tal

Metal silicate nanosheets, methods of making metal silicate nanosheets, and methods of use

Embodiments of the present disclosure relate to the preparation of colloidal dispersions or suspensions of inorganic materials with nano-sized and nano-structured morphologies, preferably the nanosheet form, compositions produced by this method, and the like.




tal

Non-volatile memory structure containing nanodots and continuous metal layer charge traps and method of making thereof

A memory device includes a semiconductor channel, a tunnel dielectric layer located over the semiconductor channel, a first charge trap including a plurality of electrically conductive nanodots located over the tunnel dielectric layer, dielectric separation layer located over the nanodots, a second charge trap including a continuous metal layer located over the separation layer, a blocking dielectric located over the second charge trap, and a control gate located over the blocking dielectric.




tal

Biomolecular sensor with plural metal plates and manufacturing method thereof

Disclosed are a biomolecular sensor and a method of fabricating the same having high sensitivity and resolution by using a plurality of metal plates that change electrical properties of a plurality of nanostructures according to the attachment of biomolecules. The biomolecular sensor includes a substrate, first and second electrodes disposed to be spaced apart from each other on the substrate, a plurality of nanostructures disposed on the substrate to connect the first and second electrodes to each other, and a plurality of metal plates that change electrical properties of the plurality of nanostructures according to the attachment of biomolecules.




tal

Device and method for forming on a nanowire made of a semiconductor an alloy of this semiconductor with a metal or a metalloid

Device for forming, on a nanowire made of a semiconductor, an alloy of this semiconductor with a metal or metalloid by bringing this nanowire into contact with electrically conductive metal or metalloid probes and Joule heating the nanowire at the points of contact with the probes so as to form an alloy such as a silicide. Application to the production of controlled-channel-length metal-silicide transistors.




tal

Methods of preparing metal quantum clusters in molecular confinement

Methods for the synthesis of metal quantum clusters within the framework of a porous gel matrix are described. For example, Ag25(glutathione)18 quantum clusters are synthesized in a cross-linked polyacrylamide gel matrix. The methods can be performed on large-scale and yields monodispersed metal quantum clusters.




tal

Liquid crystal display module

A liquid crystal display module includes a liquid crystal module and a polarizer stacked with each other. The polarizer includes a polarizing layer, a transparent conductive layer and at least two driving-sensing electrodes. The polarizing layer and the transparent conductive layer are stacked with each other. The at least two driving-sensing electrodes are spaced from each other and electrically connected with the transparent conductive layer.




tal

Nanocrystals and amorphous nanoparticles and method for production of the same by a low energy process

A process for the production of nanocrystals or amorphous nanoparticles of actives (nanomaterials), especially from the peels of grapes. A dispersion of a micrometer-sized material in a solution of surfactant or a steric stabilizer is first provided. The macrosuspension is then stirred for at least 1 minute at a rotational speed above 500 rpm using a rotor-stator mixer. The stirred mixture is passed through a jet stream or piston-gas type high pressure homogenizer. The nanomaterials produced can be incorporated into formulations for use as nutraceutical, nutritional supplement, or as supportive treatment in medical therapy. The active can be derived from the peels of grapes.




tal

Dental prosthetics comprising curable acrylate polymer compositions and methods of their use

Disclosed herein are acrylic and methacrylic acid ester-based polymeric materials containing as flexibilizing and brittleness reducing agents 1-60% of C4-C8 polyalkylene or polyalkyldiene compounds, preferably having a molecular weight of 300-2100, and the use of such materials in dentistry and medicine.




tal

Direct-to-metal and exterior durable non-skid coating

A non-skid coating described herein attempts to overcome the deficiencies of the conventional coatings with improved external durability and color retention, a reduced level of VOCs, and direct-to-metal (DTM) adhesion using organo-siloxane chemistry. The non-skid coating has a first component having an amino-functional siloxane resin; a second component having a non-aromatic epoxy resin; a spherical filler for lowering viscosity; a pigment; a coarse aggregate; and a thixotropic agent. The amino-functional siloxane resin can be an amino-functional methyl phenyl polysiloxane, diphenyl polysiloxane or silsesquioxane-based resin. The non-aromatic epoxy resin can be cycloaliphatic or aliphatic. The first component is about 5% to 20% weight of the coating, and the second component is about 80% to 95% weight of the coating.




tal

Method and apparatus for detecting a parity error in a sequence of DQPSK symbols of a digital transmission system

The present disclosure relates to a method for detecting a parity error in a sequence of DQPSK symbols of a digital transmission system, comprising determining a first demodulated symbol r1; determining a second demodulated symbol r2; determining a first parity symbol p1; determining a second parity symbol p2; determining a super-parity symbol q1; and detecting a parity error in the sequence of DQPSK symbols by comparing a combination of the first parity symbol p1 and the second parity symbol p2 against the super-parity symbol q1, wherein a parity between two DQPSK symbols describes a phase difference between the two DQPSK symbols.




tal

Cationically hardenable dental composition, process of production and use thereof

The invention relates to a hardenable dental composition comprising component (A) comprising a cationically hardenable compound, component (B) comprising an initiator being able to initiate the hardening reaction of the cationically hardenable compound, and component (C) comprising a filler, wherein the filler comprises a filler body and a filler surface, the filler surface comprising side groups with polar moieties. The invention also relates to a process of producing the dental composition, to the use of the dental composition as dental impression material and to a method of taking an impression of dental tissue.




tal

Methods of capturing and immobilizing radioactive nuclei with metal fluorite-based inorganic materials

Methods of capturing and immobilizing radioactive nuclei with metal fluorite-based inorganic materials are described. For example, a method of capturing and immobilizing radioactive nuclei includes flowing a gas stream through an exhaust apparatus. The exhaust apparatus includes a metal fluorite-based inorganic material. The gas stream includes a radioactive species. The radioactive species is removed from the gas stream by adsorbing the radioactive species to the metal fluorite-based inorganic material of the exhaust apparatus.




tal

Phase-to-amplitude converter for direct digital synthesizer (DDS) with reduced AND and reconstructed ADD logic arrays

A sine wave generator for a Direct Digital Synthesizer (DDS) converts a digital phase input into a digital sine wave output. Sine values and slopes are stored in read-only memory (ROM) for coarse upper phase bits in a first quadrant. A quadrant folder and phase splitter reflects and inverts values from the first quadrant to generate amplitudes for all four quadrants. Each sine value and slope is stored for a range of lower phase bits. A Delta bit separates upper and lower phase bits. Delta conditionally inverts the lower phase bits, the sine value, and the final polarity. A reduced AND logic array multiplies the slope by the conditionally inverted lower phase bits. A reconstructed ADD logic array then adds the conditionally inverted sine value. The conditionally inverted polarity is added to generate the final sine value. Sine generation logic is streamlined with conditional inversion based on the Delta bit.




tal

System and method for detecting accidental peripheral device disconnection

A detection device for detecting the manner in which a peripheral device is removed from an electronic device is proposed. The detection device can be on the peripheral device or the electronic device and detects whether the peripheral device was removed in a manner that indicates the removal was intentional or unintentional.




tal

Method and apparatus for generating metadata for digital content

A method and an apparatus for generating metadata for digital content are described, which allow to review the generated metadata already in course of ongoing generation of metadata. The metadata generation is split into a plurality of processing tasks, which are allocated to two or more processing nodes. The metadata generated by the two or more processing nodes is gathered and visualized on an output unit.




tal

Liquid crystal compound having fluorovinyl group, liquid crystal composition and liquid crystal display device

A liquid crystal compound having a high stability to heat, light and so forth, a high clearing point, a low minimum temperature of a liquid crystal phase, a small viscosity, a suitable optical anisotropy, a large dielectric anisotropy, a suitable elastic constant and an excellent solubility in other liquid crystal compounds, a liquid crystal composition containing the compound, and a liquid crystal display device including the composition. The compound is represented by formula (1): wherein, for example, R1 is fluorine or alkyl having 1 to 10 carbons; ring A1 and ring A2 are 1,4-phenylene, or 1,4-phenylene in which at least one of hydrogen is replaced by fluorine; Z1, Z2 and Z3 are a single bond; L1 and L2 are hydrogen or fluorine; X1 is fluorine or —CF3; and m is 1, and n is 0.




tal

Cyclohexene-3,6-diyl compound, liquid crystal composition and liquid crystal display device

To provide a compound, when the compound has both a high clearing point and a low crystallization temperature, having a wide temperature range of a liquid crystal phase and also an excellent solubility in other liquid crystal compounds, and further having general physical properties necessary for the compound, namely, stability to heat, light and so forth, a suitable optical anisotropy and a suitable dielectric anisotropy. A compound is represented by formula (1): wherein, for example, Ra and Rb are alkyl having 1 to 10 carbons; A1, A2, A3 and A4 are 1,4-phenylene; Z1, Z2, Z3 and Z4 are a single bond or alkylene having 1 to 4 carbons; and m, n, q and r are independently 0, 1, or 2, and a sum of m, n, q and r is 1, 2, 3 or 4.




tal

Liquid crystal compound having perfluoroalkyl chain, and liquid crystal composition and liquid crystal display device

The invention is to provide a new liquid crystal compound having a high clearing point, a good compatibility with other compounds, a small viscosity, and a high stability to heat, light and so forth; compound (1) is provided: R1CF2nR2 (1) wherein, for example, R1 is alkyl having 4 to 10 carbons or —(CH2)2—CH═CH2, R2 is alkyl having 2 to 10 carbons, n is 8, and R1 and R2 are not allowed to be straight-chain alkyl having an identical number of carbons.




tal

Compounds for a liquid-crystalline medium, and the use thereof for high-frequency components

The present invention relates to 1,4-diethynylbenzene derivatives having substituents in the 2,3-position (cf. formula I, Claims), to the use thereof for high-frequency components, to liquid-crystalline media comprising the compounds, and to high-frequency components, in particular antennae, especially for the gigahertz range, comprising these media. The liquid-crystalline media serve, for example, for the phase shifting of microwaves for tuneable ‘phased-array’ antennae.




tal

Use of copper-nickel catalysts for dehlogenation of chlorofluorocompounds

The disclosure describes a process for dehalogenation of chlorofluorocompounds. The process comprises contacting a saturated chlorofluorocompound with hydrogen in the presence of a catalyst at a temperature sufficient to remove chlorine and/or fluorine substituents to produce a fluorine containing terminal olefin.




tal

Catalytic gas phase fluorination of 1,1,2-trichloroethane and/or 1,2-dichloroethene to produce 1-chloro-2,2-difluoroethane

The invention is directed to a catalyst for the gas phase fluorination of 1,1,2-trichloroethane and/or 1,2-dichloroethene with HF to give 1-chloro-2,2-difluoroethane which catalyst is prepared by co-depositing FeCl3 and MgCl2 on chromia-alumina, or co-depositing Cr(NO3)3 and Ni(NO3)2 on active carbon, or by doping alumina with ZnCl2, and to a process for the preparation of 1-chloro-2,2-difluoroethane comprising a catalytic gas phase fluorination of 1,1,2-trichloroethane and/or 1,2-dichloroethene wherein one of the catalysts according to claim 2 or 3 is used.




tal

Catalytic dehydrochlorination of hydrochlorofluorocarbons

A dehydrochlorination process is disclosed. The process involves contacting RfCFClCH2X with a catalyst in a reaction zone to produce a product mixture comprising RfCF═CHX, wherein said catalyst comprises MY supported on carbon, and wherein Rf is a perfluorinated alkyl group, X ═H, F, Cl, Br or I, M=K, Na or Cs, and Y═F, Cl or Br.




tal

Preparation of fluorinated olefins via catalytic dehydrohalogenation of halogenated hydrocarbons

A process for making a fluorinated olefin having the step of dehydrochlorinating a hydrochlorofluorocarbon having at least one hydrogen atom and at least one chlorine atom on adjacent carbon atoms, preferably carried out in the presence of a catalyst selected from the group consisting of (i) one or more metal halides, (ii) one or more halogenated metal oxides, (iii) one or more zero-valent metals/metal alloys, (iv) a combination of two or more of the foregoing.




tal

Compositions comprising supercritical carbon dioxide and metallic compounds

Methods of increasing the solubility of a base in supercritical carbon dioxide include forming a complex of a Lewis acid and the base, and dissolving the complex in supercritical carbon dioxide. The Lewis acid is soluble in supercritical carbon dioxide, and the base is substantially insoluble in supercritical carbon dioxide. Methods for increasing the solubility of water in supercritical carbon dioxide include dissolving an acid or a base in supercritical carbon dioxide to form a solution and dissolving water in the solution. The acid or the base is formulated to interact with water to solubilize the water in the supercritical carbon dioxide. Some compositions include supercritical carbon dioxide, a hydrolysable metallic compound, and at least one of an acid and a base. Some compositions include an alkoxide and at least one of an acid and a base.




tal

Highly dispersed metal catalysts

The present invention relates to a novel method for preparing a new type of catalyst for the oxidation of CO in a reactant gas or air. The method provides the preparation of a catalyst having nano-sized metal particles and a capping agent deposited on a solid support. The size and distribution of the metal particles can be easily controlled by adjusting reaction condition and the capping agent used. The catalyst prepared has high activity at low temperature toward selective oxidation of CO and is stable over an extended period of time. The catalyst can be used in air filter devices, hydrogen purification processes, automotive emission control devices (decomposition of NOx, x is the integer 1 or 2), F-T synthesis, preparation of fuel-cell electrode, photocatalysis and sensors.




tal

Metal nanoparticle dispersion usable for ejection in the form of fine droplets to be applied in the layered shape

According to the present invention, a metal nanoparticle dispersion suitable to multiple layered coating by jetting in the form of fine droplets is prepared by dispersing metal nanoparticles having an average particle size of 1 to 100 nm in a dispersion solvent having a boiling point of 80° C. or higher in such a manner that the volume percentage of the dispersion solvent is selected in the range of 55 to 80% by volume and the fluid viscosity (20° C.) of the dispersion is chosen in the range of 2 mPa·s to 30 mPa·s, and then when the dispersion is discharged in the form of fine droplets by inkjet method or the like, the dispersion is concentrated by evaporation of the dispersion solvent in the droplets in the course of flight, coming to be a viscous dispersion which can be applicable to multi-layered coating.




tal

Method of synthesizing bulk transition metal carbide, nitride and phosphide catalysts

A method for synthesizing catalyst beads of bulk transmission metal carbides, nitrides and phosphides is provided. The method includes providing an aqueous suspension of transition metal oxide particles in a gel forming base, dropping the suspension into an aqueous solution to form a gel bead matrix, heating the bead to remove the binder, and carburizing, nitriding or phosphiding the bead to form a transition metal carbide, nitride, or phosphide catalyst bead. The method can be tuned for control of porosity, mechanical strength, and dopant content of the beads. The produced catalyst beads are catalytically active, mechanically robust, and suitable for packed-bed reactor applications. The produced catalyst beads are suitable for biomass conversion, petrochemistry, petroleum refining, electrocatalysis, and other applications.




tal

Implementation of multi-tasking on a digital signal processor with a hardware stack

The disclosure relates to the implementation of multi-tasking on a digital signal processor. Blocking functions are arranged such that they do not make use of a processor's hardware stack. Respective function calls are replaced with a piece of inline assembly code, which instead performs a branch to the correct routine for carrying out said function. If a blocking condition of the blocking function is encountered, a task switch can be done to resume another task. Whilst the hardware stack is not used when a task switch might have to occur, mixed-up contents of the hardware stack among function calls performed by different tasks are avoided.




tal

Dynamic energy savings for digital signal processor modules using plural energy savings states

In an example embodiment, there is described herein an apparatus comprising an interface for communicating with a plurality of digital signal processors and logic operable to send and receive data via the interface. The logic is configured to determine a first set of digital signal processors to be maintained in a ready state, a second set of digital signal processors to be maintained in a first energy saving state, and a third set of digital signal processors to be maintained in a second energy saving state.




tal

Firmware update method and apparatus of set-top box for digital broadcast system

A firmware update method and apparatus of a set-top box for a digital broadcast system is provided. A firmware update method of a set-top box for a digital broadcast system includes determining whether a newly received Code Version Table (CVT) following a public CVT which has been previously received and stored is the public CVT or a filtering CVT; and updating, when the newly received CVG is the filtering CVT, the firmware of the set-top box with a filtering firmware indicated by the filtering CVT.




tal

Process for isolating crystallized 2,2,4,4 tetramethyl-1,3-cyclobutanediol (TMCD) particles utilizing pressure filtration

A method for isolating 2,2,4,4-tetramethyl-1,3-cyclobutanediol (TMCD) solids from an isolated feed slurry formed in a TMCD process comprising TMCD, a liquid phase, and impurities by (a) treating the isolated feed slurry in a product isolation zone to produce an isolated TMCD product wet cake, a mother liquor, and impurities; wherein the product isolation zone can comprise at least one rotary pressure drum filter.




tal

Hydrogenation catalysts with acidic sites

The present invention relates to catalysts and to chemical processes employing such catalysts. The catalysts are preferably used for converting acetic acid to ethanol. The catalyst comprises acidic sites and two or more metals. The catalyst has acidic sites on the surface and the balance favors Lewis acid sites.




tal

Process for making ethanol from acetic acid using acidic catalysts

A process for selective formation of ethanol from acetic acid by hydrogenating acetic acid in the presence of a catalyst comprises a first metal on an acidic support. The acidic support may comprise an acidic support material or may comprise an support having an acidic support modifier. The catalyst may be used alone to produced ethanol via hydrogenation or in combination with another catalyst. In addition, the crude ethanol product is separated to obtain ethanol.




tal

Hydrogenation catalysts comprising a mixed oxide comprising nickel

A process is disclosed for producing ethanol comprising contacting acetic acid and hydrogen in a reactor in the presence of a catalyst comprising a binder and a mixed oxide comprising nickel and tin.




tal

Catalysts and processes for producing butanol

A catalyst composition for converting ethanol to higher alcohols, such as butanol, is disclosed. The catalyst composition comprises at least one alkali metal, at least a second metal and a support. The second metal is selected from the group consisting of palladium, platinum, copper, nickel, and cobalt. The support is selected from the group consisting of Al2O3, ZrO2, MgO, TiO2, zeolite, ZnO, and a mixture thereof.




tal

Method for producing phenylphosphonic acid metal salt composition, and crystal nucleating agent therefrom

A method for producing a phenylphosphonic acid metal salt composition, including reacting a phenylphosphonic acid compound (a) with a metal salt, metal oxide or metal hydroxide (b) that is present in an amount beyond the equivalent, the phenylphosphonic acid metal salt composition containing phenylphosphonic acid metal salt, and a surplus amount of the metal salt, the metal oxide or the surplus metal hydroxide (b). A crystal nucleating agent comprises the phenylphosphonic acid metal salt composition produced by the method.




tal

Optical resolution methods for bicyclic compounds using asymmetric catalysts

An optically active bicyclic compound is efficiently produced by optical resolution using an optically active amine.




tal

Data mining in a digital map database to identify blind intersections along roads and enabling precautionary actions in a vehicle

Disclosed is a feature for a vehicle that enables taking precautionary actions in response to conditions on the road network around or ahead of the vehicle, in particular, a blind intersection along a section of road. A database that represents the road network is used to determine locations where a blind intersection is located along a section of road. Then, precautionary action data is added to the database to indicate a location at which a precautionary action is to be taken about the blind intersection located along the section of road. A precautionary action system installed in a vehicle uses this database, or a database derived therefrom, in combination with a positioning system to determine when the vehicle is at a location that corresponds to the location of a precautionary action. When the vehicle is at such a location, a precautionary action is taken by a vehicle system as the vehicle is approaching a blind intersection.




tal

Digital circuit verification monitor

A method, a system and a computer readable medium for providing information relating to a verification of a digital circuit. The verification may be formal verification and comprise formally verifying that a plurality of formal properties is valid for a representation of the digital circuit. The method comprises replacing at least a first input value relating to the representation of the digital circuit by a first free variable, determining if at least one of the plurality of formal properties is valid or invalid after replacing the first input value by the first variable and indicating if the at least one of the plurality of formal property is valid or invalid. The use of a free or open variable that has not determined value can be directly in the description or representation of the digital circuit. It is not necessary to insert errors or to apply an error model.




tal

System and method for automated simulator assertion synthesis and digital equivalence checking

A system, method, and computer program product for automatically generating equivalent assertions in different forms for different verification tools, which may be analog or digital. A user submits a set of logic assertions that, if unclocked, are converted to clocked assertions by generating and skewing clocks to ensure simulator uniformity. A stimulus is generated, perhaps at random, or input. A test bench is either input or synthesized. For each verification tool, the test bench is simulated and simulation results are captured. An assertion status difference engine evaluates result differences between the verification tools, and identifies and outputs differences indicating a significant inconsistency. Errors in verification tool implementation and user assertion coding can be detected. The simulators used may include SPICE and Verilog, or any other simulators that differ in type, simulation algorithm, input format, or vendor implementation.




tal

Crosstalk analysis method

One implementation of the disclosure provides a crosstalk analysis method executed by a computer. The method includes steps of: executing a layout program; executing a crosstalk analysis program; acquiring, by the crosstalk analysis program, a plurality of parameters from a layout result generated by the layout program; estimating a crosstalk value according to the parameters; determining whether the crosstalk value is larger than a predetermined value; providing a layout suggestion table when the crosstalk value is larger than the predetermined value.




tal

Horizontal interconnects crosstalk optimization

A method, an apparatus, and a computer program product for wireless communication are provided. The apparatus generates a plurality of interconnect patterns for a set of longitudinal channels that are occupied by horizontal interconnects. Each interconnect pattern may be different from the other interconnect patterns. Each interconnect pattern may define relative locations for the set of horizontal interconnects and gap channels. Highest crosstalk is determined for each of the interconnect patterns and the interconnect pattern with the minimum highest crosstalk is selected as a preferred pattern. The highest crosstalk may comprise far-end crosstalk or near-end crosstalk and may be calculated for a range of frequencies or for a plurality of frequencies. The crosstalk may be calculated by modeling the interconnects as transmission lines.




tal

Load balancing on hetrogenous processing cluster based on exceeded load imbalance factor threshold determined by total completion time of multiple processing phases

Methods and systems for managing data loads on a cluster of processors that implement an iterative procedure through parallel processing of data for the procedure are disclosed. One method includes monitoring, for at least one iteration of the procedure, completion times of a plurality of different processing phases that are undergone by each of the processors in a given iteration. The method further includes determining whether a load imbalance factor threshold is exceeded in the given iteration based on the completion times for the given iteration. In addition, the data is repartitioned by reassigning the data to the processors based on predicted dependencies between assigned data units of the data and completion times of a plurality of the processers for at least two of the phases. Further, the parallel processing is implemented on the cluster of processors in accordance with the reassignment.




tal

Solid fast draining/drying rinse aid for high total dissolved solid water conditions

The present invention is a solid rinse aid composition and methods of making and using the same. Applicants have surprisingly found that the crystal modifier sodium xylene sulfonate (short chain alkyl benzene or alkyl naphthalene sulfonates) at higher percentage can act as a solidification agent. The solid rinse aid composition generally includes an short chain alkyl benzene or alkyl naphthalene sulfonates solidification agent and an effective amount of a surfactant which can include a sheeting agent component, defoamer component and/or association disruption agent. The solid rinse aid composition may be phosphate-free, aminocarboxylate-free, and GRAS if desired.




tal

Metal conservation with stripper solutions containing resorcinol

Resist stripping agents useful for fabricating circuits and/or forming electrodes on semiconductor devices for semiconductor integrated circuits and/or liquid crystals with reduced metal and metal alloy etch rates (particularly copper etch rates and TiW etch rates), are provided with methods for their use. The preferred stripping agents contain low concentrations of resorcinol or a resorcinol derivative, with or without an added copper salt, and with or without an added amine to improve solubility of the copper salt. Further provided are integrated circuit devices and electronic interconnect structures prepared according to these methods.




tal

Email administration for rendering email on a digital audio player

Methods, systems, and computer program products are provided for email administration for rendering email on a digital audio player. Embodiments include retrieving an email message; extracting text from the email message; creating a media file; and storing the extracted text of the email message as metadata associated with the media file. Embodiments may also include storing the media file on a digital audio player and displaying the metadata describing the media file, the metadata containing the extracted text of the email message.




tal

Controlling the rendering of supplemental content related to electronic books

Architectures and techniques are provided to control the rendering of supplemental content associated with electronic books. For example, electronic books may be associated with content that is in addition to the content originally provided to an individual acquiring the electronic book, such as annotations, social networking site information, media outlet information, and the like. Individuals may control the supplemental electronic book content that is rendered via their client devices via actuation of a physical input device or a representation of an input device shown via a touch sensitive display. The amount of supplemental content that is rendered may correspond to information associated with a specified number of categories of supplemental electronic book content based on a supplemental content rendering level. In other implementations, the amount of supplemental electronic book content that is rendered may correspond to an amount of supplemental content to be rendered for each category of supplemental content.




tal

Catalytic system for CO2/epoxide copolymerization

The present invention related to a method of manufacturing a polycarbonate including the process of copolymerizing epoxide compound and CO2 using cobalt(III) or chromium(III), where the ligands contains at least 3 ammonium cations, central metal has formal −1 charge, and conjugated anions of the two cationic ammonium groups are acid-base homoconjugation, as catalyst. According to the present invention, the initial induction time can be reduced when the said polycarbonate is manufactured and it is possible to improve the activity of the catalyst and the molecular weight of the obtained polymer.




tal

I-and II-type crystals of L-A-glyceryl phosphoryl choline, and method for preparing same

The present invention relates to I- and II-type crystals of L-α-glyceryl phosphoryl choline, and to a method for preparing same. More particularly, the present invention relates to noble I- and II-type anhydride crystals of L-α-glyceryl phosphoryl choline, which have a higher purity than conventional liquid L-α-glyceryl phosphoryl choline, and one advantage of which is that formulations and dosages of pharmaceuticals are easily modified, and another advantage of which is that the hygroscopicity of the crystals are much lower than that of conventional polymorphic crystals, providing excellent stability during storage. The present invention also relates to a method for preparing the I- and II-type crystals of L-α-glyceryl phosphoryl choline. The I-type crystal of L-α-glyceryl phosphoryl choline is characterized by having an onset temperature of 147° C. and an absorption peak of 150° C. based on differential scanning calorimeter (DSC) analysis, and by having diffraction patterns where 2θ-diffraction angles are 9.8±0.2°, 12.0±0.2°, 14.3±0.2°, 15.8±0.2°, and 19.6±0.2° based on X-ray diffraction (XRD) analysis. The II-type crystal of L-α-glyceryl phosphoryl choline is characterized by having an onset temperature of 62° C. and an absorption peak of 66° C., and an onset temperature of 141° C. and an absorption peak of 145° C. based on DSC analysis, and having diffraction patterns where 2θ-diffraction angles are 10.3±0.2°, 12.2±0.2°, 13.4±0.2°, 14.8±0.2°, and 20.6±0.2° based on XRD analysis.




tal

Method for producing silica-supported catalyst, and method for producing unsaturated carboxylic acid or unsaturated nitrile

A method for producing a silica-supported catalyst comprising Mo, V. Nb, and a component X (Sb and/or Te) to be used in a vapor phase catalytic oxidation or ammoxidation of proprane, comprising the steps of: (I) preparing a raw material mixture solution by mixing Mo, V, Nb, component X, a silica sol, and water;(II) obtaining a dry powder by drying the raw material mixture solution; and(III) obtaining a silica-supported catalyst by calcining the dry powder, wherein the silica sol contains 10 to 270 wt ppm of nitrate ions based on SiO2.