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Fine-tuning of the substrate binding mode to enhance the catalytic efficiency of an ortho-haloacetophenone-specific carbonyl reductase

Catal. Sci. Technol., 2020, 10,2462-2472
DOI: 10.1039/C9CY02335F, Paper
Aipeng Li, Xue Li, Wei Pang, Qing Tian, Ting Wang, Lianbing Zhang
Fine-tuning of the substrate binding mode was successfully applied for enhancing the catalytic efficiency of an ortho-haloacetophenone-specific carbonyl reductase.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Path of electron transfer created in S-doped NH2-UiO-66 bridged ZnIn2S4/MoS2 nanosheet heterostructure for boosting photocatalytic hydrogen evolution

Catal. Sci. Technol., 2020, 10,2531-2539
DOI: 10.1039/D0CY00127A, Paper
Qi Ran, Zebin Yu, Ronghua Jiang, Lun Qian, Yanping Hou, Fei Yang, Fengyuan Li, Mingjie Li, Qianqian Sun, Heqing Zhang
This work introduces the synthesis of ZnIn2S4/NH2-UiO-66/MoS2 sheet heterostructure photocatalysts and their application to photocatalytic hydrogen evolution.
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Mechanism of selective and complete oxidation in La2O3-catalyzed oxidative coupling of methane

Catal. Sci. Technol., 2020, 10,2602-2614
DOI: 10.1039/D0CY00141D, Paper
Shibin Wang, Shenggang Li, David A. Dixon
The catalytic mechanism and reaction network of oxidative coupling of methane over La2O3 are thoroughly investigated by density functional theory calculations.
The content of this RSS Feed (c) The Royal Society of Chemistry




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980 nm NIR light driven overall water splitting over a combined CdS–RGO–NaYF4–Yb3+/Er3+ photocatalyst

Catal. Sci. Technol., 2020, 10,2389-2397
DOI: 10.1039/D0CY00256A, Paper
Wei Gao, Yuqi Wu, Gongxuan Lu
Infrared light (NIR) accounts for more than 50% of the energy donated by the Sun to the Earth, but most of this type of energy is not utilized in photocatalytic reactions.
The content of this RSS Feed (c) The Royal Society of Chemistry




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New findings and current controversies in the reaction of ruthenium red and ammonium cerium(IV) nitrate: focus on the precipitated compound

Catal. Sci. Technol., 2020, 10,2491-2502
DOI: 10.1039/C9CY02499A, Paper
Bahram Sarvi, Seyedeh Maedeh Hosseini, Bahareh Deljoo, Abdelhamid El-Sawy, Alireza Shirazi Amin, Mark Aindow, Steven L. Suib, Mohammad Mahdi Najafpour
During water-oxidation reaction in the presence of RuR and CAN, a heterogeneous nano-sized Ru-Ce compound is detected, which is formed by the interaction of [(NH3)5RuORu(NH3)4ORu(NH3)5],6+/7+ nitrate ions, and the products of the reduction of CAN.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Effects of Ni loading on the physicochemical properties of NiOx/CeO2 catalysts and catalytic activity for NO reduction by CO

Catal. Sci. Technol., 2020, 10,2359-2368
DOI: 10.1039/C9CY02619C, Paper
Shuhao Zhang, Jaeha Lee, Do Heui Kim, Taejin Kim
The NO reduction by CO reaction was investigated using NiOx/CeO2 catalysts with different Ni loadings. Surface NiOx controls the catalytic activity which was related to the molecular structure and reducibility of the catalysts.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Kinetic study of the methane dry (CO2) reforming reaction over the Ce0.70La0.20Ni0.10O2−δ catalyst

Catal. Sci. Technol., 2020, 10,2652-2662
DOI: 10.1039/C9CY02192B, Paper
Lidia Pino, Cristina Italiano, Massimo Laganà, Antonio Vita, Vincenzo Recupero
The kinetic behaviour of the Ce0.70La0.20Ni0.10O2−δ catalyst during the methane dry reforming reaction was investigated in a fixed bed reactor in the temperature range of 923–1023 K with the partial pressure of CH4 and CO2 ranging between 5 and 50 kPa.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Gold-catalyzed domino cyclization enabling construction of diverse fused azaspiro tetracyclic scaffolds: a cascade catalysis mechanism due to a substrate and counterion

Catal. Sci. Technol., 2020, 10,2415-2426
DOI: 10.1039/D0CY00120A, Paper
Yunhe Li, Xiang Zhao
The detailed mechanism and origins of gold-catalyzed domino cyclization to diverse fused azaspiro tetracyclic scaffolds by cooperative dual catalysis and cascade catalysis are systematically studied.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Enhanced and selective photocatalytic reduction of CO2 by H2O over strategically doped Fe and Cr into porous boron carbon nitride

Catal. Sci. Technol., 2020, 10,2663-2680
DOI: 10.1039/D0CY00343C, Paper
Niwesh Ojha, Abhinav Bajpai, Sushant Kumar
Strategic doping of metals and non-metals into a photocatalyst can help in tuning the band gap and alignment of band structure.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Adjustable anchoring of Ni/Co cations by oxygen-containing functional groups on functionalized graphite paper and accelerated mass/electron transfer for overall water splitting

Catal. Sci. Technol., 2020, 10,2627-2643
DOI: 10.1039/D0CY00181C, Paper
Yiyi Huang, Lei Sun, Zebin Yu, Ronghua Jiang, Jun Huang, Yanping Hou, Fei Yang, Boge Zhang, Runzhi Zhang, Yalan Zhang
NCS–NCO/FGP0.44 with a cellular network of porous nanosheets and close-contact heterointerface reveals accelerated interfacial mass/electron transportation for overall water splitting.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Mechanistic insights into photocatalysis and over two days of stable H2 generation in electrocatalysis by a molecular cobalt catalyst immobilized on TiO2

Catal. Sci. Technol., 2020, 10,2549-2560
DOI: 10.1039/D0CY00330A, Paper
Open Access
Nicola Weder, Benjamin Probst, Laurent Sévery, Ricardo J. Fernández-Terán, Jan Beckord, Olivier Blacque, S. David Tilley, Peter Hamm, Jürg Osterwalder, Roger Alberto
Molecular and heterogeneous water reduction combined: Over 2 days of electrocatalysis of a cobalt polypyridyl catalyst immobilized on TiO2.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Enhanced oxygen evolution catalysis by aluminium-doped cobalt phosphide through in situ surface area increase

Catal. Sci. Technol., 2020, 10,2398-2406
DOI: 10.1039/D0CY00123F, Paper
Timothy E. Rosser, Juliana P. S. Sousa, Yasmine Ziouani, Oleksandr Bondarchuk, Dmitri Y. Petrovykh, Xian-Kui Wei, Jo J. L. Humphrey, Marc Heggen, Yury V. Kolen'ko, Andrew J. Wain
Al-doping of cobalt phosphide oxygen evolution catalysts results in enhanced performance which, based on in situ and operando analysis, is shown to result from a surface area increase associated with modified oxidation behaviour.
The content of this RSS Feed (c) The Royal Society of Chemistry




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Enhancing hydrogen evolution reaction through modulating electronic structure of self-supported NiFe LDH

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00315H, Paper
Xiao-Peng Li, Wen-Kai Han, Kang Xiao, Ting Ouyang, Nan Li, Feng Peng, Zhao-Qing Liu
NiFe-layered double hydroxide (NiFe LDH), as an efficient oxygen evolution reaction (OER) electrocatalyst, has emerged as a promising electrocatalyst for catalyzing overall water splitting in alkaline electrolyte.
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Mechanistic insights into the oxidation of copper(I) species during NH3–SCR over Cu-CHA zeolites: A DFT study

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00379D, Paper
Chong Liu, Hiroe Kubota, Takashi Toyao, Zen Maeno, Ken-ichi Shimizu
Selective catalytic reduction of nitrogen oxides using ammonia (NH3–SCR) over Cu-exchanged zeolites proceeds via reduction of Cu(II) to Cu(I) and subsequent reoxidation of Cu(I) to Cu(II). Although the mechanism of...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Selenium-catalyzed oxidation of alkenes: insight into the mechanisms and developing trend

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00400F, Perspective
Hongen Cao, Rongrong Qian, Lei Yu
Recent progresses of the selenium-catalyzed oxidation of alkenes are summarized at the mechanism level. It may be beneficial for designing novel selenium-containing catalysts and alkene oxidation protocols for the next phase of studies.
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Heterogeneous iron-containing nanocatalysts – promising systems for selective hydrogenation and hydrogenolysis

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00086H, Minireview
Anastasiya A. Shesterkina, Leonid M. Kustov, Anna A. Strekalova, Vladimir B. Kazansky
Bimetallic catalytic systems Fe–Me (Pt, Pd, Cu) demonstrate synergy in the activity/selectivity pattern in reactions involving hydrogen: selective hydrogenation of CC bonds, NO2 and carbonyl groups and hydrogenolysis of C–O bonds.
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Insights into isothiourea-catalyzed asymmetric [3 + 3] annulation of α,β-unsaturated aryl esters with 2-acylbenzazoles:Mechani-sm, origin of stereoselectivity and switchable chemoselectivity

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00295J, Paper
Congcong Wang, Shi-Jun Li, Qiao-Chu Zhang, Donghui Wei, Lina Ding
Recently, isothiourea-catalyzed asymmetric [3 + 3] annulation reactions of α,β-unsaturated aryl esters with 2-acylbenzothiazole (or 2-acylbenzoxazole) were reported with switchable chemoselectivity to form either dihydropyridone or dihydropyrone, but predicting the...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Regulation of rutile/anatase TiO2 heterophase interface by Ni12P5 to improve photocatalytic hydrogen evolution

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00634C, Paper
Qiu Chengwei, Jinjin Lin, Jinni Shen, Dan Liu, Zizhong Zhang, Huaxiang Lin, Xuxu wang
Anatase/rutile TiO2 heterophase junction composite has been documented to have much higher photocatalytic activity than single phase TiO2 (nude anatase or nude rutile) for various chemical reactions including the hydrogen...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Photocatalytic hydrogen evolution over nickel cobalt bimetallic phosphate anchored graphitic carbon nitrides by regulation of d-band electronic structure

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00556H, Paper
Yuanzheng Zhang, Yunrong Dai, Lifeng Yin, Huihui Li, Xiang Chen, Bin Chen
Non-precious metal co-catalysts with high activity and stability are extremely desirable for economically viable photocatalytic molecular hydrogen (H2) evolution. Herein, nickel cobalt phosphate (NiCo-Pi) was introduced into graphitic carbon nitride...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Pt-Ligand single-atom catalysts: tuning activity by oxide support defect density

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/C9CY02594D, Paper
Xuemei Zhou, Linxiao Chen, George E. Sterbinsky, Debangshu Mukherjee, Raymond R. Unocic, Steven L. Tait
Metal–ligand coordination stabilizes single atom Pt on pristine and defective TiO2 supports to impact local coordination and catalytic hydrosilylation activity.
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The content of this RSS Feed (c) The Royal Society of Chemistry




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Surface reconstruction and effect of Ni-modification in the selective hydrogenation of 1,3-butadiene over Mo2C-based catalysts

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00402B, Paper
Qiuchen Yang, Rui Qiu, Xixi Ma, Ruijun Hou, Kening Sun
In the current study, Mo2C, NiMo2C, H-Mo2C and H-NiMo2C were synthesized to understand the effects of Ni modification and synthesis route. The catalysts were characterized by XRD, N2-physisorption, SEM, TEM,...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Effective N-methylation of nitroarenes with methanol catalyzed by a functionalized NHC-based iridium catalyst: a green approach to N-methyl amines

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00707B, Paper
Miguel González-Lainez, M. Victoria Jiménez, Vincenzo Passarelli, Jesús J. Pérez-Torrente
Compound [IrBr(CO)2(κC-tBuImCH2PyCH2OMe)] featuring a flexible pyridine/OMe functionalized NHC ligand κ1C coordinated efficiently catalyzes the selective N-monomethylation of nitroarenes using methanol as both the reducing agent and the C1 source. A...
The content of this RSS Feed (c) The Royal Society of Chemistry




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CO activation and methanation mechanism on hexagonal close-packed Co catalysts: effect of functionals, carbon deposition and surface structure

Catal. Sci. Technol., 2020, Advance Article
DOI: 10.1039/D0CY00499E, Paper
Hai-Yan Su, Changlin Yu, Jin-Xun Liu, Yonghui Zhao, Xiufang Ma, Jie Luo, Chenghua Sun, Wei-Xue Li, Keju Sun
Regardless of the functionals used and the presence of graphitic carbon, the CO methanation rate on Co(0001) is mainly controlled by CHO decomposition.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Bifunctional rhenium-copper nanostructures for intensified and stable ethanol synthesis via hydrogenation of dimethyl oxalate

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00579G, Communication
Zhongnan Du, Meng Chen, Xuepeng Wang, Xingkun Chen, Xiaolin Mou, Yuan Tan, Wenshao Yang, Chuanqi Huang, Hejun Zhu, Ronghe Lin, Yunjie Ding
Decorating small copper nanoparticles with isolated and/or clusted oxophilic rhenium species enables the first low-copper catalytic technology for intensified and stable ethanol production under mild conditions in dimethyl oxalate hydrogenation....
The content of this RSS Feed (c) The Royal Society of Chemistry




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Synthesis of vinyl chloride monomer by acetylene hydrochlorination with a ruthenium-based N-heterocyclic carbene complex catalyst

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00512F, Paper
Ming Cai, Haiyang Zhang, Baochang Man, Jian Li, Linfeng Li, Yanqin Li, Dongyang Xie, Renpan Deng, Jinli Zhang
With the implementation of Minamata Convention and the urgent demand for green, and efficient mercury-free catalysts, the carbon-supported IPr-(Ru)/AC catalyst was synthesized and assessed for its successful application in acetylene...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Homogeneous vs. Heterogeneous: Mechanistic Insights into Iron Group Metal-Catalyzed Reductions from Poisoning Experiments

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00644K, Minireview
Axel Jacobi von Wangelin, Sebastian Sandl, Dominik Gärtner
Iron group metal catalysts constitute a promising alternative to well-established noble metal catalysts in reduction reactions. However, the development of effective 3d metal catalysts has largely been hampered by their...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Heterogenization for polyoxometalates as solid catalysts in aerobic oxidation of glycerol

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00403K, Paper
Meilin Tao, yue li, Yiming Li, Xueyan Zhang, Yurii Geletii, Xiaohong Wang, Craig L Hill
A series of heterogeneous catalysts based on phosphomolybdic salts with different Lewis metals in counter or substituent places LnPMo12O40 (L = Al3+, Fe3+, Cr3+, Ti4+, Zr4+ and Zn2+, abbreviated as...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Phosphine-catalyzed [3 + 2] annulation of 2-aminoacrylates with allenoates and mechanistic studies

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00092B, Paper
Xiao-Yun Wu, Hou-Ze Gui, Harish Jangra, Yin Wei, Min Shi, Hendrik Zipse
A convenient and efficient strategy for the synthesis of 3-pyrrolines containing an amino quaternary stereogenic center via phosphine-catalyzed formal [3 + 2] annulation of allenoates with 2-aminoacrylates is disclosed. A...
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Influence of gold on the reactivity behaviour of ceria nanorods in CO oxidation: Combining operando spectroscopies and DFT calculations

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00392A, Paper
Marc Ziemba, Christian Hess
Au/CeO2 catalysts are commonly used for low-temperature CO oxidation. While many studies focus on the properties of gold and their relevance for the activity, the influence of the support properties...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Hierarchical Z-scheme 1D/2D architecture with TiO2 nanowires decorated by MnO2 nanosheets for efficient adsorption and full spectrum photocatalytic degradation of organic pollutants

Catal. Sci. Technol., 2020, Accepted Manuscript
DOI: 10.1039/D0CY00419G, Paper
Jiejing Zhang, Yajie Hu, Hong Zheng, Pengyi Zhang
Constructing composite photocatalysts with efficient photocatalytic activity, wide optical response range and excellent stability has great significance for the removal of organic pollutants in water. Herein, we report a novel...
The content of this RSS Feed (c) The Royal Society of Chemistry




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Puranik Builders re-files IPO papers, plans to raise Rs 1k-cr to pare debt

Edelweiss Financial Services Ltd and Axis Capital will manage the company's initial share-sale. Shares of the company will be listed on the BSE and NSE.




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From Byju's to Swiggy: Next wave of tech unicorn listings could be in India

Mohandas Pai expects food delivery platforms Swiggy and Zomato, as well as PhonePe and Myntra to list in local markets in next few years




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Planning to apply for SBI Cards IPO? Check out the eligibility criteria

Normally, IPOs are open for subscription for three days but SBI Cards IPO will run for four days. The first three days, i.e. from March 2 to March 4, the issue will be open for all bidders




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The American way: those above and those below / written by John Ridley ; pencils by Georges Jeanty ; inks by John Livesay [and 3 others] ; colors by Nick Filardi ; letters by Travis Lanham

Hayden Library - PN6728.A496 R54 2018




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Batman/The Shadow: the murder geniuses / story by Scott Snyder and Steve Orlando ; script by Steve Orlando ; art by Riley Rossmo ; colors by Ivan Plascencia ; letters by Clem Robins ; cover art and original series covers by Riley Rossmo

Barker Library - PN6728.B36 S674 2017




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Sara / Garth Ennis, writer; Steve Epting, art; Elizabeth Breitweiser, color art

Barker Library - PN6728.S27 2018




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Good night paradise / Joshua Dysart, writer ; Alberto Ponticelli, art ; Giulia Brusco, color art

Barker Library - PN6728.G653 2018




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Woman world / Aminder Dhaliwal ; color by Nikolas Ilic

Barker Library - PN6733.D35 W66 2018




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Comics and sacred texts: reimagining religion & graphic narratives / edited by Assaf Gamzou, Ken Koltun-Fromm

Dewey Library - PN6712.C53 2018




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Women's manga in Asia and beyond: uniting different cultures and identities / Fusami Ogi, Rebecca Suter, Kazumi Nagaike, John A. Lent, editors

Rotch Library - PN6714.W664 2019




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Flocks / L. Nichols

Barker Library - PN6727.N488 Z46 2018




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Black Panther. writer[s], Nnedi Okorafor, Aaron Covington ; artists, André Lima Araújo, Mario del Pennino ; color artist[s], Chris O'Halloran, Ian Herring, Irma Knivila ; penciler, Tana Ford ; inkers, Tana Ford, Terry Pallot, Scott Hanna ;

Barker Library - PN6728.B53 L66 2018




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Ricanstruction: reminiscing & rebuilding Puerto Rico / publisher, executive producer, editor, title design, book design, writer, Edgardo Miranda-Rodriguez ; cover artists Tony Daniel, Danny Miki, Tomeu Morey ; inside cover artist Nicole Virella ; back

Barker Library - PN6726.R53 2018




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Frankenstein: Junji Ito story collection / story & art by Junji Ito ; translation, Jocelyn Allen ; English adaptation, Nick Mamatas ; other stories translation & adaptation, Jocelyn Allen ; touch-up art & lettering, James Dashiell ; cover &

Barker Library - PN6790.J33 I73413 2018




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Doctor Who, the Thirteenth Doctor / writer, Richard Dinnick ; letterers, Comicraft's Sarah Jacobs and John Roshell ; artists, Mariano Laclaustra [and eight others] ; inker, Fer Centurion ; colorists, Color-Ica [and four others]

Barker Library - PN6728.D6445 D56 2018




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Wakanda forever / writers, Nnedi Okorafor, Priest, Don McGregor & Reginald Hudlin ; artists, Alberto Alburquerque, Oleg Okunev, Mike Perkins, Daniel Acuna & Ken Lashley ; inkers, Ray-Anthony Height, Alberto Alburquerque, Juan Vlasco & Keith C

Barker Library - PN6728.W255 O36 2018




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Doctor Who. writers, James Peaty, Jody Houser ; artists, Iolanda Zanfardino, Pasquale Qualano, Brian Williamson [and 1 other] ; colorists, Dijjo Lima, Enrica Eren Angiolini ; letterers, Richard Starkings and Comicraft's Jimmy Betancourt

Barker Library - PN6728.D644 P43 2019




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The fearsome Doctor Fang / Tze Chun, Mike Weiss, Dan McDaid, Daniela Miwa

Barker Library - PN6728.F437 C48 2018




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Mister Miracle / Tom King, writer ; Mitch Gerads, artist and colorist ; Clayton Cowles, letterer ; Mitch Gerads, collection cover art ; Nick Derington, original series cover art

Barker Library - PN6728.M53 K56 2019




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Sabrina / by Nick Drnaso

Barker Library - PN6727.D75 S23 2018