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Medical microbiology and infection at a glance [Electronic book] / Stephen H. Gillespie, Kathleen Bamford.

By encore.st-andrews.ac.uk
Published On ::

Hoboken, NJ : Wiley-Blackwell, 2022.


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Medical histories of Belgium : New narratives on health, care and citizenship in the nineteenth and twentieth centuries [Electronic book] / ed. by Joris Vandendriessche, Benoît Majerus.

By encore.st-andrews.ac.uk
Published On ::

Manchester : Manchester University Press, [2021]


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Figures of Radical Absence : Blanks and Voids in Theory, Literature, and the Arts [Electronic book] / Alexandra-Ecaterina Irimia.

By encore.st-andrews.ac.uk
Published On ::

Berlin ; Boston : De Gruyter, [2023]


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A companion to medical anthropology [Electronic book] / edited by Merrill Singer, Pamela I. Erickson, and César E. Abadía-Barrero.

By encore.st-andrews.ac.uk
Published On ::

Hoboken, NJ : John Wiley & Sons, Inc., 2022.


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Beyond the state : The colonial medical service in British Africa [Electronic book] / Anna Greenwood.

By encore.st-andrews.ac.uk
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Manchester : Manchester University Press, [2019]


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Strategic pathway selection for photocatalytic degradation: roles of holes and radicals

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI01635A, Review Article
Yixuan Li, Xu Gao, Yuxin Li
As global resources become scarce and environmental issues become increasingly severe, developing photocatalytic technology for efficiently and cleanly degrading pollutants has become a research trend.
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Engineering a pyrene MOF composite photocatalyst toward the formation of carbon dioxide radical anions through regulating the charge transfer from type II to Z scheme via a chemical bond-modulated strategy

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI02072C, Research Article
Xin Zhao, Yajun Zhao, Yuan-Peng Li, Pengbo Lyu, Chunying Chen, Zong-Wen Mo, Chao Peng, Jiewei Liu, Li Zhang
A new approach was reported for regulating the charge transfer mechanism in a pyrene-based MOF composite, transitioning from a type-II to a Z-scheme configuration.
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Unraveling the Correlation between Biological Effects and Halogen Substituents in Cobalt bis(dicarbollide)

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02296C, Research Article
Katarzyna Zakret-Drozdowska, Bożena Szermer-Olearnik, Waldemar Goldeman, Michalina Gos, Dawid Drozdowski, Anna Gągor, Tomasz M. Goszczyński
Over the past decade, considerable scientific attention has been given to adapting cobalt bis(dicarbollides) as innovative agents with various biomedical applications. Although the studied compounds show great potential in this...
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Transesterification or polymerization? Reaction mechanism and kinetics of 2-(diethylamino)ethyl methacrylate with methanol and the competitive effect on free-radical polymerization

By pubs.rsc.org
Published On ::

React. Chem. Eng., 2024, Advance Article
DOI: 10.1039/D4RE00406J, Paper
Judith Cabello-Romero, Román Torres-Lubián, Javier Francisco Enríquez-Medrano, Adrián Ochoa-Terán, Jesús Jara-Cortés, Iván Zapata-González
Transesterification of 2-(diethylamino)ethyl methacrylate (DEAEMA) with methanol leads to the formation of methyl methacrylate (MMA) and amino alcohol. This reaction significantly affects DEAEMA polymerization giving rise to poly(DEAEMA-co-MMA).
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DNA liquid crystals with AIE effect toward humidity-indicating biomaterials

By pubs.rsc.org
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Soft Matter, 2024, 20,3243-3247
DOI: 10.1039/D3SM01531A, Communication
Guoqiang Zhang, Jing Zhao, Qikai Liang, Zhongtao Wu, Lei Zhang, Xiliang Luo
A DNA-containing material displaying a trackable humidity-induced change in fluorescence could accurately indicate in real time the environmental relative humidity at room temperature in 4 minutes.
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Kinetic and reactivity of gas-phase reaction of acyclic dienes with hydroxyl radical in the 273–318 K temperature range

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,12303-12312
DOI: 10.1039/D3RA08750F, Paper
Open Access
Chenyang Xue, Xinmiao Xu, Han Lyu, Yunfeng Li, Yangang Ren, Jinhe Wang, Yujing Mu, Abdelwahid Mellouki, Zongzheng Yang
The relative position of two CC on the acyclic dienes could determine its reactivity. The number and type of alkyl group and the number of addition sites on diene could also strongly affect its reactivity toward OH radical.
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Electrochemical oxidative radical cascade cyclization of dienes and diselenides towards the synthesis of seleno-benzazepines

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,12556-12560
DOI: 10.1039/D4RA01914H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ling Hu, Jingyi Zhang, Minghan Li, Yulin Feng, Fangling Lu
An electrochemical approach to access seleno-benzazepines through an oxidative radical cascade cyclization of dienes with diselenides under metal-free, external oxidant-free and base-free conditions.
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Rational design of a lysosome-targeted fluorescent probe for monitoring the generation of hydroxyl radicals in ferroptosis pathways

By pubs.rsc.org
Published On ::

RSC Adv., 2024, 14,12864-12872
DOI: 10.1039/D4RA00562G, Paper
Open Access
Lili Zhong, Datian Fu, Jin Xu, Linyan Tan, Haimei Wu, Min Wang
A novel hydrocyanine-based turn-on fluorescence probe HCy-Lyso, with excellent lysosome-targeting ability and ˙OH-responsive efficiency, has been applied for monitoring the variation in lysosomal ˙OH levels during ferroptosis.
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Versatile poly(N-vinylcaprolactam)-grafted-hydroxypropyl cellulose polymers with tailored thermo- and pH-responsive properties via sustainable organocatalyzed atom transfer radical polymerization

By pubs.rsc.org
Published On ::

Polym. Chem., 2024, 15,4244-4254
DOI: 10.1039/D4PY00931B, Paper
Muhammad Asif Iqbal, Asif Mahmood, Waheed Al-Masry, Chan Ho Park, Sadaf Ul Hassan, Toheed Akhter
This study explores the synthesis of dual pH- and thermo-responsive poly(N-vinylcaprolactam)-grafted-hydroxypropyl cellulose (PNVCL-g-HPC) polymers via visible-light-driven, metal-free organocatalyzed atom transfer radical polymerization (O-ATRP).
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Heterogenous catalysis for oxygen tolerant photoredox atom transfer radical polymerization and small-molecule dehalogenation

By pubs.rsc.org
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Polym. Chem., 2024, 15,4264-4280
DOI: 10.1039/D4PY00899E, Paper
Open Access
Kriti Kapil, Mingkang Sun, Ting-Chih Lin, Hironobu Murata, Grzegorz Szczepaniak, Khidong Kim, Stephen DiLuzio, Jaepil Jeong, Mitchell Baumer, Stefan Bernhard, Tomasz Kowalewski, Krzysztof Matyjaszewski
Heterogeneous photocatalysts (PCs) have garnered attention for their sustainability and cost-effectiveness.
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Crystal structure of poly(trimethylene 2,5-furandicarboxylate) redux – a new model supported by computational spectroscopy

By pubs.rsc.org
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Polym. Chem., 2024, 15,4349-4363
DOI: 10.1039/D4PY00779D, Paper
Catarina F. Araújo, Simão V. Pandeirada, Inês M. Oliveira, Guilherme B. Rosa, Beatriz Agostinho, Armando J. D. Silvestre, Andreia F. Sousa, Svemir Rudić, Pedro D. Vaz, Mariela M. Nolasco, Paulo Ribeiro-Claro
The crystal structure of biobased poly(trimethylene 2,5-furandicarboxylate) is revisited following new evidence from vibrational spectroscopy and computational chemistry tools.
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Bisbenzothieno[b]-fused BODIPYs in panchromatic photoinitiating for the free radical and cationic photopolymerization and application in 3D printing

By pubs.rsc.org
Published On ::

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00926F, Paper
Yangyang Xu, Wenlong Tang, Hui Deng, Jianjun Zhang, Zhongquan Zhu, Changjiang Yu, Haiguang Zhu, Ke Sun, Jiazhu Li, Jacques Lalevée
Abstract: Polymerization reactions induced by lights occupy an increasing share in the area of polymer synthesis; however, the effective photopolymerization under visible light emitting diodes (LEDs) rather than UV still...
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Alternating Radical Copolymerization of α-Styrylboronic Acid Pinacol Ester with Electron-Deficient Olefins

By pubs.rsc.org
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Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00976B, Paper
Yiyang Xiao, Zepeng Zhang, Yan Xu, Jianbo Wang
Here, α-styryl boronic acid pinacol ester (StBpin) has been found to undergo alternating radical copolymerization with electron-deficient olefin comonomers, including n-butyl acrylate, N,N-dimethylacrylamide, acrylonitrile, and N-ethylmaleimide. Compared with styrene, which...
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Acrylate–methacrylate radical copolymerization kinetics of sparingly water-soluble monomers in polar and nonpolar solvents

By pubs.rsc.org
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Polym. Chem., 2024, 15,4542-4553
DOI: 10.1039/D4PY01015A, Paper
Noushin Rajabalinia, Fatemeh Salarhosseini, Robin A. Hutchinson
The influence of solvent on radical copolymerization kinetics is studied to provide insight to emulsion polymerization systems.
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Recent Advances of Versatile Fluorophores for Multifunctional Biomedical Imaging in the NIR-II Region

By pubs.rsc.org
Published On ::

J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01957A, Review Article
Kaiming Ma, Qunying Jiang, Yang Yang, Fan Zhang
Fluorescence imaging in the second near-infrared region (NIR-II, 1,000-1,700 nm) enables high-resolution visualization of deep-tissue biological architecture and physiopathological events, due to the reduced light absorption, scattering and tissue autofluorescence....
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Chemically engineered exogenous organic reactions in living cells for in situ fluorescence imaging and biomedical applications

By pubs.rsc.org
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J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01925C, Review Article
Gang Song, Zhiwen Yang, Yiming Huang, Haotian Bai, Fengting Lv, Shu Wang
Key intracellular in situ synthesis processes, including the synthesis of near-infrared fluorescent dyes, intracellular oxidative cross-linking, polymerization, and bioorthogonal reactions, as well as their biomedical applications were summarized.
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Recent Advances of Two-Dimensional Materials for biomedical Application

By pubs.rsc.org
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J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB01787K, Review Article
Ranran Zhang, Zichao Yan, Ming Gao, Bingxin Zheng, Bin Yue, Meng Qiu
Two-dimensional (2D) materials exhibit significant potential in biomedical applications, particularly as drug carriers. 2D materials, including graphene, black phosphorus, transition metal dichalcogenides, transition metal carbides/nitrides, and hexagonal boron nitride, have...
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One-pot rapid preparation of long-term antioxidant and antibacterial biomedical gels based on lipoic acid and eugenol for accelerating cutaneous wound healing

By pubs.rsc.org
Published On ::

J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01844C, Paper
Yungang Feng, Fangrui Xie, Rui Ding, Qingrong Zhang, Youzhi Zeng, Li Li, Lianbin Wu, Yunlong Yu, Linxuan Fang
A medical antibacterial gel with long term and high antioxidant activity prepared from eugenol and lipoic acid showed good tissue repair and regeneration for burns and trauma.
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Lactobionic acid modified cobalt coordination polymer-coated peroxymonosulfate nanoparticles generate sulfate/hydroxy dual-radicals for targeted cancer therapy

By pubs.rsc.org
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J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01777C, Paper
Jiahui Li, Jiaxuan Li, Zelong Chen, Yichen Wan, Yi Wang, Zhichao Pei, Yuxin Pei
LCP NPs were prepared by forming a coordination polymer on peroxymonosulfate through the coordination between imidazole-2-carboxaldehyde and Co2+, then modified with lactobionic acid to improve the efficacy of sulfate/hydroxy dual-radical therapy.
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Research Progress of Nitroxide Radical-Based MRI Contrast Agents: From Structure Design to Application

By pubs.rsc.org
Published On ::

J. Mater. Chem. B, 2024, Accepted Manuscript
DOI: 10.1039/D4TB02272F, Review Article
Tao Luo, Bo Wang, Runxin Chen, Qi Qi, Ruodai Wu, Shunzi Xie, Hanbing Chen, Jialei Han, Dalin Wu, Shuaishuai Cao
Magnetic resonance imaging (MRI) remains a cornerstone of diagnostic imaging, offering unparalleled insights into anatomical structures and pathological conditions. Gadolinium-based contrast agents have long been the standard in MRI enhancement,...
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Cillian Murphy Dedicates His Oscar To...

By www.rediff.com
Published On :: Mon, 11 Mar 2024 10:47:18 +0530

Accepting his Best Actor Oscar for the biopic Oppenheimer, Irish actor Cillian Murphy gave a shout-out to his homeland, saying, 'I'm a very proud Irishman standing here tonight.'


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Generation, manipulation, detection and biomedical applications of magnetic droplets in microfluidic chips

By pubs.rsc.org
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Analyst, 2024, Advance Article
DOI: 10.1039/D4AN01175A, Minireview
Chenyang Xu, Huanhuan Shi, Zhongjian Tan, Yun Zheng, Weizheng Xu, Zhengxian Dan, Jiacong Liao, Zhiying Dai, Yali Zhao
This review discusses the formation and manipulation of magnetic droplets on microfluidic chips and classifies related detection techniques. Applications in biomedicine were reviewed. Future development of this emerging field is provided.
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Comparing coupled cluster and composite quantum chemical methods for computing activation energies and reaction enthalpies of radical propagation reactions

By pubs.rsc.org
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Phys. Chem. Chem. Phys., 2024, 26,27536-27543
DOI: 10.1039/D4CP03676J, Paper
Timothy B. Huber, Ralph A. Wheeler
The accuracy of DLPNO-CCSD(T)/CBS and composite methods G3(MP2)-RAD and CBS-RAD is assessed against CCSD(T)/aug-cc-pVTZ for activation energies and reaction enthalpies in hydrocarbon radical addition reactions relevant to free radical polymerization.
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Insights of the peroxychloroformyl radical ClC(O)OO via microwave spectrum

By pubs.rsc.org
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Phys. Chem. Chem. Phys., 2024, 26,27669-27676
DOI: 10.1039/D4CP03506B, Paper
Ching-Hua Chang, Wen Chao, Cheng-Han Tsai, Mitchio Okumura, Frank A. F. Winiberg, Yasuki Endo
Pure rotational spectra of trans-ClC(O)O2 (left) and cis-ClC(O)O2 (right), and the potential energy curve connecting the two conformers. The energy diagram and the observed transitions for the trans-ClC(O)O2 are also shown.
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Performance of functionalized graphene oxide with organic radical scavengers in proton exchange membranes

By pubs.rsc.org
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Phys. Chem. Chem. Phys., 2024, 26,27817-27828
DOI: 10.1039/D4CP03151B, Paper
Yu Hu, Jiaxing Wang, Shuai Wang, Yuan Feng
A diazonium salt reaction is used to prepare benzoic acid-functionalized graphene oxide as a bi-functional filler for a Nafion membrane, and the corresponding composite membrane has improved chemical durability and proton conductivity.
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Radical reactions enabled by polyfluoroaryl fragments: photocatalysis and beyond

By pubs.rsc.org
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Chem. Soc. Rev., 2024, Advance Article
DOI: 10.1039/D3CS00889D, Review Article
Mikhail O. Zubkov, Alexander D. Dilman
The review summarizes advances in the radical chemistry of polyfluorinated arenes under photocatalytic conditions. The fluoroaryl fragment serves as enabling motif for the reaction design and efficient generation of reactive intermediates.
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Engineered two-dimensional nanomaterials based diagnostics integrated with internet of medical things (IoMT) for COVID-19

By pubs.rsc.org
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Chem. Soc. Rev., 2024, 53,3774-3828
DOI: 10.1039/D3CS00719G, Review Article
Mohd. Abubakar Sadique, Shalu Yadav, Raju Khan, Avanish K. Srivastava
Engineered 2D nanomaterials-based smartphone-assisted detection approaches integrated with IoMT, focusing on reliable, sensitive, and rapid diagnostics for COVID-19.
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Self-indicating polymers: a pathway to intelligent materials

By pubs.rsc.org
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Chem. Soc. Rev., 2024, 53,4045-4085
DOI: 10.1039/D3CS00431G, Review Article
Mobina Bayat, Hanieh Mardani, Hossein Roghani-Mamaqani, Richard Hoogenboom
Self-indicating polymers undergo detectable variations in response to stimuli. Important mechanisms of self-indication are aggregation, phase transition, covalent and non-covalent bond cleavage, isomerization, charge transfer, and energy transfer.
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Degradable biomedical elastomers: paving the future of tissue repair and regenerative medicine

By pubs.rsc.org
Published On ::

Chem. Soc. Rev., 2024, 53,4086-4153
DOI: 10.1039/D3CS00923H, Review Article
Ben Jia, Heyuan Huang, Zhicheng Dong, Xiaoyang Ren, Yanyan Lu, Wenzhi Wang, Shaowen Zhou, Xin Zhao, Baolin Guo
This review critically analyzes degradable biomedical elastomers, focusing on their degradation, synthesis, microstructure, and role in tissue repair. It guides experts in balancing degradation with tissue repair for improved applications.
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Radical anions of 1,1-azoliumdithiocarboxylates

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05486E, Communication
Martin Simon Luff, Kai Oppel, Ivo Krummenacher, Holger Braunschweig, Udo Radius
The 1,1-azoliumdithiocarboxylate cAACMe-CS2 (1a) was prepared and its redox chemistry was evaluated and compared to NHC-based dithiocarboxylates IDipp CS2 (1b) and IMes-CS2 (1c). Radical anions [carbene CS2]·– were prepared by...
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Metal-free photocatalysts with charge-transfer excited states enable visible light-driven atom transfer radical polymerization

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC04470C, Communication
Yuchen Huang, Yangxin Liu, Yingde Yan, Yanjun Gong, Yifan Zhang, Yanke Che, Jincai Zhao
Photoredox-catalyzed atom transfer radical polymerization (O-ATRP) offers powerful tools for the precise control of polymer synthesis. Metal-free photocatalysts are particularly desirable due to their high level of control in O-ATRP...
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Base-Promoted Cascade 5-exo-dig Annulation/Carboxylation of o-(1-Alkynyl)benzenesulfonamides with CO2: Divergent Synthesis of Mono- or Gem-dicarboxylic Esters

By pubs.rsc.org
Published On ::

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC05239K, Communication
Yang Yao, Junxue Bai, Peidong Cheng, Han Yang, Jianwei Sun, Song Sun
A base-promoted cascade 5-exo-dig cyclization/carboxylation of o-alkynylsulfamides with CO2 has been accomplished, furnishing a variety of benzosultams-containing acrylates in good yields by using CO2 as the carboxylic source. Notably, in...
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The structural, electronic and thermodynamic properties of the designed p-benzoquinone based dicationic ionic liquids: insight from DFT–GD3 and QTAIM

By pubs.rsc.org
Published On ::

Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00119B, Paper
Hossein Roohi, Sajedeh Habibipour, Khatereh Ghauri
In this work, physicochemical properties of the dicationic ionic liquids [BTAD][A1–8]2 ([BTAD]2+ = [p-C6O2(N3H2)2]2+ and A1–8 = [CH3CO2]−, [CF3CO2]−, [N(CN)2]−, [CF3SO3]−, [ClO4]−, [BF4]−, [NTf2]− and [PF6]−) were theoretically investigated.
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Interruption volontaire de grossesse médicamenteuse

By www.vuibert.fr
Published On :: Wed, 23 Oct 2024 04:01:24 +0000

24,00 €

Philippe Faucher, Danielle Hassoun
4e édition
octobre 2024
160 pages
Un guide simple et concis pour bien prescrire l'IVG médicamenteuse
Livre
Nouveau
978-2-311-66541-3
Toutes les informations utiles - La prise en charge - La législation à jour
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Indicative of Supremacy

By www.thehindu.com
Published On :: Sat, 16 Jul 2016 00:11:45 +0530


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Peptide-linked perylenebisimide and ferrocene dicarboxylic acid conjugates with tunable optoelectronic properties

By pubs.rsc.org
Published On ::

New J. Chem., 2024, 48,7225-7234
DOI: 10.1039/D3NJ05809C, Paper
Biswanath Hansda, Soumyajit Hazra, Niladri Hazra, Purnadas Ghosh, Arindam Banerjee
Peptide linked perylenebisimide and ferrocene dicarboxylic acid conjugates display wonderful and tunable optoelectronic properties.
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Theoretical investigation of the effect of radical substituents on the open-shell character of polycyclic aromatic hydrocarbons

By pubs.rsc.org
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New J. Chem., 2024, Advance Article
DOI: 10.1039/D4NJ00555D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tomohito Shinozuka, Daiki Shimizu, Kenji Matsuda
Radical substituents was found to significantly alter the open-shell character y of PAHs compared to non-radical substituents.
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KOH-mediated synthesis of amides from azides and 1,3-dicarbonyl compounds

By pubs.rsc.org
Published On ::

New J. Chem., 2024, Advance Article
DOI: 10.1039/D3NJ05813A, Paper
Zhuoran Yang, Yao Xu, Xiaoming Liao, Wenjun Wang, Chang Lyu, Xiaoxiang Zhang
Aryl amides were prepared through KOH-mediated [3+2] cycloaddition/Wolff rearrangement from organic azides and 1,3-dicarbonyl compounds.
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Consequences of twisting of the flexible arms of imidazole-derived urea in zinc-dicarboxylate coordination polymers

By pubs.rsc.org
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CrystEngComm, 2024, 26,1976-1985
DOI: 10.1039/D4CE00005F, Paper
Satyendra Verma, Rinki Brahma, Jubaraj B. Baruah
A semi-flexible imidazole-based urea ligand, 1-(3-(1H-imidazol-1-yl)propyl)-3-phenylurea, and three zinc-dicarboxylate coordination polymers possessing the ligand were synthesized and characterized.
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Introduction of new guest molecules into BEDT-TTF radical-cation salts with tris(oxalato)ferrate

By pubs.rsc.org
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CrystEngComm, 2024, 26,1962-1975
DOI: 10.1039/D4CE00099D, Paper
Open Access
Toby J. Blundell, Elizabeth K. Rusbridge, Rebecca E. Pemberton, Michael J. Brannan, Alexander L. Morritt, Joseph O. Ogar, John D. Wallis, Hiroki Akutsu, Yasuhiro Nakazawa, Shusaku Imajo, Lee Martin
We present the crystal structures of five new BEDT-TTF radical-cation salts with tris(oxalato)ferrate anions using solid or liquid additives toluene, phenol, benzaldehyde, 4-bromobenzaldehyde, and kojic acid.
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‘Sharp increase in Railway freight traffic indicative of strong revival in economic activity post-Covid’

By www.thehindubusinessline.com
Published On :: Tue, 31 Jan 2023 18:40:17 +0530

Revenue-earning freight traffic for April–Nov period was saw an 8.3 per cent higher y-o-y at 976.8 million tonnes


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T'gana to constitute dedicated panel for survey on Backward Class quota

By www.newkerala.com
Published On :: Mon, 04 Nov 2024 10:40:03 +0530


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PM Modi virtually inaugurates new manufacturing plant of medical devices at Meril Company in Vapi

By www.newkerala.com
Published On :: Wed, 30 Oct 2024 21:26:02 +0530


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On the mechanism of carboxylate elimination from carbohydrate monoester-derived radicals

By pubs.rsc.org
Published On ::

Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00241E, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Julia A. Turner, Hendrik Zipse, Mark S. Taylor
Computational analysis of the HAT-induced expulsion of carboxylic acids from monoacylated pyranosides implicates concerted elimination through a hydrogen-bonded transition state.
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Catalyst- and base-free visible light-enabled radical relay trihalomethylation/functional group-migration/carbonylation with CX3SO2Cl

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Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00292J, Paper
Jinkai Hu, Chenglei Yang, Xiaotao Qin, Hui Liu, Tongtong Ma, Ao-tong Shi, Qing-Long Lv, Xingman Liu, Jinhui Yang, Dianjun Li
A visible light-enabled photocatalyst-free radical trihalomethylation/cyano (or benzo[d]thiazol-2-yl) 1,4-migration/carbonylation reaction of 2-hydroxy-2-hex-5-enenitrile (or (benzo[d]thiazol-2-yl)-pent-4-enol) with CX3SO2Cl (X = F, Cl) is reported.
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