This invention relates to a process for polymerizing ethylene comprising contacting ethylene and optional comonomers with a catalyst system comprising an activator and a transition metal compound represented by the formula: ##STR1## Wherein R1 and R2 are independently hydrogen or a group having up to 100 carbon atoms, Cp1 is a bulky ligand; Cp2 is a bulky ligand or a heteroatom optionally bound to a C1 to C50 hydrocarbyl group, n is the valence state of the transition metal, Tm is a Group 3 to 10 metal, and each X is independently an anionic leaving group.

Polysubstituted cyclopentadiene compound wherein at least two different substituents are present from the group consisting of linear, branched and cyclic alkyls, aralkyls and alkenyls, and a process for the preparation of a cyclopentadiene compound substituted with at least two different groups chosen from the group consisting of linear, branched, cyclic and aromatic alkyls and alkenyls, characterized in that it comprises the reacting of a halide of a first substituting group in a mixture of the cyclopentadiene compound and an aqueous solution of a base, in which the quantity of the base relative to the cyclopentadiene compound is between 5 and 30 mol/mol, in the presence of a phase transfer catalyst, followed by the addition of a halide of a second or optionally a third substituting group to the reaction mixture.

The invention relates to glasses for use in solid laser applications, particularly short-pulsed, high peak power laser applications. In particular, the invention relates to a method for broadening the emission bandwidth of rare earth ions used as lasing ions in solid laser glass mediums, especially phosphate-based glass compositions, using Nd and Yb as co-dopants. The invention further relates to a laser system using a Nd-doped and Yb-doped phosphate laser glass, and a method of generating a laser beam pulse using such a laser system.

Provided is a light-emitting glass which is applicable to, e.g., white illuminators including a light-emitting diode as a light source, and which emits light of a warm white color when irradiated with near ultraviolet light and combines long-term weatherability with high heat resistance; a light-emitting device containing same and a process for producing same. The light-emitting glass includes, as the base glass, borosilicate or silicate glass having a separated-phase structure, whereby the base glass is efficiently doped with, for example, transition metal ion clusters which emit light of a warm white color upon irradiation with near ultraviolet light. With this glass, it is possible to attain increases in excitation wavelength and emission wavelength. The glass thus emits, based on a multiple scattering effect, high-intensity light of a warm white color upon irradiation with near ultraviolet light.

The invention relates to powder comprising at least one element M, at least one element A and at least one element X, in the respective proportions (n+1±ε1), 1±ε2 and n±ε3, in which: A is chosen from Cd, Al, Ga, In, Tl, Si, Ge, Sn, Pb, P, As and S;M is a transition metal;X is chosen from B, C and N;n is an integer equal to 1, 2 or 3; andε1, ε2 and ε3 independently represent a number ranging from 0 to 0.2, said powder having a mean particle size of less than 500 nm.

The invention is directed to a pulverulent compound of the formula NiaM1bM2cOx(OH)y where M1 is at least one element selected from the group consisting of Fe, Co, Zn, Cu and mixtures thereof, M2 is at least one element selected from the group consisting of Mn, Al, Cr, B, Mg, Ca, Sr, Ba, Si and mixtures thereof, 0.3≦a≦0.83, 0.1≦b≦0.5, 0.01≦c≦0.5, 0.01≦x≦0.99 and 1.01≦y≦1.99, wherein the ratio of tapped density measured in accordance with ASTM B 527 to the D50 of the particle size distribution measured in accordance with ASTM B 822 is at least 0.2 g/cm3·μm. The invention is also directed to a method for the production of the pulverulent compound and the use as a precursor material for producing lithium compounds for use in lithium secondary batteries.

According to one embodiment, a glass container may include a body formed from a Type I, Class B glass composition according to ASTM Standard E438-92. The body may have an inner surface, an outer surface and a wall thickness extending between the outer surface and the inner surface. The body may also include a compressively stressed layer extending into the wall thickness from at least one of the outer surface and the inner surface. A lubricous coating may be positioned on at least a portion of the outer surface of the body, wherein the outer surface of the body with the lubricous coating has a coefficient of friction less than or equal to 0.7.

The invention relates to a granulated powder intended, in particular, for the production of ceramic sintered parts, said powder having the following chemical weight composition, based on dry matter, namely: a zirconia stabiliser selected from the group containing Y2O3, Sc2O3, MgO, CaO, CeO2, and mixtures thereof, the weight content of stabiliser, based on the total zirconia and stabiliser content, being between 2% and 20% and the MgO+CaO content being less than 5% based on the total zirconia and stabiliser content; at least 1% of a first binder having a glass transition temperature less than or equal to 25° C.; 0-4% of an additional binder having a glass transition temperature greater than 25° C.; 5-50% alumina; 0-4% of a temporary additive different from the first binder and the additional binder, the total content of the first binder, the additional binder and the temporary additive being less than 9%; less than 2% impurities; and ZrO2 to make up 100%. According to the invention, the median diameter D50 of the powder is between 80 and 130 μm, the percentile D99.5 is less than 500 μm and the relative density of the granules is between 30% and 60%.

A process to separate a multi-component hydrocarbon stream which includes ethylene and other components with at least some of the components being present in a number of phases, is provided. The process includes in a first flash stage, flashing the multi-component hydrocarbon stream, from an elevated pressure and temperature to a pressure in the range of 10-18 bar(a), producing a first ethylene-containing vapor stream at a pressure in the range of 10-18 bar(a) and a multi-phase stream which includes some ethylene. In a second flash stage, the multi-phase stream is flashed to a pressure of less than 6 bar(a), producing a second vapor stream at a pressure of less than 6 bar(a) and a bottoms stream. The first ethylene-containing vapor stream is removed from the first flash stage, the second vapor stream is removed from the second flash stage and the bottoms stream is removed from the second flash stage.

A process for the production of aromatics through the reforming of a hydrocarbon stream is presented. The process utilizes the differences in properties of components within the hydrocarbon stream to increase the energy efficiency. The differences in the reactions of different hydrocarbon components in the conversion to aromatics allows for different treatments of the different components to reduce the energy used in reforming process.

A process is presented for the increasing the yields of aromatics from reforming a hydrocarbon feedstream. The process includes splitting a naphtha feedstream into a light hydrocarbon stream, and a heavier stream having a relatively rich concentration of naphthenes. The heavy stream is reformed to convert the naphthenes to aromatics and the resulting product stream is further reformed with the light hydrocarbon stream to increase the aromatics yields. The catalyst is passed through the reactors in a sequential manner.

Disclosed is a method for removing weakly basic nitrogen compounds from a hydrocarbon feed stream by contacting the hydrocarbon feed stream with a basic catalyst to convert a portion of the weakly basic nitrogen compounds to basic nitrogen compounds. The method also includes contacting the hydrocarbon feed stream with an acidic adsorbent to adsorb the basic nitrogen compounds from the stream. The hydrocarbon feed stream comprises an aromatic compound and a weakly basic nitrogen compound.

Disclosed is a method for removing weakly basic nitrogen compounds from a hydrocarbon feed stream by contacting the hydrocarbon feed stream with acidic clay to produce a hydrocarbon effluent stream having a lower weakly basic nitrogen compound content relative to the hydrocarbon feed stream. The hydrocarbon feed stream comprises an aromatic compound and a weakly basic nitrogen compound.

A perpendicular spin-transfer torque magnetic random access memory (STTMRAM) element includes a fixed layer having a magnetization that is substantially fixed in one direction and a barrier layer formed on top of the fixed layer and a free layer. The free layer has a number of alternating laminates, each laminate being made of a magnetic layer and an insulating layer. The magnetic layer is switchable and formed on top of the barrier layer. The free layer is capable of switching its magnetization to a parallel or an anti-parallel state relative to the magnetization of the fixed layer during a write operation when bidirectional electric current is applied across the STTMRAM element. Magnetic layers of the laminates are ferromagnetically coupled to switch together as a single domain during the write operation and the magnetization of the fixed and free layers and the magnetic layers of the laminates have perpendicular anisotropy.

The instant invention provides for novel cationic lipids that can be used in combination with other lipid components such as cholesterol and PEG-lipids to form lipid nanoparticles with oligonucleotides. It is an object of the instant invention to provide a cationic lipid scaffold that demonstrates enhanced efficacy along with lower liver toxicity as a result of lower lipid levels in the liver. The present invention employs low molecular weight cationic lipids with one short lipid chain to enhance the efficiency and tolerability of in vivo delivery of siRNA.

A method of creating a semiconductor device is disclosed. An end of a carbon nanotube is unzipped to provide a substantially flat surface. A contact of the semiconductor device is formed. The substantially flat surface of the carbon nanotube is coupled to the contact to create the semiconductor device. An energy gap in the unzipped end of the carbon nanotube may be less than an energy gap in a region of the carbon nanotube outside of the unzipped end region.

The method for detection of cyanide in water is a method for the detection of a highly toxic pollutant, cyanide, in water using ZnO2 nanoparticles synthesized locally by an elegant Pulsed Laser Ablation technique. ZnO2 nanoparticles having a median size of 4 nm are synthesized from pure zinc metal target under UV laser irradiation in a 1-10% H2O2 environment in deionized water. The synthesized ZnO2 nanoparticles are suspended in dimethyl formamide in the presence of Nafion, and then ultrasonicated to create a homogenous suspension, which is used to prepare a thin film of ZnO2 nanoparticles on a metal electrode. The electrode is used for cyanide detection.

Disclosed are a biomolecular sensor and a method of fabricating the same having high sensitivity and resolution by using a plurality of metal plates that change electrical properties of a plurality of nanostructures according to the attachment of biomolecules. The biomolecular sensor includes a substrate, first and second electrodes disposed to be spaced apart from each other on the substrate, a plurality of nanostructures disposed on the substrate to connect the first and second electrodes to each other, and a plurality of metal plates that change electrical properties of the plurality of nanostructures according to the attachment of biomolecules.

Device for forming, on a nanowire made of a semiconductor, an alloy of this semiconductor with a metal or metalloid by bringing this nanowire into contact with electrically conductive metal or metalloid probes and Joule heating the nanowire at the points of contact with the probes so as to form an alloy such as a silicide. Application to the production of controlled-channel-length metal-silicide transistors.

A process for the production of nanocrystals or amorphous nanoparticles of actives (nanomaterials), especially from the peels of grapes. A dispersion of a micrometer-sized material in a solution of surfactant or a steric stabilizer is first provided. The macrosuspension is then stirred for at least 1 minute at a rotational speed above 500 rpm using a rotor-stator mixer. The stirred mixture is passed through a jet stream or piston-gas type high pressure homogenizer. The nanomaterials produced can be incorporated into formulations for use as nutraceutical, nutritional supplement, or as supportive treatment in medical therapy. The active can be derived from the peels of grapes.

An aqueous epoxy resin system AB is described comprising an aqueously dispersed epoxy resin A having, on the average, at least one epoxy group per molecule, and a water-soluble or water-dispersible curing agent B which comprises the reaction product of an amine B1 having at least one primary and/or at least one secondary amino group, an adduct B2 of a polyalkylene ether polyol B21 and an epoxide component B22, and an aromatic compound B3 having at least one acidic group selected from the group consisting of hydroxyl and carboxyl groups, which system can be applied by rolling, spraying or brushing to provide corrosion protection on base metals.

A molding composition formulation includes a thermoset cross-linkable 12 to 45 micron polymeric resin. Hollow glass microspheroids are present from 2 to 12 total weight percent. An article formed from such a composition is further strengthened by the addition of a surface activating agent bonded to the surface of the glass microspheroids. Conventional particulate fillers when added to an inventive formulation provide enhanced performance when the filler particle has a size sufficiently small to insert within adjacent microspheroid interstitial voids. An unsaturated polyester resin so formed is particularly well suited for the formation of sheet molding compound formulations.

The present invention relates to a process for the production of a ready-to-use epoxy composition having a filler content of at least 55 vol.-%, relative to the complete ready-to-use epoxy composition, which comprises: providing a liquid A, which comprises at least one epoxy resin,providing a liquid B, which comprises at least one curing agent,providing a solid component C, which comprises at least one filler,wherein in a first step one of the liquids A or B is filled in a mixing container,in a second step the solid component C is deposited on top of the liquid in the mixing container,in a third step the remaining liquid A or B is deposited on top of the solid component C, andin a fourth step the components are mixed to obtain the ready-to-use epoxy composition.

A composite material and method of making and using the same is described. In particular a dental (and preferably photocurable) composite material, and the use of a composite material according to the invention as a dental material and a method for preparation of a composite material according to the invention. Also disclosed are novel radically polymerizable monomers comprising at least one polyalicyclic structure element and certain ethylenic structure elements, which are particularly suitable for use in a composite material according to the invention.

Provided are an adhesive composition with good storage stability, heat resistance, moisture resistance reliability, and adhesion properties; and a curl- and heat-resistant adhesive film and a wiring film using the adhesive composition. The adhesive composition contains 100 parts by weight of a phenoxy resin (A) having plural alcoholic hydroxyl groups in a side chain of the molecule thereof; 2 to 60 parts by weight of a polyfunctional isocyanate compound (B) having an isocyanate group and at least one functional group selected from vinyl, acrylate, and methacrylate groups in the molecule thereof; and 5 to 30 parts by weight of a maleimide compound (C) having plural maleimide groups in the molecule thereof or/and reaction product thereof, in which a total amount of the components (B) and (C) is from 7 to 60 parts by weight.

Provided is a thermosetting resin composition including an inorganic filler and a thermosetting resin matrix component, in which the inorganic filler includes secondary sintered particles each formed of primary particles of scaly boron nitride, and at least some of the secondary sintered particles each have a maximum cavity diameter of 5 μm to 80 μm. The thermosetting resin composition can be used for providing a heat conductive sheet in which electrical insulation property is kept by controlling where the defects such as voids and cracks occur and their size, and which has excellent heat conductivity.

Hydroswellable, absorbable and non-absorbable, aliphatic, segmented polyurethanes and polyurethane-urea capable of swelling in the biological environment with associated increase in volume of at least 3 percent have more than one type of segments, including those derived from polyethylene glycol and the molecular chains are structurally tailored to allow the use of corresponding formulations and medical devices as carriers for bioactive agents, rheological modifiers of cyanoacrylate-based tissue adhesives, as protective devices for repairing defective or diseased components of articulating joints and their cartilage, and scaffolds for cartilage tissue engineering.

Provided are a thermosetting adhesive composition excellent in storage stability, reliability, and low-temperature adhesion properties; and a curl-resistant heat-resistant film and a wiring film obtained using the composition. The thermosetting adhesive composition includes 100 parts by weight of a phenoxy resin having a bisphenol S skeleton in the structure thereof; 5 to 30 parts by weight of a maleimide compound containing a plurality of maleimide groups in the structure thereof; and 3 to 20 vol % of an inorganic needle-like filler. The heat resistant adhesive film is obtained by applying the thermosetting adhesive composition onto a polyimide film, followed by drying. The wiring film is obtained by placing a conductor wiring layer on the heat resistant adhesive film.

Aqueous copolymer dispersions for a variety of uses, including coating compositions or binders for plasters and paints, are disclosed. The aqueous copolymer dispersions may comprise one or more silicon containing compounds, in particular hydrolyzable silane compounds without any additional reactive group.

A method, system and computer program product for intelligently responding to hardware failures so as to optimize system performance. An administrative server monitors the utilization of the hardware as well as the software components running on the hardware to assess a context of the software components running on the hardware. Upon detecting a hardware failure, the administrative server analyzes the hardware failure to determine the type of hardware failure and analyzes the properties of the workload running on the failed hardware. The administrative server then responds to the detected hardware failure based on various factors, including the type of the hardware failure, the properties of the workload running on the failed hardware and the context of the software running on the failed hardware. In this manner, by taking into consideration such factors in responding to the detected hardware failure, a more intelligent response is provided that optimizes system performance.

Methods and apparatus for output of high-bandwidth debug data/traces in electronic devices using embedded high-speed debug port(s). Debug data is received from multiple blocks and buffered in a buffer. The buffer's output is operatively coupled to one or more high-speed serial I/O interfaces via muxing logic during debug test operations. The buffered data is encoded as serialized data and sent over the one or more high-speed serial I/O interfaces to a logic device that receives serialized data and de-serializes it to generate parallel debug data that is provided to a debugger. The buffer may be configured as a bandwidth-adapting buffer that facilitates transfer of debug data that is received at a variable combined data rate outbound via the one or more high-speed serial I/O interfaces at a data rate corresponding to the bandwidth of the serial I/O interfaces.

An approach for introspection of a software component and generation of a conditional memory dump, a computing device executing an introspection program with respect to the software component is provided. An introspection system comprises one or more conditions for generating the conditional memory dump based on operations of the software component. In one aspect, a computing device detects, through an introspection program, whether the one or more conditions are satisfied by the software component based on information in an introspection analyzer of the introspection program. In addition, the computing device indicates, through the introspection program, if the one or more conditions are satisfied by the software component. In another aspect, responsive to the indication, the computing device generates the conditional memory dump through the introspection program.

A system, method and computer program product for avoiding a processing flaw in a computer processor triggered by a predetermined sequence of hardware events. The system may include a detecting unit and a power-on reset unit. The detecting unit detects that the predetermined sequence of hardware events is going to occur at the computer processor. The power-on reset unit initializes the computer processor to a state stored in computer memory in response to detecting the sequence of hardware events.

A Test Wrapper and associated Test Access Mechanism (TAM) architecture for facilitating testing of IP blocks integrated on a System on a Chip (SoC). The TAM architecture includes a Test Controller and one or more Test Wrappers that are integrated on the SoC proximate to IP blocks. Test data and commands corresponding to input from an external tester are packaged by the Test Controller and sent to one or more Test Wrappers via an interconnect fabric. The Test Wrappers interface with one or more IP test ports to provide test data, control, and/or stimulus signals to the IP blocks to facilitate circuit-level testing of the IP blocks. Test results for the circuit-level tests are returned to the Test Controller via the fabric. Test Wrappers may be configured to pass through interconnect signals, enabling functional testing of IP blocks to be facilitated via test packages and test results transmitted between the Test Controller and the IP blocks via the fabric. Test wrappers may also be configured to test multiple IP blocks comprising a test partition.

In a wireless communication system, a compact control signaling scheme is provided for signaling the selected retransmission mode and codeword identifier for a codeword retransmission when one of a plurality of codewords being transmitted over two codeword pipes to a receiver fails the transmission and when the base station/transmitter switches from a higher order channel rank to a lower order channel rank, either by including one or more additional signaling bits in the control signal to identify the retransmitted codeword, or by re-using existing control signal information in a way that can be recognized by the subscriber station/receiver to identify the retransmitted codeword. With the compact control signal, the receiver is able to determine which codeword is being retransmitted and to determine the corresponding time-frequency resource allocation for the retransmitted codeword.

Method and apparatus for managing data in a memory. In accordance with some embodiments, a first data object and an associated first ECC data set are generated and stored in a non-volatile (NV) main memory responsive to a first set of data blocks having a selected logical address. A second data object and an associated second ECC data set are generated responsive to receipt of a second set of data blocks having the selected logical address. The second data object and the second ECC data set are subsequently stored in the in the NV main memory responsive to a mismatch between the first ECC data set and the second ECC data set.

Within a radio communication network infrastructure transmitting data organized into a sequence of symbols to a receiving device over a plurality of radio links, data to be transmitted is encoded according to an error correction coding scheme in order to produce a set of systematic symbols and a set of corresponding redundancy symbols; the systematic symbols and a first subset of the corresponding redundancy symbols are transmitted, over a first radio link among said plurality of radio links, in broadcast mode, and a second subset of the corresponding redundancy symbols, distinct from the first one, is transmitted over a second radio link among said plurality of radio links.

Embodiments of the present disclosure describe device, methods, computer-readable media and system configurations for decoding codewords using a side channel. In various embodiments, a memory controller may be configured to determine that m of n die of non-volatile memory (“NVM”) have failed iterative decoding. In various embodiments, the memory controller may be further configured to generate a side channel from n-m non-failed die and the m failed die other than a first failed die. In various embodiments, the memory controller may be further configured to reconstruct, using iterative decoding, a codeword stored on the first failed die of the m failed die based on the generated side channel and on soft input to an attempt to iteratively decode data stored on the first failed die. In various embodiments, the iterative decoding may include low-density parity-check decoding. Other embodiments may be described and/or claimed.

A packet transmission/reception apparatus and method is provided. The packet transmission method of the present invention includes acquiring a source payload including partial source symbols from a source block, generating a source packet including the source payload and an identifier (ID) of the source payload, generating a repair packet including a repair payload corresponding to the source payload and an ID of the repair payload, generating a Forward Error Correction (FEC) packet block including the source and repair packets, and transmitting the FEC packet block. The source payload ID includes a source payload sequence number incrementing by 1 per source packet. The packet transmission/reception method of the present invention is advantageous in improving error correction capability and network resource utilization efficiency.

A wireless communication system including a sender apparatus having a plurality of transmitting antennas that performs MIMO transmission of a plurality of data blocks; and a receiver apparatus that receives the plurality of data blocks. The sender apparatus transmits a process number via a control channel different from a data channel to the receiver apparatus, and wherein when the MIMO diversity transmission is performed, the receiver apparatus performs HARQ processing in the received data blocks based on not a process number which prevents the data blocks from competing but the received process number from the sender apparatus.

The present invention relates to a method for the degradation of pollutants in water and/or soil. More specific, the present invention relates to a method for the on-site decontamination or re-mediation of water and/or soil which are contaminated with organic compounds. Moreover, the invention relates to a method for forming a barrier against the spreading of a contamination with pollutants within the water and/or soil, especially within groundwater (aquifer). Further, the invention relates to means for use in these methods, and to the production of such means.

The invention relates to the treatment of carbonaceous radioactive waste, comprising the delivery of waste to one or more radioactive isotope separation stations isotopes, said isotopes being among at least carbon 14, chlorine 36, and tritium. Advantageously, the delivery to each of the stations occurs in wet form, with water being a common medium for conveying the waste to each of the separation stations.

A method is provided for the decontamination of radioactive carbonaceous material, such as graphite, in which an injection of steam is planned into the material, concurrent with a first roasting thermal treatment of the material at a temperature between 1200° C. and 1500° C. Advantageously, the first treatment may be followed by a second treatment at a lower temperature with an injection of carbon oxide for oxidation according to the Boudouard reaction.

A method of disposing nuclear waste in underground rock formations is presented. The method includes the steps of selecting a land area having a rock formation positioned there-below of a depth able to prevent radioactive material placed therein from reaching the surface and drilling a vertical wellbore from the surface, to a depth ranging between 5,000 feet and 25,000 feet, into the underground rock formation or repository. A plurality of horizontal laterals or horizontal wellbores, ranging in length from 500 feet to 40,000 feet, are drilled from the vertical wellbore into the underground rock formation or repository. Nuclear waste to be stored within these laterals is encapsulated in a special waste canister and these nuclear waste canisters are positioned within the horizontal laterals wherein they are sealed to prevent loss and leakage. Means are also provided by which these canisters are adapted to allow retrievability of the canisters from the wellbore at a later date and to return the waste to the surface for use after retrieval.

Certain exemplary embodiments can provide a system, machine, device, manufacture, circuit, composition, and/or user interface adapted for and/or resulting from, and/or a method and/or machine-readable medium comprising machine-implementable instructions for, activities that can comprise and/or relate to, in a treatment zone, reacting an oxygen-comprising gas, one or more selected ferric/ferrous chelates, one or more selected nitrates and/or nitrites, and/or anaerobic wastewater.

Method of extracting syngas between the zone in a furnace where oxygen-starved combustion of biomass occurs and the zone in the furnace where secondary air is added to complete combustion, conditioning and cleaning the extracted syngas, and delivering it in a metered amount to the oxidizer or upstream of the oxidizer to reduce or eliminate the need for additional fossil fuels once the oxidizer has achieved its operating temperature. The gasifier or furnace burns solid waste and produces a syngas containing relatively high levels of CO, which is extracted from the furnace, conditioned, and introduced into an RTO as a fuel source. In certain embodiments, no extraction of syngas from the furnace takes place; the furnace conditions are manipulated so that normally undesirable levels of CO and other VOC's remain in the process stream. The heat from the furnace is used as intended (e.g., to heat a dryer), the stream is conditioned, and ultimately proceeds to a downstream RTO. Since the gas stream remains rich in CO and VOC's, its fuel value in the RTO is substantially higher than otherwise would be the case.

An environmentally beneficial process for utilizing waste drill cuttings from oil and gas exploration. The waste drill cuttings (20) are used as a filler and combined with plastic to provide a plastic based product (26) in the plastics industry. In an embodiment the cuttings are thermally treated and formed into pellets. In a further embodiment the cuttings are treated and mixed with recycled plastic to be formed into pellets. The pellets are then used in the manufacture of rigid plastic products such as bollards, planters, benches and decking.

An apparatus and method for the granulation of radioactive waste in which a preprocessing method for the vitrification of radioactive waste is simplified to conform to onsite conditions of a nuclear power plant, additives are improved, and pellets suitable for vitrification are manufactured. The apparatus for the granulation of radioactive waste includes: a body frame having an inlet and an outlet; a hopper supplying the radioactive waste to be transferred and fed through the inlet; a feeder transferring/supplying the radioactive waste supplied to a specific position and in a certain quantity; a stirrer pulverizing/mixing lumps of the radioactive waste supplied; an additive supply part supplying a lubricant to the radioactive waste fed into the stirrer; and a pellet press pressing the radioactive waste fed through the feeder into a pellet shape and discharging the pellet through the outlet.

A method for vitrification of waste to reduce the formation of persistent secondary phases comprising separating at least one glass frit constituent from an initial glass frit to form a modified glass frit. The waste, modified glass frit, and the at least one glass frit constituent are mixed together with the modified glass frit and the at least one glass frit constituent being added as separate components. The resulting mixture is vitrified.

The present invention provides an efficient and low cost method for processing radioactively-contaminated water. The method for processing radioactively-contaminated water comprising a freeze concentration step of generating ice having lowered concentration of radioactive substance from radioactive substance containing contaminated water and concentrating the radioactive substances in the residual contaminated water by the interface progressive freeze concentration process. Preferably, the method further comprises a nitrogen substitution step of reducing dissolved oxygen in the contaminated water and adding nitrogen gas to the contaminated water, as a previous step of the freeze concentration step. Preferably, the radioactive substance is radioactive cesium.