cluster

The „chemical tug-of-war” in carborane clusters: distinct tuning on different sides of the cluster

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI02566K, Research Article
Dalma Gál, Daniel Buzsaki, Balázs Szathmári, Tamas Holczbauer, Antal Udvardy, Júlia Kertész Szilágyiné, Denis Kargin, Clemens Bruhn, Rudolf Pietschnig, Zsolt Kelemen
The special C-C bond in the icosahedral closo-dicarbadodecaboranes and its high plasticity have been highlighted several times, which is reflected in the ease of tuning the C-C bond distance with...
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cluster

Atomically precise Ag25(SR)18 nanoclusters: a stable photosensitizer for photocatalysis

Inorg. Chem. Front., 2024, 11,7991-8002
DOI: 10.1039/D4QI01976H, Research Article
Linjian Zhan, Junyi Zhang, Boyuan Ning, Yunhui He, Guangcan Xiao, Zhixin Chen, Fang-Xing Xiao
Ag25(SR)18 nanocluster is utilized to couple with transition metal chalcogenides for constructing TMC/Ag25(SR)18 heterostructures, which demonstrate boosted photoactivities toward selective organic transformation and heavy metal reduction.
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cluster

A tetranuclear-cluster-based MOF with a low-polarity pore environment for efficient C2H6/C2H4 separation

Inorg. Chem. Front., 2024, 11,7947-7954
DOI: 10.1039/D4QI01685H, Research Article
Meng Feng, Jiantang Li, Xirong Wang, Jingyu Wang, Dongmei Wang, Banglin Chen
Benefitting from reticular chemistry, the newly developed MOF material ZJNU-400 establishes a low-polarity environment that enables reversed ethane adsorption and facilitates the efficient separation of C2H6/C2H4.
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cluster

A long-range synergistic effect between Ptn clusters and Zn1 single atoms for efficient selective hydrogenations

Inorg. Chem. Front., 2024, 11,7822-7830
DOI: 10.1039/D4QI02027H, Research Article
Haisheng Wei, Jing Li, Xiaorui Yan, Tiantian Liu, Kairui Li, Dan Feng, Yujing Ren
Benefiting from the long-range synergistic effect between Ptn clusters and Zn1 single atoms, Ptn@Zn1-N–C displays superior catalytic performance in selective hydrogenations.
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cluster

Deep learning-enabled detection of rare circulating tumor cell clusters in whole blood using label-free, flow cytometry

Lab Chip, 2024, 24,2237-2252
DOI: 10.1039/D3LC00694H, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Nilay Vora, Prashant Shekar, Taras Hanulia, Michael Esmail, Abani Patra, Irene Georgakoudi
We present a deep-learning enabled, label-free flow cytometry platform for identifying circulating tumor cell clusters in whole blood based on the endogenous scattering detected at three wavelengths. The method has potential for in vivo translation.
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cluster

Star Copolymers with Tunable Clusteroluminescence

Polym. Chem., 2024, Accepted Manuscript
DOI: 10.1039/D4PY01198H, Communication
Zixuan Zhou, Xiang Chen, Yang Wang, Ting Li, Xuhui Zhang, Bihua Xia, Shibo Wang, Weifu Dong, Jinliang Qiao
Clusteroluminescence (CL) has recently drawn more attention due to its unique photophysical behaviors that differ from traditional conjugated luminogens. However, the design of red emission from such systems is still...
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cluster

Comparing coupled cluster and composite quantum chemical methods for computing activation energies and reaction enthalpies of radical propagation reactions

Phys. Chem. Chem. Phys., 2024, 26,27536-27543
DOI: 10.1039/D4CP03676J, Paper
Timothy B. Huber, Ralph A. Wheeler
The accuracy of DLPNO-CCSD(T)/CBS and composite methods G3(MP2)-RAD and CBS-RAD is assessed against CCSD(T)/aug-cc-pVTZ for activation energies and reaction enthalpies in hydrocarbon radical addition reactions relevant to free radical polymerization.
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cluster

Machine-learning-accelerated structure prediction of PtSnO nanoclusters under working conditions

Phys. Chem. Chem. Phys., 2024, 26,27624-27632
DOI: 10.1039/D4CP03769C, Paper
Fanke Zeng, Wanglai Cen
Credible property calculations based on the structure prediction of multi-component catalyst clusters under working conditions via a machine-learning-accelerated genetic algorithm and ab initio thermodynamics approach.
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cluster

Hydrogen bond network structures of protonated 2,2,2-trifluoroethanol/ethanol mixed clusters probed by infrared spectroscopy combined with a deep-learning structure sampling approach: the origin of the linear type network preference in protonated fluoroal

Phys. Chem. Chem. Phys., 2024, 26,27751-27762
DOI: 10.1039/D4CP03534H, Paper
Po-Jen Hsu, Atsuya Mizuide, Jer-Lai Kuo, Asuka Fujii
Infrared spectroscopy combined with a deep-learning structure sampling approach reveals the origin of the unusual structure preference in protonated fluorinated alcohol clusters.
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cluster

Effects of surface oxygen vacancy on CO2 adsorption and its activation towards C2H4 using metal (Cu, Pd, CuPd) cluster-loaded TiO2 catalysts: A first principles study

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03507K, Paper
Sajjad Hussain, Lina Zhang, Zhengzheng Xie, Jianjun Yang, Qiuye Li
The conversion of the highly selective CO2 reduction reaction (CO2RR) into desired value-added multicarbon compounds, like C2H4, is crucial, but it is mainly constrained by high energy barrier for C-C...
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cluster

A Comprehensive Guide for Accurate Conformational Energies of Microsolvated Li+ Clusters with Organic Carbonates

Phys. Chem. Chem. Phys., 2024, Accepted Manuscript
DOI: 10.1039/D4CP03487B, Paper
Arseniy A. Otlyotov, Andrey Moshchenkov, Timofey P. Rozov, Anna A. Tuma, Alexander S. Ryzhako, Yury Minenkov
Organic carbonates and their mixtures are frequently used in electrolyte solutions in lithium-ion batteries. Rationalization and tuning of the related Li+ solvation processes are rooted in the proper identification of...
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cluster

Solid-state synthesis of ligand-assisted lead halide nanoclusters

Chem. Commun., 2024, 60,13396-13399
DOI: 10.1039/D4CC04623D, Communication
David C. Zeitz, Kai-Chun Chou, Jin Z. Zhang
A solid-state synthesis of blue-emitting lead halide nanoclusters has been demonstrated for the first time.
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cluster

Rapid and sensitive detection of vanillylmandelic acid based on a luminescent fourteen-metal Tb(III) planar nanocluster

Chem. Commun., 2024, Accepted Manuscript
DOI: 10.1039/D4CC03667K, Communication
Yanheng Meng, Shiqing Wang, Xiaoli Lv, Xianfeng Huang, Wei-Bing Zhang, Xiaojun Wu, Desmond Schipper, Xiaoping Yang
A 14-metal Tb(III) nanocluster with four CO32- anions as templates was constructed for the quantitative and qualitative detection of vanillylmandelic acid (VMA) with high sensitivity and selectivity. The luminescence response...
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cluster

Copper nanoclusters: emerging photoredox catalysts for organic bond formations

Chem. Commun., 2024, Advance Article
DOI: 10.1039/D4CC04774E, Feature Article
Open Access
Arunachalam Sagadevan, Kathiravan Murugesan, Osman M. Bakr, Magnus Rueping
In this feature article, we provide an overview of the photocatalytic capabilities of copper-based nanoclusters for organic bond-forming reactions.
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cluster

Solvent-polarity-controlled assembly of polynuclear titanium-calixarene complexes: constructing isolated {Ti7}, {Ti13}, {Ti24} and {Tb2Ti13} clusters

CrystEngComm, 2024, Advance Article
DOI: 10.1039/D3CE01275A, Paper
Yanyan Wang, Ying Xiong, Wuping Liao
The assembly of polynuclear titanium-calixarene complexes is based on Ti4–C8A SBUs.
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cluster

Multicolor circularly polarized luminescence: pendant primary amine/diphenylalanine chiral copolymers with clustering-triggered emission

Mater. Chem. Front., 2024, 8,3596-3607
DOI: 10.1039/D4QM00228H, Research Article
Ryo Yonenuma, Aoi Takenaka, Tamaki Nakano, Hideharu Mori
Clustering-triggered emission (CTE) materials without π-conjugate chromophores have attracted increasing attention. In this study, we designed CTE-based circularly polarized luminescence (CPL) block and random copolymers, showing multicolor CPL.
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cluster

Intercluster charge ordering in monoclinic and triclinic Ba–Mo-based hollandite phases

Mater. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QM00622D, Research Article
Eslam M. Elbakry, Jared M. Allred
Reproducible synthesis of the three distinct crystal types of Mo-based hollandites. Metal–metal bond orders correlate to electron count per metal.
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cluster

Engineering in situ growth of Au nanoclusters on hydrophilic paper fibres for fluorescence calligraphy-based chemical logic gates and information encryption

Nanoscale Horiz., 2024, 9,2007-2015
DOI: 10.1039/D4NH00307A, Communication
Jun Jiang Luo, Dun Ying Guo, Zi Bo Qu, Hong Qun Luo, Nian Bing Li, Hao Lin Zou, Bang Lin Li
The staining of modified papers with HAuCl4 solutions enables the in situ growth of Au nanoclusters, and the improved fluorescence stability and uniform material distribution facilitate the chemical logic gates and information encryption systems.
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cluster

Cluster-doping in silicon nanocrystals

Nanoscale Horiz., 2024, 9,2042-2050
DOI: 10.1039/D4NH00235K, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Atta ul Haq, Marius Buerkle, Bruno Alessi, Vladimir Svrcek, Paul Maguire, Davide Mariotti
Sn-cluster doping of Si nanocrystals represents a new approach to property tuning, which results in a significant bandgap reduction and an atypical size-dependent behaviour, as confirmed by both experimental and theoretical studies.
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cluster

Clustering around Koppal

Aequs Aerospace to create space for large-scale manufacture of toys at Koppal




cluster

Green-emitting CsPbI3 nanorods decorated with CsPb2I5 and Cs4PbI6 nanoclusters

J. Mater. Chem. C, 2024, 12,17611-17619
DOI: 10.1039/D4TC03500C, Paper
Paundra Rizky Pratama, Azzah Dyah Pramata, Fuko Shiga, Jonas Karl Christopher N. Agutaya, Yusuke Inomata, Biplab Manna, Agung Purniawan, Yuji Akaishi, Tetsuya Kida
This work presents green-emitting CsPbI3 nanorods decorated Cs4PbI6 and CsPb2I5 nanoclusters with a color-tuning approach via multiple-phase combinations without changing elements. These materials have stable emission and color purity.
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cluster

Metal–support interactions in metal oxide-supported atomic, cluster, and nanoparticle catalysis

Chem. Soc. Rev., 2024, 53,10450-10490
DOI: 10.1039/D4CS00527A, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Denis Leybo, Ubong J. Etim, Matteo Monai, Simon R. Bare, Ziyi Zhong, Charlotte Vogt
Metal–support interactions (MSI) impact catalyst activity, stability, and selectivity. This review critically evaluates recent findings, theoretical advances, and MSI tuning strategies, offering new perspectives for future research in the field.
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cluster

Triplet–triplet annihilation-based photon upconversion using nanoparticles and nanoclusters

Mater. Horiz., 2024, Advance Article
DOI: 10.1039/D4MH00117F, Review Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Yoshiki Niihori, Taiga Kosaka, Yuichi Negishi
We introduce the triplet sensitizabilities of semiconductor nanoparticles and metal nanoclusters for triple–triplet annihilation-based photon upconversion. This review aims to explore the potential of new applications for inorganic nanomaterials.
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cluster

Thermo-growing ion clusters enabled healing strengthening and tough adhesion for highly reliable skin electronics

Mater. Horiz., 2024, 11,1923-1933
DOI: 10.1039/D3MH01975F, Communication
Song Chen, Xinyu Chen, Kaiying Luo, Wenwei Yang, Xueling Yan, Lan Liu
A thermo-growing ion cluster-based elastomer was developed to achieve healing strengthening and tough adhesion features.
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cluster

Tech Clusters [electronic journal].

National Bureau of Economic Research




cluster

Stimulating Peer Effects? Evidence from a Research Cluster Policy [electronic journal].




cluster

Geographic Clustering and Resource Reallocation Across Firms in Chinese Industries [electronic journal].




cluster

The Effect of High-Tech Clusters on the Productivity of Top Inventors [electronic journal].

National Bureau of Economic Research




cluster

Economic preferences across generations and family clusters: A large-scale experiment [electronic journal].




cluster

Clustering, Growth, and Inequality in China [electronic journal].




cluster

Combination of dimensional reduction and active site addition strategies for preparing unique {RE9}-cluster-based MOFs: efficient CO2 fixation and Knoevenagel condensation

Inorg. Chem. Front., 2024, 11,2071-2080
DOI: 10.1039/D3QI02527F, Research Article
Ying Zhao, Dan Wu, Yidan Qiao, Guo-Ping Yang, Lu-Fang Ma, Yao-Yu Wang
A series of 2D {RE9}-cluster-based rare-earth MOFs were built by dimensional reduction and active site addition strategies. They exhibit excellent catalytic activity in CO2 fixation and Knoevenagel condensation under mild conditions.
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cluster

Tailoring two magic number Au13 nanoclusters with N-containing diphosphine ligands: a classical icosahedral core vs. an unprecedented UFO- shaped core

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00334A, Research Article
Jing Liu, Jia-Chuan Liu, Hai-Ling Wang, Pei-Yu Liao, Jian-Hua Jia, Ming-Liang Tong
Two magic number Au13 nanoclusters were tailored using two N-containing multidentate phosphine ligands with a classical icosahedral core and an unprecedented “UFO”-shaped polyhedral core, respectively.
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cluster

Controlling the structural and adsorption features of polyoxovanadate-based metal–organic clusters by adjustable template effect

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00254G, Research Article
Yan-Hu Wang, Ke-Wei Tong, Chao-Qin Chen, Jing Du, Guo-Ping Yang, Peng Yang
An adjustable template effect was employed to activate the evolution of polyoxovanadate-based metal–organic clusters, resulting in unprecedented structural archetypes as well as customized dye and iodine adsorption features.
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cluster

Efficient doped and non-doped light-emitting diodes based on a TADF-emitting Cu4Br4 cluster

Inorg. Chem. Front., 2024, Advance Article
DOI: 10.1039/D4QI00210E, Research Article
Xin Lu, Shao-Jie Wu, Ya-Shu Wang, Shan-Yue Wei, Lingyi Meng, Xi-He Huang, Xu-Lin Chen, Can-Zhong Lu
A sublimable Cu4Br4 cluster, chelated by bidentate N^P ligands with a donor–acceptor configuration, realizes highly efficient doped and non-doped cluster light-emitting diodes.
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cluster

N-heterocyclic carbene-stabilized Cu9 clusters with combined thermally activated delayed fluorescence and phosphorescence

Inorg. Chem. Front., 2024, 11,2498-2507
DOI: 10.1039/D4QI00160E, Research Article
Lin-Mei Zhang, Mo Xie, Hui-Zhi Wei, Shang-Fu Yuan, Dong-Sheng Li, Tao Wu
Two NHC-stabilized Cu9 clusters showcase both TADF and direct phosphorescence in thermal equilibrium. The combined harvesting mechanism arises from the simultaneous presence of a small ΔE(S1 − T1) gap and relatively strong spin–orbit coupling.
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cluster

An unprecedented {Y2 ⊂ Y10} type disk-like Y12 nanocluster featuring electroluminescence property in OLED device

Inorg. Chem. Front., 2024, Accepted Manuscript
DOI: 10.1039/D4QI00635F, Research Article
Lin-Ping Shi, Wen-Liang Li, Pu-Yue Wang, Xiaoming Wu, Zhao-Quan Yao, Jiong-Peng Zhao, Fuchen Liu
Although great efforts have been made in exploring the exquisite rare-earth (RE) clusters, the design and construction of planar RE-clusters with disk-like geometrical features are still scarce. Herein, a novel...
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cluster

Substituent effect in determining the total structure of an all-alkynyl-protected Ag98 nanocluster for methanol tolerant oxygen reduction reaction

Chem. Sci., 2024, 15,18161-18169
DOI: 10.1039/D4SC04318A, Edge Article
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Xiaoqin Cui, Xuehuan Zhang, Ting Li, Sheng Zhu, Gaoyi Han, Huan Li
A sterically demanding ortho-CF3 substituent defines not only the arrangement of ligands on a Ag98(2-CF3PhCC)48Cl4 nanocluster (Ag98) but also the inter-cluster interactions. Ag98 shows excellent methanol tolerance in the oxygen reduction reaction.
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cluster

M12L24 nanospheres as supramolecular templates for the controlled synthesis of Ir-nanoclusters and their use in the chemo-selective hydrogenation of nitro styrene

Chem. Sci., 2024, Accepted Manuscript
DOI: 10.1039/D4SC06324D, Edge Article
Open Access
Lotte L. Metz, Rens Ham, Eduard Bobylev, Kelly J. H. Brouwer, Alfons van Blaaderen, Rim van de Poll, Victor Drozhzhin, Emiel J. M. Hensen, Joost N. H. Reek
Controlled preparation of ultrafine metal nanoclusters (<2 nm) is challenging, yet important as the properties of these clusters are inherently linked to their size and local microenvironment. In the present...
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cluster

Analysis of the cryptic biosynthetic gene cluster encoding the RiPP curacozole reveals a phenylalanine-specific peptide hydroxylase

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC02262A, Edge Article
Open Access
Samantha Hollands, Julia Tasch, David J. Simon, Dimah Wassouf, Isobel Barber, Arne Gessner, Andreas Bechthold, David L. Zechel
The noncanonical biosynthesis of curacozole by Streptomyces curacoi is shown to be dependent on the bldA-encoded Leu-tRNAUUA. The minimal biosynthetic gene cluster is defined, and the functions of key biosynthetic enzymes are established in vitro.
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cluster

Cationic Al oxo-hydroxide clusters: syntheses, molecular structures, and functional applications

Chem. Sci., 2024, Advance Article
DOI: 10.1039/D4SC05707D, Perspective
Open Access
Naoki Ogiwara, Wei Zhou, Sayaka Uchida
Al oxo-hydroxide clusters are formed through the hydrolysis of Al3+-containing solutions, exhibiting a diversity of sizes and shapes. The assembly of these clusters demonstrates functional applications, such as adsorption and heterogeneous catalysis.
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cluster

Tirupati universities form cluster to work towards conserving biodiversity

IIT-T, IISER Tirupati, SPMVV and Dravidian University comes together to create campus biodiversity registers as part of APSCHE-IIC research programme




cluster

An electrochemiluminescence microsensor based on DNA-silver nanoclusters amplification for detecting cellular adenosine triphosphate

Anal. Methods, 2024, 16,2019-2024
DOI: 10.1039/D4AY00212A, Paper
GuanQi Wu, Jian Chen, JinXin Dou, XiangWei He, Hai-Fang Li, Jin-Ming Lin
An ECL microsensor integrating RCA magnification and in situ DNA-templated AgNC generation for sensitive detection of cellular ATP.
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cluster

A Multimode Biosensor Based on Prussian Blue Nanoparticle Loaded with Gold Nanoclusters for the Detection of Aflatoxin B1

Anal. Methods, 2024, Accepted Manuscript
DOI: 10.1039/D3AY02330C, Paper
zhaodi Fu, juan Huang, Wei Wei, zhihui Wu, Xingbo Shi
Herein, a novel fluorescent/colorimetric/photothermal biosensor is proposed for aflatoxin B1 (AFB1) detection in food based on Prussian blue nanoparticles (PBNPs) (~50 nm), gold nanocluster (AuNCs) and aptamer (Apt) within three...
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cluster

FM asks RRBs to develop suitable products aligning with MSME clusters

Increase disbursements in ground-level agriculture, focus on asset quality, boost digital and mobile banking service to further enhance financial inclusion: FM to PSU banks, RRBs




cluster

Graphene-supported organoiridium clusters catalyze N-alkylation of amines via hydrogen borrowing reaction

RSC Adv., 2024, 14,35163-35171
DOI: 10.1039/D4RA06595F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Tsun-Ren Chen, Siang-Yu Chiu, Wen-Jen Lee, Yi-Siou Tsai, Yu-Sheng Huang
Graphene-supported organic iridium clusters (GSOIC) exhibit excellent N-alkylation on various substrates under green processes.
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cluster

Stability and magnetic properties of transition metal (V, Cr, Mn, and Fe) doped cobalt oxide clusters: a density functional theory investigation

RSC Adv., 2024, 14,36031-36039
DOI: 10.1039/D4RA05482B, Paper
Open Access
Nguyen Thi Mai, Tran Dang Thanh, Do Hung Manh, Nguyen Thi Ngoc Anh, Ngo Thi Lan, Phung Thi Thu, Nguyen Thanh Tung
Con−1TMOn−2+ (n = 6–8), (TM = V, Cr, Mn, and Fe) clusters are investigated using density functional theory calculations.
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cluster

Solvent-dependent Ln(III) clusters assembled by immobilization of CO2 in the air: zero-field single-molecule magnets and magnetic refrigerant materials

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02310B, Paper
Cai-Ming Liu, Xiang Hao, Zhao-Bo Hu, He-Rui Wen
The automatic fixation of CO2 in the air plays a key role in the construction of Dy(III) single-molecule magnets (SMMs) and Gd(III) magnetic refrigeration molecular materials using Ln(III)Cl3 (Ln =...
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cluster

Coinage metal(I) clusters supported by a 1,10-phenanthroline-phosphine: orange-to-NIR phosphorescence, metallophilic interactions and enhanced cytotoxicity

Dalton Trans., 2024, 53,18027-18036
DOI: 10.1039/D4DT02642J, Paper
Alexander V. Artem'ev, Maria P. Davydova, Lyubov S. Klyushova, Evgeniy H. Sadykov, Mariana I. Rakhmanova, Taisiya S. Sukhikh
Based on 2-(diphenylphosphino)-1,10-phenanthroline, a series of small metal(I) clusters, exhibiting orange to NIR phosphorescence and strong dose-dependent cytotoxicity.
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cluster

Asymmetric triply bridged lanthanide binuclear clusters with distinctly different magnetic behaviors

Dalton Trans., 2024, Accepted Manuscript
DOI: 10.1039/D4DT02652G, Communication
Yue Yang, Yu-Xia Wang, Yu-Zhe Lei, Peng Cheng
Isomorphic binuclear clusters Gd and Dy with antiferromagnetic and ferromagnetic couplings are separately exhibiting single-molecule magnetic behavior and strong magnetocaloric entropy.
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cluster

Coir cluster to be operational in Coimbatore in 2025