An improved biomass feed system and processes for transporting biomass to downstream processing locations are disclosed. The system uses a pressurized gas to assist in the transporting of the biomass to the conversion reactor.

Disclosed is a process for biomass conversion which includes co-processing the biomass with thermoplastic and non-thermoplastic polymer based materials in a catalytic pyrolysis reactor to convert such to liquid hydrocarbons; wherein hydrogen atoms originating with the polymer materials can remove oxygen from oxygenated hydrocarbons produced in the conversion of the biomass in the reactor.

A process for the conversion of biomass to hydrocarbon products such as transportation fuels, kerosene, diesel oil, fuel oil, chemical and refinery plant feeds. The instant process uses a hydrocarbon or synthesis gas co-feed and hot pressurized water to convert the biomass in a manner commonly referred to as hydrothermal liquefaction.

Method of extracting syngas between the zone in a furnace where oxygen-starved combustion of biomass occurs and the zone in the furnace where secondary air is added to complete combustion, conditioning and cleaning the extracted syngas, and delivering it in a metered amount to the oxidizer or upstream of the oxidizer to reduce or eliminate the need for additional fossil fuels once the oxidizer has achieved its operating temperature. The gasifier or furnace burns solid waste and produces a syngas containing relatively high levels of CO, which is extracted from the furnace, conditioned, and introduced into an RTO as a fuel source. In certain embodiments, no extraction of syngas from the furnace takes place; the furnace conditions are manipulated so that normally undesirable levels of CO and other VOC's remain in the process stream. The heat from the furnace is used as intended (e.g., to heat a dryer), the stream is conditioned, and ultimately proceeds to a downstream RTO. Since the gas stream remains rich in CO and VOC's, its fuel value in the RTO is substantially higher than otherwise would be the case.

Methods or preparing para-xylene from biomass by carrying out a Diels-Alder cycloaddition at controlled temperatures and activity ratios. Methods of preparing bio-terephthalic acid and bio-poly(ethylene terephthalate (bio-PET) are also disclosed, as well as products formed from bio-PET.

The present invention provides a resin capable of contributing greatly to solve environmental problems and problems related to exhaustion of fossil fuel resources and having physical properties suited for practical use. The polyester according to the present invention has a diol and a dicarboxylic acid as constituent components and has an amount of terminal acid of 50 equivalents/metric ton or less.

A biomass gasification gas purification system includes a dust collector for removing dust in biomass gasification gas (containing tar components) acquired by gasifying biomass by a biomass gasification furnace, a desulfurizer for removing sulfur oxide components in the dust-removed biomass gasification gas, a pre-reforming reactor for reforming tar components in the desulfurized biomass gasification gas, a steam feed unit for feeding steam to an upstream side of the pre-reforming reactor, and a natural-gas feed unit for feeding natural gas on an upstream side of the desulfurizer.

The present invention relates to methodology and constructs for modifying plant architecture and enhancing plant biomass and/or sucrose yield.

A biomass conveying and distributing system for separating and distributing lighter biomass residue from heavier or denser biomass, utilizing available air flow from the cleaning system of the harvester. The harvester will discharge a flow of heavier or denser biomass with an airborne flow of lighter biomass residue. The system includes a conveyor for receiving and conveying the heavier or denser biomass, and residue distributing apparatus disposed above the conveyor in a path of at least a portion of the airborne flow of lighter residue, including at least one deflector configured and operable for redirecting the airborne flow sidewardly away from the conveyor, above a passage through which the conveyor passes carrying the heavier biomass away from the harvester.

A feed system for a biomass collection device uses a conveyor for dropping a flow comprising a mixture of denser or heavier biomass to be collected such as cobs, and less dense or lighter biomass residue such as leaf trash, through a space, and rotary feed apparatus below for receiving the flow, operable for propelling the received flow into a collection device, in combination with a fan configured and operable for directing a flow of air along a second path intersecting the first path in a manner to divert at least a substantial portion of the less dense or lighter biomass residue away from the feed apparatus, while allowing substantially all of the denser or heavier biomass to continue along the first path to the feed apparatus for feeding into the collection device. Distribution apparatus along the second path can then be used to spread the diverted biomass.

A biomass feed system includes a device to propel an airborne flow of the biomass along a trajectory within a collection device. At least one air flow port is disposed and operable in cooperation with at least one fan for discharging a flow of air for creating a blanket of pressurized air within the interior cavity beneath the trajectory for supporting and extending a distance of travel of the biomass within the collection device. The collection device can include an air flow outlet adjacent to a terminal end of the trajectory, to and through which the pressurized air will flow, in a manner for lifting and carrying at least some of the airborne biomass farther into the interior cavity. And, vanes or other elements can be provided to used to achieve better sideward distribution.

Systems for treating biomass for the production of ethanol are disclosed. The systems are configured to treat a liquid component separated from biomass to yield sugars available to be fermented into a fermentation product. The systems comprise a filter configured to remove particulate matter to provide a filtered component and an apparatus configured to remove inhibitors from the filtered liquid component provide a treated liquid component comprising sugars available for fermentation. Methods for treating for treating biomass useful in the production of a fermentation product are also disclosed. The methods include the steps of filtering a liquid component to remove particulate matter thereby yielding a filtered liquid component, and treating the filtered liquid component to remove inhibitors thereby yielding a treated liquid component comprising sugars available to be fermented into a fermentation product.

An improved rapid thermal conversion process for efficiently converting wood, other biomass materials, and other carbonaceous feedstock (including hydrocarbons) into high yields of valuable liquid product, e.g., bio-oil, on a large scale production, is disclosed. In the process, biomass material, e.g., wood, is fed to a conversion system where the biomass material is mixed with an upward stream of hot heat carriers, e.g., sand, that thermally convert the biomass into a hot vapor stream. The hot vapor stream is rapidly quenched with quench media in one or more condensing chambers located downstream of the conversion system. The rapid quenching condenses the vapor stream into liquid product, which is collected from the condensing chambers as a valuable liquid product.

A pyrolytic conversion assembly for processing biomass including: a rotary kiln including a tube for heating the biomass at pressure having a sealable inlet at a first, higher end for ingress of the biomass, and a sealable outlet at a lower end for egress of charcoal formed from the biomass; and heating elements disposed around the kiln to provide a localized source of heating at a predetermined distance from the sealable inlet for reflux condensation of gas from the biomass.

A biomass pyrolysis process is provided in which biomass feedstock is mixed with a heat carrier. The heat carrier at least partly comprises char. The ratio by weight of biomass to char is in the range 1:1 to 1:20. The process may be carried out by in a screw/auger pyrolysis reactor in which the solid feedstock components are conveyed along the reactor by a first screw. A second screw conveys at least a portion of the solid products of the biomass pyrolysis back to a heat transfer medium input port. Thus, the heat transfer medium includes char from the biomass pyrolysis.

This invention relates to a process for thermochemically transforming biomass or other oxygenated feedstocks into high quality liquid hydrocarbon fuels. In particular, a catalytic hydropyrolysis reactor, containing a deep bed of fluidized catalyst particles is utilized to accept particles of biomass or other oxygenated feedstocks that are significantly smaller than the particles of catalyst in the fluidized bed. The reactor features an insert or other structure disposed within the reactor vessel that inhibits slugging of the bed and thereby minimizes attrition of the catalyst. Within the bed, the biomass feedstock is converted into a vapor-phase product, containing hydrocarbon molecules and other process vapors, and an entrained solid char product, which is separated from the vapor stream after the vapor stream has been exhausted from the top of the reactor. When the product vapor stream is cooled to ambient temperatures, a significant proportion of the hydrocarbons in the product vapor stream can be recovered as a liquid stream of hydrophobic hydrocarbons, with properties consistent with those of gasoline, kerosene, and diesel fuel. Separate streams of gasoline, kerosene, and diesel fuel may also be obtained, either via selective condensation of each type of fuel, or via later distillation of the combined hydrocarbon liquid.

A process and system is disclosed for optimizing a key parameter of a biomass feedstock that enhances bio-oil production. The process and system involves optimizing the values of the key parameter in multiple biomass feedstocks by regulating their feed rates and blending those feedstocks to produce a cumulative biomass feedstock with an optimal value for the key parameter. The key parameter in the biomass feedstocks is measured and the feed rates of the multiple biomass feedstocks are adjusted in order to produce a cumulative biomass feedstock exhibiting optimal values for the desired key parameter. The key parameters can include compositional properties, such as lignin content or mineral content, and/or fluidization properties of the biomass materials, such as density, particle cohesion force, or particle size.

A process and a unit for fluidized bed torrefaction and grinding of particles of a biomass with a largest dimension of 2 cm to 5 cm, and which unit contains an envelope having a general shape of a sector having a) two substantially vertical walls delimiting that sector; and b) at least one inclined wall defining three zones, from bottom to top: a lower zone provided with a fluidization means, and provided with a grinder placed at the bottom of that zone; an intermediate zone (2) provided with a fluidization means; and an upper zone (3) provided with a fluidization means; and a pipe (11) for introducing the particles reaching into the unit to the level of the intermediate zone.

Techniques, systems, apparatus and material are described for generating renewable energy from biomass waste while sequestering carbon. In one aspect, a method performed by a reactor to dissociate raw biomass waste into a renewable source energy or a carbon byproduct or both includes receiving the raw biomass waste that includes carbon, hydrogen and oxygen to be dissociated under an anaerobic reaction. Waste heat is recovered from an external heat source to heat the received raw biomass waste. The heated raw biomass waste is dissociated to produce the renewable fuel, carbon byproduct or both. The dissociating includes compacting the heated raw biomass waste, generating heat from an internal heat source, and applying the generated heat to the compacted biomass waste under pressure.

A method for processing biomass to produce biofuel includes decomposing lignocellulosic material into byproduct polymers that include lignin, decomposing the lignin into targeted chemical fragments, and chemically converting the targeted chemical fragments into a biofuel.

A green process and system are disclosed for utilizing a biomass filter aid in the filtration of a bio-oil. The process comprises filtering a bio-oil containing residual solids from a conversion reaction in the presence of the biomass filter aid to produce a filtered bio-oil. The biomass filter aid facilitates efficient removal of residual solids from the bio-oil. The spent biomass filter aid containing the residual solids may be recycled as a conversion feedstock or used as a combustion heat source in the biomass conversion system.

Techniques, systems, apparatus and material are disclosed for generating renewable energy from biomass waste while sequestering carbon. In one aspect, a method performed by a reactor to dissociate raw biomass waste into a renewable source energy or a carbon byproduct or both includes receiving the raw biomass waste that includes carbon, hydrogen and oxygen to be dissociated under an anaerobic reaction. Waste heat is recovered from an external heat source to heat the received raw biomass waste. The heated raw biomass waste is dissociated to produce the renewable fuel, carbon byproduct or both. The dissociating includes compacting the heated raw biomass waste, generating heat from an internal heat source, and applying the generated heat to the compacted biomass waste under pressure.

Methods, devices and systems for continuously converting biomass are described herein. A device has a feed section for holding a moving bed of biomass, namely wood, having a drying section, a flame zone for degassing, and a, smolder zone for carbonizing the biomass into a solid converted product, namely charcoal. The device includes a tank for collecting the solid converted product arranged below a grate and coupled with the feed section in a gas-tight manner. The system comprising the device, a biogas plant and/or a combined heat and power plant conveys the liquid converted product, namely pyroligneous acid or acetic acid, to the biogas plant and/or the solid converted product, namely charcoal, to the combined heat and power plant.

A process for heat treatment of a solid, with a coolant solid, in which a stage for mixing the solid with the pre-heated coolant solid is carried out, with the coolant solid being a solid hydrocarbon. The solid hydrocarbon is ground, before the mixing stage with the solid, to obtain a solid hydrocarbon powder with a grain size of between 20 μm and 300 μm. The solid is ground, before the mixing stage with the coolant solid, to obtain solid pellets with a thickness of between 1 mm and 30 mm, a width of between 1 mm and 40 mm, and a length of between 1 mm and 100 mm. The mixing is carried out at a temperature of between 80° C. and 700° C.

A process is disclosed for converting biomass to fuels and/or valuable chemicals. The process comprises the steps of a) activating biomass to make it more susceptible to conversion; c) partially converting the biomass to a solubilized material; and d) subjecting the unconverted biomass to a second conversion step. The process optionally comprises a step b) of adding a solvent to the activated biomass. In a preferred embodiment the solubilized biomass obtained in step c) is removed before the unconverted biomass is subjected to step d).

The invention relates to a method for obtaining cellulose by separating lignin from a biomass comprising lignocellulose in the form of plants or plant parts, wherein the biomass comprising lignocellulose is solubilized in a boiler in an alkaline medium comprising alkanol amine, and dissolved lignin is separated from the resulting raw cellulose. Said method is characterized in that the biomass comprising lignocellulose is not from a wood source, and is solubilized at a temperature of less than approximately 170° C. in a solubilizing agent based on alkanol amine and water, wherein the weight ratio of alkanol amine to water is set to 80:20 to 20:80, and raw cellulose thus produced is separated from the waste lye using a typical method. Said method is particularly advantageous for obtaining cellulose from annual plants, particularly wheat straw. The method is advantageously improved in that the solubilization takes place in the presence of a catalyst, particularly of anthrachinon. An advantageous bleaching process may be performed subsequently. Said method is characterized by great economic efficiency, particularly due to the high reclamation rates of the alkanol amine used, and leads to lower environmental impact in wastewater, and to reduced disposal costs. The design of the method leads to a greater yield of cellulose and largely prevents degradation of alkanol amine, particularly monoethanol amine (MEA).

Method for production of cellulose and hemicellulose fibers from lignocellulose biomass obtained from sugarcane leaves and buds by applying a process comprising the stages of: a) Diminishing the particle size of the lignocellulose biomass to a range between 3 and 15 mm, b) Subjecting the product obtained to treatment with one or more solvents and/or a mixture of specific catalysts, c) Carry out sudden decompression to an atmospheric pressure, d) Collecting the pretreated material in a cyclone, e) Optionally separating the liquid and solid fractions through washing and filterung f) Optionally, treating the solid fraction in a reactor with a mixture of ethanol and chlorine dioxide, d) Wash the product obtained to achieve cellulose efficiency above 50% and of lignin of 5 to 7%, fiber lengtht in a range to 1,5 to 2,7 mm, breaking length (km) of 7,0 -8,9, Burst index (kPam2/g) of 4,5-7,2 and Tear index (mNm2/g) of 8,2-8, The obtained high-resistance cellulose and hemicellulose is especially suitable for the paper production and polymer-type plastics.

Biomass (e.g., plant biomass, animal biomass, and municipal waste biomass) is processed to produce useful products, such as fuels. For example, systems are described that can use feedstock materials, such as cellulosic and/or lignocellulosic materials, to produce ethanol and/or butanol, e.g., by fermentation.

Provided herein are systems and methods for biomass digestion and products formed thereof. The products include one or more biogases, U.S. Environmental Protection Agency classified Class A Biosolids, and pathogen reduced organic liquid fertilizer. Through the digestion of waste materials using sequential phases in an efficient digestion process, enhanced biomass conversion efficiency and improved output of products (in quantity and/or quality) are obtained with a significant reduction in dwell time in each phase.

A method for treating a synthesis gas from a gasification step. The synthesis gas is cooled to condense heavy organic impurities and water. At the end of the cooling step, light organic impurities and inorganic impurities are adsorped by at least one adsorption bed. The water and heavy tars are separated by decantation from the step of cooling the synthesis gas. At least one adsorption bed is regenerated by temperature-modulated or pressure-modulated desorption.

A harvesting system and method providing a row insensitive plant cutting and gathering capability, suitable for harvesting tall, stalky plants such as sweet sorghum, cane, and the like, in high volume, which also billet cuts the harvested plants. Multiple plants are cut simultaneously on a continuous basis at any locations across a header of the system, and the cut plants are gathered into a continuous overlapping flow having a vertical extent or thickness of several stalks or canes and their associated foliage. The flow is then vertically compacted into a mat of reduced thickness while being conveyed into a billet cutter, which cuts the stalks or canes into billets of a desired length and discharges the billets to a desired location, all while the harvester is moving through a field harvesting. The system can be incorporated into a conventional sugarcane harvester in place of conventional base cutters and row dividers.

An apparatus for forming a water storage material from a biomass input material using supercritical or subcritical fluid processing, the water storage material capable of absorbing a liquid and releasing the liquid. The apparatus utilizes supercritical fluid processing, subcritical fluid processing, charring, or a combination thereof. The apparatus includes a controller configured to control the apparatus. The apparatus further including a processing station configured to hold the biomass input material, and to use the biomass input material for processing into the water storage material.

Described herein are systems and methods for achieving fast pyrolysis of wood and other carbonaceous solids in rotary reactors. Novel heating, feeding and condensing methods result in high oil yields near those currently achieved with more complicated fast pyrolysis systems. High intensity burners are arranged and controlled to produce high heating rates and uniform temperature of the rotating cylindrical walls of the reactors. The feeding system delays the onset of pyrolysis until the solids fall onto the heated kiln walls. The pyrolysis gases and vapors are rapidly withdrawn and quenched with recycled liquids. The first condenser incorporates a clean out nozzle. Char products are readily separated and discharged into a heat exchanger where heat is recovered and used together with heat from reactor flue gas to dry the solids prior to being fed to the reactor.

A method for producing synthetic gas from biomass by: a) grinding the biomass, feeding the biomass into a pyrolysis furnace while spraying a first superheated water vapor into the pyrolysis furnace, controlling the temperature of the pyrolysis furnace at 500-800° C., contacting the biomass with the first superheated water vapor for a pyrolysis reaction to yield crude synthetic gas and ash including coke; b) cooling the ash, and separating the coke from the ash; c) transporting the crude synthetic gas and the coke into a gasifier, spraying a second superheated water vapor into the gasifier, controlling the gasifier at an operating temperature of 1200-1600° C., contacting the biomass with the second superheated water vapor for a gasification reaction to yield primary synthetic gas; and d) cooling, removing dust, deacidifying, and desiccating the primary synthetic gas to obtain clean synthetic gas.

The disclosed embodiments provide systems for the removal and use of tar from a biomass gasification system. For example, in one embodiment, a biomass gasification system includes a reactor configured to gasify a biomass fuel in the presence of air to generate a producer gas. The system also includes an absorber configured to receive a mixture of the producer gas and tar and to absorb the tar into an organic solvent to produce treated producer gas and a rich solvent mixture containing at least a portion of the tar. The system further includes a recycle line configured to direct the rich solvent mixture to a biomass gasifier.

Embodiments presented herein describe an apparatus and method to control the conversion of carbonaceous materials, particularly biomass and those biomass resources, into a high performance solid fuel. This method, and the apparatus described as the means to accomplish this method, provides a process having a control system that enables the system to produce a fuel of uniform quality, even with a change in biomass supply.

A two-stage reactor is disclosed for the conversion of solid particulate biomass material. The reactor is designed to maximize conversion of the solid biomass material, while limiting excess cracking of primary reaction products. The two-stage reactor comprises a first stage reactor, in which solid biomass material is thermally pyrolyzed to primary reaction products. The primary reaction products are catalytically converted in a second stage reactor.

A process is provided comprising subjecting a quantity of plant biomass fibers to a pretreatment to cause at least a portion of lignin contained within each fiber to move to an outer surface of said fiber, wherein a quantity of pretreated tacky plant biomass fibers is produced; and densifying the quantity of pretreated tacky plant biomass fibers to produce one or more densified biomass particulates, wherein said biomass fibers are densified without using added binder.

23 February 2017

Although most renewable energy policy frameworks treat biomass as carbon-neutral at the point of combustion, biomass emits more carbon per unit of energy than most fossil fuels. 

Two big trends are converging in the world of power generation -- Combined Heat & Power (CHP) and biomass. CHP is gaining ground in many areas of the world due to the fact that its superior efficiency often results in major economic gains (CHP takes the waste heat from a turbine and uses it to generate steam which is often uses in district heating, or in industrial processes).

U.K. electricity from low-carbon sources accounted for almost a quarter of the country’s generation in the fourth quarter as Drax Group Plc converted a second coal-power plant to burn wood.

A Louisiana lumber town has become the crossroads for an unusual buyer and seller in the U.S. municipal market: private-equity firm KKR & Co. and the world’s biggest manufacturer of wood pellets.

AlgaEnergy SA, part-owned by Spain’s Iberdrola SA and Repsol SA, is in talks with potential partners to set up a plant in Mexico to supply the American markets with biomass made from algae.

Drax Group Plc, Dong Energy A/S and SSE Plc will get guaranteed power prices for U.K. biomass and offshore wind plants, the first renewable energy projects to benefit from a new aid program.

Billionaire Rubens Ometto’s Cosan SA has the potential to triple its power generation by burning sugar-cane leftovers if the government offers power-purchase contracts for biomass producers.