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The role of the stabilizing/leaving group in palladium catalysed cross-coupling reactions

Dalton Trans., 2024, 53,18013-18020
DOI: 10.1039/D4DT02533D, Paper
Open Access
Lorenzo Palio, Francis Bru, Tommaso Ruggiero, Laurens Bourda, Kristof Van Hecke, Catherine Cazin, Steven P. Nolan
Despite the widespread use of well-defined PdII complexes as pre-catalysts for cross-coupling processes, the role of the throw-away ligand is still underexplored.
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Beyond the triple bond: unlocking dinitrogen activation with tailored superbase phosphines

Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02703E, Paper
Vilakkathala U. Krishnapriya, Cherumuttathu H. Suresh
Dinitrogen activation has long been a challenging goal in chemistry. Tailored superbase phosphines offer a promising approach to overcome this challenge by going beyond the traditional triple bond.
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Recent Advances in Syntheses and Emerging Applications of 2D Borophene based Nanomaterials with a Focus on Supercapacitors

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02573C, Frontier
Prashanta Pal, Mahasweta Nandi
Two dimensional (2D) nanosheet of boron i.e. borophene, triggered interest in progressive research as a result of the vast field of opportunities to explore, from its innovative synthetic techniques to...
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Alleviating hypoxia by integrating MnO2 with metal-organic frameworks coated upconversion nanocomposites for enhanced photodynamic therapy in vitro

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02605E, Paper
Junxun Zhou, Mengyue Jiang, Qiangqiang Zhang, Yuan Jiang, Haifang Wang, Lining Sun
Photodynamic therapy (PDT) requires the participation of abundant oxygen while the hypoxic tumor microenvironment limits the efficacy of PDT. Here, upconversion luminescent nanocomposites coated with metal-organic frameworks (MOFs) were synthesized...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Price pooling mantra: Wake up to expensive electricity



  • Siddhartha P Saikia

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Art camp in support of cancer patients in Mysuru soon




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Tension erupts in Mandya over entry of Dalits into temple

Former MLA M. Srinivas took the initiative in leading the entry of Dalits into the temple. However, a small group of persons opposed the move, took away the processional deity and tore down the temple plaque and board.




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B.S. Yediyurappa says he will respond to allegations of corruption after bypolls




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Karnataka Minister Zameer Ahmed Khan kicks up another row with ‘racist’ remark about Union Minister H.D. Kumaraswamy

The Housing Minister is already facing flak for the wakf controversy that has snowballed into a big issue in Karnataka




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Sahitya Sammelana: ₹50 lakh set aside for drinking water supply




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Karnataka’s KSRTC introduces UPI payments for cashless ticketing

As part of this initiative, KSRTC has equipped its buses with advanced Electronic Ticketing Machines, which are designed to accept UPI payments, along with debit and credit cards, making transactions quick and convenien




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Ronaldo panned for promoting supplement

The most scathing criticism came from Dr. Cyriac Abby Phillips, a Indian hepatologist and social media influencer known as 'The Liver Doc' on X.




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Dharavi lights up Diwali with 1 million handcrafted diyas




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Dharavi lights up Diwali with a million handcrafted diyas




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Samson says support from captain Suryakumar, coach Gambhir helped him overcome doubt over his ability after failures

“I received a lot of phone calls from Gautam bhai and Surya, telling me what to work on,” says the Kerala batter, after his century against South Africa




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Deserving finalists Calicut and Forca Kochi to battle it out for Super League Kerala crown

When the two sides met in the league phase, Calicut won a match (1-0) while the other was drawn (1-1)




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Ranji Trophy | Jagadeesan tons up again as TN battles to a draw against Assam

Pradosh chips in with a half-century as the team reaches 217 for two in its second essay; the host clinches three points for its first-innings lead while the visitor gains a point




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Messi and Miami eliminated from MLS Cup playoffs in first round

Inter Miami, led by Lionel Messi, suffers a shocking playoff elimination after a 3-2 defeat to Atlanta United




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Junior men’s hockey World Cup: Tamil Nadu likely to host

The junior men’s hockey world cup will be held in November-December 2025.




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Football king Calicut takes home Super League Kerala crown

The host downs Forca Kochi 2-1 to win the inaugural edition of the tournament much to the delight of the crowd




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McSweeney to open, Inglis also handed maiden Test call up for BGT opener

Nathan McSweeney had emerged as a strong contender for the opener's spot, earning backing from the likes of David Warner and Ricky Ponting




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U Mumba edge past UP Yoddhas in thrilling PKL match, Haryana Steelers beat Gujarat Giants




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Super League Kerala has scored a fine goal on debut

The beautiful game may no longer be a clear winner when it comes to the State’s most popular sports, and it could do with the fillip provided by the league




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Rajangad Bawa — doing everything in his power to make up for lost time

The breakout star of the U-19 World Cup two years ago talks about the attention, the adulation and his struggles with a shoulder tear; the hard road back to the top, NCA’s guidance and looking up to Hardik Pandya




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Enhanced removal efficiency of Tetradesmus obliquus for nevirapine removal via co-substrate supplementation: removal mechanisms, relative gene expression and metabolomics

Environ. Sci.: Water Res. Technol., 2024, Advance Article
DOI: 10.1039/D4EW00576G, Paper
Karen Reddy, Nirmal Renuka, Muneer Ahmad Malla, Brenda Moodley, Faizal Bux, Sheena Kumari
The bioremediation of pharmaceutical wastewater by microalgae has gained scientific attention due to its cost-effectiveness and environmental friendliness.
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Production of birnessite-type manganese oxides by biofilms from oxygen-supplemented biological activated carbon (BAC) filters

Environ. Sci.: Water Res. Technol., 2024, 10,2844-2857
DOI: 10.1039/D4EW00208C, Paper
Amanda Larasati, Olga Bernadet, Gert Jan W. Euverink, H. Pieter J. van Veelen, Maria Cristina Gagliano
The application of a novel enrichment approach revealed the potential of manganese-oxidizing bacteria (MnOB) from full-scale biofilters treating wastewater to produce manganese oxides as crystalline, efficient birnessite catalysts.
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Different routes of bismuth mineral transformation during pertechnetate and perrhenate uptake for subsurface remediation

Environ. Sci.: Water Res. Technol., 2024, 10,2646-2654
DOI: 10.1039/D4EW00496E, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
D. Boglaienko, M. E. Bowden, N. M. Escobedo, Q. M. Collins, A. R. Lawter, T. G. Levitskaia, C. I. Pearce
Removal of pertechnetate 99TcO4 and perrhenate ReO4 during mineral transformation of the non-toxic basic bismuth subnitrate for subsurface remediation.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Applicability of β-lactamase entrapped agarose discs for removal of doripenem antibiotic: reusability and scale-up studies

Environ. Sci.: Water Res. Technol., 2024, Advance Article
DOI: 10.1039/D4EW00572D, Paper
Huma Fatima, Amrik Bhattacharya, Sunil Kumar Khare
Schematic diagram illustrating antibiotic removal via β-lactamase-entrapped agarose discs in a fixed-bed column bioreactor, highlighting the potential for scale-up.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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CNG price may rise ₹4-6 on input supply cuts to gas retailers

City gas retailers are forced to buy imported and costlier liquefied natural gas to make up for the shortfall, which will lead to a hike in CNG prices that varies from ₹4-6/kg




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CK Birla Group to sell Orient Cement to Adani Group at ₹8100 crore equity value

The transaction is subject to regulatory approvals, including approval by Competition Commission of India and mandatory open offer under the relevant SEBI regulations




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Supreme Court to pronounce verdict in Byju’s case on October 23

During back-to-back hearing in the case, the apex court had questioned whether the BCCI could be allowed to strike a “personal agreement” with Byju’s promoter and “walk away” with its money.




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Paytm gets NPCI nod to onboard new UPI users

In a major action against Paytm Payments Bank (PPBL), the RBI had on January 31 directed it to stop accepting deposits or top-ups in any customer accounts, wallets, FASTags and other instruments, as it cited persistent non-compliance and continued material supervisory concerns




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Bvlgari starts digital boutique in India in tie up with Tata CLiQ Luxury

The digital boutique will also house Bvlgari time-pieces including the Serpenti, the Octo Finissimo collection, as well as the Octo Roma.




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Mahindra October auto sales up 20% YoY to 96,648 units; SUV sales up 25%

Including exports, the total SUV sales were 55,571 units. The domestic sales for Commercial Vehicles stood at 28812 units




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Royal Enfield October sales up 31% to 1,10,574 units

The company exported 8,688 motorcycles during the month




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TCS signs multi year deal with Air France-KLM to modernise the airline group’s data

Over the next three years, TCS will modernise the airline group’s data by moving it to cloud, promoting the next generation of data-driven aviation. 




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Fintech Progcap to digitise supply chains of MSMEs to make them part of formal economy




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Vedanta plans to invest $500 million in group firm AvanStrate Inc.

“This investment is aimed at driving innovation and expansion within ASI, strengthening its focus on R&D,” the company said




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Kerala vlogger couple found dead at home in Parassala

The Youtube couple was found dead by their son, who works as a home nursing trainee in Ernakulam.




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Wayanad gears up for byelection preparations




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Water supply disruption in Thiruvananthapuram city




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Water supply to 11 wards in Thiruvananthapuram to be disrupted till 10 a.m. on November 3




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Sufi Qawwali group Warsi Brothers from Rampur to perform in Thiruvananthapuram




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Expo at Huddle Global 2024 to showcase Deep Tech, R&D start-ups

CM to open conclave on Nov. 28. Event a platform for start-ups to present their advanced solutions and engage in interactive demonstrations before major stakeholders from across the world




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Police fail to confirm hacking of IAS officer’s phone in row over religious WhatsApp group

Opposition accuses CM of turning a blind eye to the infiltration of the IAS by fundamentalists




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Livelihood support for 187 extremely poor under Ujjeevanam in capital district

Aid up to ₹50,000 made available to 207 individuals by Kudumbashree district mission




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‘Mallu Hindu’ WhatsApp group row: Kerala government suspends two IAS officials

Officials subjected to punitive action are Industries department Director K. Gopalakrishnan and Special Secretary, Agriculture, N. Prasanth.




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How do you make every rupee count?

How does one remit money overseas without spending a fortune? Parents and students share their experiences




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Which segments will benefit from the uptick in hotels?

The leisure segment is expected to do very well, but choice of the location is important, says Manav Thadani




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How smartly is Bhopal shaping up?

The Bhopal Smart City project has made steady progress: CEO Chandramauli Shukla