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Oxygen vacancy-induced efficient hydrogen spillover in Ni17W3/WO3−x/MoO3−x for a superior pH-universal hydrogen evolution reaction

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00729H, Paper
Open Access
Yiqing Sun, Yiwei Bao, Di Yin, Xiuming Bu, Yuxuan Zhang, Kaihang Yue, Xiaoshuang Qi, Ziyan Cai, Yongqiang Li, Xiulan Hu, Johnny C. Ho, Xianying Wang
By regulating the oxygen vacancy in the WO3−x/MoO3−x support synergistically, the active phase transition can be accomplished at low voltage, resulting in fast intermediate hydrogen uptake/transfer/desorption kinetics on the prepared catalyst surface and interface.
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Heteroatom-doped Graphene for Marvellous Hydrogen Storage: Unveiling Recent Advances and Future Pathways

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00717D, Review Article
Shankar Ghotia, Tripti Rimza, Shiv Singh, Neeraj Dwivedi, Avanish Kumar Srivastava, Pradip Kumar
Hydrogen energy and storage are gaining significant attention due to their potential to address various energy and environmental challenges. Storage of hydrogen in a solid–state media is an area of...
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The balancing act between high electronic and low ionic transport influenced by perovskite grain boundaries

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA04458K, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Nadja Glück, Nathan S. Hill, Marcin Giza, Eline Hutter, Irene Grill, Johannes Schlipf, Udo Bach, Peter Müller-Buschbaum, Achim Hartschuh, Thomas Bein, Tom Savenije, Pablo Docampo
Grain size and orientation's impact on charge carriers is explored via a new solvent engineering method for MAPbI3 solar cells. Drift-diffusion simulations connect s-shaped JV curves to slower ions.
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A bioinspired sulfur-surrounded iron catalyst for ammonia synthesis

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00710G, Paper
Na Zhang, Yubing Si, Qiang Fu, Xing Chen
A nitrogenase-inspired inorganic compound consisting of iron (Fe) and molybdenum disulfide (MoS2) is designed with a promising capability of N2 fixation using first principles.
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A heterostructured WO3–SnO2 nanocomposite for the efficient photocatalytic production of H2O2 under visible light

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01223B, Paper
Diya Xie, Chen Chen, Yaru Wang, Cheng Sun, Yiming Xu, Jianguo Huang
A WO3–SnO2 (WSN) nanocomposite was synthesized with unique heterostructures formed in-between the two phases, resulting in the efficient production of H2O2 under visible light due to the synergistic effect.
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Regulating Pt-Covalent Triazine Frameworks Schottky Junction by Tailor-Made Nitrogen Sites towards Efficient Photocatalysis

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00618F, Paper
Chao Li, Lijiang Guan, Jin Zhang, Cheng Cheng, Zhaoqi Guo, Zhihong Tian, Li-Ming Yang, Shangbin Jin
Covalent triazine frameworks (CTFs) of designable nitrogen-rich structures, which can form Schottky Junction with Pt nanoparticles, have been extensively studied in photocatalysis. However, how to tune the interaction inside the...
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Tuning the ion conductivity of Zr-based metal organic framework ionogels by linker functionalization

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D3TA06986A, Paper
Open Access
Antonija Ferbezar, Roman Zettl, Katharina Hogrefe, Harald Fitzek, Bernhard Gadermaier, Martin Wilkening, Ilie Hanzu
Solid-state ion conductors have improved significantly in the past decade. Envisioned applications range from metal anode batteries and fuel cells to sensors and medical technologies. The choice of solid electrolytes...
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Multifunctional buried interface modification for efficient and stable SnO2-based perovskite solar cells

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00108G, Paper
Rui Wu, Junhua Meng, Yiming Shi, Zhengchang Xia, Chunxia Yan, Lisheng Zhang, Wenkang Liu, Jinliang Zhao, JinXiang Deng, Xing Wang Zhang
Buried interface modification with multiple roles is key to boost the performance of perovskite solar cells (PSCs). Herein, a multifunctional passivator, N-(2-hydroxyethyl) ethylene diamine triacetic acid trisodium salt (HEDTA-3Na), is...
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Efficient photocatalytic hydrogen evolution based on Z-scheme 2D OV-LaVO4/Mo-doped SV-ZnIn2S4 heterojunctions

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00754A, Paper
Wei Guan, Lin Zhang, Peng Wang, Ying Wang, Haoyu Wang, Xingchen Dong, Liyan Yu, Zhixing Gan, Lifeng Dong, Lina Sui
The purposeful design and construction of two-dimensional (2D) semiconductor heterojunctions offers a promising avenue for achieving efficient photocatalytic activity. However, the challenge of enabling efficient charge migration at the interface...
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Oxygen insertion at the cage center: an unconventional tuning strategy for enhancing the photocatalytic performance of atomically precise copper cluster cocatalysts

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D3TA07218E, Paper
Yun-Dong Cao, Di Yin, Ming-Liang Wang, Hong Liu, Yi Feng, Lin-Lin Fan, Cai-Li Lv, Guang-Gang Gao
This work not only confirms the long-standing prediction that the Cu8 center can accommodate an oxygen atom but also demonstrates a novel central atom regulation strategy to obtain highly active copper clusters as photocatalysts.
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Enhancing CO2 gasification-reforming of municipal solid waste with Ni/CeO2 and Ni/ZrO2 catalysts

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA00665H, Paper
Shiyu Zhang, Yibing Peng, Mengna Wu, Qinghai Li, Yanguo Zhang, Hui Zhou
CO2 gasification-reforming facilitates CO2 utilization and yields CO-rich syngas for municipal waste management. Catalysts are essential for enhancing syngas production via catalytic tar reforming.
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Cubic-to-hexagonal Structural Phase Transition in Metal Halide Compounds: A DFT Study

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D3TA06604E, Paper
Iván Ornelas-Cruz, Ramiro M. dos Santos, José E. González, Matheus Paes Lima, Juarez L. F. Da Silva
Phase transitions into photo-inactive structural phases have impacted the use of metal halide perovskites as photovoltaic materials. However, the chemical composition has been found to mitigate this issue. This study...
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Enhanced Hydrogen Production by Assisted Biomass Gasification Using Lithium Manganate as Bifunctional Material

J. Mater. Chem. A, 2024, Accepted Manuscript
DOI: 10.1039/D4TA00224E, Paper
Open Access
Carlos Hernández-Fontes, Nan Wang, Nayeli Gómez-Garduño, Heriberto Pfeiffer
The rising energy demand, among other economic and technological factors, increases the greenhouse gas emissions. Therefore, it is crucial to develop technologies to produce clean energy, such as hydrogen (H2)...
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S-doped TiN supported N, P, S-tridoped TiO2 with hetero-phase junctions for fuel cell startup/shutdown durability

J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA01475H, Paper
Mitsuharu Chisaka, Jubair A. Shamim, Wei-Lun Hsu, Hirofumi Daiguji
A platinum group metal-free S-doped TiN-supported N, P, S-tridoped TiO2 catalyst with anatase/rutile TiO2 hetero-phase junctions is revealed to display a high durability against fuel cell startup/shutdown cycles not to lose its anion dopants.
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Dak Prescott underwent season-ending surgery Wednesday

Cowboys quarterback Dak Prescott underwent successful surgery in New York on Wednesday, Clarence Hill of alldlls.com reports.




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Plasticity tunable artificial synapses based on organic electrochemical transistors with aqueous electrolytes

J. Mater. Chem. C, 2024, Advance Article
DOI: 10.1039/D4TC03569K, Paper
Ruhua Wu, Miao Xie, Yuhua Cheng, Dan Zhao, Liang-Wen Feng, Jianhua Chen, Wei Huang
By regulating ion transporting kinetics and ion diffusion distances in organic mixed ionic–electronic conductor channels, highly tunable short- and long-term plasticity are obtained in vOECTs with aqueous electrolytes.
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Breaking the Trade-off Between ∆EST and Oscillator Strength in Hybrid LR/SR-CT Compounds for Enhanced TADF Performance

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC04549A, Paper
Nikhitha R., Anirban Mondal
Achieving an ideal thermally activated delayed fluorescence (TADF) emitter requires balancing a minimal singlet-triplet energy gap (∆EST) with a considerable oscillator strength (f), which are typically mutually exclusive. By strategically...
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Multimodal anti-counterfeiting inks: modern use of an ancient pigment in synergy with a persistent phosphor

J. Mater. Chem. C, 2024, Accepted Manuscript
DOI: 10.1039/D4TC04228J, Paper
ALESSANDRO LO BIANCO, Francesco Armetta, Vitalii Boiko, Dariusz Hreniak, Maria Luisa Saladino
A multi-level luminescent, transparent and not-permanent inks for anti-counterfeiting systems and security was developed. The inks emit a radiation of different wavelength depending on the radiation used to illuminate them,...
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The Mushroom Color Atlas: An Interactive Web Site Lets You Explore the Incredible Spectrum of Colors Created from Fungi

Enter the Mushroom Color Atlas, and you can discover the “beautiful and subtle colors derived from dyeing with mushrooms.” Featuring 825 colors, each associated with different types of mushrooms, the interactive atlas lets you appreciate the broad spectrum of colors latent in the fungi kingdom. The shades, tints, and hues will surprise you. Julie Beeler, […]




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A cafe in Coimbatore pays an ode to the riding community with a nutritious menu




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Two prison staff placed under suspension in Salem




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Entrepreneurs in Salem undergo training in business and financial excellence




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Ambulance aggregator service under consideration: Ganesh Kumar

Aimed at enhancing emergency response across Kerala




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State Library Council Awards declared, M. Leelavathy wins I.V. Das award for overall contributions




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Preethi Abraham takes charge as Accountant General of Kerala




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Hope SC will hold accountable those who reduced homes to rubble: Mehdi

“I hope that the court will hold accountable those who have committed these crimes, and have reduced homes to rubble.”




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Mamata calls for unity of hills and plains; focuses on development in north Bengal

This is her first official visit to Darjeeling in two years; she did not go to the hills even during the 2024 Lok Sabha election campaigns




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Use fog safety devices to ensure punctuality and safety of trains in winters: SCR GM




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Nirmal Municipality junior assistant in ACB net




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Google.org awards USD 1 mn grant to Karya to boost ai-based economic opportunities for low-income communities




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EU, Belgium, Denmark and Germany envoys visit Adani's Khavda, Mundra businesses, Gautam Adani says It was a privilege




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India among top 10 countries in patents, trademarks, and industrial designs: WIPO 2024 report




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A multifunctional “three-in-one” fluorescent theranostic system for hepatic ischemia–reperfusion injury

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC04962D, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Jihong Liu, Dongni Yin, Wen Zhang, Xin Wang, Tony D. James, Ping Li, Bo Tang
A single-component multifunctional fluorescent theranostic system (MB-Gly) for use during hepatic ischemia-reperfusion injury (HIRI) has been developed.
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Synthesis of highly condensed phospholes by Lewis acid-assisted dehydrogenative Mallory reaction under visible light irradiation

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC05657D, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ikki Kamiyoshi, Yuki Kojima, Shibo Xu, Kosuke Yasui, Yuji Nishii, Koji Hirano
A photo-promoted oxidative cyclization, that is, Mallory reaction of 2,3-diarylbenzophopholes has been developed. With an assistance of Bi(OTf)3 Lewis acid, the reaction proceeds smoothly under visible light irradiation even without...
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Goalpara Sainik school gave countless cadets to country: Assam Guv




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'PM Modi's govt gives highest priority to over 35 mn Indian diaspora', says EAM Jaishankar on website launch for Pravasi Bharatiya Divas




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$19 mn Loss & Damage funding pledged by Sweden at COP29, bringing total pledged funding to $720 mn




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Chandigarh's air quality continues to be worse than Punjab, Haryana




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India's CO2 emissions account 8pc of global total, to rise by 4.6pc in 2024: Report




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UP: Devotees celebrate 'Tulsi Vivah' at Balua Ghat in Prayagraj, marking sacred union of Lord Vishnu, Vrinda




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There will be census in country but not based on caste: Union Minister Shobha Karandlaje




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Union Education Minister Dharmendra Pradhan urges states to support exam reforms for zero-error entrance test




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Union Jal Shakti Minister CR Paatil chairs 13th high-powered review meeting of Brahmaputra Board




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COP29: India, other developing countries demand fair climate finance commitments

India, LMDCs advocate for equitable climate finance at COP29, pushing for transparency, fairness, and flexibility in financial commitments




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France’s bullfighters see red over bill to ban under-16s

Although public opinion favours outlawing bullfighting in France, a bid to ban the practice failed in 2022




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Stachydrine, a pyrrole alkaloid with promising therapeutic potential against metabolic syndrome and associated organ dysfunction

RSC Med. Chem., 2024, 15,3652-3673
DOI: 10.1039/D4MD00425F, Review Article
Semim Akhtar Ahmed, Prasenjit Manna, Jagat Chandra Borah
Metabolic syndrome is a multifaceted condition marked by interconnected risk factors, significantly increasing the risk of serious diseases like cardiovascular disease, type 2 diabetes, and stroke.
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Tamil Nadu CM Stalin to launch Phase II of nutritional intervention programme for malnourished children, mothers

Mothers of over 76,700 babies in the age group of zero to six months, identified as malnourished, would be covered under Phase II of the programme




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IIT-M students develop robot for O.P. Jindal university’s Constitution Museum

It is trained to respond to questions from visitors in Hindi and English, IIT-M professor says




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DUSU election results to be announced on November 21

The counting of votes for both the central panel and college representatives will begin at 8:30 a.m. on November 21 at the DU Conference Centre




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Mangaluru Junction - CSMT Superfast Express to get LHB coaches in March 2025

Train No. 12133 Mumbai CSMT-Mangaluru Junction Superfast Express will get an LHB rake from March 1 while its pairing service, Train No. 12134 Mangaluru Junction-Mumbai CSMT Superfast Express, will get an LHB rake from March 2