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Lewis acid ionic liquid catalysed synthesis of bioderived surfactants from β-pinene

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Polym. Chem., 2024, 15,4327-4338
DOI: 10.1039/D4PY00925H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Philippa L. Jacob, Fabricio Machado, Graham A. Rance, Gary Walker, Vincenzo Taresco, Daniel J. Keddie, Steven M. Howdle
Earth abundant catalysis and more sustainable post-polymerisation functionalisation have been applied in the synthesis of β-pinene derived polymeric surfactants.
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Comment on “Limonene as a renewable unsaturated hydrocarbon solvent for living anionic polymerization of β-myrcene” by A. Dev, A. Rösler and H. Schlaad, Polym. Chem., 2021, 12, 3084

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Polym. Chem., 2024, 15,4364-4365
DOI: 10.1039/D4PY00913D, Comment
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Akhil Dev, Alexander Rösler, Helmut Schlaad
Polymyrcenyllithium chains in DL-limonene solution are present as dimeric associates and not as single chains.
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Functionalization of nano-objects in living anionic polymerization-induced self-assembly and their use for improving thermal properties of epoxy resins

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Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY01008F, Paper
Guicun Guo, Jiali Wu, Jingwei Zhang, Peng Zhou, Ding Shen, Penghan Li, Guowei Wang
Using LAPISA or LAPICA, stabilized PDVB@(PI-b-PS) and PDVB@(PI-b-PS/PS) nano-objects were prepared, functionalized and used as additives for epoxy resin, providing improved Tgs, integrated interfaces, uniform distributions, and scalable applications.
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Increase of spatiotemporal resolution and reproducible layer thicknesses in cationic vat photopolymerization

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Polym. Chem., 2024, Advance Article
DOI: 10.1039/D4PY01046A, Paper
Emile Goldbach, Xavier Allonas, Christian Ley, Lucile Halbardier, Céline Croutxé-Barghorn
Pyridines allow a good control of the cationic photopolymerization of epoxies.
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Bisbenzothieno[b]-fused BODIPYs in panchromatic photoinitiating for the free radical and cationic photopolymerization and application in 3D printing

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Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY00926F, Paper
Yangyang Xu, Wenlong Tang, Hui Deng, Jianjun Zhang, Zhongquan Zhu, Changjiang Yu, Haiguang Zhu, Ke Sun, Jiazhu Li, Jacques Lalevée
Abstract: Polymerization reactions induced by lights occupy an increasing share in the area of polymer synthesis; however, the effective photopolymerization under visible light emitting diodes (LEDs) rather than UV still...
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Protic poly(diallylmethylammonium) poly(ionic liquid)s proton exchange membranes with low fluorine content

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Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01099J, Paper
Yuliana Pairetti, Antonela Gallastegui, Zaneta Wojnarowska, Marian Paluch, Ilaria Aziz, Nerea Casado, Luke Austin O'Dell, Maria Forsyth, David Mecerreyes
Proton exchange membranes (PEM) are s key component in electrolyzers and fuel cells for green hydrogen technologies. One important coming issue in these technologies is the need of reducing the...
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Efficient bionic nanozyme based on AuPt NPs@ZIF-90 used for cyclic catalysis multimodal tumor therapy

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J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01987C, Paper
Wan Huang, Song Zhang, Li Luo, Yalong Pan, Lijun Han, Yao Yu
Novel efficient bionic nanozyme based on AuPt NPs@ZIF-90 used for cyclic catalysis multimodal tumor therapy.
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Tadpole-like cationic single-chain nanoparticles display high cellular uptake

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J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01970A, Paper
Yen Vo, Radhika Raveendran, Cheng Cao, Linqing Tian, Rebecca Y. Lai, Martina H. Stenzel
Single-chain nanoparticles with cationic polymer blocks arranged in a tadpole structure display the highest cellular uptake.
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Lactobionic acid modified cobalt coordination polymer-coated peroxymonosulfate nanoparticles generate sulfate/hydroxy dual-radicals for targeted cancer therapy

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J. Mater. Chem. B, 2024, Advance Article
DOI: 10.1039/D4TB01777C, Paper
Jiahui Li, Jiaxuan Li, Zelong Chen, Yichen Wan, Yi Wang, Zhichao Pei, Yuxin Pei
LCP NPs were prepared by forming a coordination polymer on peroxymonosulfate through the coordination between imidazole-2-carboxaldehyde and Co2+, then modified with lactobionic acid to improve the efficacy of sulfate/hydroxy dual-radical therapy.
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In situ study of the interactions between metal surfaces and cationic surfactant corrosion inhibitors by surface-enhanced Raman spectroscopy coupled with visible spectroscopy

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Analyst, 2024, 149,5372-5380
DOI: 10.1039/D4AN00861H, Paper
Open Access
Felix Frank, Daniela Tomasetig, Peter Nahringbauer, Wolfgang Ipsmiller, Gerd Mauschitz, Karin Wieland, Bernhard Lendl
Coupling Raman and VIS spectroscopy enables the study of AgNP aggregations induced by surfactants.
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Cation effects and charge inversion contribute to the electrostatic stabilisation of protein bioconjugates in neat ionic liquids

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Phys. Chem. Chem. Phys., 2024, 26,27648-27659
DOI: 10.1039/D4CP01811G, Paper
Lokesh Soni, Raj Kumar, Kamendra P. Sharma, Ajay Singh Panwar
Dispersion of protein–polymer surfactant bioconjugates was stabilised by a combination of surface overcharging and steric exclusion of long chain cations in neat aprotic ionic liquid.
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Dynamics of ionic liquids by means of nuclear magnetic resonance relaxation – overview of theoretical approaches

By pubs.rsc.org
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Phys. Chem. Chem. Phys., 2024, 26,27248-27259
DOI: 10.1039/D4CP03183K, Review Article
Danuta Kruk, Elzbieta Masiewicz, Roksana Markiewicz, Rajendra Kumar Singh
Nuclear magnetic resonance relaxometry probes the translational and rotational dynamics of ionic liquids. To take advantage of this unique experimental potential, appropriate theoretical models are needed.
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Insight into physico-chemical properties of oxalatoborate-based ionic liquids through combined experimental-theoretical characterization

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Phys. Chem. Chem. Phys., 2024, Advance Article
DOI: 10.1039/D4CP02296C, Paper
Open Access
Matteo Palluzzi, Giorgia Mannucci, Akiko Tsurumaki, Matteo Busato, Maria Assunta Navarra, Paola D’Angelo
An anion–anion attraction was inferred from the thermal behavior of oxalate-borate ionic liquids and confirmed through computational methods.
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Carboxylative cyclization of atmospheric CO2 with alkynol catalyzed by a 1-methylhydantoin anion-functionalized ionic liquid via chelative interactions

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC03586K, Communication
Yujun Guo, Tingting Chen, Yingjie Xu
[1-MHy]− acts as a “pincer ligand” to form chelative interactions with –OH to enhance MBY activation, thus ensuring efficient [P4442][1-MHy]-catalyzed reaction of atmospheric pressure CO2 with MBY under metal- and solvent-free conditions.
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Exploring the effect of pressure on the crystal structure and caloric properties of the molecular ionic hybrid [(CH3)3NOH]2[CoCl4]

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Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC05125D, Communication
Open Access
Pedro Dafonte-Rodríguez, Ignacio Delgado-Ferreiro, Javier García-Ben, Angel Ferradanes-Martínez, María Gelpi, Julian Walker, Charles James McMonagle, Socorro Castro-García, María Antonia Señarís-Rodríguez, Juan Manuel Bermúdez-García, Manuel Sánchez-Andújar
The hybrid metal halide [(CH3)3NOH]2CoCl4 exhibits a first-order phase transition at T ∼ 343 K.
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Enhancing the performance of ionic conductivity for solid-state electrolytes: an effective strategy of injecting lithium ions within anionic metal–organic frameworks

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Chem. Commun., 2024, 60,13416-13419
DOI: 10.1039/D4CC04515G, Communication
Lu Shi, Xin Wang, Zhiliang Liu
An ionotropic MOF (Li+[Cu-BTC]) with lithium ions in the pores of the lattice was synthesized, which displays outstanding lithium ionic conducting properties over a wide temperature range.
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The structural, electronic and thermodynamic properties of the designed p-benzoquinone based dicationic ionic liquids: insight from DFT–GD3 and QTAIM

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Mol. Syst. Des. Eng., 2024, Advance Article
DOI: 10.1039/D4ME00119B, Paper
Hossein Roohi, Sajedeh Habibipour, Khatereh Ghauri
In this work, physicochemical properties of the dicationic ionic liquids [BTAD][A1–8]2 ([BTAD]2+ = [p-C6O2(N3H2)2]2+ and A1–8 = [CH3CO2]−, [CF3CO2]−, [N(CN)2]−, [CF3SO3]−, [ClO4]−, [BF4]−, [NTf2]− and [PF6]−) were theoretically investigated.
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Effects of Mixed Phases on Ionic Conductivities for (LaF3)1–x(PbF2)x Fast-Fluoride-Ion-Conducting Solid Electrolytes

By pubs.rsc.org
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New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ01063A, Paper
Ming Zhang, Yaowei Hao, Qiaojun Nie, Xiaocao Cao, Jiafan Zheng, Kai Zhang, Jun Zheng, Haodong Wang, Yafang Zhao, Jiayi Liu, Zhiguang Lin, Zhongrong Shen
The research on all-solid-state fluoride-ion batteries (FIBs) with a high theoretical energy density has attracted considerable attention due to their enhanced safety features and superior capacity. The selection of solid...
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Ultrasound-assisted ionic liquid-mediated green method for synthesis of 1,3-diphenylpyrazole-based spirooxindolopyrrolizidines, their anti-tubercular activity, molecular docking study and ADME predictions

By pubs.rsc.org
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New J. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4NJ00563E, Paper
Sravanthi Baddepuri, G. Rama Krishna, Jyothi Kumari, Sriram Dharmarajan, Srinivas Basavoju
The aim of the study is to develop the synthesis of a novel series of potent anti-tubercular (anti-TB) activity of 1,3-diphenylpyrazole-based spirooxindolopyrrolizidine derivatives via an efficient green approach achieved by...
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A zwitterionic salt–cocrystal: in vitro insights from niraparib tosylate, an anti-cancer drug

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00114A, Paper
Ramesh Reddy Mudda, Ramesh Devarapalli, Arijit Das, Pulla Reddy Lakkireddy, C. Malla Reddy, Ramanaiah Chennuru
Schematic representation showing nomenclature of different cocrystals.
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Ionic liquid-functionalized metal organic frameworks and their composite membranes for enhanced proton transport

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CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00186A, Highlight
Jeong Hwa Song, Seyoung Koo, Dong Won Kang
Post-synthetic modification is gaining prominence as a highly effective strategy for enhancing the functionality of porous materials without significant structural changes. Recently, there is growing interest in research focusing on...
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Structural diversity and tetrel bonding significance in lead(II) complexes with pyrazoylisonicotinoylhydrazone and varied anionic co-ligands

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CrystEngComm, 2024, Accepted Manuscript
DOI: 10.1039/D4CE00325J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Ghodrat Mahmoudi, Isabel Garcia-Santos, Roi Fernández-Vázquez, Rosa Maria Gomila, Alfonso Castineiras, Esmail Doustkhah, Ennio Zangrando, Antonio Frontera
Four lead(II) complexes featuring pyrazoylisonicotinoylhydrazone ligand paired with various anionic co-ligands (azido, thiocyanato, nitrito, and nitrato) were synthesized and thoroughly examined using structural, analytical, and spectroscopic techniques. These ligands, in...
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Highly enhanced cationic dye adsorption from water by nitro-functionalized Zn-MOF nano/microparticles and a biomolecular binder for improving the reusability

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00131A, Paper
Gunasekaran Arunkumar, Mehboobali Pannipara, Abdullah G. Al-Sehemi, Savarimuthu Philip Anthony
Zn-MOF with a nitro-functionalized ligand exhibited enhanced cationic dye adsorption, and binder coating improved the reusability.
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Nitro group and K+-based secondary building units for the self-assembly of 3D coordination polymers built on dinuclear dianionic helicate connectors

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CrystEngComm, 2024, Advance Article
DOI: 10.1039/D4CE00255E, Paper
Open Access
Raúl Mendoza-Báez, Alan Molina-Renteria, Juan Olguín
Two dinuclear dianionic helicates, K2[MII2(L)3] M = MnII (1) and NiII (2), based on 2-hydroxy-5-nitrobenzaldehyde, self-assemble into novel 3D coordination polymers due to nitro groups acting as secondary assembly instruction.
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Use of ionic liquids in amidation reactions for proteolysis targeting chimera synthesis

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Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00304G, Paper
Michela Eleuteri, Jenny Desantis, Gabriele Cruciani, Raimondo Germani, Laura Goracci
Selective degradation of disease-causing proteins using proteolysis targeting chimeras (PROTACs) has gained great attention, thanks to its several advantages over traditional therapeutic modalities.
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Sustainable preparation of 2-acylbenzothiazoles under the cooperation of ionic liquids and microwave irradiation

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Org. Biomol. Chem., 2024, Advance Article
DOI: 10.1039/D4OB00315B, Paper
Shoushun Wang, Mengjie Liu, Yiyuan Yue, Xiude Hu, Yalin Zhang, Guodong Shen, Ruiguo Dong, Lilong Shi, Bing Yu, Xianqiang Huang
A series of 2-acylbenzothiazole derivatives were sustainably synthesized for the first time under the cooperation of ionic liquids and microwave irradiation, metal- and extra-additives-free conditions.
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Tailoring the adsorption properties of imidazole-based halogen bonded organic frameworks for anionic dye removal

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Mater. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QM00735B, Research Article
Shumeng Wang, Hongqiang Dong, Guanfei Gong, Siyi Lin, Jiahao Zhao, Zhennan Tian, Ya Lu, Xuguan Bai, Meimei Zhang, Lu Wang, Kang-Da Zhang, Shigui Chen
A novel class of [N⋯I⋯N]+ halogen-bonded XOFs were synthesized using imidazole ligands. XOF-TIB showed strong adsorption capacity and selectivity for anionic dyes, with excellent stability and reusability for environmental remediation.
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Isomer effect study of pyridinium-type cationic fluorophores: multiple functions and internal optical mechanisms

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Mater. Chem. Front., 2024, 8,3790-3798
DOI: 10.1039/D4QM00578C, Research Article
Yasong Cao, Caili Zhang, Zhonghua Zhao, Haowen Huang, Jiatong Xu, Richao Shen, Cheng Zeng, Jiawei Lv, Ziqiang Lei, Hengchang Ma
Reliable, reasonable isomer effect study based on pyridinium-type cationic fluorophores of o-, m-, and p-TPA-Pyr-BP.
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Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics

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Mater. Chem. Front., 2024, 8,3674-3701
DOI: 10.1039/D4QM00454J, Review Article
Karishma Prasad, Vivian Nguyen, Bingheng Ji, Jasmine Quah, Danielle Goodwin, Jian Wang
This review briefly summarizes the chemical flexibility and physical properties of heteroanionic compounds and their potential applications as multiferroics.
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How Mind-Controlled Bionic Arms Fuse To The Body

By www.wired.com
Published On :: Fri, 15 Dec 2023 17:00:00 +0000

A game-changer in prosthetics has been introduced to the world, and for the first time, amputees are regaining sensation through an electrical signal from their prosthetic arm. Max Ortiz-Catalan, a professor of bionics, explains the process of implanting these mind-controlled bionic arms through direct skeletal attachment. The researcher takes us through every step of this groundbreaking advancement in bionic medicine, from surgically implanting electrodes to fitting the prosthesis and training for everyday use. Director: Lisandro Perez-Rey Editor: Jordan Calig Expert: Prof. Max Ortiz Catalan Line Producer: Joseph Buscemi Associate Producer: Kameryn Hamilton Production Manager: D. Eric Martinez Production Coordinator: Fernando Davila Post Production Supervisor: Alexa Deutsch Post Production Coordinator: Ian Bryant Supervising Editor: Doug Larsen Assistant Editor: Justin Symonds


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Microphase-separation-induced polyzwitterionic ionogel with tough, highly conductive, self-healing and shape–memory properties for wearable electrical devices

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J. Mater. Chem. A, 2024, 12,30618-30628
DOI: 10.1039/D4TA04228J, Paper
Guang Zeng, Wenshuo Gao, Weicheng Qiu, Guanling Li, Shousen Chen, Xin He, Guoxing Sun, Weijia Yang, Yue Xin
A polyzwitterionic ionogel with a phase separation structure was designed to achieve a balance between mechanical robustness and ionic conductivity. This design holds immense potential for applications in wearable sensors.
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Electrode–electrolyte interphases in lithium-based rechargeable batteries with ionic liquid electrolytes: recent advances and future perspectives

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J. Mater. Chem. A, 2024, Advance Article
DOI: 10.1039/D4TA06184E, Review Article
Taohong He, Yushan Han, Bofang Shi, Jianan Wang, Honghui Yang
The characteristics of interphase formation between ionic liquid-based electrolytes and various electrodes are reviewed to support the development of improved electrolyte designs for lithium-based batteries.
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Non-toxic ionic liquids for silk processing 

By www.thehindubusinessline.com
Published On :: Mon, 15 Jul 2024 12:59:19 +0530

A team at IASST Guwahati has identified 4 different Ionic Liquids that can be effective in extracting silk proteins from raw fibres 


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Ruhani Sharma: I play a close-to-reality cop in ‘HER’; there is no scope for ‘Singham’ style of histrionics

By www.thehindu.com
Published On :: Tue, 18 Jul 2023 19:06:24 +0530

Ruhani Sharma talks about headlining the Telugu cop drama franchise ‘HER’, says she never imagined herself as a sharpshooter 


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Improved photovoltaic performance and stability of perovskite solar cells by adoption of an n-type zwitterionic cathode interlayer

By pubs.rsc.org
Published On ::

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00253A, Communication
Young Wook Noh, Jung Min Ha, Jung Geon Son, Jongmin Han, Heunjeong Lee, Dae Woo Kim, Min Hun Jee, Woo Gyeong Shin, Shinuk Cho, Jin Young Kim, Myoung Hoon Song, Han Young Woo
Integration of NDI-ZI as a cathode interlayer in perovskite solar cells improves both device efficiency and stability, mitigating halide and Ag ion migration by chemically capturing ions via electrostatic Coulombic interactions.
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Correction: In situ construction of a continuous ionic conductive coating for a high-performance Li3VO4 anode

By pubs.rsc.org
Published On ::

Inorg. Chem. Front., 2024, 11,2187-2187
DOI: 10.1039/D4QI90020K, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Lulu Wang, Cheng Zeng, Jianing Liang, Chun Zhai, Hao Liu, Tianyou Zhai, Huiqiao Li
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Post-synthetic modification of a covalent organic framework via a thiol–ene reaction for improving fluorescence detection and removal of cationic crystal violet carcinogenic dye

By pubs.rsc.org
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Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00419A, Research Article
Ke Li, Bing Yan
Based on a thiol–ene reaction, a covalent organic framework containing olefins (COF-A) is modified with 2-mercaptoacetic acid to prepare COF-S-COOH for the first time, which greatly improves the sensing and adsorption capacity for crystal violet.
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Dozee launches MillionICU initiative for critical care infrastructure

By www.thehindubusinessline.com
Published On :: Thu, 20 May 2021 14:47:15 +0530

Central monitoring cells allow for remote parient monitoring


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Understanding ketone hydrogenation catalysis with anionic iridium(III) complexes: The crucial role of counterion and solvation

By pubs.rsc.org
Published On ::

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC04629C, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Paven Kisten, Sandrine Vincendeau, Eric Manoury, Jason Martin Lynam, John M. Slattery, Simon B Duckett, Agusti Lledos, Rinaldo Poli
The catalytic asymmetric hydrogenation of ketones reflect an important way to prepare valuable chiral alcohols. Understanding how transition metals promote these reactions is key to the rational design of more...
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Cationic Al oxo-hydroxide clusters: syntheses, molecular structures, and functional applications

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Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05707D, Perspective
Open Access
Naoki Ogiwara, Wei Zhou, Sayaka Uchida
Al oxo-hydroxide clusters are formed through the hydrolysis of Al3+-containing solutions, exhibiting a diversity of sizes and shapes. The assembly of these clusters demonstrates functional applications, such as adsorption and heterogeneous catalysis.
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Synthesis of cationic N-acylated thiazolidine for selective activity against Gram-positive bacteria and evaluation of N-acylation's role in membrane-disrupting activity

By pubs.rsc.org
Published On ::

RSC Med. Chem., 2024, Advance Article
DOI: 10.1039/D4MD00626G, Research Article
Aleena Pious, Vignesh Venkatasubramanian, Dharshini Karnan Singaravelu, Subburethinam Ramesh, Fuad Ameen, Anbazhagan Veerappan
Lipidation modulates the Gram-selective antibacterial activity of QPyNATh.
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Nanoconfinement effects on the dynamics of an ionic liquid-based electrolyte probed by multinuclear NMR

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Soft Matter, 2024, 20,8436-8445
DOI: 10.1039/D4SM01058B, Paper
Open Access
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Andrei Filippov, Maiia Rudakova, Victor P. Archipov, Faiz Ullah Shah
Diffusivity is controlled by exchange of ions between “narrow” and “large” pores that results in an abnormal temperature variation. Li+ ions are solvated inside the porous glasses and their diffusivity remains slower as compared to the organic ions.
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Visible-light heterogeneous photocatalysis with an ionic porous organic polymer (IPOP): synthesis of β-keto sulfoxides and benzothiophene diesters by tandem radical addition–oxidation reactions

By pubs.rsc.org
Published On ::

Org. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QO01382D, Research Article
Ajay Kumar Sahoo, Parag Tamuly, Jarugu Narasimha Moorthy
An IPOP, constructed constructed from cyanuric chloride and the readily accessible 2,5-di(pyridin-4-yl)thiazolo[5,4-d]thiazole (BpyTzTz), is shown to exhibit excellent visible light absorption and serve as a metal-free heterogeneous photocatalyst.
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Clues from an ionic cocrystal structure: from catalysis to mechanochemistry

By pubs.rsc.org
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RSC Adv., 2024, 14,34843-34847
DOI: 10.1039/D4RA05652C, Paper
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Bandana Sar, Mollah Rohan Ahsan, Arijit Mukherjee
A crystal structure is no longer conceived as a static entity; rather, it often mirrors crystallization pathways, linking crystal structures with a solution scenario.
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Tailoring dual cross-linked polymer-ionic liquid composites by blending co-crystallizable polymers for stretchable electronics

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RSC Adv., 2024, 14,36022-36030
DOI: 10.1039/D4RA05968A, Paper
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Minjun Kim, Moonsung Park, Hobin Seon, Sohyun Choi, Hee Joong Kim, Sangwon Kim
A dual cross-linked polymer-ionic liquid composite exhibits self-healing capabilities and is ideal for wearable strain sensor applications.
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Chitosan supported ionic liquid, a multifaceted catalyst for streamlined and efficient synthesis of carboxylic, amino acid and carbohydrate esters

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RSC Adv., 2024, 14,36193-36208
DOI: 10.1039/D4RA05725B, Paper
Open Access
Praachi Kakati, Satish Kumar Awasthi
Development of a solid heterogeneous catalyst in the form of an ionic liquid incorporated in chitosan which shows high recyclability. This was used in a solvent free esterification reaction of carboxylic acids, amino acids and carbohydrates.
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Rational fabrication of an anionic zinc carboxylate framework as a fluorescent probe for 2,6-pyridinedicarboxylic acid

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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02529F, Paper
Hui-Hui Xie, Hao Yu, Xiuling Xu, Si-Fu Tang
An anionic zinc carboxylate framework has been fabricated as a fluorescent sensor for the detection of 2,6-pyridinedicarboxylic acid (DPA).
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Ionic-liquid Functionalized Metal-organic Framework and Its High Performance Solid Electrolyte for Lithium-ion Conduction

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Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02756F, Paper
Xiang Kun Cui, Yu Ding, Li Feng, Li Ming Chen, Yang Mei Hu, Hui Chen, Chong-Qing Wan
Herein, we report a new type solid-state electrolyte based on MOF matrix and Li+ ionic liquid. By covalent bonding the Li+ ionic liquids (MIMS·LiTFSI) on the stable UiO-67 framework, the...
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Cationic first-row transition metal saccharinate complexes with tris(2-pyridylmethyl)amine: synthesis, structures and anticancer studies

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Dalton Trans., 2024, Advance Article
DOI: 10.1039/D4DT02258K, Paper
Ceyda Icsel, Seyma Aydinlik, Muhittin Aygun, Veysel T. Yilmaz
Highly cytotoxic dinuclear oxo-bridged Fe(III) saccharinate complex with tris(2-pyridylmethyl)amine induces excessive ROS generation, mitochondrial and DNA damage in HT29 colon cancer cells.
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XRDMatch: a semi-supervised learning framework to efficiently discover room temperature lithium superionic conductors

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Energy Environ. Sci., 2024, Advance Article
DOI: 10.1039/D4EE02970D, Paper
Zheng Wan, Zhenying Chen, Hao Chen, Yizhi Jiang, Jinhuan Zhang, Yidong Wang, Jindong Wang, Hao Sun, Zhongjie Zhu, Jinhui Zhu, Linyi Yang, Wei Ye, Shikun Zhang, Xing Xie, Yue Zhang, Xiaodong Zhuang, Xiao He, Jinrong Yang
We propose XRDMatch, a semi-supervised learning framework that integrates consistency regularization and pseudo-labeling. Using X-ray diffraction patterns as descriptors, it effectively addresses data scarcity by leveraging abundant unlabeled data.
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