ruixiang Peng, Wei Song, Jiangwei Gao, Xueliang Yu, Tingting Feng, Yongqi Bai, Ziyi Ge
A series of novel block donors were synthesized, achieving excellent PCE of 19.57% in rigid OSCs and 18.03% in f-OSCs, along with an outstanding crack-onset strain value of 40.29%.
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Superhydrophobic and robust hetero-metal-polymer hybrid interphase enables deep-cycling zinc metal anodes

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04122D, Paper
Mengyu Liu, Wentao Yuan, Xinghan Qu, Xianghao Ru, Xiaotong Li, Tingxuan Wang, Xinke Wang, Yuanyuan Wang, Yongchang Liu, Ning Zhang
Realizing stable zinc (Zn) metal anodes under deep cycling conditions is the prerequisite for practical rechargeable Zn batteries but remains a significant challenge, due to severe water erosion and dendrite...
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A thermal evaporation–trapping strategy to synthesize flexible and robust oxygen electrocatalysts for rechargeable zinc–air batteries

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03005B, Paper
Hong-Bo Zhang, Yu Meng, Lingzhe Fang, Fei Yang, Shangqian Zhu, Tao Li, Xiaohua Yu, Ju Rong, Weiwei Chen, Dong Su, Yi Mei, Peng-Xiang Hou, Chang Liu, Minhua Shao, Jin-Cheng Li
A thermal evaporation–trapping strategy is developed to fabricate a flexible N-doped carbon fiber cloth loaded with both CoFe-oxide nanoparticles and atomic Co/Fe–Nx sites, showing outstanding oxygen electrocatalytic performance.
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An electric double layer regulator empowers robust solid-electrolyte interphase for potassium metal batteries

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03978E, Paper
Xueyu Lian, Liang Xu, Zhijing Ju, Ziang Chen, Xiaopeng Chen, Yuyang Yi, Zhengnan Tian, Tao Cheng, Shi Xue Dou, Xinyong Tao, Jingyu Sun
The electric double layer (EDL) plays a key role in constructing solid electrolyte interphase (SEI) for high-energy metal anodes. Nevertheless, the significance of EDL and its associated influence remain elusive...
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A donor:hole-transport layer alloy for high-efficiency and stable binary organic solar cells with promoted hole collection and suppressed recombination

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE04072D, Paper
Xianghui Zeng, Ting Xu, Hansheng Chen, Baoshen Deng, Qing Yan, Xuanlin Wen, Zijian Li, Haoxuan Zeng, Chuanlin Gao, Yaodong Xiao, Jiwei Liao, Hui Liu, Bin He, Peigang Han, Guangye Zhang, Shunpu Li, Yiwang Chen, Chen Xie
A donor-based nanoparticle (NPs)-incorporated hole-transport layer was synthesized for fine-tuning the energy level of anodes in organic solar cells. The conventional and inverted devices achieved record efficiencies of 19.9% and 17.2%, respectively.
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Dual Promotion of Oxygen Reduction on Pt in Membrane Electrode Assembly by Hydroxyphenyl Metal Porphyrins

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04320K, Paper
Meihua Tang, Chunping Wang, Zhenying Zheng, Xiaoxiao Wang, Fulong Zhu, Shengli Chen
The oxygen reduction reaction (ORR) in proton exchange membrane fuel cells (PEMFCs) is severely hindered by the strong adsorption of sulfonate groups in perfluorinated sulfonic acid (PFSA) ionomers on Pt,...
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Metastable interphase induced pre-strain compensation enables efficient and stable perovskite solar cells

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE03801K, Paper
Hongyu Xu, Yun Xiao, Karim A Elmestekawy, Pietro Caprioglio, Qiuyang Li, Qixuan Zhong, Yongqiang Ji, Tianyu Huang, Haoming Yan, Yingguo Yang, Laura M Herz, Qihuang Gong, Henry Snaith, Rui Zhu, Lichen Zhao
High-efficiency metal halide perovskite solar cells (PSCs) include the rigid substrates with low thermal-expansion coefficients (TECs), resulting in a significant TEC mismatch with the perovskites with high TECs at the...
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Interfacial coordination utilizing chelating ligands for operationally stable perovskite solar modules

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE02803A, Paper
Bingkun Tian, Peikun Zhang, Tianjun Liu, Weicun Chu, Yuyang Long, Peng Xu, Ying Jiang, Jinping Zhang, Yajing Tang, Xiangnan Sun, Riming Nie, Xiaoming Zhao, Wanlin Guo, Zhuhua Zhang
Perovskite solar cells (PSCs) feature a higher maximum theoretical efficiency and a lower cost than silicon-based solar cells, while also offering additional advantages of being flexible and transparent. However, the...
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A monolithic Co-FeCo8S8 electrode for stable anion exchange membrane water electrolyzer driven by fluctuating power supply

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04993D, Communication
Jahangir Khan, Heming Liu, Tianhao Zhang, Xin Kang, Zhiyuan Zhang, Yuxiao Dong, Shanlin Li, Jiarong Liu, Qiangmin Yu, Bilu Liu
Integrating water electrolysis and green electricity offers a promising approach towards sustainable and clean energy. However, such a system demands electrodes that can swiftly and stably adapt to fluctuating power...
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Unveiling nanoscale fluid miscible behaviors with nanofluidic slim-tube

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE02292K, Paper
Zengding Wang, Tianjiang Zhang, Shanchao Liu, Keli Ding, Tengyu Liu, Jun Yao, Hai Sun, Yongfei Yang, Lei Zhang, Wendong Wang, Cunqi Jia, Mojdeh Delshad, Kamy Sepehrnoori, Junjie Zhong
We developed a nanofluidic method to visualize fluid miscible behaviors in nanoscale and multiscale porous media. Nano-confinement reduces MMP, while multiscale structures increase MMP, unveiling distinct miscible stages.
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Hydrogel electrolytes with an electron/ion dual regulation mechanism for highly reversible flexible zinc batteries

Energy Environ. Sci., 2024, 17,8570-8581
DOI: 10.1039/D4EE03067B, Paper
Fusheng Luo, Song Yang, Qing Wu, Yue Li, Jinlong Zhang, Yanhui Zhang, Jun Huang, Haibo Xie, Yiwang Chen
The unique electron/ion dual regulation mechanism is established in the well-designed hydrogel electrolyte by integrating polyacrylamide network and carboxylated multi-walled carbon nanotubes for high performance flexible ZIBs.
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Naphtho[1,2-c:5,6-c']bis([1,2,3]thiadiazole) enables the design of efficient halogen-free polymer donors and fabrication of organic solar cells with >19% efficiency

Energy Environ. Sci., 2024, 17,8593-8608
DOI: 10.1039/D4EE02414A, Paper
Tao Jia, Yongmin Luo, Yulong Hai, Tao Lin, Xudong Qin, Ruijie Ma, Kezhou Fan, Aleksandr A. Sergeev, Top Archie Dela Peña, Yao Li, Mingjie Li, Kam Sing Wong, Gang Li, Jiaying Wu, Shengjian Liu, Fei Huang
Fusion and isomerization strategies are used to develop an electron-withdrawing motif naphtho[1,2-d:5,6-d']bis([1,2,3]thiadiazole) (iNT) and a halogen-free polymer donor achieving an efficiency of 19.1%.
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A wearable DC tribovoltaic power textile woven by P/N-type organic semiconductor fibers

Energy Environ. Sci., 2024, 17,8621-8632
DOI: 10.1039/D4EE02662D, Paper
Open Access
Beibei Fan, Guoxu Liu, Yiming Dai, Zefang Dong, Ruifei Luan, Likun Gong, Zhi Zhang, Zhong Lin Wang, Chi Zhang
A high-performance, wearable tribovoltaic DC power supply textile was prepared using a traditional weaving process. The WDPs have high flexibility, excellent environmental robustness, lower internal resistance, and washability.
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Superhalide structure and iodide-proof interphase via electrolyte regulation enable ultrastable zinc-iodine batteries

Energy Environ. Sci., 2024, 17,8643-8657
DOI: 10.1039/D4EE02192D, Paper
Wenjing Deng, Renfei Feng, Xiaolei Wang
A superhalide electrolyte structure and iodide-proof solid electrolyte interphase are introduced to simultaneously obtain efficient conversion activity and anode stability for reversible zinc–iodine batteries.
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An energy-efficient tellurium electrode enabled by a Cs2TeI6 perovskite structure for durable aqueous Zn–Te batteries

Energy Environ. Sci., 2024, 17,8633-8642
DOI: 10.1039/D4EE02916J, Paper
Jinye Li, Chengjun Lei, Pengjie Jiang, Chen Xu, Tingting Liu, Xiao Liang
CsI in 2 M ZnSO4 aqueous electrolyte facilitates the formation of Cs2TeI6 perovskite phase for Te electrode, effectively suppressing Te4+ hydrolysis and sustaining fast redox kinetics in multi-electron transfer Zn–Te aqueous batteries.
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Polymer electrolytes with high cation transport number for rechargeable Li–metal batteries: current status and future direction

Energy Environ. Sci., 2024, 17,8457-8481
DOI: 10.1039/D4EE03097D, Review Article
Xinyuan Shan, Zhaowei Song, Hang Ding, Lengwan Li, Yuhang Tian, Alexei P. Sokolov, Ming Tian, Kang Xu, Peng-Fei Cao
The high-cation transport number polymer electrolytes (HTPEs) with simultaneously high cation transport number and high ionic conductivity could provide a solution to enable high-performance solid-state batteries.
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Weakened hydrogen bond connectivity promotes interfacial mass transfer for industrial level scalable biomass electrooxidation

Energy Environ. Sci., 2024, 17,8801-8809
DOI: 10.1039/D4EE03482A, Paper
Zhaohui Yang, Lan Chen, Yijun Yin, Chenyang Wei, Zhimin Xue, Tiancheng Mu
The inhomogeneous valence distribution due to in the intrinsic electric field of a material can weaken the interfacial H-bonding connectivity under the bias potential, which promotes the mass transfer of HMF during the HMF electrooxidation reaction.
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Microenvironment engineering of covalent organic framework based single/dual-atom catalysts toward sustainable energy conversion and storage

Energy Environ. Sci., 2024, 17,8482-8528
DOI: 10.1039/D4EE03704A, Review Article
Ligang Wang, Jialu Li, Shufang Ji, Yuli Xiong, Dingsheng Wang
The recent advances in design principles, synthetic strategies, advanced characterization techniques and promising applications of state-of-the-art COF-based SACs/DACs were comprehensively discussed and explored.
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Harnessing enhanced lithium-ion storage in self-assembled organic nanowires for batteries and metal-ion supercapacitors

Energy Environ. Sci., 2024, 17,8874-8884
DOI: 10.1039/D4EE02777A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ievgen Obraztsov, Rostislav Langer, Jean G. A. Ruthes, Volker Presser, Michal Otyepka, Radek Zbořil, Aristides Bakandritsos
Mesoscale engineering of small organic molecules towards a 3D nanowire network offers a potent toolkit for improved energy storage performance.
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Advancing high-efficiency, stretchable organic solar cells: novel liquid metal electrode architecture

Energy Environ. Sci., 2024, 17,8915-8925
DOI: 10.1039/D4EE03406F, Paper
Seungbok Lee, Sungjun Oh, Seungseok Han, Dongchan Lee, Jihyung Lee, Yonghwi Kim, Hoe-Yeon Jeong, Jin-Woo Lee, Min-Ho Lee, Wu Bin Ying, Seonju Jeong, Seungjae Lee, Junho Kim, Yun Hoo Kim, Bumjoon J. Kim, Eun-chae Jeon, Taek-Soo Kim, Shinuk Cho, Jung-Yong Lee
Highly efficient and stretchable organic solar cells were developed with a novel liquid metal top electrode. Metallic interlayers enabled its fabrication via thermal evaporation, achieving 14.6% PCE and 70% PCE retention under 63% strain.
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Electrodialysis and nitrate reduction (EDNR) to enable distributed ammonia manufacturing from wastewaters

Energy Environ. Sci., 2024, 17,8787-8800
DOI: 10.1039/D4EE03002H, Paper
Open Access
Jinyu Guo, Matthew J. Liu, Chloe Laguna, Dean M. Miller, Kindle S. Williams, Brandon D. Clark, Carolina Muñoz, Sarah J. Blair, Adam C. Nielander, Thomas F. Jaramillo, William A. Tarpeh
Underutilized wastewaters containing dilute levels of reactive nitrogen (Nr) can help rebalance the nitrogen cycle.
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Global softening to manipulate sound velocity for reliable high-performance MgAgSb thermoelectrics

Energy Environ. Sci., 2024, 17,8810-8819
DOI: 10.1039/D4EE03521F, Paper
Open Access
Airan Li, Longquan Wang, Jiankang Li, Takao Mori
A global softening strategy using stearic acid in MgAgSb to reduce sound velocity has been shown to enhance its thermoelectric performance, achieving high zT values and demonstrating strong potential for low-grade heat harvesting.
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Charge target collection from different triboelectrification domains by electrostatic induction and polarization enabled air discharges

Energy Environ. Sci., 2024, 17,8942-8953
DOI: 10.1039/D4EE04035J, Paper
Kaixian Li, Siqi Gong, Shaoke Fu, Hengyu Guo, Chuncai Shan, Huiyuan Wu, Jian Wang, Shuyan Xu, Gui Li, Qionghua Zhao, Xue Wang, Chenguo Hu
New channels of dynamic dielectric polarization enabled discharges (DPD) are proposed and combined with electrostatic induction enabled discharges (EID) to achieve charge target collection from different triboelectrification domains.
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Towards efficient and stable organic solar cells: fixing the morphology problem in block copolymer active layers with synergistic strategies supported by interpretable machine learning

Energy Environ. Sci., 2024, 17,8954-8965
DOI: 10.1039/D4EE03168G, Paper
Yu Cui, Qunping Fan, Hao Feng, Tao Li, Dmitry Yu. Paraschuk, Wei Ma, Han Yan
Interpretable machine learning identifies the causal structure–property relationships and key control factors in block copolymer organic solar cells with excellent power conversion efficiency and thermal stability.
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Bicontinuous-phase electrolyte for a highly reversible Zn metal anode working at ultralow temperature

Energy Environ. Sci., 2024, 17,8966-8977
DOI: 10.1039/D4EE02815E, Paper
Mi Xu, Beinuo Zhang, Yudong Sang, Dan Luo, Rui Gao, Qianyi Ma, Haozhen Dou, Zhongwei Chen
A bicontinuous-phase electrolyte with a well-balanced solvation sheath is proposed, which delivers fast desolvation kinetics and generates a uniform in situ solid electrolyte interface, thus achieving a long-lasting Zn anode at low temperatures.
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Weaving electron-rich alkynes: a durable in situ skin for stabilizing zinc anodes

Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE03164D, Paper
Xin Liu, Weimian Zhang, Ying Liu, Xiaodong Li, Deyi Zhang, Kun Wang, Lifeng Liu, Changshui Huang
An electron-rich alkyne of thiophdiyne (e-TDYP) is engineered in situ onto a zinc anode to regulate the EDL properties. The synergy between the conjugated thiophene and alkyne groups of e-TDYP facilitates the desolvation and ion-capture.
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Self-assembled porous salt crystals for solar-powered crystallization

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE04741A, Paper
Jie Yu, Lenan Zhang, Jintong Gao, Wenyu Han, Ruzhu Wang, Zhenyuan Xu
Thermally localized solar evaporation has been recognized as an efficient and suitable pathway for desalination and brine treatment. However, the annoying salt crystallization inside the porous evaporator brings challenges for...
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Anti-Freezing Hydrogel Electrolyte with Regulated Hydrogen Bond Network Enables High-Rate and Long Cycling Zinc Batteries

Energy Environ. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4EE02772H, Paper
Shaojie Guo, Mengyu Yan, DongMing Xu, Pan He, Kaijian Yan, Jiexin Zhu, Yongkun Yu, Zeya Peng, Yanzhu Luo, Feifei Cao
Zinc-based batteries, utilizing hydrogel electrolytes, present significant promise as power sources for next-generation flexible devices due to their stretchable nature and enhanced safety features. Nonetheless, the current hydrogel electrolytes require...
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Public hearing on Brane Enterprises on Nov. 17




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A law that enables vigilante violence

The amended Section 4 of the U.P. Prohibition of Unlawful Conversion of Religion Act gives the police unhindered powers and vigilante groups the full backing of the legal system to harass and intimidate religious minorities and interfaith couples




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Caste census data will be made public barring personal info of individuals, says Revanth Reddy

The data from the ongoing caste survey will not only be a road map for welfare and development, but also help the government in taking steps to increase the OBC quota; without accurate data, our goal of increasing reservations for BCs will not be achieved




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Are pro-natalist policies the way to address the ageing population problem?




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Maharashtra Assembly polls: A litmus test for Marathas

The Marathas may find it difficult to retain their socio-political domination




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Fabrication and evaluation of a flexible antenna device composed of a compatible iron-oxide clay in a PDMS graphene matrix

React. Chem. Eng., 2024, 9,901-909
DOI: 10.1039/D2RE00352J, Paper
Ameen Abdelrahman, Fouad Erchiqui, Mourad Nedil
We create a flexible and robust conductive polymer composite based on iron oxide and a thin film of clay doped with graphene nanoparticles, and test its application as a wearable device for underground workers.
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General synthesis of secondary imines via reductive coupling of carbonyl and nitro compounds employing a reusable cobalt catalyst

React. Chem. Eng., 2024, 9,925-929
DOI: 10.1039/D3RE00509G, Paper
Chaochong Zhang, Yurong He, Peng Zhou, Yuandie Ma, Ziliang Yuan, Guoqiang She, Zhe Zheng, Juncheng Hu, Qingqing Jiang, Jason Chun-Ho Lam, Bo Han, Zehui Zhang, Bing Liu
Reusable nitrogen-doped carbon-encapsulated Co nanoparticle catalysts are found robust for the synthesis of secondary imines via the reductive amination of carbonyl compounds with NH3 or directly with nitro compounds.
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Understanding the effects of forced and bubble-induced convection in transport-limited organic electrosynthesis

React. Chem. Eng., 2024, 9,930-939
DOI: 10.1039/D3RE00579H, Paper
Casey K. Bloomquist, Melisa Dogan, James S. Harris, Benjamin D. Herzog, William J. Tenn III, Eray S. Aydil, Miguel A. Modestino
Insights from data-driven surrogate models reveal that the Sherwood number characterizes mass transport conditions independent of the convection method, offering design guidelines for scaling up organic electrosynthesis.
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Continuous flow synthesis of the ionizable lipid ALC-0315

React. Chem. Eng., 2024, 9,959-966
DOI: 10.1039/D3RE00630A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jakob B. Wolf, Ju Weon Lee, Matthew B. Plutschack, Dario Cambié, Andreas Seidel-Morgenstern, Peter H. Seeberger
The ionizable lipid ALC-0315 is the major component of the lipid nanoparticles used to encapsulate the mRNA in the Biontech–Pfizer COVID-19 vaccine.
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Merging inline crystallization and pulsed flow operation to enable enantiospecific solid state photodecarbonylation

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00058G, Paper
Open Access
Bavo Vandekerckhove, Bart Ruttens, Bert Metten, Christian V. Stevens, Thomas S. A. Heugebaert
Photoelimination of α-chiral ketones in the solid state results in highly regio- and enantiospecific C–C bond formation. By combining inline crystallisation and pulsatile flow, the photochemistry of these slurries can now be run fully continuously.
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Efficient aqueous-phase hydrogenation of m-xylylenediamine to 1,3-cyclohexandimethylamine over a highly active and stable ruthenium catalyst

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00712J, Paper
Jing Guo, Heng Shao, Le Gao, Wancheng Ma, Wei Zhang, Long Huang, Haibin Chu
The strong interaction between Ru and –NH2 in Ru/NH2–Al2O3 led to the formation of highly dispersed Ru and modification of its electronic properties, and consequently greatly enhanced its performance and stability.
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Enhancing mass transport to accelerate photoreactions and enable scale-up

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D3RE00689A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Florian Gaulhofer, Markus Metzger, Alexander Peschl, Dirk Ziegenbalg
The importance of mixing in photoreactors along the direction of light propagation for competitive photochemical reactions is experimentally demonstrated in the MISCOP mini-plant photoreactor.
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On a seamlessly replicable circular photoreactor for lab-scale continuous flow applications

React. Chem. Eng., 2024, Accepted Manuscript
DOI: 10.1039/D4RE00109E, Paper
Yi-Hsuan Tsai, Martin Cattoen, Guillaume Masson, Gabrielle Christen, Lisa Traber, Morgan Donnard, Frederic R. Leroux, Guillaume Bentzinger, Sylvain Guizzetti, Jean-Christophe M. Monbaliu
A cost effective and replicable continuous flow circular photoreactor system is introduced. All body parts of the reactor are 3D-printed and the electronics are purchased from various mainstream suppliers. The...
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Hydrogenolysis of furfuryl alcohol over CuCeMgAl mixed metal oxide catalysts derived from layered double hydroxides

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00070F, Paper
Zhihui Wang, Wenbo Li, Xinyao Fu, Chen Zhang, Wei Zhang, Long Huang, Cuiqing Li
LDH-derived CuCeMgAl mixed metal oxide catalysts were synthesized. Ce addition promoted Cu dispersion and improved catalyst basicity, resulting in high activity in furfuryl alcohol hydrogenolysis and high selectivity toward 1,2-pentanediol.
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Ashok Leyland sees a positive shift in the e-bus procurement market with reasonable bidding rates

Dheeraj Hinduja expressed confidence that these initiatives are helping establish a more stable and predictable framework for procuring electric vehicles, which will benefit the sector’s long-term growth




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ZEISS India expands its GCC, plans to double workforce by 2028

The company currently employs 2,500 people across various functions




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Colour in every blade

Decorative grasses have become increasingly popular in the recent years. They survive with very little water




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Home-grown solutions to life’s little problems

Subashree has proved a home garden is all it takes to have good health, good looks and a good life




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It’s a techie life: Blossoms of creativity

There are a growing number of techies who practise the art of vegetative propagation




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Enjoy the winter blooms

Keep your garden fresh and insect-free during winter. Hema Vijay tells you how




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Birthday Boy Dhoni Spotted At Wimbledon

Dhoni will be 41 on July 7.