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Expandable TFE copolymers, methods of making, and porous, expanded articles thereof

A true tetrafluoroethylene (TFE) copolymer of the fine powder type is provided, wherein the copolymer contains polymerized comonomer units of at least one comonomer other than TFE in concentrations of at least or exceeding 1.0 weight percent, and which can exceed 5.0 weight percent, wherein the copolymer is expandable, that is, the copolymer may be expanded to produce strong, useful, expanded TFE copolymeric articles having a microstructure of nodes interconnected by fibrils. Articles made from the expandable copolymer may include tapes, membranes, films, fibers, and are suitable in a variety of end applications, including medical devices.




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Method for manufacturing ethylene vinyl acetate copolymer sheet for solar cell encapsulant

Provided is a method for manufacturing a sheet for a solar cell encapsulant which has stability against yellowing after a crosslinking process and thus good appearance with improved productivity in the sheet manufacture process, specifically to a method for manufacturing a sheet for a solar cell encapsulant characterized by melt-mixing a resin composition with an organic peroxide, a co-crosslinking agent and a silane coupling agent at the degradation temperature of the organic peroxide or less, wherein the resin composition is obtained by melt-mixing EVA resin with an antioxidant, an UV absorber and a light stabilizer at 80-220° C., and forming a sheet from the obtained melt-mixed resin composition.




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Separation of single-walled carbon nanotubes by electronic type using block copolymers

The separation of single-walled carbon nanotubes (SWNTs), by electronic type using centrifugation of compositions of SWNTs and surface active block copolymers in density gradient media.




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Method of increasing paper surface strength by using acrylic acid/acrylamide copolymer in a size press formulation containing starch

The invention provides methods and compositions for increasing the strengthening effect of a starch coating on paper. The method involves contacting the starch with a synthetic polymer before the starch is cooked. This changes how the starch gelatinizes and how the polymer gets distributed on the paper resulting in greater paper surface strength.




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Copolymer blend compositions for use to increase paper filler content

Disclosed are methods for increasing the filler content of paper or paperboard, comprising (a) combining a heterogeneous polymer blend with a ground calcium carbonate filler; (b) combining the resulting mixture with a pulp slurry; and (c) processing the resulting slurry mixture to form a sheet of paper or paperboard. Also disclosed are methods of increasing the filler content of paper or paperboard comprising (1) combining either a heterogeneous polymer blend or a ground calcium carbonate filler with a pulp slurry, (2) combining the remaining component with the pulp slurry; and (c) processing the resulting pulp slurry mixture to form a sheet of paper or paperboard.




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Production of and drying of copolymer fibers

The present invention concerns processes for reducing water in never-dried fiber comprising copolymer derived from the copolymerization of para-phenylenediamine, 5(6)-amino-2-(p-aminophenyl)benzimidazole; and terephthaloyl dichloride, the process having the following steps in a continuous process, (a) a step of drying a never-dried fiber having at least 0.1% sulfur at less than 150° C. until the moisture content of the fiber is less than 60 weight percent; and (b) a step of further drying the fiber above 150° C. while the moisture content of the fiber is no more than 60 weight percent; and the fiber being further heated to at least 350° C. in either an additional continuous or separate step.




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Three distinct glycosylation pathways are involved in the decoration of Lactococcus lactis cell wall glycopolymers [Microbiology]

Extracytoplasmic sugar decoration of glycopolymer components of the bacterial cell wall contributes to their structural diversity. Typically, the molecular mechanism that underpins such a decoration process involves a three-component glycosylation system (TGS) represented by an undecaprenyl-phosphate (Und-P) sugar-activating glycosyltransferase (Und-P GT), a flippase, and a polytopic glycosyltransferase (PolM GT) dedicated to attaching sugar residues to a specific glycopolymer. Here, using bioinformatic analyses, CRISPR-assisted recombineering, structural analysis of cell wall–associated polysaccharides (CWPS) through MALDI-TOF MS and methylation analysis, we report on three such systems in the bacterium Lactococcus lactis. On the basis of sequence similarities, we first identified three gene pairs, csdAB, csdCD, and csdEF, each encoding an Und-P GT and a PolM GT, as potential TGS component candidates. Our experimental results show that csdAB and csdCD are involved in Glc side-chain addition on the CWPS components rhamnan and polysaccharide pellicle (PSP), respectively, whereas csdEF plays a role in galactosylation of lipoteichoic acid (LTA). We also identified a potential flippase encoded in the L. lactis genome (llnz_02975, cflA) and confirmed that it participates in the glycosylation of the three cell wall glycopolymers rhamnan, PSP, and LTA, thus indicating that its function is shared by the three TGSs. Finally, we observed that glucosylation of both rhamnan and PSP can increase resistance to bacteriophage predation and that LTA galactosylation alters L. lactis resistance to bacteriocin.




copo

Three distinct glycosylation pathways are involved in the decoration of Lactococcus lactis cell wall glycopolymers [Microbiology]

Extracytoplasmic sugar decoration of glycopolymer components of the bacterial cell wall contributes to their structural diversity. Typically, the molecular mechanism that underpins such a decoration process involves a three-component glycosylation system (TGS) represented by an undecaprenyl-phosphate (Und-P) sugar-activating glycosyltransferase (Und-P GT), a flippase, and a polytopic glycosyltransferase (PolM GT) dedicated to attaching sugar residues to a specific glycopolymer. Here, using bioinformatic analyses, CRISPR-assisted recombineering, structural analysis of cell wall–associated polysaccharides (CWPS) through MALDI-TOF MS and methylation analysis, we report on three such systems in the bacterium Lactococcus lactis. On the basis of sequence similarities, we first identified three gene pairs, csdAB, csdCD, and csdEF, each encoding an Und-P GT and a PolM GT, as potential TGS component candidates. Our experimental results show that csdAB and csdCD are involved in Glc side-chain addition on the CWPS components rhamnan and polysaccharide pellicle (PSP), respectively, whereas csdEF plays a role in galactosylation of lipoteichoic acid (LTA). We also identified a potential flippase encoded in the L. lactis genome (llnz_02975, cflA) and confirmed that it participates in the glycosylation of the three cell wall glycopolymers rhamnan, PSP, and LTA, thus indicating that its function is shared by the three TGSs. Finally, we observed that glucosylation of both rhamnan and PSP can increase resistance to bacteriophage predation and that LTA galactosylation alters L. lactis resistance to bacteriocin.




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Digest of researches and criticisms bearing on the revision of the British pharmacopoeia, 1898 : 1899 to 1902 inclusive / prepared for the Pharmacopoeia Committee of the General Council of Medical Education and Registration of the United Kingdom by W. Cha

London : printed for the Council by Spottiswoode, 1903.




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Dr Pereira's elements of materia medica and therapeutics : abridged and adapted for the use of medical and pharmaceutical practitioners and students, and comprising all the medicines of the British pharmacopoeia, with such others as are frequently ord

London : Longmans, Green, 1872.




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Elements of materia medica : containing the chemistry and natural history of drugs, their effects, doses, and adulterations : with observations on all the new remedies recently introduced into practice, and on the preparations of the British Pharmacopoeia

London : J. Churchill, 1864.




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Kotak Coporate Bond Fund- Retail Plan-Growth Option

Category Debt Scheme - Corporate Bond Fund
NAV 2034.9063
Repurchase Price 2034.9063
Sale Price 2034.9063
Date 21-Oct-2016




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ON COMPLETING 20 GLORIOUS YEARS (marcopolo)

To the team of Equitymaster , I became a member in January 2016 and am very impressed by your website and the ideals you stand for. Making profit or loss is a different issue altogether. Taking calculated risks and playing Russian Roulette are two differe..




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Correction: Block copolymer hierarchical structures from the interplay of multiple assembly pathways

Polym. Chem., 2020, 11,2762-2762
DOI: 10.1039/D0PY90057E, Correction
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Alessandro Ianiro, Meng Chi, Marco M. R. M. Hendrix, Ali Vala Koç, E. Deniz Eren, Michael Sztucki, Andrei V. Petukhov, Gijsbertus de With, A. Catarina C. Esteves, Remco Tuinier
The content of this RSS Feed (c) The Royal Society of Chemistry




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A covalently crosslinked silk fibroin hydrogel using enzymatic oxidation and chemoenzymatically synthesized copolypeptide crosslinkers consisting of a GPG tripeptide motif and tyrosine: control of gelation and resilience

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00187B, Paper
Hiromitsu Sogawa, Takuya Katashima, Keiji Numata
A covalently crosslinked silk fibroin hydrogel was successfully formed via an enzymatic crosslinking reaction using copolypeptides, which consist of a glycine–proline–glycine tripeptide motif and tyrosine, as linker molecules.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of acrylamide-based block-copolymer brushes under flow: monitoring real-time growth and surface restructuring upon drying

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00219D, Paper
Open Access
Joydeb Mandal, Andrea Arcifa, Nicholas D. Spencer
Block-copolymer brushes of water-soluble acrylamides have been synthesised by SI-ATRP under continuous flow and their growth monitored in situ by means of a quartz-crystal microbalance with dissipation (QCM-D).
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Highly active bimetallic nickel catalysts for alternating copolymerization of carbon dioxide with epoxides

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00174K, Paper
Yu-Chia Su, Chih-Hsiang Tsui, Chen-Yen Tsai, Bao-Tsan Ko
Catalyst 1 was reported for the first time to be effective for nickel-catalyzed CO2/CHO copolymerization at 1 atm CO2 pressure.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Enhanced thermomechanical property of a self-healing polymer via self-assembly of a reversibly cross-linkable block copolymer

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00310G, Paper
Hyang Moo Lee, Suguna Perumal, Gi Young Kim, Jin Chul Kim, Young-Ryul Kim, Minsoo P. Kim, Hyunhyup Ko, Yecheol Rho, In Woo Cheong
Introduction of a self-healable block copolymer increases the mechanical property whilst maintaining self-healing efficiency.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Smart functionalized phosphonic acid based copolymers: new structures for old purposes

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00337A, Paper
Xavier Solimando, Yohann Catel, Norbert Moszner, Jean-Jacques Robin, Sophie Monge
Innovative well-defined acidic photopolymerizable phosphorus-based copolymers were prepared and tested in well-known dental applications to improve the adhesion of dental self-etch adhesives (SEAs).
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Polymerization of dopamine accompanying its coupling to induce self-assembly of block copolymer and application in drug delivery

Polym. Chem., 2020, 11,2811-2821
DOI: 10.1039/D0PY00085J, Paper
Yudian Qiu, Zongyuan Zhu, Yalei Miao, Panke Zhang, Xu Jia, Zhongyi Liu, Xubo Zhao
The polymerization of dopamine and its coupling occur in succession, which synergistically induces the self-assembly of block copolymer to yield ordered structures, including micelles and vesicles.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Vesicular assemblies of thermoresponsive amphiphilic polypeptide copolymers for guest encapsulation and release

Polym. Chem., 2020, 11,2889-2903
DOI: 10.1039/D0PY00135J, Paper
Mahammad Anas, Somdeb Jana, Tarun K. Mandal
Thermoresponsive amphiphilic polypeptide copolymers are synthesized via different polymerization techniques for their self-assembly into vesicular aggregates for guest encapsulation and release.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Thermally triggerable, anchoring block copolymers for use in aqueous inkjet printing

Polym. Chem., 2020, 11,2869-2882
DOI: 10.1039/D0PY00244E, Paper
George E. Parkes, Helena J. Hutchins-Crawford, Claire Bourdin, Stuart Reynolds, Laura J. Leslie, Matthew J. Derry, Josephine L. Harries, Paul D. Topham
Towards the goal of shifting from toxic organic solvents to aqueous-based formulations in commercial inkjet printing, a series of well-defined amphiphilic block copolymers have been synthesized via RAFT polymerization.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Aromatic thioketone-mediated radical polymerization of methacrylates and the preparation of amphiphilic quasi-block copolymers

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00322K, Paper
Haoyu Yu, Jianwei Shao, Dong Chen, Li Wang, Wantai Yang
TfXT exhibits strong ability to control radical polymerization of methyl methacrylate and has been used in preparing amphiphilic quasi-block copolymer.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Alternating ring-opening copolymerization of epoxides with saturated and unsaturated cyclic anhydrides: reduced viscosity poly(propylene fumarate) oligomers for use in cDLP 3D printing

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00453G, Paper
Yongjun Shin, Matthew L. Becker
A ring-opening copolymerization of propylene oxide with saturated and unsaturated anhydrides using Mg(BHT)2(THF)2 catalyst followed by an isomerization yields poly(propylene fumarate) (PPF) oligomers with improved properties for 3D printing.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Epoxy-functional diblock copolymer spheres, worms and vesicles via polymerization-induced self-assembly in mineral oil

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00380H, Paper
Philip J. Docherty, Chloé Girou, Matthew J. Derry, Steven P. Armes
Epoxy-functional poly(stearyl methacrylate)-poly(glycidyl methacrylate) spheres, worms or vesicles can be prepared by RAFT dispersion polymerization of glycidyl methacrylate in mineral oil at 70 °C.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Rapid production of block copolymer nano-objects via continuous-flow ultrafast RAFT dispersion polymerisation

Polym. Chem., 2020, Advance Article
DOI: 10.1039/D0PY00276C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Sam Parkinson, Stephen T. Knox, Richard A. Bourne, Nicholas J. Warren
Continuous-flow reactors are exploited for conducting ultrafast RAFT dispersion polymerisation for the preparation of diblock copolymer nanoparticles.
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Comprehensive theoretical and experimental study of near infrared absorbing copolymers based on dithienosilole

Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00330A, Paper
Katarzyna Brymora, Wissem Khelifi, Sylvie Blanc, Lionel Hirsch, Antoine Bousquet, Christine Lartigau-Dagron, Frederic Castet
In recent contributions [Eur. Polym. J. 2013, 49, 4176; Macromolecules 2019, 52, 13, 4820], we reported a series of low band gap copolymers with the objective of shifting the absorption...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Room Temperature Synthesis of Block Copolymer Nano-Objects with Different Morphologies via Ultrasound Initiated RAFT Polymerization-Induced Self-Assembly (Sono-RAFT-PISA)

Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00461H, Paper
Jing Wan, Bo Fan, Yiyi Liu, Tina Hsia, Kaiyuan Qin, Tanja Junkers, Boon M. Teo, San Thang
Polymerization-induced self-assembly (PISA), which allows scalable synthesis of nano-objects, has drawn significant research attention in the past decade. However, the initiation methods in most of the current reported PISA are...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Photo-induced copper mediated copolymerization of activated-ester methacrylate polymers and their use as reactive precursors to prepare multi-dentate ligands for the water transfer of inorganic nanoparticles

Polym. Chem., 2020, 11,2969-2985
DOI: 10.1039/D0PY00212G, Paper
Binh T. Mai, Markus J. Barthel, Aidin Lak, Tommaso Avellini, Ana Maria Panaite, Emille M. Rodrigues, Luca Goldoni, Teresa Pellegrino
Polymers bearing activated ester groups are synthesized using photo-ATRP and used as precursors for direct synthesis of multi-phosphonic acid functionalized ligands which are able to transfer different nanoparticles with distinct cores into water.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Development and disassembly of single and multiple acid-cleavable block copolymer nanoassemblies for drug delivery

Polym. Chem., 2020, 11,2934-2954
DOI: 10.1039/D0PY00234H, Review Article
Arman Moini Jazani, Jung Kwon Oh
Acid-degradable block copolymer-based nanoassemblies are promising intracellular candidates for tumor-targeting drug delivery as they exhibit the enhanced release of encapsulated drugs through their dissociation.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of well-defined heteroglycopolymers via combining sequential click reactions and PPM: the effects of linker and heterogeneity on Con A binding

Polym. Chem., 2020, 11,3054-3065
DOI: 10.1039/D0PY00302F, Paper
Meina Liu, Xingyou Wang, Dengyun Miao, Caiyun Wang, Wei Deng
A versatile post- polymerization modification strategy to synthesize well-defined glycopolymers via the combination of RAFT polymerization and sequential CuAAC and thiol–ene click reactions was developed.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Secondary structure drives self-assembly in weakly segregated globular protein–rod block copolymers

Polym. Chem., 2020, 11,3032-3045
DOI: 10.1039/C9PY01680E, Paper
Helen Yao, Kai Sheng, Jialing Sun, Shupeng Yan, Yingqin Hou, Hua Lu, Bradley D. Olsen
Imparting secondary structure to the polymer block can drive self-assembly in globular protein–helix block copolymers, increasing the effective segregation strength between blocks with weak or no repulsion.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Morphological Evolution and Mechanical Properties of "Anchor Chain" Nanodomain Structure of Reactive Amphiphilic Triblock Copolymer in Epoxy Resin

Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00365D, Paper
Quan Zhou, Qi Liu, Yueru Yu, Yuxiao Zhuang, Yizhe Lv, Hanliang Xiao, Ning Song, Lizhong Ni
A novel epoxy-reactive amphiphilic poly(3,4-epoxy cyclohexyl methyl methacrylate)-block-poly(dimethylsiloxane)-block-poly(3,4-epoxy cyclohexylmethyl methacrylate) (PMETHB-b-PDMS-b-PMETHB) triblock polymer was synthesized via atomic transfer radical polymerization (ATRP) with a controlled molecular chain length and low dispersion,...
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Precise Tracking and Modulating Aggregation Structures of Conjugated Copolymers in Solutions

Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00456A, Paper
Zi-Yuan Wang, Ze-Fan Yao, Yang Lu, Li Ding, Zi-Di Yu, Hao-Yang You, Xin-Yi Wang, Yang-Yang Zhou, Lin Zou, Jie-Yu Wang, Jian Pei
The effects of the backbone shape of the conjugated polymers on the aggregation features in solutions, and further on the morphology in solid states are rarely reported. Herein, four copolymers,...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Ring-opening copolymerization of cyclic epoxide and anhydride using a five-coordinate chromium complex with a sterically demanding amino triphenolate ligand

Polym. Chem., 2020, Accepted Manuscript
DOI: 10.1039/D0PY00155D, Paper
Ho Kyun Ryu, Dae Young Bae, Hyeongi Lim, Eunsung Lee, Kyung-sun Son
An alternating ring-opening copolymerization (ROCOP) of epoxides (cyclohexene oxide, limonene oxide) and anhydrides (phthalic anhydride, naphthalic anhydride and maleic anhydride) was performed using a chromium complex containing a sterically demanding...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Diblock Copolypeptoids: A Review of Phase Separation, Self-Assembly and Biological Applications

J. Mater. Chem. B, 2020, Accepted Manuscript
DOI: 10.1039/D0TB00477D, Review Article
Sunting Xuan, Ronald N Zuckermann
Polypeptoids are biocompatible, synthetically accessible, chemically and enzymatically stable, chemically diverse, and structurally controllable. As a bioinspired and biomimetic material, it has attracted considerable attention due to its great potential...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Paediatric pharmacopoeia : pocket prescriber




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Tourism competitiveness in the Italy-France cross-border area : the role of knowledge and innovation transfer / Iacopo Cavallini, Barbara Burchi and Marco Celi

Cavallini, Iacopo, author




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Energy fables: challenging ideas in the energy sector / edited by Jenny Rinkinen, Elizabeth Shove and Jacopo Torriti

Dewey Library - HD9502.A2 E543847 2019




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[ASAP] Modifying the Electrocatalyst–Ionomer Interface via Sulfonated Poly(ionic liquid) Block Copolymers to Enable High-Performance Polymer Electrolyte Fuel Cells

ACS Energy Letters
DOI: 10.1021/acsenergylett.0c00532




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Understanding of copolymers containing pyridine and selenophene simultaneously and their polarity conversion in transistors

Mater. Chem. Front., 2020, Advance Article
DOI: 10.1039/C9QM00739C, Research Article
So-Huei Kang, Myeonggeun Han, Yongjoon Cho, Jisu Hong, Seongmin Heo, Seonghun Jeong, Yong-Young Noh, Changduk Yang
Two n-type pyridine and selenophene-containing polymers were synthesized and the structure–property relationships were investigated, followed by polarity switching from ambipolarity to unipolar characteristics via the doping method.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Fused-ring phenazine building blocks for efficient copolymer donors

Mater. Chem. Front., 2020, 4,1454-1458
DOI: 10.1039/D0QM00080A, Research Article
Wenting Li, Qishi Liu, Ke Jin, Ming Cheng, Feng Hao, Wu-Qiang Wu, Shengjian Liu, Zuo Xiao, Shangfeng Yang, Shengwei Shi, Liming Ding
Phenazine copolymer donors demonstrate an efficiency of 15.14% in nonfullerene organic solar cells.
The content of this RSS Feed (c) The Royal Society of Chemistry




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[ASAP] Polymer Dynamics in Block Copolymer Electrolytes Detected by Neutron Spin Echo

ACS Macro Letters
DOI: 10.1021/acsmacrolett.0c00236




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[ASAP] Stabilizing Phases of Block Copolymers with Gigantic Spheres via Designed Chain Architectures

ACS Macro Letters
DOI: 10.1021/acsmacrolett.0c00193




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Conformation-dependent design of sequences in copolymers [electronic resource] / volume editor, Alexei R. Khokhlov ; with contribution by V.O. Aseyev [and others]

New York : Springer, [2006]




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[ASAP] Tuning the Ambipolar Character of Copolymers with Substituents: A Density Functional Theory Study

The Journal of Physical Chemistry Letters
DOI: 10.1021/acs.jpclett.0c00678




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[ASAP] Wormlike Nanovector with Enhanced Drug Loading Using Blends of Biodegradable Block Copolymers

Biomacromolecules
DOI: 10.1021/acs.biomac.0c00169




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[ASAP] Smart Glycopolymeric Nanoparticles for Multivalent Lectin Binding and Stimuli-Controlled Guest Release

Biomacromolecules
DOI: 10.1021/acs.biomac.0c00292




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[ASAP] A Single Enzyme Mediates the “Quasi-Living” Formation of Multiblock Copolymers with a Broad Biomedical Potential

Biomacromolecules
DOI: 10.1021/acs.biomac.0c00126




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[ASAP] Enzymatic Conversion of Galactose Polymers into Copolymers Containing Galactonic Acid by Glucose Oxidase

Biomacromolecules
DOI: 10.1021/acs.biomac.0c00212